Preparation Of Silicon Nanoparticles Research Articles

Photorenewable Azobenzene Polymer Brush-Modified Nanoadsorbent for Selective Adsorption of LDL in Serum

The elevated concentration of low-density lipoprotein (LDL) is recognized as a leading factor of hyperlipidemia (HLP), and selective adsorption of serum LDL is regarded as a practical therapy. Based on the superior structure-function characteristics of stimuli-responsive materials, a photorenewable nanoadsorbent (SiO2@Azo@Gly) with high selectivity and reusability was developed using azobenzene as the functional ligand. Its principle was certified by the preparation of silicon nanoparticles with atom transfer radical polymerization (ATRP)-initiating groups via a sol-gel reaction and their subsequent grafting of azobenzene polymer brushes by surface-initiated ATRP, followed by modification with glycine. Immobilization of carboxylated azobenzene polymer brushes onto the nanoparticles endowed SiO2@Azo@Gly with high adsorption selectivity and reusability. The advanced nanoadsorbent exhibited excellent LDL adsorption capacity at about 27 mg/g and could be regenerated by illumination with high efficiency (circulations ≥ 5); this was further verified by transmission electron microscopy (TEM) and Fourier-transform infrared (FTIR) analysis. SiO2@Azo@Gly also demonstrated superior adsorption efficiency and selectivity in serum from HLP patients, the respective adsorption capacities of LDL, triglyceride, and total cholesterol were about 15.65, 24.48, and 28.36 mg/g, and the adsorption to high-density lipoprotein (cardioprotective effect) was only about 3.66 mg/g. Green regeneration of the nanoadsorbent could be achieved completely through a simple photoregeneration process, and the recovery rate was still 97.9% after five regeneration experiments.

Effect of Methane Injection Methods on the Preparation of Silicon Nanoparticles with Carbon Coating in Induction Thermal Plasma

Effect of Methane Injection Methods on the Preparation of Silicon Nanoparticles with Carbon Coating in Induction Thermal Plasma

Preparation of Silicon Nanoparticles by Pyrolysis of Organosilicon Compounds inside the Porous Carbon

To increase the capacity of the negative electrode for lithium-ion secondary batteries, we prepared Si-containing carbon microspheres. The target compound was obtained by thermal decomposition of hexaphenyldisilane embedded in porous carbon particles that contained Si-nanoparticles characterized by various methods. When charging/discharging characteristics were evaluated using a cell having the obtained material as a negative electrode, a remarkable improvement in charging characteristics was observed.

Preparation of Silicon Nanoparticles by Pulse Erosion and Analysis with Molecule Dynamic Simulation

Preparation of Silicon Nanoparticles by Pulse Erosion and Analysis with Molecule Dynamic Simulation

Anaerobic vs. aerobic preparation of silicon nanoparticles by stirred media milling. The effects of dioxygen, milling solvent, and milling time on particle size, surface area, crystallinity, surface/near-surface composition, and reactivity

Silicon nanoparticles milled anaerobically in heptane or mesitylene are smaller and much more reactive than SiNPs milled aerobically in the same solvents for equal attritor milling times.

Dynamics analysis of cavitation disintegration of microparticles during nanopowder preparation in a new Water Jet Mill (WJM) device

A physical analysis of cavitation-based implosive breakage of solid particles focusing on practical application during fine particle disintegration in a liquid suspension is submitted in the present paper. The physical source of the cavitation dynamics phenomena involved is an extreme velocity gradient induced by an ultrahigh-energy liquid jet mixing together with a slow liquid suspension of milled particles. Extreme tensile stresses occurring at velocity gradients over 1000 ms −1mm −1 at the operating temperature of 65 °C generates high-intensity pure vapor cavitation in the degassed water dispersion with extreme values of impact pressure in the final of bubble implosions on particle surfaces. Preparation of silicon nanoparticles with median diameter approximately 148 nm using a newly developed “Water Jet Mill” (WJM) device is demonstrated in the present article as an example of application of the aforementioned disintegration method as well as of theoretical analysis of this method. The disintegration method is characterized by a high potential for milling of submicron particles with high efficiency.