Vapor Pressure Research Articles

Effects of water table depth variations on canopy transpiration from Mongolian pine plantations in arid ecosystems

Groundwater is a critical moisture source for the growth and survival of dryland forests. Spatiotemporal variations in water table depth (WTD) affect soil water availability in the root zone, which influences canopy transpiration (Ec). However, to date, relatively few studies have been conducted on how changes in WTD regulate Ec. We measured the meteorological variables, volumetric water content (VWC), sap flow, and WTD in 2022 and 2023 from April to October in three Mongolian pine plantations located in Mu Us Sandy Land, China. The initial WTDs were 4 m (WTD4), 9 m (WTD9), and 13 m (WTD13), respectively. The mean VWC did not differ significantly between WTD4, WTD9, and WTD13 in the 0–50 cm layer. However, there was a significant decrease in the mean VWC with increasing WTD in the 50–200 cm layer (p < 0.05). Ec decreased significantly with increasing WTD (p < 0.01), with mean daily Ec of 1.25, 0.75, and 0.28 mm day−1 for WTD4, WTD9, and WTD13, respectively. Under soil drought conditions, Ec decreased significantly at WTD9 and WTD4 (p < 0.05). Meanwhile, Ec at WTD13 did not vary significantly under the different soil moisture conditions. At WTD9 and WTD13, Ec was mainly influenced by VWC. Meanwhile, at WTD4, Ec was influenced by the vapor pressure deficit and solar radiation. The diameter at breast height and leaf area index at WTD13 were significantly lower than those at WTD9 and WTD4 (p < 0.05). Although Mongolian pine could alleviate soil drought by adjusting Ec through morphological and physiological adaptations, it still suffered from the adverse effects of reduced water availability at deep WTD sites. This study establishes a basis for predicting the response of forests in semi-arid areas to changes in WTD. It contributes to the optimization of silvicultural design in similar areas and reduces ecological risks from the over-exploitation of groundwater.

Evaluation of Machine Learning Application on the Prediction of Particulate Matter Concentrations in Small/Medium-Sized City

Objectives:In this study, Machine Learning (ML) algorithms were evaluated to predict the concentration of particulate matter (PM10 and PM2.5) using air quality and meteorological data in small/medium-sized city.Methods:ML models, including Multiple Linear Regression (MLR), Decision Tree Regression (DTR), Random Forest (RF), Extreme Gradient Boosting (XGB), Light Gradient Boosting Machine (LGB), were used to predict PM10 and PM2.5 concentrations. Five air quality variables, including NO2, SO2, CO, PM10 and PM2.5, and seven meteorological variables, including temperature, humidity, vapor pressure, wind speed, precipitation, local atmospheric pressure, and sea-level atmosphere pressure, were collected from three air quality monitoring stations and one meteorological observatory from 2017 to 2022. A total of 52,583 sets of data were used for ML. The prediction accuracies of the applied ML models were evaluated using the Root Mean Squared Error (RMSE), Mean Absolute Error (MAE), and Coefficient of determination (R2).Results and Discussion:Higher ML performance was obtained when using the data including PM10 and PM2.5 compared to the data excluding these variables. Among five different ML models, the XGB model showed the highest accuracy in predicting PM10 and PM2.5 one hour in the future. However, poorer performance was obtained as the predicted period increased from one hour to 72 hours.Conclusion:The application of ML algorithms for the short-term prediction of PM10 and PM2.5 was successful in this study. However, more input variables and deep learning algorithms are needed for long-term prediction of PM10 and PM2.5.

Low‐temperature bubble formation in silica glass

AbstractPhase separation was observed in silica glass following low‐temperature heat treatment in high water vapor pressure through the formation of bubbles. Although the 6 day diffusion treatment in saturated water vapor pressure at 250°C does not normally cause phase separation, the reactive fracture surface and subsurface damage caused by polishing with cerium oxide (CeO2) allowed for an increase in water absorption during treatment and heterogeneous nucleation of the bubbles at damaged sites. The sub‐surface damage, characteristic of blunt contact damage, was only revealed when the polished sample was etched. The formation of bubbles and polishing damage were observed in two silica glasses—one containing chlorine impurities and the other containing OH impurities. Raman spectra collected after fracture or polishing and water diffusion treatment demonstrated an increase in the abundance of –OH species including silanol (SiOH) groups and an evolution in the glass structure in the bubble regions compared with the bubble‐free regions. These results indicate an increase in the reactivity between water and glass fracture surfaces relative to the bulk.

Simulation study on the cavitation flow characteristics of liquid ammonia in the nozzle under high-pressure injection conditions

In this study, a non-isothermal compressible cavitating flow simulation model for liquid ammonia in high-pressure injector, accounting for the phase change properties, was established. The model was validated using experimental data from existing literature. The cavitation phase change process of liquid ammonia within the injector nozzle was investigated, and the differences in cavitation distribution between ammonia and diesel were explored. The results indicate that with increasing injection pressure, the vapor volume fraction of ammonia increases linearly, while that of diesel fuel shows a rapid initial rise followed by a decelerating trend. In terms of flow coefficient, ammonia is lower than diesel, though the two values converge at higher injection pressures. Under low injection pressure, the heat absorbed by the cavitation phase change of ammonia exceeded the heat generated by the high-speed friction of ammonia flow against the nozzle wall, leading to a temperature drop at the nozzle inlet. Conversely, at high injection pressure, the temperature of ammonia on the nozzle wall increases by more than 20 K, resulting in a rapid rise in saturated vapor pressure and significantly intensifying the cavitation effect. Compared to ammonia, diesel experienced a higher temperature rise within the nozzle but exhibited smaller variations in saturated vapor pressure, making the temperature effect on cavitation less pronounced. Diesel’s higher density and viscosity resulted in lower flow velocities compared to ammonia, leading to more developed cavitation in the lower wall region of the nozzle and creating a higher pressure region on the upper wall of the nozzle, which was more distant from the nozzle inlet and inhibited cavitation development there. The research results provide theoretical support for the design of liquid ammonia injectors.

Synthesis and Characterization of Calcium Sulfoaluminate Hydrates—Ettringite (AFt) and Monosulfate (AFm)

The goal of the presented work was to find the most favorable conditions for the synthesis and stabilization of chemically pure ettringite and monosulfate. The reaction was carried out by mixing pure tricalcium aluminate (C3A) and gypsum (CS¯H2) in an excess amount of water. The impact of hydration time (2–7 days), C3A:CS¯ molar ratio (1:1–1:3) and water vapor pressure of the selected drying agents (anhydrite-III and supersaturated CaCl2 solution) on the phase composition of the products was evaluated. After 7 days of hydration, either ettringite or monosulfate was obtained as the main product, depending on the C3A:CS¯ molar ratio. The synthesis carried out at a C3A:CS¯ molar ratio of 1:3 produced pure ettringite. In the case of the sample characterized by the ratio of 1:1 (typical of monosulfate), a considerable portion of ettringite (27.9%) was present in the final products along the AFm phase. Therefore, a different synthesis method has to be selected in order to obtain pure monosulfate. The results showed that thermal analysis, X-ray diffractometry and FTIR spectroscopy can be used to distinguish the characteristic features of ettringite and monosulfate.

A molecular study of CO2 adsorption performance of functionalized Mg-MOF-74 at different water vapor concentrations and pressures

This study numerically evaluates the CO2 adsorption capability of functionalized Mg-MOF-74 at different water vapor concentrations and pressures. The −O-Li- and –NO2 display the most advantageous adsorption locations for CO2 and enhance the adsorption energy for H2O within the secondary building unit region. The enhancement of CO2 adsorption at 1 bar is achieved through the incorporation of Li-O and –NO2, whereas introducing –CH3 improves the selectivity of Mg-MOF-74 towards CO2/H2O. The absorption of CO2 at 10 bar is influenced by the available void space within the pores and altering the functional groups leads to a reduced porosity, thereby hindering the CO2 adsorption. However, –CH3 can effectively improve the CO2/H2O selectivity. The increased CO2 adsorption sites by the functionalization is more advantageous for enhancing CO2 adsorption capacity in gas/vapor mixtures at low pressures. Furthermore, enhancing absorbent hydrophobicity results in an enhanced selectivity for CO2/H2O, thereby facilitating CO2 adsorption at elevated pressures.

Impacts of High Temperature and Vapor Pressure Deficit on the Maize Opened Spikelet Ratio and Pollen Viability

High temperatures (HTs) and high vapor pressure deficits (VPDs) have significant impacts on maize yields, partly due to the high sensitivity of maize tassels. However, there are few studies quantifying the impacts of HTs and VPDs on maize tassel performance under changing environments. Therefore, we carried out a two-year field experiment that included 20 inbred lines and four sowing dates. Compared with the first sowing date, the seed set in the second sowing date decreased by ~80% in both years. The opened spikelet ratio (OSR) and pollen viability (PV) were the key determinants of seed set, and their respective correlation coefficients with seed set were 0.58 and 0.90. The OSR and PV decreased by ~20% and ~50%, respectively, under high-temperature stress. When Tmax exceeded 32.5 °C or the VPD exceeded 0.91 KPa, PV began to decline; when Tmax exceeded 33.8 °C or VPD exceeded 1.10 KPa, the OSR began to decline. The OSR was more dependent on genotypic background than PV (28.4% vs. 19.7%). The maize tassel water content was significantly correlated with the OSR and PV. Based on the OSR and PV values, the 20 genotypes were divided into three different groups, namely the high H, middle M, and low L groups. The H group, on average, had the highest kernel number per ear and seed set, followed by the M and L groups. The average seed sets of the H, M, and L genotypes under the second sowing date were 17.4%, 10.9%, and 0%, respectively, in 2019 and 13.8%, 7.9%, and 0.6%, respectively, in 2020. The present results indicate that selecting maize varieties with a high OSR is an effective approach for improving maize yield under heat stress.

Suppressing Se Vacancies in Sb2Se3 Photocathode by In Situ Annealing with Moderate Se Vapor Pressure for Efficient Photoelectrochemical Water Splitting.

Sb2Se3 emerges as a promising material for solar energy conversion devices. Unfortunately, the common deep-level defect VSe (selenium vacancy) in Sb2Se3 results in a low solar conversion efficiency. The post selenization process has been widely adopted for suppressing VSe. However, the effect of selenization on suppressing VSe is often compromised and even more VSe are induced due to defect-correlation. Herein, high-quality Sb2Se3 films are prepared using an unconventional selenization process, with precisely regulating in situ annealing Se vapor pressure. It is found that moderate Se vapor pressure annealing can efficiently suppress VSe by overcoming defect-correlation, as well as promotes grain growth and forms a better heterojunction band alignment. Consequently, the Sb2Se3 photocathode shows a high-level photocurrent of 19.5 mA cm-2 at 0 VRHE, an onset potential of 0.40 VRHE and a half-cell solar-to-hydrogen conversion efficiency of 1.9%, owing to the inhibited charge recombination, excellent charge transport and interface charge extraction. This work provides a significant insight to suppress deep-level defect VSe by adjusting Se vapor pressure for efficient Sb2Se3 photocathode.

Examining the Influence of Silver(I) Ion Coordination Environment in Ionic Liquids on Olefin-Paraffin Separations using Inverse Gas Chromatography.

Silver(I) ions (Ag+) undergo selective π-complexation with olefins and have been employed as separation media for the isolation of olefins from structurally similar paraffins. Ionic liquids (ILs) possess minimal vapor pressures, exceptional thermal stabilities, low melting points, as well as provide a favorable environment for π-complexation between Ag+ ions and olefins. The development of molecular drivers capable of highly selective olefin/paraffin separation systems with Ag+-containing ILs necessitates a comprehensive understanding of all factors that affect olefin solubility and selectivity. This study examines how coordinating different ligand species to Ag+ ions produces separation media with varying interaction strengths to olefins. Four coordination compounds, (4,4'-dimethyl-2,2'-bipyridine)silver(I) bis[(trifluoromethyl)sulfonyl]imide ([Ag+(DMBP)][NTf2-]), bis(pyridine)silver(I) [NTf2-] ([Ag+(Py)2][NTf2-]), bis(2,6-lutidine)silver(I) [NTf2-] ([Ag+(Lut)2][NTf2-]), and (triphenylphosphine)silver(I) [NTf2-] ([Ag+(PPh3)][NTf2-]) were dissolved in the 1-decyl-3-methylimidazolium [NTf2-] ([DMIM+][NTf2-]) IL and employed as stationary phases for inverse gas chromatography. Ligand coordination to the Ag+ ion was observed to modulate interactions of unsaturated hydrocarbons. The [Ag+(Py)2][NTf2-] complex offered the greatest olefin retention among the coordination complexes reaching 54% of the 1-octene retention factor of the uncoordinated [Ag+][NTf2-]. Hydrogen (H2) exposure studies showed ligand-dependent rates of reduction from Ag+ ion to elemental silver (Ag0). The [Ag+(PPh3)][NTf2-] complex exhibited superior stability, compared to the neat [Ag+][NTf2-] salt, reducing the retention factor of 1-octene by 15.3% and 19.4%, respectively, after 200 h of H2 exposure at 70 °C. The results from this study show that coordination complexes with Ag+ ions are useful in highly selective and efficient petroleum processing systems.

A Multiscalar Standardized Vapor Pressure Deficit Index for Drought Monitoring and Impacts

ABSTRACTVapour pressure deficit (VPD) is a critical measure of the atmospheric demand for water and can be used to assess short‐term and seasonal drought. To provide for probabilistic comparisons of VPD across space and time, we develop a Standardized Vapor Pressure Deficit Index (SVPDI). Similar to the way that other standardised drought indices are used, SVPDI allows for the analysis and comparison of changes in VPD across regions with different base level VPD values. It also should be useful for analysing impacts on vegetation that has varying levels of adaptation to high VPD. We use 1‐, 3‐, 6‐ and 12‐month timescales for the development of SVPDI and show that the gamma distribution is superior to other zero‐limited probability distributions for analysing VPD and, therefore, for calculating SVPDI. Then, focusing on the short‐term variations at the 1‐ and 3‐month timescales, we show how SVPDI has changed globally from 1958 to 2023 and how those changes differ from those of the commonly used Standardized Precipitation Evaporation Index (SPEI). We find that SVPDI shows more widespread drying conditions that also are larger in magnitude compared to those of SPEI. Although the two indices are moderately well correlated across the terrestrial surface, we discover that they are more decoupled in humid and arid regions compared to dry sub‐humid and semi‐arid regions. Using four locations that have recently experienced severe drought, we find that SVPDI generally showed longer drought duration and more severe drought events in the last decade when compared to SPEI.

Global influence of soil texture on ecosystem water limitation.

Low soil moisture and high vapour pressure deficit (VPD) cause plant water stress and lead to a variety of drought responses, including a reduction in transpiration and photosynthesis1,2. When soils dry below critical soil moisture thresholds, ecosystems transition from energy to water limitation as stomata close to alleviate water stress3,4. However, the mechanisms behind these thresholds remain poorly defined at the ecosystem scale. Here, by analysing observations of critical soil moisture thresholds globally, we show the prominent role of soil texture in modulating the onset of ecosystem water limitation through the soil hydraulic conductivity curve, whose steepness increases with sand fraction. This clarifies how ecosystem sensitivity to VPD versus soil moisture is shaped by soil texture, with ecosystems in sandy soils being relatively more sensitive to soil drying, whereas ecosystems in clayey soils are relatively more sensitive to VPD. For the same reason, plants in sandy soils have limited potential to adjust to water limitations, which has an impact on how climate change affects terrestrial ecosystems. In summary, although vegetation-atmosphere exchanges are driven by atmospheric conditions and mediated by plant adjustments, their fate is ultimately dependent on the soil.

Pump-Free Pneumatic Actuator Driven by the Vapor Pressure at the Gas-Liquid Equilibrium of Aqua Ammonia.

Currently, pneumatic soft actuators are widely used due to their impressive adaptability, but they still face challenges for more extensive practical applications. One of the primary issues is the bulky and noisy air compressors required to generate air pressure. To circumvent this critical problem, this work proposes a new type of air pressure source, based on the vapor pressure at the gas-liquid equilibrium to replace conventional air pumps. Compared with the previous phase transition method, this approach gains advantages such as generating gas even at low temperatures (instead of boiling point), more controllable gas output, and higher force density (since both ammonia and water contribute to the gas pressure). This work built mathematical models to explain the mechanism of converting energy to output action force from electrical energy and found the aqua ammonia system is one of the optimal choices. Multiple prototypes were created to demonstrate the capability of this method, including a pouch actuator that pushed a load 20,555 times heavier than its dead weight. Finally, based on the soft actuator, an untethered crawling robot was implemented with onboard batteries, showing the potentially extensive applications of this methodology.

Optimizing wheat supplementary irrigation: Integrating soil stress and crop water stress index for smart scheduling

A two-year field experiment was conducted to integrate soil moisture stress with the Crop Water Stress Index (CWSI) for optimizing irrigation in winter wheat (Triticum aestivum L.) under varying irrigation regimes. The study took place at the Water Technology Centre (WTC-02) of ICAR-IARI, New Delhi, where the climate shows a blend of monsoon-influenced humid subtropical and semi-arid conditions. Using a randomized block design (RBD), five irrigation treatments were applied: full irrigation and deficit irrigation (DI) at 15 %, 30 %, 45 %, and 60 % levels. Canopy and ambient air temperature data, along with vapor pressure deficit (VPD), were recorded using a developed integrated sensing device to empirically determine the lower baseline equations and upper threshold for CWSI computation at pre-heading and post-heading stages. The slope (m), intercept (c) of the lower baseline equation, and upper threshold (UL) for pre-heading and post-heading were found: m: −1.94, c: −1.33, UL: 1.92°C and m: −1.30, c: −2.37, UL: 2.0°C, respectively. Results showed that increasing water deficit levels led to significant reductions in grain yield, biomass production, and harvest index. A strong negative correlation (R² = 0.95 and 0.93) between mean seasonal CWSI and yield attributes highlighted the utility of CWSI in yield prediction under varying irrigation regimes. It is recommended to schedule irrigation based on the CWSI approach when CWSI ≥0.35 for optimum wheat yields. Integrating CWSI with soil moisture stress provides valuable real-time insights into crop water status, enabling more precise and smart irrigation scheduling.

Secondary electron emission measurements from imidazolium-based ionic liquids

Abstract The electron-induced secondary electron emission (SEE) yields of imidazolium-based ionic liquids are presented for primary electron beam energies between 30 and 1000 eV. These results are important for understanding plasma synthesis of nanoparticles in plasma discharges with an ionic liquid electrode. Due to their low vapor pressure and high conductivity, ionic liquids can produce metal nanoparticles in low-pressure plasmas through reduction of dissolved metal salts. In this work, the low vapor pressure of ionic liquids is exploited to directly measure SEE yields by bombarding the liquid with electrons and measuring the resulting currents. The ionic liquids studied are [BMIM][Ac], [EMIM][Ac], and [BMIM][BF4]. The SEE yields vary significantly over the energy range, with maximum yields of around 2 at 200 eV for [BMIM][Ac] and [EMIM][Ac], and 1.8 at 250 eV for [BMIM][BF4]. Molecular orbital calculations indicate that the acetate anion is the likely electron donor for [BMIM][Ac] and [EMIM][Ac], while in [BMIM][BF4], the electrons likely originate from the [BMIM]$^+$ cation. The differences in SEE yields are attributed to varying ionization potentials and molecular structures of the ionic liquids. These findings are essential for accurate modeling of plasma discharges and understanding SEE mechanisms in ionic liquids.

Winter torpor patterns of tricolored bats (Perimyotis subflavus) in the southeastern United States

Abstract The Tricolored Bat (Perimyotis subflavus) has suffered significant population declines in much of its geographic range due to white-nose syndrome (WNS). Our aim was to describe the torpor patterns of tricolored bats within the southeastern United States to further our understanding of their winter ecology and potential susceptibility to WNS in currently unimpacted areas based on data from bats in both a WNS-affected hibernaculum and an unaffected hibernaculum. We placed temperature-sensitive radio transmitters on tricolored bats in a site in northwestern South Carolina that was WNS-positive and another site in northwestern Florida that was WNS-negative, and determined torpid and arousal skin temperatures (TSK), torpor bout duration (TBD), and arousal duration (AD) during 3 winters. Mean hibernacula temperature (TH) and vapor pressure deficit (VPDH) in both hibernacula were within the range of optimal Pseudogymnoascus destructans (Pd) growth (TH = 12.7 to 13.6 °C, VPDH = 0.028 to 0.059 kPA). Mean torpid TSK was 15.7 ± 0.1 °C and mean TBD was 4.1 ± 0.2 days across sites. Sex was the best predictor of TBD with males having significantly longer TBD than females. Torpid TSK was positively related to TH and negatively related to VPDH. Because the TSK of a bat was similar to the optimal growth temperatures of Pd, our findings suggest that even though winters in the southeastern United States are more benign than in other parts of the Tricolored Bat range, the warmer temperatures in southern hibernacula may provide optimal conditions for the growth of Pd. Greater understanding of the physiological responses of tricolored bats in hibernacula across their range will provide important data on the potential for WNS morbidity and mortality in unaffected areas and allow for a better distribution of resources for prevention and treatment of WNS.

Drought-Induced Alterations in Carbon and Water Dynamics of Chinese Fir Plantations at the Trunk Wood Stage.

Over the past three decades, China has implemented extensive reforestation programs, primarily utilizing Chinese fir (Cunninghamia lanceolata (Lamb.) Hook) in southern China, to mitigate greenhouse gas emissions and counter extreme climate events. However, the effects of drought on the carbon sequestration capacity of these forests, particularly during the trunk wood stage, remain unclear. This study, conducted in Huitong, Hunan, China, from 2008 to 2013, employed the eddy covariance method to measure carbon dioxide (CO2) and water fluxes in Chinese fir forests, covering a severe drought year in 2011. The purpose was to elucidate the dynamics of carbon and water fluxes during a drought year and across multi-normal year averages. The results showed that changes in soil water content (-8.00%), precipitation (-18.45%), and relative humidity (-5.10%), decreases in air temperature (-0.09 °C) and soil temperature (-0.79 °C), and increases in vapor pressure deficit (19.18%) and net radiation (8.39%) were found in the drought year compared to the normal years. These changes in environmental factors led to considerable decreases in net ecosystem exchange (-40.00%), ecosystem respiration (-13.09%), and gross ecosystem productivity (-18.52%), evapotranspiration (-12.50%), and water use efficiency (-5.83%) in the studied forests in the drought year. In this study, the occurrence of seasonal drought due to uneven precipitation distribution led to a decrease in gross ecosystem productivity (GEP) and evapotranspiration (ET). However, the impact of drought on GEP was greater than its effect on ET, resulting in a reduced water use efficiency (WUE). This study emphasized the crucial role of water availability in determining forest productivity and suggested the need for adjusting vegetation management strategies under severe drought conditions. Our results contributed to improving management practices for Chinese fir plantations in response to changing climate conditions.

Stomatal closure as a driver of minimum leaf conductance declines at high temperature and vapor pressure deficit in Quercus.

Rising global temperatures and vapor pressure deficits (VPD) are increasing plant water demand and becoming major drivers of large-scale plant mortality. Controlling transient leaf water loss after stomatal closure (gmin) is recognized as a key trait determining how long plants survive during soil drought. Yet, substantial uncertainty remains regarding how gmin responds to elevated temperatures and VPD and the underlying mechanisms. We measured gmin in 24 Quercus species from temperate and Mediterranean climates to determine if gmin was sensitive to a coupled temperature and VPD increase. We also explored mechanistic links to phenology, climate, evolutionary history, and leaf anatomy. We found that gmin in all species exhibited a non-linear negative temperature and VPD dependence. At 25°C (VPD = 2.2 kPa), gmin varied from 1.19 to 8.09 mmol m-2 s-1 across species but converged to 0.57 ± 0.06 mmol m-2 s-1 at 45°C (VPD = 6.6 kPa). In a subset of species, the effect of temperature and VPD on gmin was reversible and linked to the degree of stomatal closure, which was greater at 45°C than at 25°C. Our results show that gmin is dependent on temperature and VPD, is highly conserved in Quercus species, and is linked to leaf anatomy and stomatal behavior.

Numerical simulation of fluid flow characteristics and ultrasonic cavitation performance in novel-designed stirred tank sonoreactor

A novel-designed stirred tank sonoreactor was developed to well solve large-scale dispersion of nanoparticles in liquid phase system. The fluid flow characteristics and ultrasonic cavitation performance in the sonoreactor were numerically simulated by CFD method. By comparing the pressure, cavitation bubble and velocity distribution under different situations, it is found that larger ultrasonic amplitude, relatively smaller ultrasonic frequency, higher saturated vapor pressure and lower viscosity of liquid medium are beneficial to ultrasonic cavitation. Besides, the acoustic flow action is strengthened with the increase of ultrasonic frequency and decrease of gas-liquid mixture's average density. For the designed sonoreactor, it is critical that high-frequency transducers should be determined near the bottom and upper region of the kettle, and large-amplitude transducers can be confirmed in the middle position. The research findings will provide theoretical and technical supports for developing state-of-the-art sonoreactors and optimizing ultrasonic process parameters in the industrialized preparation of nanocomposites.

The Synergistic Effect of the Same Climatic Factors on Water Use Efficiency Varies between Daily and Monthly Scales

The coupled processes of ecosystem carbon and water cycles are usually evaluated using the water use efficiency (WUE), and improving WUE is crucial for maintaining the sustainability of ecosystems. However, it remains unclear whether the WUE in different ecosystem responds synchronously to the synergistic effect of the same climate factors at daily and monthly scales. Therefore, we employed a machine learning-driven factor analysis method and a geographic detector model, and we quantitatively evaluated the individual effects and the synergistic effect of climate factors on the daily mean water use efficiency (WUED) and monthly mean water use efficiency (WUEM) in different ecosystems in China. Our results showed that (1) among the 10 carbon flux monitoring sites in China, WUED and WUEM exhibited the highest positive correlations with the near-surface air humidity and the highest negative correlation with solar radiation. The correlation between WUEM and climate factors was generally greater than that between WUED and climate factors. (2) There were significant differences in the order of importance and degree of impact of the same climate factors on WUED and WUEM in the different ecosystems. Among the 10 carbon flux monitoring sites in China, the near-surface air humidity imposed the greatest influence on the WUED and WUEM changes, followed by the near-surface water vapor pressure. (3) There were significant differences in the synergistic effects of the same climate factors on WUED and WUEM in the different ecosystems. Among the 10 carbon flux monitoring sites in China, the WUED variability was most sensitive to the synergistic effect of solar radiation and photosynthetically active radiation, while the WUEM variability was most sensitive to the synergistic effect of the near-surface air humidity and soil moisture. The research results indicated that synchronous responses of the WUE in very few ecosystems to the same climate factors and their synergistic effect occurred at daily and monthly scales. This finding enhances the understanding of sustainable water resource use and the impact of climate change on water use efficiency, providing crucial insights for improving climate-adaptive ecosystem management and sustainable water resource utilization across different ecosystems.

Flash Drought Intensification due to Enhanced Land–Atmospheric Coupling in India

Abstract Land–atmospheric feedback influences the occurrence and severity of flash droughts. However, the observed and projected changes in flash droughts and associated land–atmospheric coupling have not been examined over India. Moreover, the causes of the rapid depletion of soil moisture during flash droughts are not well known. We identify major flash droughts and associated soil moisture–vapor pressure deficit (SM–VPD) coupling in India using ERA5 and simulations from global climate models (CMIP6-GCMs). The summer monsoon season (June–September) witnesses more than 60% of the flash drought events and a relatively higher rate of flash drought development. The flash drought frequency has mainly decreased during India’s observed climate (1980–2019), which is projected to decline further in the future warming climate. On the other hand, the flash drought development rate has significantly increased during the observed period, which is projected to enhance further under the warming climate. SM–VPD coupling during the flash drought onset-development phase is considerably higher (threefold to fivefold) than during the normal condition (in the absence of flash drought). The high (low) SM–VPD coupling explains the faster (slower) flash drought development rate in the observed and future warming climate. The strength of SM–VPD coupling has increased in the recent period and is projected to increase further in the future warming climate. The increased SM–VPD coupling can intensify future flash droughts in India, especially during the summer monsoon season, with considerable implications for agriculture, water resources, and ecosystems. Significance Statement This study aims to understand better the role of land–atmospheric coupling in explaining flash drought characteristics (frequency and development rate) in India. Strong land–atmospheric (SM–VPD) feedback might influence the regional weather patterns during flash drought, which often negatively impacts humans and the ecosystem. We explain the causes and drivers of increasing (decreasing) flash drought development rate (frequency) in India. The long-term change in SM–VPD coupling drives the frequency of flash drought, whereas an anomalous instantaneous change in coupling controls the flash drought development rate. More intense flash droughts contributed by the increased land–atmospheric coupling are projected in the future. Predicting the SM–VPD coupling metric can facilitate more time for preparedness, resulting in minimizing the flash drought impacts.