Presence Of Grain Growth Research Articles

Heat Treatments for Minimization of Residual Stresses and Maximization of Tensile Strengths of Scalmalloy® Processed via Directed Energy Deposition.

Scalmalloy® is an Al-Mg-Sc-Zr-based alloy specifically developed for additive manufacturing (AM). This alloy is designed for use with a direct aging treatment, as recommended by the manufacturer, rather than with a multistep treatment, as often seen in conventional manufacturing. Most work with Scalmalloy® is conducted using powder bed rather than powder-fed processes. This investigation seeks to fill this knowledge gap and expand beyond single-step aging to promote an overall balanced AM-fabricated component. For this study, directed energy deposition (DED)-fabricated Scalmalloy® components were subjected to low-temperature treatments to minimize residual stresses inherent in the material due to the layer-by-layer build process. X-ray diffraction (XRD) indicated the possibility of stress minimization while reducing the detriment to mechanical strength through lower temperature treatments. Microstructural analyses consisting of energy dispersion spectroscopy (EDS) and electron backscatter diffraction (EBSD) revealed the presence of grain growth detrimentally affecting the strength and elongation made possible by very small grains inherent to AM and rapid solidification. Tensile testing determined that treatment at 175 °C for 1 h provides the best relief from the existing residual stresses; however, this is accompanied by a diminishment in the yield and tensile strength of 19 and 9.5%, respectively. It is noted that treatment at 175 °C for 2 h did not provide as great of a decrease in residual stresses, theorized to be the result of grain growth and other strengthening mechanisms further stressing the structure; however, the residual stresses are still significantly diminished compared with the as-built condition. Furthermore, a minimal reduction of the tensile strengths indicates the possibility of finding a balance between property diminishment and stress state through the work proposed here.

Characterisation of SA210 Grade A1 virgin and failed boiler steel tube materials

Abstract The present work is to study the metallurgical phenomena causing the failure of the tubes made with SA210 Grade (Gr) A1 used in thermal power plants. Both the virgin and failed SA210 Gr A1 tubes, having 150 mm length, 50 mm diameter and 11 mm wall thickness were taken for study. The optical microscopy revealed the presence of grain growth. The average grain size was 5 µm for the virgin steel and 12 µm for the failed tube. Scanning Electron Microscopy (SEM) confirmed grain growth and the presence of voids. The Energy Dispersive X-Ray Analysis reports (EDAX) revealed the variation in the composition of elements such as ‘Fe’, ‘Mn’, ‘Si’ and ‘C’ between the two tubes. A maximum hardness value of 194.8 and 174.3 VHN were observed for the virgin tube and the failed tube materials, respectively.

Controlling Morphology in Polycrystalline Films by Nucleation and Growth from Metastable Nanocrystals.

Solution processingofpolycrystalline compound semiconductor thin film using nanocrystals as a precursor is considered one of the most promising and economically viable routes for future large-area manufacturing. However, in polycrystalline compound semiconductor films such as Cu2ZnSnS4 (CZTS), grain size, and the respective grain boundaries play a key role in dictating the optoelectronic properties. Various strategies have been employed previously in tailoring the grain size and boundaries (such as ligand exchange) but most require postdeposition thermal annealing at high temperature in the presence of grain growth directing agents (selenium or sulfur vapor with/without Na, K, etc.) to enlarge the grains through sintering. Here, we show a different strategy of controlling grain size by tuning the kinetics of nucleation and the subsequent grain growth in CZTS nanocrystal thin films during a crystalline phase transition. We demonstrate that the activation energy for the phase transition can be varied by utilizing different shapes (spherical and nanorod) of nanocrystals with similar size, composition, and surface chemistry leading to different densities of nucleation sites and, thereby, different grain sizes in the films. Additionally, exchanging the native organic ligands for inorganic surface ligands changes the activation energy for the phase change and substantially changes the grain growth dynamics, while also compositionally modifying the resulting film. This combined approach of using nucleation and growth dynamics and surface chemistry enables us to tune the grain size of polycrystalline CZTS films and customize their electronic properties by compositional engineering.

SPATIALLY RESOLVING THE HK Tau B EDGE-ON DISK FROM 1.2 TO 4.7 μm: A UNIQUE SCATTERED LIGHT DISK

We present spatially resolved scattered light images of the circumstellar disk around HK Tau B at 3.8 and 4.7 μm taken with the Keck Telescope Laser Guide Star Adaptive Optics (AO) system, and 1.6-2.12 μm images taken with the Very Large Telescope/NACO AO system. Combined with previously published optical Hubble Space Telescope data, we investigate the spatially resolved scattered light properties of this edge-on circumstellar disk and probe for the presence of large grains. The 0.6-3.8 μm scattered light observations reveal strong, and in some cases, unusual, wavelength dependencies in the observed disk morphology. The separation between the two scattered light nebulae, which is directly proportional to the disk-mass-opacity product, decreases by 30% between 0.6 and 3.8 μm. Over the same wavelength range, the FWHM of the disk nebulosity declines by a factor of two, while the flux ratio between the two nebulae increases by a factor of ~8. No other disk known to date shows a flux ratio that increases with wavelength. Both the FWHM and nebula flux ratio are affected by the scattering phase function and the observed behavior can most readily be explained by a phase function that becomes more forward throwing with wavelength. The multi-wavelength scattered light observations also confirm the asymmetric nature of the disk and show that the level of asymmetry is a function of wavelength. We use the MCFOST radiative transfer code to model the disk at four wavelengths, corresponding to the I, H, Ks, and L' bandpasses. A single power-law grain size distribution can recreate the observed disk properties simultaneously at all four wavelengths. Bayesian analysis of the dust parameters finds a 99% probability that the maximum grain size is 5.5 μm or larger. We also find that the grain size distribution is steep, with a 99% probability of a power-law index of 4.2 or larger, suggesting that these large grains are a small fraction of the overall dust population. The best-fit dust asymmetry parameter for each individual wavelength shows an unusual behavior, increasing with wavelength from the optical through the near-infrared, peaking at ~0.8 between 2.2 and 3.8 μm, then decreasing by a factor of two by ~12 μm. Comparing the wavelength dependence of the asymmetry parameter for HK Tau B with those for the interstellar medium (ISM) and dark cloud dust models, we find considerable evolution from an ISM state and argue for the presence of grain growth within the disk. Further, comparing the wavelength dependence of the asymmetry parameter for GG Tau, HV Tau C, and HK Tau B, the three disks that have been spatially resolved in scattered light between 0.8 and 3.8 μm, finds a diverse range of dust properties, indicating differing degrees of grain growth for disks at a similar age.