The variation characteristics of rain storms (RSs) are closely related to complex internal physical processes and external dynamic and thermodynamic conditions. Using a 17-year observational rainfall dataset from the Tropical Rainfall Measuring Mission (TRMM) Precipitation Radar (PR), the diurnal cycles of various RS characteristics and their responses to the South China Sea Summer Monsoon (SCSSM) are investigated in South China (SC) during the presummer rainy season (PSRS). Before SCSSM outbreaks, the RSs in the western inland region of SC (WSC) have stronger precipitation intensities and convective features due to orographic lifting, especially at night, while those in the eastern inland region of SC (ESC) have higher RS occurrence frequencies with higher moisture transport, especially in the afternoon. The onset of the SCSSM leads to abundant moisture and sufficient convective available potential energy over the entire SC area, resulting in significant increases in the occurrence frequency, convective fraction, and precipitation top height of RSs. In the WSC, the weakened upward motion and smaller convective inhibition limit RS development, resulting in weaker rainfall intensity. In the ESC, a particularly unstable atmosphere and enhanced low-level moisture transport in the afternoon lead to a larger three-dimensional size, more active convection, and greater precipitation intensity in the RSs. These results offer fresh insight into the diurnal variation in rainfall during the PSRS and can be effectively used to evaluate numerical model simulations.