Presence Of Hydrogenic Impurity Research Articles

Oscillator strengths of the intersubband transitions in a semiconductor spherical quantum dot with the donor impurity in the center

Oscillator strengths have been studied for a series of single-electron intersubband optical transitions nl → n′l′ (l ⩽ 4) in a spherical quantum dot (QD) with the donor impurity in the center (D0). Energy spectrum calculations were performed under effective mass approximation by assuming a spherically symmetric confining potential of finite depth. On the basis of the analytical solutions, the Schrödinger and Poisson equations' energies of states and corresponding wave functions were determined. The oscillator strength of each transition depends on the energy difference of two states and the dipole matrix element, i.e. wave functions of states. The effects of increasing the dot size in the presence of hydrogenic impurity on the oscillator strength of three series of transitions for a CdTe/ZnTe QD are presented in this paper.

Effect of hydrogen on the formation of the atomic structure of linear carbon chains: An ab initio approach

An ab initio study of the features of the formation of the atomic structure of carbon chains, which are structural parts of films of linear carbon chains, has been performed using the electron density functional theory. It has been shown that the formation and stabilization of experimentally observed kinks of carbon chains require the presence of hydrogen impurities in the chamber during the synthesis of linear carbon chains. The kinks of a carbon chain are formed in the process of the adsorption of hydrogen atoms on a chain. The optimal kink angle of carbon chains has been determined. The stability of kinks of carbon chains has been estimated as a function of the length of linear fragments. An additional mechanism has been proposed for the formation of kinks in carbon chains owing to the joining of short carbon chains with hydrogen ends.

Impurity optical absorption in parabolic quantum well

Optical absorption in GaAs parabolic quantum well in the presence of hydrogenic impurity is considered. The absorption coefficient associated with the transitions between the upper valence subband and donor ground state is calculated. The impurity ground state wave function and energy are obtained using the variational method. Dependence of the absorption spectra on impurity position in quantum well was investigated. It is shown, that along with quantum well width decrease the absorption threshold shifts to higher frequencies. Results obtained within frames of parabolic approximation are compared with results for rectangular infinite-barrier quantum well case. The acceptor state → conduction band transitions considered as well.

Effects of hydrogen impurities on shock structure and stability in ionizing monatomic gases: 2. Krypton

At shock Mach numbers [Formula: see text] in pure krypton, at initial pressures p0 ~ 5 Torr, and final electron number densities ne ~ 1017 cm−3, the translational shock front in a 10 cm × 18 cm hypervelocity shock tube develops sinusoidal instabilities which affect the entire shock structure including the ionization relaxation region, the electron-cascade front and the final quasi-equilibrium state. By adding a small amount of hydrogen (~0.5% of the initial pressure), the entire flow is stabilized. However, the relaxation length for ionization is drastically reduced to about one half of its pure-gas value. Unlike argon the stability appears to diminish with the addition of hydrogen beyond about 0.5%. Using the familiar two-step collisional model coupled with radiation-energy loss and the appropriate chemical reactions, it was possible from dual-wavelength interferometric measurements to deduce a more precise value for the krypton–krypton collision excitation cross-section, S*Kr–Kr = 1.2 × 10−19 cm2/eV, with or without the presence of hydrogen impurities. The reason for the success of hydrogen, and not other gases, in bringing about stabilized Shock waves in argon and krypton is not clear. It was also found that the electron-cascade front approached closely to the translational-shock front with increasing proximity to the shock-tube wall. This effect appears independent of the wall material and is not affected by the evolution of adsorbed water vapour from the walls or by water added deliberately to the test gas. The sinusoidal instabilities investigated here may offer some important clues to the abatement of instabilities that lead to detonations and explosions.