Detachment faults play a crucial role in accommodating crustal thinning and controlling basin architecture in extensional tectonic settings. This study focuses on the characterization of extensional structures at the Necking Domain of the central Campos Rifted Margin, southeast Brazil. Based on seismic reflection and magnetic data we interpreted a system of long offset detachment faults, here named as the Marlim Detachment System. This system is characterized by three distinct large-displacement detachment faults which systematically root at subhorizontal intracrustal reflectors, interpreted as middle crust ductile shear zones, indicating a depth-dependent accommodation of extensional strain. The detachment fault systems resulted in highly tilted upper crustal blocks, which lead to intense erosion of the footwall and the pre-salt sequences eastward. The large horizontal displacement of the hanging wall blocks by most of the detachment faults created deep and wide half-grabens resulting in thick syn-rift sedimentary wedges. The basement structural framework seems to reflect a northward strike-rotation from NE-to NS-direction of the fault systems. That rotation promoted the segmentation of the Marlim Detachment System and points out an oblique-slip extensional kinematics during rifting. We propose that the observed tectonic style at the Necking Domain of central Campos is the result of its interaction with the Vitória-Colatina Transfer Zone to the north and the Araruama Transfer Zone to the south, configuring the Marlim area as a structurally transition zone. The tectonostratigraphic analysis suggests a migration of the deformation from continent to ocean from Hauterivian to Aptian, and a polyphase and/or tardi-tectonic deformation of the Necking Domain in the central Campos Rifted Margin.