Presence Of Multi-walled Nanotubes Research Articles

Shear induced crystallization in different polymorphic forms of PVDF induced by surface functionalized MWNTs in PVDF/PMMA blends.

Shear induced crystallization in PVDF/PMMA blends, especially at higher fractions of PMMA, can be quite interesting in understanding the structure-property correlation and processing of these blends. In a recent submission (Phys. Chem. Chem. Phys., 2014, 16, 2693-2704), we clearly demonstrated, using dielectric spectroscopy, that the origin of segmental relaxations concerning the crystalline segments of PVDF in PVDF/PMMA blends in the presence of MWNTs (multiwalled nanotubes) was strongly contingent on the size of the crystallite. We now understand that the fraction of PMMA in the blends governs the origin of polymorphism in PVDF. This motivated us to systematically study the effect of shear on the crystallization behavior of PVDF especially in blends with different polymorphic forms of PVDF. Two model blends were selected; one with a mixture of α and β crystals and the other predominantly rich in α crystals. Initially, physical ageing, at different oscillation frequencies (1 rad s(-1) and 0.1 rad s(-1)), was monitored by melt rheology and subsequently, the effect of steady shear was probed in situ without changing the history of the samples. Intriguingly, the rate of crystallization was observed to be significantly higher for higher oscillation frequencies, which essentially suggest that shear has induced crystallization in the blends. More interestingly, the effect of steady shear was more pronounced in the blends rich in α crystals (bigger crystallites as observed from SAXS) and at lower oscillation frequencies.

Cooperativity and Structural Relaxations in PVDF/PMMA Blends in the Presence of MWNTs: An Assessment through SAXS and Dielectric Spectroscopy

Intermolecular cooperativity and structural relaxations in PVDF/PMMA blends were studied in this work with respect to different surface modified (amine, ∼NH2; carboxyl acid, ∼COOH and pristine) multiwalled nanotubes (MWNTs) at 1 wt % near blend’s Tg and in the vicinity of demixing using dielectric spectroscopy, SAXS, DSC, and WAXD. Intermolecular cooperativity at Tg and configurational entropy was addressed in the framework of cooperative rearranging region (CRR) at Tg. Because of specific interactions between PVDF and NH2-MWNTs, the local composition fluctuates at its average value resulting in a broad Tg. The scale of cooperativity (ξCRR) and the number of segments in the cooperative volume (NCRR) is comparatively smaller in the blends with NH2-MWNTs. This clearly suggests that the number of segments cooperatively relaxing is reduced in the blends due to specific interactions leading to more heterogeneity. The configurational entropy at Tg, as derived from Vogel-Fulcher and Adam–Gibbs analysis, was reduced in the blends in presence of MWNTs manifesting in entropic penalty of the chains. The crystallite size and the amorphous miscibility was evaluated using SAXS and was observed to be strongly contingent on the surface functional groups on MWNTs. Three distinct relaxations—αc due to relaxations in the crystalline phase of PVDF, αm indicating the amorphous miscibility in PVDF/PMMA blends, and αβ concerning the segmental dynamics of PMMA—were observed in the blends in the temperature range Tg < T < Tc. The dynamics as well as the nature of relaxations were observed to be dependent the surface functionality on the MWNTs. The dielectric permittivity was also enhanced in presence of MWNTs, especially with NH2-MWNTs, with minimal losses. The influence of the MWNTs on the spherulite size and crystalline morphology of the blends was also confirmed by POM and SEM.

Experimental study on the heat transfer enhancement of MWNT-water nanofluid in a shell and tube heat exchanger

Heat transfer enhancement of multi-walled carbon natube(MWNT)/water nanofluid in a horizontal shell and tube heat exchanger has been studied experimentally. Carbon nanotubes were synthesized by the use of catalytic chemical vapor deposition (CCVD) method over Co–Mo/MgO nanocatalyst. Obtained MWNTs were purified using a three stage method. COOH functional groups were inserted for making the nanotubes hydrophilic and increasing the stability of the nanofluid. The results indicate that heat transfer enhances in the presence of multi-walled nanotubes in comparison with the base fluid.

Tantalum based coated substrates for controlling the diameter of carbon nanotubes

The diameter of carbon nanotubes deposited on TaN coated silicon substrates by catalytic chemical vapor deposition strongly depends on the N/Ta ratio in the coating. The coating characteristics are tailored by controlling the deposition parameters in a plasma reactive sputtering process. Photoelectron emission spectroscopy and X-ray diffraction of the coatings show the formation of a composite material. The presence of multi-wall nanotubes is confirmed by transmission electron microscopy. The results show that the structure of the TaN coating modifies the catalyst (Fe) effect changing the kinetics of the nanotube growth.

Catalytic effects on carbon/carbon composites fabricated by a film boiling chemical vapor infiltration process

Chemical vapor infiltration (CVI) has been widely studied under several conditions to obtain C/C composites. A “film boiling technique” (so-called Kalamazoo), by the use of liquid precursor, based on thermal gradient CVI has been recently developed as one of the very effective techniques to increase the carbon yield and the densification rate. A small cold wall type laboratory reactor has been realized to analyze the kinetics of reactions and the deposited pyrocarbon matrix. In this study, ferrocene, as the source of catalyst, is mixed to the liquid precursor to induce a catalytic effect on the film boiling technique since the transition metals are known to increase the carbon deposition rate. In addition to an important increase of the densification rate, it is revealed that the deposition mechanism and microtextures are completely modified by the presence of catalyst, with the presence of multiwall nanotubes within the matrix. A model has been adapted from Allendorff and Hunt's work to interpret this peculiar deposition mechanism.

Multiwalled carbon nanotube polymer composites: Synthesis and characterization of thin films

AbstractThe aim of this article was to elucidate the basic relationships between processing conditions and the mechanical and electrical properties of multiwalled carbon nanotube reinforced polymer composites. In conventional chopped fiber reinforced polymer composites, uniform distributions of fibers throughout the matrix are critical to producing materials with superior physical properties. Previous methods have dispersed carbon nanotubes by aggressive chemical modification of the nanotubes or by the use of a surfactant prior to dispersion. 1, 2 Here, ultrasonic energy was used to uniformly disperse multiwalled nanotubes (MWNTs) in solutions and to incorporate them into composites without chemical pretreatment. Polystyrene (PS) solutions containing MWNTs were cast and spun to yield thin film MWNT composites. The rheology of PS/MWNT suspensions was modeled using the Carreau equation. MWNTs were found to align at the shear rates generated by the spin casting process. The tensile modulus and strain to failure of samples compared well to classical micromechanical models, increasing with MWNT loading. The composite films showed lower strains at the yield stress than neat PS films. The presence of MWNTs at 2.5 vol % fraction approximately doubles the tensile modulus, and transforms the film from insulating to conductive (surface resistivity, ρ, approaching 103 Ω/□). © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 2660–2669, 2002