Precambrian Metamorphic Basement Research Articles

Metallogenic Difference between the Late Aptian Nansu and Aishan Pluton in Jiaodong: Constraints from in Situ Apatite Elemental and Nd Isotopic Composition

A series of Mo-polymetallic deposits have been developed in the Jiaodong Peninsula. Notably, these Mo-dominant deposits formed essentially during the same period as the well-known world-class Au deposits in this area, hinting at a potentially unique geological correlation between them. Therefore, conducting thorough research on Mo deposits in Jiaodong holds significant importance in exploring the area’s controlling factors of Mesozoic metal endowments. To reveal the petrogenesis and metallogenic potentials of Mo-fertile and ore-barren granitoid, apatite grains from the Late Aptian Nansu granodiorite and Aishan monzogranite are investigated in this study. Detailed petrographical observations, combined with in situ analysis of electron probe micro-analyzer (EPMA) and Laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), have been conducted on apatite grains from the Nansu and Aishan plutons. This comprehensive analysis, encompassing both major and trace elements as well as isotopic characteristics of apatite, aims to elucidate the metallogenic differences within the late Early Cretaceous granitoids of Jiaodong. The results reveal that the apatite grains across all samples belong to fluorapatites, suggesting their magmatic origin. Additionally, chondrite-normalized rare earth element (REE) patterns of apatites in ore-fertile and ore-barren granitoids exhibit a “right-leaning” trend, characterized by relative enrichments in light REEs and depletions in heavy REEs. Both the Nansu and Aishan plutons exhibit moderately negative Eu anomalies (with averages δEu values of 0.44 and 0.51, respectively), along with slightly positive Ce anomalies (averaging δCe values of 1.08 and 1.11, respectively). A negative correlation is observed between their δEu and δCe values, indicating that the parental magmas of ore-fertile and ore-barren granitoids were formed in a relatively oxidizing environment. The calculated apatite OH contents for the Nansu pluton range from 0.26 to 1.38, while those for the Aishan pluton vary between 0.24 and 1.51, indicating comparable melt H2O abundances. Consequently, the results suggest that neither the oxygen fugacities nor the water contents of the parental magma can account for the metallogenic differences between Nansu and Aishan plutons. The apatite in the Nansu pluton exhibits a higher Ce/Pb ratio and a relatively lower Th/U ratio, indicating the involvement of a greater volume of fluids in the magmatic evolution process of this ore-bearing granitoid. Apatite grains sourced from the Nansu and Aishan plutons exhibit εNd(t) values ranging from −16.63 to −17.61 (t = 115.7 Ma) and −17.86 to −20.86 (t = 116.8 Ma), respectively. These results suggest that their parental magmas primarily originated from the partial melting of Precambrian metamorphic basement rocks within the North China Craton, with a minor contribution from mantle-derived materials. Additionally, the presence of mafic microgranular enclaves in both the Nansu and Aishan plutons indicates that both have undergone magma mixing processes. The binary diagrams plotting the ratios of Ba/Th, Sr/Th, and U/Th against La/Sm demonstrate that apatite grains of ore-fertile granitoid exhibit a distinct trend towards sediment melting. This suggests the potential incorporation of sedimentary materials, particularly those rich in molybdenum, into the magmatic source of the Nansu pluton, ultimately leading to the occurrence of molybdenum mineralization.

Devonian continental arc magmatism in the southern Central Asian Orogenic Belt: Evidence from the Dunhuang Block, NW China

Reconstruction of periods and sources of continental arc magmatism provides critical insights for deciphering the thermal evolution and geodynamics of the continental lithosphere and unveiling subduction-related episodes of accretion and orogeny. The Dunhuang Block, located in the southern Central Asian Orogenic Belt, is built upon a Precambrian metamorphic crystalline basement that is intruded by numerous Paleozoic granitoids. In this paper, we present new zircon U-Pb ages, whole-rock geochemistry and Sr-Nd-Pb-Hf isotopes from the Hanxiakouzi and Shuangta granodiorite plutons outcropped in the central and northern Dunhuang Block, respectively. The U-Pb zircon dating indicate that the Hanxiakouzi and Shuangta granodiorites were emplaced at ca. 366–363 Ma, i.e., in the late Devonian. Geochemically, the Hanxiakouzi granodiorites are medium- to high-K, I-type granites possessing high Sr and Sr/Y, i.e., similar to adakites. The Hanxiakouzi granodiorites show negative εNd(t) values (−8.2 to −6.6), significant positive εHf(t) values (+0.7 to +8.1), and evolved Pb isotope features suggesting their derivation by melting of subducted terrigenous sediments, interaction of melts with mantle peridotite, and assimilation of ancient crust during magma ascent. The Shuangta granodiorites belong to high-K calc-alkaline I-type granites with medium Sr and low Sr/Y. The Shuangta granodiorites yield negative εNd(t) values (−2.9 to −3.1) and negative to positive zircon εHf(t) values (−1.8 to +3.6), suggesting their formation by partial melting of ancient mafic crust with addition of minor mantle-derived melt and subducted terrigenous sediments. In general, Hf-in-zircon isotopes characteristics of the late Paleozoic granitic rocks in the Dunhuang Block indicate that the southern Dunhuang area carries more ancient crust materials than the central and northern Dunhuang areas, indicating a lateral heterogeneity of the middle Paleozoic crust. Conclusively, the middle Paleozoic granitoids of the Dunhuang Block were emplaced at an active continental margin of the southern Paleo-Asian Ocean.

Zircon U–Pb ages and Hf–O isotopes of Xiaomasa Miocene granite in the Ximeng area, western Yunnan, southwest China: Constraints on petrogenesis and tectonic setting

Characteristic granites of the East Tethyan Tectonic Domain (ETTD) are primarily exposed along the Himalayan orogenic belt and Gangdese batholith in the north, extend from western Yunnan in the centre, and through the Burma batholith to Peninsular Malaysia in the south. Western Yunnan is an important part of the ETTD magmatic arc, featuring characteristic granites that mainly developed between the Jurassic and Paleogene. Nonetheless, compared to other regions of the ETTD, Miocene magmatism has been poorly documented in western Yunnan. The Xiaomasa granite occurs in the Ximeng area of western Yunnan. In this study, we present U–Pb ages, and Hf–O isotope data for zircon crystals from the Xiaomasa granite pluton. Laser Ablation–Multicollector–Inductively Coupled Plasma–Mass Spectrometry (LA–MC–ICP–MS) zircon U–Pb dating yields precise emplacement ages of 15.8–16.1 Ma for the Xiaomasa granite, indicating that Miocene granitic magmatism occurred in western Yunnan. Zircons from the Xiaomasa granite have negative εHf(t) values ranging from −6.6 to −11.6, relatively high δ18O values (6.8%–10.2‰), and two‐stage Hf isotopic model ages (1.51–1.83 Ga). Zircon Hf–O isotopic characteristics indicate that the Xiaomasa granite was mainly derived from partial melting of ancient continental crust. The Ximeng Precambrian metamorphic basement is a probable material source for the granite. The Xiaomasa granite was probably produced by partial melting of the thickened Ximeng ancient metamorphic basement under a reduced pressure environment, reflecting a cumulative effect of the escape of Sundaland caused by the dynamics of the continuous India–Asia collision.

Three-Dimensional Lithospheric Electrical Structure beneath the Handan-Xingtai District, North China: Implications for Tectonic Control of Skarn-Iron Mineralization

In this study, we determined the lithospheric electrical structure beneath the Handan-Xingtai district and its adjacent regions using magnetotelluric sounding data. To the west of the Handan-Xingtai district, the crust and upper mantle beneath the Taihang Mountains are mainly characterized by high resistivity (>1000 Ωm, which we interpreted to be the relic cratonic lithosphere. In contrast, the lithosphere beneath the North China Plain to the east shows high-conductivity features (<100 Ωm) overall, which may indicate that it has suffered significant modifications. Additionally, other geological and geophysical studies suggested that this district was located in a significant boundary zone where the lithospheric thickness, temperature and geochemistry properties sharply changed. Combined with our resistivity model, we attributed this to the different degrees of lithospheric modification. Specifically, since the late Mesozoic, the subduction, roll-back and dehydration of the Pacific slab caused an unsteady asthenospheric flow and upwelling; therefore, the deep-derived melts and fluids concentrated within the uppermost mantle had even underplated or intruded into the crust, while this process had a negligible effect on the Taihang Mountains. Small-scale mantle convection and upwelling are likely to occur in this kind of transfer zone of lithospherice properties, leading to mantle-derived melts and fluids transporting upwardly near the surface, which was confirmed by the significantly enhanced conductivity beneath the ore district in our resistivity model. During this process, Fe derived from mantle-source magma or relic Precambrian metamorphic basement beneath the Taihang Mountains was extracted and emplaced along with the Yanshanian magmatism.

Paleozoic tectonic setting and evolution of the Central Tianshan Block: Insights from Devonian arc-related granitoids

• Distinct Devonian arc-related granitoids record three phases of magmatism . • Devonian granitoids were derived from remelting of Mesoproterozoic rocks with addition of mantle and juvenile crustal components. • The Central Tianshan Block was a continental arc during the Paleozoic bipolar subduction of the Kangguer oceanic slabs. The Central Tianshan Block of the Central Asian Orogenic Belt (CAOB) contains Precambrian metamorphic basement and voluminous Paleozoic granitoids, but its Paleozoic tectonic setting remains debated. This study presents new geochronological and geochemical data for the granitoids in the Shuangqing district in combination with published data from the Central Tianshan Block to constrain the tectonic setting and evolution of the Central Tianshan Block. Zircon U–Pb dating of the different granitoid plutons identified three phases of magmatism, a foliated granite (408.9 ± 2.6 Ma), a K-feldspar granite (397.7 ± 2.5 Ma), and a granodiorite (porphyry) (ca. 390–388 Ma). These Devonian granitoids show medium- to high-K calc-alkaline affinities, large ion lithophile elements (LILE; e.g., Rb and Ba) enrichment, and high field strength elements (HFSE; e.g., Nb, Ta, and Ti) and Eu depletion, consistent with subduction-related I-type granitoids. They have negative ε Nd (t) values (−5.2 to −3.4), old zircon T DM C ages (1623–1036 Ma), and variable zircon ε Hf (t) values (−3.54 to +5.70), indicating they were mainly sourced from remelting of Mesoproterozoic rocks with variable incorporation of mantle and juvenile crustal components in their magma sources. Combining with published data and this study, we suggest the Central Tianshan Block was a continental arc in the Ordovician to Carboniferous during the bipolar subduction of the Kangguer oceanic slabs. During the Devonian, the subduction of the Kangguer oceanic slabs formed the Central Tianshan continental arc to the south, accompanied by emplacement of multiphase arc-related granitoids in the Shuangqing district.

Multiple episodes of early Precambrian magmatism and tectonism in the Tarim Craton: A North China connection

The accretion and recycling of Archean-Paleoproterozoic continental crust is the key to understanding the formation and evolution of early continental crust. Early Precambrian metamorphic basement is well developed in the Aktashtagh area, southeastern margin of the Tarim Craton, northwestern China. We report zircon SHRIMP UPb dating, LA-MC-ICP-MS LuHf isotopic analysis and whole-rock geochemical analysis on 16 samples (mainly TTG, tonalite-trondhjemite-granodiorite) from Aktashtagh. Multiple episodes of early Precambrain magmatism, including 3.72 Ga, 3.63 Ga, 3.10 Ga, 2.83–2.69 Ga, 2.55–2.50 Ga, 2.05–2.02 Ga and 1.93–1.82 Ga events, have been identified in the Aktashtagh region. The most intense magmatism occurred in the late Mesoarchean to early Neoarchean. Significantly, 3.63 Ga and 3.10 Ga TTG rocks are identified, together with more extensive 2.8–2.7 Ga and ∼ 2.5 Ga TTG rocks. The TTG suites are dominated by tonalitic, with some trondhjemitic and grandioritic rocks. They show large variations in REE contents, are mainly distributed in the high- and medium-pressure fields in the Sr/Y-Y and La/Yb-Yb diagrams, and the 2.7 Ga TTG rocks commonly show higher and more variable Sr/Y and La/Yb ratios. The 3.63–3.10 Ga TTG rocks have magmatic zircon εHf(t) values of −3.9 to +3.1 and tDM1(Hf) model ages of 3.9–3.6 Ga, whereas the ∼2.7–2.51 Ga TTG rocks have magmatic zircon εHf(t) values of −13.4 to +2.1 and tDM1(Hf) model ages of 3.3–3.0 Ga. The ∼2.7 to ∼2.0 Ga meta-gabbroic-dioritic rocks have magmatic zircon εHf(t) values of −19.7 to +0.6 and tDM1(Hf) model ages of 3.2–2.4 Ga. Metamorphic zircon ages of 3.56 Ga, 2.75–2.73 Ga, 2.53–2.51 Ga, 2.03–1.96 Ga and ∼ 1.85 Ga are also recorded, whereas ∼2.83 Ga, 2.53–2.40 Ga, 2.05–2.02 Ga and 1.86–1.83 Ga crustally-derived K-rich granites are identified, with the most important occurring in the late Neoarchean and late Paleoproterozoic. In this regard, the Tarim Craton is similar to the North China Craton in its early Precambrian geological evolution. The main difference is that the Paleoproterozoic tectonothermal event in the Tarim Craton started as early as 2.00 Ga, whereas in the North China Craton it occurred between 1.95 and 1.80 Ga.

Precambrian Tectonic Evolution of Southern Kongling Terrane, Yangtze Craton: Constraint From the Detrital Zircon U‐Pb Geochronology of the Metasedimentary Rocks

AbstractThe Kongling terrane (Huangling dome) outcrops Precambrian metamorphic basement of the Yangtze craton. However, the Precambrian tectonic evolution of the southern Kongling terrane remains poorly constrained. In this contribution, we report zircon geochronology of the metasedimentary rocks from southern Kongling terrane of the Yangtze craton. Zircon U‐Pb dating results yielded magmatic age clusters at ca. 3,000 Ma, ca. 1,520 Ma, ca. 1,150 Ma, ca. 860 Ma, 900–920 Ma, and 980 Ma, and metamorphic age at ca. 2,900 Ma. These data display that the southern Kongling terrane witnessed Mesoarchean magmatism and metamorphic event, Mesoproterozoic and Neoproterozoic magmatism. In combination with previous studies, it is proposed that the Precambrian metamorphic basement of the Yangtze craton was amalgamated by the multi‐stage subduction‐collision processes at ca. 3,000–2,900 Ma, ca. 2,000–1,800 Ma, and ca. 1,100–940 Ma. In addition, the Proterozoic processes were related to the assembly and breakup of Columbia and Rodinia supercontinents.

Genesis of the Jiudian gold deposit, Jiaodong Peninsula, eastern China: Fluid inclusion and C[sbnd]H[sbnd]O–Pb isotope constraints

The Jiudian large-size gold deposit occurs as quartz veins in the footwall of the ZhaoPing Fault, and belongs to the southern section of the ZhaoPing metallogenic belt in Jiaodong Peninsula, eastern China. This study presents new fluid inclusion, geochemical, stable isotopic, and mineralogical data that provide insights into the sources of the ore metals, the temperature of mineralization, and the nature of the fluids involved in four different ore-forming stages. Cathodoluminescence imaging indicates four stages of quartz: the early-stage euhedral quartz that unrelates to mineralization and contains small-size fluid inclusions (Qz-1), the quartz containing abundant fluid inclusions and coexisting with pyrite (Qz-2 and Qz-3), and the late-stage quartz occurring as sulfide-barren veinlets crosscutting previous veins or mineral assemblages (Qz-4). Fluid inclusions include three types: H2O–CO2 ± CH4 (Type 1), two-phase aqueous inclusions (Type 2), and liquid aqueous inclusions (type 3). Fluid inclusions in Qz-1 are dominated by type 1, but in Qz-4 are only type 3; whilst Qz-2 and Qz-3 contain all three types fluid inclusions. Type 1 inclusions comprise three phases (liquid H2O + liquid CO2 + vapor CO2), with two carbonic phase ratios cluster at 10 %–30 % and 60 %–90 %. Type 2 inclusions also comprise two types, with vapor/liquid ratios focusing at 10 %–40 % and 60 %–80 %, respectively. All the fluid inclusions have homogenization temperatures of 198.5–329.2 °C, salinities of 3.95–12.39 wt% NaCl equivalent, and densities of 0.72–0.96 g/cm3. The quartz of main mineralization stages recorded the highest salinity, although the density of the fluids did not change markedly over time. These fluid inclusion data indicate that the Jiudian deposit has been formed from a mesothermal fluid system enriched in CO2 and CH4, and genetically belongs to the orogenic-type. The C, H, O and Pb isotopic data indicate that the ore-forming metals and fluids were mainly sourced from Precambrian metamorphic basement and Mesozoic granites, with a small contribution from the mantle. This suggests that the Early Precambrian host-rocks significantly contributed metals to the ore-forming system. Therefore, a new genetic model for the Jiudian gold deposit is proposed to incorporate the Early Precambrian basement, Mesozoic intrusive rocks and ZhaoPing fault system.

New constraints for crustal sulfur contamination of gold source: Evidence from complex δ34S of pyrite in the northwestern Jiaodong gold province, China

The formation processes of the complex δ34S variations for the Jiaodong-type gold deposits are still equivocal, which cannot give a robust identification for the sulfur sources, by inference, Au sources. The δ34S and trace elements of ore-related pyrite collected from the northwestern Jiaodong gold province (Jiaojia and Sanshandao-Xinli goldfields) are analyzed by in-situ methods, to reveal more clues for understanding the complex δ34S variations and ore material sources. Gold deposits in the northwestern Jiaodong contain quartz-Au-pyrite (Py-a) stage (III) and quartz-Au-pyrite (Py-b)-polymetallic stage (IV). In the Jiaojia goldfield, Py-a has a δ34S range of 9.9–24.4‰, whereas Py-b has a δ34S range of 7.3–9.3‰. In the Sanshandao-Xinli goldfield, Py-a has a δ34S range of 6.9–34.7‰, and δ34S of Py-b ranges in 0.2–19.2‰. Single-point and mapping analyses show that As-Au-Co-Ni contents have considerable variations in Py-a and Py-b. The δ34S and As-Au-Co-Ni contents in Py-a and Py-b show diverse correlations. Equilibrium and Rayleigh (or sulfidation) fractionations cannot account for the large δ34S variation due to the pyrite-chalcopyrite-pyrrhotite buffer. The rapid decompression with oxidization of ore-forming fluids by immiscibility can only result in the δ34S decrease, rather than increase to 14.0–34.7‰ from the concentrated δ34S range of 9.6–13.4‰ in Py-a and Py-b. Therefore, the analyzed δ34S values in the ore-related pyrites should represent those of ore-forming fluids. Considering the simple physicochemical processes cannot reconcile the complex matches between large δ34S variations and As-Au-Co-Ni contents, it is suggested the As-rich and Au-As-rich ore-forming fluids with large δ34S range and variable Co-Ni concentrations should flow into mineralization sites during stages III and IV in the Sanshandao-Xinli goldfield. The sulfur with large δ34S range and Au-As-Co-Ni elements with variable contents in the ore-related pyrites of the Jiaojia and Sanshandao-Xinli goldfields were most likely inherited from the sedimentary sulfides that were reduced from seawater sulfates, by comparisons with those in the typical sedimentary, metamorphic hydrothermal and magmatic hydrothermal pyrites. Combining with previous researches for the ore-forming materials sources of the Jiaodong-type gold deposits, the metamorphic Precambrian rocks, especially those metasedimentary rocks containing sulfides reduced from seawater sulfates, can be considered as the feasible ore-forming materials sources for the large δ34S range and variable trace elements in the Jiaojia and Sanshandao-Xinli goldfields. Through the δ34S comparison for the Jiaodong-type gold deposits, we propose an important process that the single-sourced ore-forming fluids, which were initially derived from the metasomatized lithospheric mantle, have extracted the ore materials (including sulfur-Au-As elements) from the metamorphic Precambrian rocks (possible Precambrian metamorphic basement in the Jiaodong gold province or the subducted Late Neoproterozoic rocks of the YC), and mixed heterogeneously to precipitate pyrites with complex δ34S and trace elements throughout the Jiaodong-type gold deposits.

Trace element and S-Pb isotopic compositions of pyrite from the Precambrian metamorphic rocks and their derivative pegmatites in the Xiaoqinling district, southern North China Craton: Implications for possible gold source of the Early Cretaceous gold deposits

The North China Craton is well endowed with numerous Early Cretaceous gold deposits that are mainly hosted in Archean to early Paleoproterozoic metamorphic rocks and late Mesozoic granitoid intrusions intruding the former. Whether or not gold was sourced from those metamorphic rocks remains hotly debated. Here we present trace element and S-Pb isotope data of pyrite from the Neoarchean to early Paleoproterozoic metamorphic rocks in the Xiaoqinling district of southern North China Craton and late Paleoproterozoic pegmatites derived from the former rocks, in an attempt to provide new insights into the gold sources for Early Cretaceous gold lodes genesis in this district. Pyrite from the metamorphic rocks typically occurs as inclusions in rock-forming minerals or disseminated grains roughly distributed along the foliation of the rocks, whereas pyrite from the pegmatites usually occurs as disseminations closely associated with quartz and magnetite. The textural data suggest that pyrite in the metamorphic rocks and pegmatites are of metamorphogenic and magmatogenic origins, respectively. LA-ICP-MS spot analyses show that pyrite both from the metamorphic rocks and pegmatites has Au contents mostly below the detection limit, with minor analyses revealing Au marginally higher than the detection limit. Considering that Au is moderately incompatible and highly siderophile, the very low gold contents in pyrite allow us to infer that the metamorphic rocks contain negligible gold. Pyrite grains from the metamorphic rocks and pegmatites have broadly consistent δ34S values ranging from −2.7 to 31.5 (mean = 17.6) per mil and 6.3 to 17.9 (mean = 14.3) per mil, respectively. Similarly, they have comparable, highly radiogenic lead isotopes, which are 16.859–24.889 for 206Pb/204Pb, 15.355–15.694 for 207Pb/204Pb, and 37.480–43.848 for 208Pb/204Pb. The sulfur and lead isotopes of pyrites from the metamorphic rocks and pegmatites are distinct from those of Early Cretaceous gold deposits hosted by these rocks. Taken together, the pyrite trace element and S-Pb isotope data presented here preclude the Precambrian metamorphic basement rocks as an important gold source for the extensive Early Cretaceous gold mineralization in the Xiaoqinling district and, by inference, other major Early Cretaceous gold provinces across the North China Craton.

Geochronology and structural deformation of Precambrian metamorphic basement in the eastern Jiangnan orogenic belt: constraints on the assembly time of the Yangtze and Cathaysia blocks

Geochronology and structural deformation of Precambrian metamorphic basement in the eastern Jiangnan orogenic belt: constraints on the assembly time of the Yangtze and Cathaysia blocks

Precambrian metamorphic basement of the southern Lhasa terrane, Tibet

The Precambrian basement of the Lhasa terrane provides important information for understanding the formation and evolution of the Tibetan Plateau. However, due to the paucity of exposure, the properties of the Precambrian basement of the Lhasa terrane remain poorly known. Here we report zircon U–Pb ages, bulk-rock geochemical and zircon Hf isotopic data on the orthogneisses in the Milin area of the southeastern Lhasa terrane, southern Tibet. Inherited magmatic zircon cores of these gneisses yield protolith crystalline ages of 1556–1517 Ma, whereas the zircon rims give metamorphic ages of 1197–1192 Ma, both could be local provenance for the Mesoproterozoic detrital zircons in the Neoproterozoic–Paleozoic strata in the Lhasa terrane. Geochemical data indicate that the protoliths of the Mesoproterozoic rocks are continental arc-like granitoids with bulk-rock εNd(t) values of −3.7 to +0.7 (TDM2 = 1.99–2.34 Ga) and zircon core εHf(t) values of +1.8 to +8.6 (TDM2 = 1.71–2.17 Ga), suggesting their most likely derivation from partial melting of Paleoproterozoic crustal materials. We propose that the Mesoproterozoic gneisses in the Milin area represent the Precambrian metamorphic basement of the Lhasa terrane, likely related to the growth of Columbia supercontinent. Local exposure of the Precambrian metamorphic basement may be caused by crustal rapid uplift and erosion in the late Cenozoic and their inhomogeneous distribution.

Geology, geochemistry and genesis of Keyue: A newly discovered Pb-Zn-Sb-Ag polymetallic deposit associated with magmatic center in Southern Tibet, China

The Keyue Pb-Zn-Sb-Ag polymetallic deposit is located within the North Himalayan Metallogenic Belt (NHMB). This study aims to clarify whether the Keyue deposit has close association in time and space with magmatism, and discuss the significance for further exploration. Orebodies are hosted by the Lower Jurassic Ridang Formation black carbonaceous slate and controlled by the NE-trending faults. Keyue is characterized by multiple stages of hydrothermal veins, including Mn-Fe Carbonate-sulfide (I), quartz-sulfide-sulfosalt mineral (II) and quartz-calcite-stibnite veins (III).Hydrothermal minerals contain six types of fluid inclusions, including H2O-rich bi-phase aqueous (type I), pure CO2 (type II), CO2-rich H2O-CO2-NaCl tri-phase (type III), H2O-rich H2O-CO2-NaCl tri-phase (type IV), halite-bearing tri-phase (type V) and halite-bearing H2O-CO2-NaCl multiphase inclusions (type VI). All six types of inclusions were observed in stage II quartz, whereas only types I and III inclusions in stage I siderite and sphalerite and type I inclusions in stage III quartz and calcite. Type I inclusions in stage I display total homogenization temperatures (Th, total) ranging from 250.1 to 289.3 °C, with salinities of 9.6–16.3 wt% NaCleq. Types I, III, IV and V inclusions in stage II yield Th, total of 175.5–282.7 °C, 188.8–286.3 °C, 214.3–287.5 °C and 198.3–266.0 °C, with corresponding salinities of 4.0–21.5 wt% NaCleq, 0.6–2.9 wt% NaCleq, 0.0–11.0 wt% NaCleq and 30.1–33.2 wt% NaCleq, respectively. Type I inclusions in stage III have Th,total values of 172.3–240.7 °C and salinities of 3.1–12.6 wt% NaCleq. Fluid phase separation occurred in stages I and II, resulting in CO2 and H2S release, pH increase and rapid Pb-Zn-Ag precipitation, whereas mixing of magmatic fluids and meteoric water in stage III caused the cooling, dilution and stibnite precipitation.Fluid inclusion analysis and C-H-O isotopic compositions indicate that the initial hydrothermal fluids were magmatic water, with increasing input of meteoric water with time. The δ34SCDT values of sulfides from three stages are similar and range from 4.8 to 10.3 ‰ (average 7.7 ‰), showing characteristics of mixture of magmatic and sedimentary sulfur. The Pb isotopic compositions of sulfides are closely consistent with those of Cenozoic leucogranite and Precambrian metamorphic crystalline basement in the NHMB, suggesting that the ore-forming metals were sourced from the hidden causative Himalayan leucogranite formed by the decompression melting of metamorphic crystalline domains.Combining evidence from geochronology, fluid inclusions, isotopes suggest that the Keyue Pb-Zn-Sb-Ag and Cuonadong W-Sn-Be mineralization at different locations around the Cuonadong Dome constitute an integrated magmatic-hydrothermal system, with the distal end-member Pb-Zn-Sb-Ag veins centered on the Cuonadong leucogranites-related W-Sn-Be mineralization. Pegmatite-skarn-type W-Sn-Be polymetallic mineralization may occur at deeper sites beneath the Keyue area, and the distal Pb-Zn-Sb-Ag veins controlled by faults within strata also need more attention around these leucogranite domes in the NHMB.

A new understanding of Demala Group complex in Chayu Area, southeastern Qinghai-Tibet Plateau: Evidence from zircon U-Pb and mica 40Ar/39Ar dating

The Chayu area is located at the southeastern margin of the Qinghai-Tibet Plateau. This region was considered to be in the southeastward extension of the Lhasa Block, bounded by Nujiang suture zone in the north and Yarlung Zangbo suture zone in the south. The Demala Group complex, a set of high-grade metamorphic gneisses widely distributed in the Chayu area, is known as the Precambrian metamorphic basement of the Lhasa Block in the area. According to field-based investigations and microstructure analysis, the Demala Group complex is considered to mainly consist of banded biotite plagiogneisses, biotite quartzofeldspathic gneiss, granitic gneiss, amphibolite, mica schist, and quartz schist, with many leucogranite veins. The zircon U-Pb ages of two granitic gneiss samples are 205 ± 1 Ma and 218 ± 1 Ma, respectively, representing the ages of their protoliths. The zircons from two biotite plagiogneisses samples show core-rim structures. The U-Pb ages of the cores are mainly 644–446 Ma, 1213–865 Ma, and 1780–1400 Ma, reflecting the age characteristics of clastic zircons during sedimentation of the original rocks. The U-Pb ages of the rims are from 203 ± 2 Ma to 190 ± 1 Ma, which represent the age of metamorphism. The zircon U-Pb ages of one sample taken from the leucogranite veins that cut through granitic gneiss foliation range from 24 Ma to 22 Ma, interpreted as the age of the anatexis in the Demala Group complex. Biotite and muscovite separates were selected from the granitic gneiss, banded gneiss, and leucogranite veins for ⁴⁰Ar/³⁹Ar dating. The plateau ages of three muscovite samples are 16.56 ± 0.21 Ma, 16.90 ± 0.21 Ma, and 23.40 ± 0.31 Ma, and the plateau ages of four biotite samples are 16.70 ± 0.24 Ma, 16.14 ± 0.19 Ma, 15.88 ± 0.20 Ma, and 14.39 ± 0.20 Ma. The mica Ar-Ar ages can reveal the exhumation and cooling history of the Demala Group complex. Combined with the previous research results of the Demala Group complex, the authors refer that the Demala Group complex should be a set of metamorphic complex. The complex includes not only Precambrian basement metamorphic rock series, but also Paleozoic sedimentary rock and Mesozoic granitic rock. Based on the deformation characteristics, the authors concluded that two stages of the metamorphism and deformation can be revealed in the Demala Group complex since the Mesozoic, namely Late Triassic-Early Jurassic (203–190 Ma) and Oligocene–Miocene (24–14 Ma). The early stage of metamorphism (ranging from 203–190 Ma) was related to the Late Triassic tectono-magmatism in the area. The anatexis and uplifting-exhumation of the later stage (24–14 Ma) were related to the shearing of the Jiali strike-slip fault zone. The Miocene structures are response to the large-scale southeastward escape of crustal materials and block rotation in Southeast Tibet after India-Eurasia collision.

Precambrian metamorphic crustal basement cannot provide much gold to form giant gold deposits in the Jiaodong Peninsula, China

The Jiaodong gold deposits, eastern China define a giant gold province in the Precambrian high-grade metamorphic crustal basement. Given the early metamorphism, the crustal basement would have been so depleted in gold that cannot be the main source for the later Mesozoic gold deposits. However, previously reported gold contents from crustal rocks were variably high (e.g., >5–10 ppb) and often interpreted to reflect the contribution of crustal basement. In this study, after careful field sampling, we obtained high-precision Au and S contents (with Cu and Ag for many samples) to solve the controversial issue. The Au contents were determined by internal standardization to platinum which was obtained from isotope dilution via high-sensitivity Element XR, and/or another independent method by GFAAS after polyurethane foam pretreatment. These methods achieved low procedural blanks (<0.02 ppb) and reliable analyses of low-Au samples. The analyzed metamorphic crustal rocks are from surface outcrops (n = 30) and crustal xenoliths (n = 10) in the Jiaobei terrane, where hosts the predominant Jiaodong gold resources (>85% of 5000 t). The Archean and Paleoproterozoic metamorphic outcrop rocks were sampled far from gold deposits and faults with the minimum effect of ore-forming fluids, and they display overall low Au contents (0.20 ± 0.18 ppb and 0.47 ± 0.29 ppb, respectively). More importantly, the crustal xenoliths trapped in pre-mineralization Guojialing granodiorites were not affected by hydrothermal overprint and better reflect the pristine features of the metamorphic basement. Although the crustal xenoliths contain variable sulfides with a wide range of Cu, Ag and S contents, they show rather low Au contents (0.18 ± 0.15 ppb). These results indicate the strong depletion of Au contents in the Precambrian crustal basement, consistent with the metamorphic devolatilization model. The Precambrian metamorphic crustal basement thus was rather difficult as the main gold source for the Jiaodong gold deposits, suggesting alternative sources.

UAS-Derived Surficial Deformation around the Epicenter of the 2016 Mw 5.8 Pawnee, Oklahoma, USA, Earthquake

ABSTRACT Unmanned aerial systems (UAS) provide a framework for recording perishable surficial data or information. Open fractures exhibiting regular en-echelon patterns were captured by a 12-megapixel, FL-9 mm camera attached to a Phantom IV UAS over the epicenter of the magnitude (Mw) 5.8 earthquake of September 3, 2016, 15 months later. The Digital Surface Models (DSMs) and orthoimagery offered a spatial resolution (∼1 cm) sufficient to identify small-scale plastic deformations that appear to be controlled by en-echelon joint sets developed in the underlying formation. The fissure boundaries and intersections are remarkably linear and sharp. They appeared to have been recently formed, presumably by seismic swarms believed to have been associated with wastewater injection. The DSMs revealed a series of conjugate patterns suggestive of regional systematic joints with apparent subsidence of infilling up to 50 cm. The earthquakes emanated from the Precambrian metamorphic basement, with epicentral clusters at ∼5- and 8-km depths. Low energy release from depths &amp;gt;1.5 km appears to be locally attenuated by an unconsolidated “soil cap,” which likely formed an impedance contrast. The maximum deformation direction from the cumulative energy of earthquakes correlates with a wrench fault tectonics model that could conceivably produce the observed en-echelon joint sets observed in the orthoimagery and DSMs. These features were observed within 275 m of the reported Mw 5.8 epicenter. The remarkably linear repeating pattern of deformation appears to express fissures that preserve the wrench fault fractures generated by the Mw 5.8 earthquake emanating from discontinuity suites within marine sandstone, shale, and limestone of Pennsylvanian to Permian age.

Formation of the Neoproterozoic Rifting Depression Groups of the Tarim Basin and its Hydrocarbon Potential: Responded to the Initial Opening of the Proto‐Tethy Ocean

AbstractThe largest and superimposed Tarim basin developed on the one of the three bigger craton, Tarim Craton, in China. The early Paleozoic is the heyday of its development and cratonization, and then changes to the different property basin. The reserved sedimentary strata of Neoproterozoicare recognized mainly in the local of outcrops periphery orogenic belts, but drilling core in the basin reveals them seldom. The proto‐type of the initial Tarim Basinis always a mystery. The vast desert, huge‐thickness of sedimentary strata, multiple tectonic movements, and a low quality of deep data are the keys to getting to know him. We comprehensive field outcrops, wells, seismic reflection profiles with higher SNRs and aeromagnetic data, recognized about 20 normal fault‐controlled rifting depressions of the Cryogenian and Ediacaran, which scattered throughout the basin, and developed on the Precambrian metamorphic and crystalline basement. The structural framework is clearly different from that of the overlying Phanerozoic. The rifting depressions consist of mainly half grabens, symmetrical troughs and horst‐grabens. From the northeast to southwest of the basin, they are divided into three rifting depression groups (RDG) with the WNW, ENE, and NW‐trends that are mainly controlled by normal faults. From the Cryogenian to Ediacaran, most of the main inherited faults to active and eventually ceased at the end of the Ediacaran or Early Cambrian, while subsidence centers appeared and migrated eastward along the faults. They formed under the NNE‐SSW oriented and NNW‐SSE‐oriented extensional paleo‐stress fields (relative to the present) during the Neoproterozoic, and were accompanied by clockwise shearing. According to the analysis of the activities of syn‐sedimentary faults, filling sediments, magmatic events, and coordination with aeromagnetic anomalies, the tectonic properties of the fault depressions are different and are primarily continental rifts or intra‐continental fault‐controlled basins. The formation of the rifting depression was associated with the initial opening of the South Altun‐West Kunlun Ocean and the South Tianshan Ocean, which were located at the northern and southern margins of the Tarim Block, respectively, in response to the break‐up of the Supercontinent Rodinia and the initial opening of the Proto‐Tethys Ocean.Inthe RDG developedfluvial, shallow marine and carbonate platform facies, accompanied with multiple phases of magma activities and glaciations during the Cryogenian and Ediacaran. The structural architectures of interfaces between the Neoproterozoic and Cambrian are mainly angular and parallel unconformities in the RDG. Over the parallel unconformities in the RDGs are beneficial for the organic‐rich and /or phosphorites of the Yuertus Formation of the Lower Cambrian. The main fault belts of RDGs also controlled the small platform margin and slope break belt of in the Cambrian. The Neoproterozoic and the Lower Cambrian petroleum systems of the basin might be controlled by the RDGs in the initiation of the Tarimcraton.

Ore-controlling structures of the Xiangshan volcanic Basin, SE China: Revealed from three-dimensional inversion of Magnetotelluric data

We report a high-resolution three-dimensional (3D) Magnetotelluric (MT) study to define the mineralizing system of the Xiangshan (XS) volcanic Basin, which hosts the largest volcanic-related uranium deposits in China. MT data from 81 stations were collected and inverted, using a 3D Truncated Newton (TRN) inversion algorithm. The generated electrical resistivity model reveals a high resistivity layer in the shallow, followed by a conductivity layer, and they were formed respectively by the Cretaceous Ehuling Formation and Daguding Formation. Under these Cretaceous formations, a series of high resistivity features delineate the Precambrian metamorphic basement. The contact zone between the high resistivity and conductivity layer corresponds to the inter-formational surface in the Cretaceous volcanic cover, whereas the contact zone between the volcanic cover and metamorphic basement represents the unconformity surface which was supported by gravity data. The identified faults in the 3D resistivity model coincide with the NE- and NS-trending faults observed on the surface. These faults are the crucial ore-controlling structures with high permeability allowing the ore-forming fluids to migrate upwards. We reveal a possible genetic model for the uranium mineralization in the XS volcanic Basin. The mixture of the descending meteoric water and ascending magmatic fluids along the deep faults formed the ore-forming fluids. The precipitation and enrichment of uranium were prone to occur in the ring faults, interfaces, unconformity surfaces and those geologic contacts intersecting with faults, where the physical and chemical properties of the ore-forming fluids were changed. Given that the mafic magmatism generally was coeval with the uranium mineralization, the deep-seated magmatism is supposed to be the force that drove the fluids upwards and governed the circulative convection of ore-forming fluids in the XS volcanic Basin.

Geology and in-situ sulfur and lead isotope analyses of the Jinlongshan Carlin-type gold deposit in the Southern Qinling Orogen, China: Implications for metal sources and ore genesis

The Jinlongshan gold deposit, Shaanxi Province, central China, is a large deposit (>150 t Au) in the Southern Qinling Orogen. Gold mineralization is hosted in Upper Devonian to Lower Carboniferous carbonaceous clastic-carbonate sequences. Four stages of pyrite and paragenetic sulfides have been identified based on morphology and paragenesis. Laser-ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) and laser ablation multi-collector inductively coupled plasma mass spectrometry (LA–MC–ICP–MS) analyses were conducted to determine the chemical and S–Pb isotopic composition of the sulfides. Pre-ore stage pyrites (Py1 and Py2) contain relatively high concentrations of Mn, Co, Ni, Cu, Zn, Sb, and Pb exhibiting a wide range of δ34S values, ranging from –29.9‰ to +48.4‰. These two pyrites were formed by bacterial and thermochemical sulfate reduction of Upper Devonian marine sulfate, respectively. Main-ore stage pyrite (Py3) and arsenopyrite (Apy) contain high concentrations of Au, As, Cu, Sb, Hg, and Tl with restricted ranges of δ34S values from 9.6‰ to 15.3‰, which is interpreted as resulting from the underlying low-grade metamorphic Paleozoic sedimentary rocks by the decomposition of pyrite and/or inorganic reduction of sulfate. Late- or post-ore stage pyrite (Py4) is characterized by low concentrations of Au, Ag, Sn, Hg, and Bi and exhibited variable δ34S values, ranging from –4.4‰ to +27.7‰, that may reflect the mixing of metamorphic fluids with meteoric water. Similarly, the Pb isotope composition of ore-stage sulfides resembles those of underlying low-grade metamorphic Paleozoic sedimentary rocks whereas differs from Precambrian metamorphic basement rocks and granitoids around the basin, indicating that the metals of the Jinlongshan gold deposit were sourced from the underlying Paleozoic sedimentary rocks.Detailed fieldwork revealed that the deposit has mainly undergone four deformation events. The ore bodies developed in NE-trending dextral oblique-slip reverse faults of D3 that crosscut WNW-trending shear zones of D2. The timing and corresponding stress regimes of the D3 event suggest that it formed in a local extensional environment of Yanshanian intracontinental orogeny of Qinling orogenic belt. Gold metallogenesis of the Jinlongshan gold deposit occurred during the transition of tectonic setting from compression to extension, which reactivated the shear zones and migrated deep ore-bearing fluids to NE-trending brittle faults. The geological and geochemical features of the Jinlongshan gold deposit are more analogous to the Carlin-type deposits than other orogenic gold deposits worldwide; therefore, we propose it is a typical Carlin-type gold deposit in South Qinling Orogen.

Geophysical constraints on the Luhoi (Tanzania) geothermal conceptual model

We present the results of the gravimetric, magnetic and magnetotelluric geophysical campaign aimed to constrain the geothermal conceptual model of the Luhoi geothermal field, a poorly known system located in the Tanzanian southeastern coastal sedimentary basin. Regional assessment by existing potential field data reveals that Luhoi lies at the margin of a wide regional NE trending uplifted block that involves the Precambrian metamorphic basement complex. In the geothermal field area, 3D geophysical modelling has imaged a local asymmetric horst of Cretaceous age, 1 km wide and 5 km long, with the same regional NE trend. The horst is formed by the denser Kipatimu Lower Cretaceous sandstones surrounded by the Upper Cretaceous Ruaruke claystones that are down thrown up to 1 km by normal faulting. Far from the horst, lithology mainly controls the modelled electrical resistivity distribution: the Ruaruke claystones show low resistivity (1–6 Ωm) primarily due to its clay content, while the Kipatimu sandstones have generally higher resistivity (10–30 Ωm) because of their prevalent electrolytic conduction. However, anomalous low resistivity values (1–5 Ωm) in the shallower portion of the Kipatimu sandstones forming the horst indicate enhanced electrical conduction due to the cation exchange capacity (CEC) of clay. The CEC estimated values from electrical resistivity are in the range 2−30 meq/100 g, suggesting the presence of kaolinite and illite and excluding the occurrence of smectite, which is the typical clay mineral in the cap-rock of high-temperature geothermal systems. This shallow clay-rich layer together with the Ruaruke claystones act as a regionally continuous clay cap confining the reservoir formed by moderately hot water (close to 100 °C from water geothermometers) in the permeable Kipatimu sandstones layer that reach a maximum depth of ca. 2 km, likely heated by a slightly enhanced geothermal flux attributable to crustal extension. At Luhoi, the local horst structure imaged by the geophysical models pushes up the sandstone reservoir at very shallow depth (about 500 m from the surface), strongly enhancing the local geothermal gradient and originating the surface thermal manifestations that are controlled by the system of normal faults.