Presence Of Dipole-dipole Interaction Research Articles

Polymer and micellar catalysis in d-fructose oxidation by imidazolium fluorochromate: A kinetic and mechanistic study

This work investigated the oxidation of d-fructose using imidazolium fluorochromate (IFC) as an oxidant and analyzed how sodium dodecyl sulfate (SDS) and polyethylene glycol (PEG-400) affected the reaction kinetics. The process exhibited a unit-order dependence on IFC, d-fructose, and perchloric acid concentration. Perchloric acid was the primary source of hydrogen ions in the reaction mixture. The stoichiometry of the reaction indicated that 3 mol of d-fructose requires 4 mol of IFC. Acrylonitrile, a radical-generating species, did not impact the reaction rate, indicating the absence of a free radical intermediate. The reaction rate decreases as the Mn (II) ions concentration increases, suggesting the involvement of Cr (IV) species in the reaction. The dielectric value of the reaction medium (D) had an inverse effect on the rate, and the outcomes were consistent with the Amis (log k1 and 1/D) and Kirkwood plots (log k1 and (D-1/2D+1)), indicating the presence of dipole-dipole interactions in the process. SDS and PEG-400 catalyzed the reaction. The reaction showed significant catalysis before reaching the critical micelle concentration (CMC). However, the observed rate constants stabilized at higher SDS concentrations exceeding the CMC. Piszkiewicz's cooperativity model was employed to describe the surfactant catalysis, while the Benesi-Hildebrand equation was utilized to explain polymer catalysis. The activation parameters are ΔH† = 44.3 ± 1.3 kJ mol−1, and ΔS† = −133.4 ± 4.3 J K−1 mol−1. The products of the reaction have been identified by spectral analysis as d-arabinoniclactone and formic acid. The formation of an ester complex followed by its decomposition was proposed as the rate-limiting step in the proposed mechanistic reaction pathway.

Study of Bragg scattering in the presence of dipole-dipole interaction in plasmonic nanohybrids

We have developed a theory of the Bragg scattering for metallic nanohybrid made of an ensemble of metallic nanorods doped in a substrate. The substrate can gas, liquid or solid. An external laser field is applied to study the Bragg scattered light. The photons from the incident laser interact with the surface plasmons od nanorods and produce surface plasmon polaritons (SPPs). The incident laser field also induced dipoles in the ensemble of nanorods and they interact with each other via the dipole-dipole interaction (DDI). We have developed a theory for Bragg scattering for metallic nanohybrids using the coupled-mode formulism based on Maxwell’s equation in the presence of SPP and DDI fields. It is found that the theory of Bragg scattered depends on the susceptibility induced by the SPP and DDI fields. We used the quantum mechanical density matrix method to calculate the susceptibility. An analytical expression of the Bragg scattered light intensity is obtained. These expressions can be useful for experimental scientists and engineers who can used them to compare their experiments and make new types of plasmonic devices. Next, we have compared our theory with the experiment data for a nanohybrid made of ensemble of Au-nanoris doped in water. We found a good agreement between theory and experiments. We have also performed the numerical simulations to study the effect of SPP and DDI fields on the Bragg intensity. We have predicted an enhancement the Brag intensity due to the SPP and DDI couplings. The enhancement is due to the two extra scattering mechanisms of the SPP and DDI polaritons with acoustic phonons. We have also found that the one peak in the Bragg intensity can be split int many peaks due the SPP coupling, DDI coupling and phase factor. The splitting is due the Bragg factor appearing in the theory, and it includes the coupling of the incident laser, SPP and DDI electric fields with of acoustic phonons. The enhancement effect can be used to fabricate new types of nanosensors. Similarity, splitting phenomenon can be used to fabricate new types nanoswitches where one peak can be considered as the OFF position and many peaks can be considered as the ON position.

The smectic ZA phase: Antiferroelectric smectic order as a prelude to the ferroelectric nematic

We have structurally characterized the liquid crystal (LC) phase that can appear as an intermediate state when a dielectric nematic, having polar disorder of its molecular dipoles, transitions to the almost perfectly polar-ordered ferroelectric nematic. This intermediate phase, which fills a 100-y-old void in the taxonomy of smectic LCs and which we term the "smectic ZA," is antiferroelectric, with the nematic director and polarization oriented parallel to smectic layer planes, and the polarization alternating in sign from layer to layer with a 180 Å period. A Landau free energy, originally derived from the Ising model of ferromagnetic ordering of spins in the presence of dipole-dipole interactions, and applied to model incommensurate antiferroelectricity in crystals, describes the key features of the nematic-SmZA-ferroelectric nematic phase sequence.

Influence of deformed cavity field and atomic dipole interaction on the quantum correlations of two-qubit system

The possibility of generating of some quantum correlations of the entangled or separable initial two-qubit system interacting with a deformed cavity mode in the presence of dipole-dipole interaction is discussed. These quantum correlations are the coherence, non-separability and steering degrees which are quantifiers by using l_1 norm of coherence, Entanglement of Formation and Einstein–Podolsky–Rosen -steering. It is shown that maximizing or minimizing the quantum correlations depends on the initial setting states of the two-qubit system. To maximize the quantum correlations on the presence of deformation, one has to prepare the initial two-qubit system in an entangled state, setting large values of the coupling dipole and decreasing the effect of the deformation parameter.

Multipartite stationary entanglement generation in the presence of dipole-dipole interaction in an optical cavity

Engineering a stationary entanglement between atoms or ions placed at small distances is a challenging problem in quantum information science. In this paper, the stationary and dynamics of entanglement in a system of dipole-coupled qubits interacting with a single-mode optical cavity in the strong coupling regime are theoretically investigated. We find that the entanglement in the steady state can be induced and tuned in nonresonance cases by considering the dipole-dipole interaction (DDI) between the qubits. We also point out that the novel measure used in this study can quantify the net multiqubit entanglement in the system. By increasing the DDI intensity, the behavior of the system depends on the number of qubits. Interestingly, with only two qubits, the amounts of steady-state entanglement enhances as the DDI intensity increases. For a system with more than two qubits, we find that DDI in the weak range of intensity plays a constructive role in the entanglement between qubits. However, it could destroy the stationary entanglement as the interaction between qubits intensifies. The entanglement of a system consisting of more than two qubits tends to disappear for an ensemble of qubits with smaller interatomic distances that lead to stronger dipolar interaction between nonadjacent qubits. Finally, we study the atomic population transfer as well as the transmitted spectrum.

Spin dynamics in spin-orbit-coupled spin-2 dipolar ultracold atomic gases

In this paper, we study the spin dynamics of spin-orbit-coupled (SOC) spin-2 Bose–Einstein condensates (BECs) with dipole–dipole interaction (DDI). Numerical results are obtained by solving the nonlocal Gross–Pitaevskii equation. Our discussions are divided into two parts. In the absence of DDI, the spin dynamics presents periodic oscillation. Increasing the magnetization makes the amplitude increase, and increasing SOC strength accelerates the spin dynamics and thus changes the period. Nevertheless, in the presence of DDI, the periodicity oscillation of spin dynamics is broken. The thermalization time decreases with the increase of magnetization for fixed SOC strength. In addition, the thermalization time becomes zero with strong SOC strength when magnetization is fixed. We also show the formation of domain in density profile when DDI is considered. Moreover, the components m = 2 and m = −2 exchange their location with a little increase of SOC strength. This is a specific reflection of the competition between the SOC and DDI.

Effects of dipolar interaction on vortex formation in spin-orbit coupled spin-1 rotating condensates

In this paper, we study the vortex formation of spin-orbit coupled (SOC) spin-1 dipolar Bose–Einstein condensates by numerically solving the Gross–Pitaevskii equation. We focus the effects of dipole–dipole interaction (DDI) on vortex structures and dynamics behavior. We find that the symmetry of density profiles in vortex lattice formation process and time evolution of the angular momentum is broken in the presence of DDI. This is due to the symmetry breaking of anisotropy DDI. Also, the total angular momentum decreases with increasing the relative dipole strength. However, it is shown that increasing SOC strength can improve the rotation efficiency. This result reflects the SOC dominates the DDI.

Quantum router modulated by the dipole-dipole interaction in a X-shaped coupled cavity array

We theoretically investigate the single-photon router using two dipole-dipole interaction (DDI) atoms embedded in a multichannel coupled cavity arrays (CCAs). When the atoms are symmetrically coupled to the cavity, the DDI influences both the height and position of the two peaks and gives rise to a shift in the position of the resonance. It is also shown that the effects of DDI are similar to the positive detuning. On the other hand, for the atom-cavity asymmetric coupling case, it is found that, Fano-line shapes are revealed evidently in the scattering spectra by adjusting the interatomic DDI. Moreover, Fano resonance can also be controlled by modulating the atom-cavity coupling strength and the detuning in the presence of DDI. Finally, in the incident channel the total reflection of the single photon is obtained based on the coherent resonance and the existence of the photonic bound states. Based on these characteristics, it is a feasible scheme to generate a Fano-typed router and it could be useful for designing the single-photon devices.

Realization of a Strongly Interacting Fermi Gas of Dipolar Atoms.

We realize a two-component dipolar Fermi gas with tunable interactions, using erbium atoms. Employing a lattice-protection technique, we selectively prepare deeply degenerate mixtures of the two lowest spin states and perform high-resolution Feshbach spectroscopy in an optical dipole trap. We identify a comparatively broad Feshbach resonance and map the interspin scattering length in its vicinity. The Fermi mixture shows a remarkable collisional stability in the strongly interacting regime, providing a first step towards studies of superfluid pairing, crossing from Cooper pairs to bound molecules, in presence of dipole-dipole interactions.

Computer simulations of equilibrium magnetization and microstructure in magnetic fluids

In this work, Monte Carlo and Brownian Dynamics simulations are developed to compute the equilibrium magnetization of a magnetic fluid under action of a homogeneous applied magnetic field. The particles are free of inertia and modeled as hard spheres with the same diameters. Two different periodic boundary conditions are implemented: the minimum image method and Ewald summation technique by replicating a finite number of particles throughout the suspension volume. A comparison of the equilibrium magnetization resulting from the minimum image approach and Ewald sums is performed by using Monte Carlo simulations. The Monte Carlo simulations with minimum image and lattice sums are used to investigate suspension microstructure by computing the important radial pair-distribution function go(r), which measures the probability density of finding a second particle at a distance r from a reference particle. This function provides relevant information on structure formation and its anisotropy through the suspension. The numerical results of go(r) are compared with theoretical predictions based on quite a different approach in the absence of the field and dipole-dipole interactions. A very good quantitative agreement is found for a particle volume fraction of 0.15, providing a validation of the present simulations. In general, the investigated suspensions are dominated by structures like dimmer and trimmer chains with trimmers having probability to form an order of magnitude lower than dimmers. Using Monte Carlo with lattice sums, the density distribution function g2(r) is also examined. Whenever this function is different from zero, it indicates structure-anisotropy in the suspension. The dependence of the equilibrium magnetization on the applied field, the magnetic particle volume fraction, and the magnitude of the dipole-dipole magnetic interactions for both boundary conditions are explored in this work. Results show that at dilute regimes and with moderate dipole-dipole interactions, the standard method of minimum image is both accurate and computationally efficient. Otherwise, lattice sums of magnetic particle interactions are required to accelerate convergence of the equilibrium magnetization. The accuracy of the numerical code is also quantitatively verified by comparing the magnetization obtained from numerical results with asymptotic predictions of high order in the particle volume fraction, in the presence of dipole-dipole interactions. In addition, Brownian Dynamics simulations are used in order to examine magnetization relaxation of a ferrofluid and to calculate the magnetic relaxation time as a function of the magnetic particle interaction strength for a given particle volume fraction and a non-dimensional applied field. The simulations of magnetization relaxation have shown the existence of a critical value of the dipole-dipole interaction parameter. For strength of the interactions below the critical value at a given particle volume fraction, the magnetic relaxation time is close to the Brownian relaxation time and the suspension has no appreciable memory. On the other hand, for strength of dipole interactions beyond its critical value, the relaxation time increases exponentially with the strength of dipole-dipole interaction. Although we have considered equilibrium conditions, the obtained results have far-reaching implications for the analysis of magnetic suspensions under external flow.

Control of fluorescence in quantum emitter and metallic nanoshell hybrids for medical applications

We study the light emission from a quantum emitter and double metallic nanoshell hybrid systems. Quantum emitters act as local sources which transmit their light efficiently due to a double nanoshell near field. The double nanoshell consists of a dielectric core and two outer nanoshells. The first nanoshell is made of a metal, and the second spacer nanoshell is made of a dielectric material or human serum albumin. We have calculated the fluorescence emission for a quantum emitter-double nanoshell hybrid when it is injected in an animal or a human body. Surface plasmon polariton resonances in the double nanoshell are calculated using Maxwell's equations in the quasi-static approximation, and the fluorescence emission is evaluated using the density matrix method in the presence of dipole-dipole interactions. We have compared our theory with two fluorescence experiments in hybrid systems in which the quantum emitter is Indocyanine Green or infrared fluorescent molecules. The outer spacer nanoshell of double metallic nanoshells consists of silica and human serum albumin with variable thicknesses. Our theory explains the enhancement of fluorescence spectra in both experiments. We find that the thickness of the spacer nanoshell layer increases the enhancement when the fluorescence decreases. The enhancement of the fluorescence depends on the type of quantum emitter, spacer layer, and double nanoshell. We also found that the peak of the fluorescence spectrum can be shifted by changing the shape and the size of the nanoshell. The fluorescence spectra can be switched from one peak to two peaks by removing the degeneracy of excitonic states in the quantum emitter. Hence, using these properties, one can use these hybrids as sensing and switching devices for applications in medicine.

Photoluminescence Quenching in Quantum Emitter, Metallic Nanoparticle, and Graphene Hybrids

We have developed a theory for photoluminescence quenching and plasmonic properties in hybrid nanosystems made from three nanosystems such as a quantum emitters, metallic nanoparticles, and graphene. The metallic nanoparticles and graphene have surface plasmons which couple with probe photons and create surface plasmon polaritons. Therefore, the excitons in the quantum emitters interact with surface plasmon polaritons via the dipole-dipole interaction. Due to this interaction, energy is exchanged between the nanosystems. The second quantized formulation and the quantum density matrix method have been used to calculate photoluminescence and the radiative and non-radiative decay processes in the presence of dipole-dipole interaction. We have compared our theory with experiments of two and three nanosystems, and a good agreement between theory and experiments is achieved. It has been found that the photoluminescence quenching in hybrid systems not only occurs through the direct non-radiative energy transfer from the quantum emitter to the metal nanoparticle and to graphene but also occurs through the indirect non-radiative energy transfer from quantum emitter to the metal nanoparticle via graphene and from the quantum emitter to graphene via metal nanoparticle. These are interesting findings and they can be used to fabricate nanoswitches and nanosensors for medical applications.

Locally gauge-invariant spin response ofHe3−Bfilms with Majorana surface states

A locally gauge-invariant theory of the spin response of a thin film of $^3$He-$B$ film is given that describes fluctuation effects arising from the coupled dynamics of the superconducting order parameter (the collective mode) and in-gap Majorana surface states. In contrast to a mean-field calculation of the spin response, which predicts a nonzero imaginary longitudinal spin susceptibility at frequencies inside the bulk gap due to absorption from the Majorana states, our gauge-invariant theory shows that this response is strongly suppressed above the collective mode frequency and vanishes if dipole-dipole interactions are neglected. In the presence of dipole-dipole interactions, in sufficiently thin films, and at ultra-low temperatures, the Majorana states lead to a distinctive magnetic-field- and temperature-dependent damping of the collective mode, a feature that may be observable in longitudinal NMR experiments.

Observation of suppression of light scattering induced by dipole-dipole interactions in a cold-atom ensemble.

We study the emergence of collective scattering in the presence of dipole-dipole interactions when we illuminate a cold cloud of rubidium atoms with a near-resonant and weak intensity laser. The size of the atomic sample is comparable to the wavelength of light. When we gradually increase the number of atoms from 1 to ~450, we observe a broadening of the line, a small redshift and, consistently with these, a strong suppression of the scattered light with respect to the noninteracting atom case. We compare our data to numerical simulations of the optical response, which include the internal level structure of the atoms.

Competition Effects in Presence of Dipole-dipole Interaction in Two Atom Systems: A Steady State Analysis

Competition Effects in Presence of Dipole-dipole Interaction in Two Atom Systems: A Steady State Analysis

Magnetic interactions in an ensemble of cubic nanoparticles: A Monte Carlo study

The ensemble of spatially disordered and randomly oriented spherical monodispersed single-domain magnetic nanoparticles with cubic anisotropy was studied by the Monte Carlo method. In the presence of dipole-dipole interactions, the effect of both particle volume and interparticle separation was investigated with respect to the characteristic parameters of hysteresis loops and zero field cooled and field cooled magnetization curves. The coercive field and remanent magnetic moment were shown to depend strongly on the dimensionless parameter $\ensuremath{\beta}={k}_{B}T/({K}_{1}V)$ ($T$ temperature, $V$ particle volume, ${K}_{1}$ cubic anisotropy constant). It was revealed that strong dipole-dipole interactions suppress both the coercive field and the remanent magnetic moment of densely packed nanoparticles. Yet, the effect quickly diminishes with the increasing interparticle distances and becomes rather insignificant for separations exceeding three particle diameters. The blocking temperature was found to be weakly affected by dipolar interactions, but mainly governed via $\ensuremath{\beta}$, i.e., by the nanoparticle volume and the strength of crystalline anisotropy. The role of dipole-dipole interactions on magnetic properties of nanoparticles was further elucidated by a comparison of the simulation results for a single cluster with an infinite periodic arrangement of such clusters.

Angular and linear momentum of excited ferromagnets

The angular momentum vector of a Heisenberg ferromagnet with isotropic exchange interaction is conserved, while under uniaxial crystalline anisotropy the projection of the total spin along the easy axis is a constant of motion. Using Noether's theorem, we prove that these conservation laws persist in the presence of dipole-dipole interactions. However, spin and orbital angular momentum are not conserved separately. We also define the linear momentum of ferromagnetic textures. We illustrate the general principles with special reference to the spin transfer torques and identify the emergence of a non-adiabatic effective field acting on domain walls in ferromagnetic insulators.

Phase transitions in dipolar spin-1Bose gases

We study phase transitions in homogeneous spin-1 Bose gases in the presence of long-range magnetic dipole-dipole interactions (DDI). We concentrate on three-dimensional geometries and employ momentum shell renormalization group to study the possible instabilities caused by the dipole-dipole interaction. At the zero-temperature limit where quantum fluctuations prevail, we find the phase diagram to be unaffected by the dipole-dipole interaction. When the thermal fluctuations dominate, polar and ferromagnetic condensates with DDI become unstable and we discuss this crossover in detail. On the other hand, the spin-singlet condensate remains stable in the presence of dipole-dipole interactions.

3,3′-(Ethane-1,2-diyl)bis(2-thioxo-1,3-oxazolidin-4-one)

The asymmetric unit of the title compound, C8H8N2O4S2, contains one half of a centrosymmetric mol­ecule. A short C⋯O distance of 3.012 (4) Å between the carbonyl groups of neighbouring mol­ecules indicates the presence of dipole–dipole inter­actions. The crystal packing exhibits also weak inter­molecular O⋯S [3.239 (3) Å] and C—H⋯O inter­actions.

Controlling spontaneous emission in photonic-band-gap materials doped with nanoparticles

The phenomenon of spontaneous emission cancellation has been investigated in photonic-band-gap materials in the presence of dipole-dipole interaction. The material is densely doped with an ensemble of five-level nanoparticles. The mean field theory is used to calculate the effect of the dipole-dipole interaction whereas the linear response theory is used to calculate the expressions for the real and imaginary susceptibilities. Numerical simulations are performed for an isotropic photonic-band-gap material. Interesting results are predicted such as the control of the spontaneous emission cancellation by moving the resonance energies between the energy band and energy gap. It is also found that the photonic-band-gap material can be switched between absorptive and nonabsorptive states by changing the strength of the dipole-dipole interaction and the resonance energies in the energy band.