Precambrian Cambrian Boundary Research Articles

Cycling of rare earth elements at the Precambrian-Cambrian boundary

The Great Unconformity at the Precambrian-Cambrian boundary marks a global erosion surface, and a time gap which in places exceeded a billion years. The weathered sub-Cambrian rocks include abundant granites and pegmatites. These rocks and others were mineralized in several regions. The basal Cambrian sediments show that rare commodities including gold and rare earth elements (REEs) were concentrated from sub-Cambrian sources by both chemical and physical processes. The clay-rich unconformity in Europe demonstrates the weathering of Palaeoproterozoic pegmatites (∼1.2 billion years older) and liberation of strontium and REEs to reprecipitate as authigenic phosphate minerals. This is consistent with a global strontium isotope excursion at the Precambrian-Cambrian boundary. The global extent of sub-Cambrian granites and pegmatites indicates a possible exploration play for REEs. More generally, the abundance of ores exposed on the surface globally, and examples of early Cambrian enrichment, indicate that the surface has high potential for exploration of rare elements.

Revisiting Ediacaran to early Cambrian depositional history of western North China: did it remain passive until the mid-Paleozoic?

Whether the North China Block (NCB) remained in extension from its cratonization to the mid-Paleozoic is questionable. Here, we conduct a synthesis of zircon U–Pb data of Statherian–Ordovician sandstones to provide a historical review of provenance changes in the western NCB through time. In contrast to typical NCB basement sources characterized by c. 2.7–1.8 Ga ages with spectral peaks at c. 2.5 and 1.9 Ga during much of c. 1.8–0.45 Ga, Ediacaran to Cambrian Stage 3 succussions contain abundant zircons with Meso- to Neoproterozoic ages. The exotic provenance, further verified by southeastward palaeo-flow, implies sources from the western Bainaimiao arc terrane (BAT), where basement rocks with suitable ages exist. Hence, the BAT should have evolved at the NCB margin before c. 0.56 Ga, but after rifting of the NCB (until c. 773 Ma). This event led to a craton-wide stratigraphic break during the Mesoproterozoic–Ediacaran. The presence of 521–515 Ma detrital zircons in Cambrian Stage 3 strata indicates subduction onset of the Palaeo-Asian Ocean before c. 515 Ma, coincident with the Precambrian–Cambrian boundary paraconformity. A sequence of depositional shifts triggered by the tectonic activities of the BAT unveils a complicated plate reorganization history of the northern NCB, contesting the view that the NCB remained passive from the Statherian. Supplementary material : Figures S1, S2 and Tables S1 and S2 are available at https://doi.org/10.6084/m9.figshare.c.7040743

Position of the Precambrian–Cambrian Boundary in the Sections of Western Mongolia according to the Malacological Data

Position of the Precambrian–Cambrian Boundary in the Sections of Western Mongolia according to the Malacological Data

A new model for Early Paleozoic ichnostratigraphy based on trace fossil assemblages from Brazil

Trace fossils are not generally utilized as biostratigraphic indicators due to their long stratigraphic ranges. Despite the use of intricate behavioral traces in the absence of other indicators, existing models like the Precambrian–Cambrian boundary and Cruziana stratigraphy encounter limitations due to crucial data gaps and regional constraints. To surmount these challenges, in this paper, we critically assess established models and present a new framework for Early Paleozoic strata, drawing on trace fossils from the intracratonic basins of Brazil. Our ichnostratigraphic model is calibrated using ichnological data from the Parnaíba, Paraná, and Amazonas basins, including new data. The analysis focuses on trace fossils in strata that are independently dated using chitinozoan, miospore, and acritarch biozonation. Key ichnotaxa, such as Arthrophycus and Cruziana, are identified as prominent indicators of the Llandovery Stage in Brazil. Occurrences of Heimdallia and Musculopodus in the Tianguá Formation also may be used to suggest a Llandovery interval. Notably, Bifungites, found widely across Brazilian basins, emerges as a potential ichnomarker for the Early to mid-Paleozoic interval, with a global presence throughout Cambrian to Mississippian deposits. While current ichnostratigraphic models lack robust calibration with chronostratigraphic or biostratigraphic data, our new proposed model integrates key ichnotaxa, including Bifungites, Climactichnites, Heimdallia, Oldhamia, and Musculopodus, surpassing those pre-existing zonations based on Cruziana and arthrophycids. These ichnotaxa exhibit unique features and narrow temporal ranges, meeting essential biostratigraphic criteria. Although their spatial distribution is somewhat limited, our new model, which is continually evolving with new data, holds promise for enhancing global stratigraphic correlations, particularly where independent age information is available.

The Proterozoic Qinggouzi microfossil assemblage and its biostratigraphic constraints on the Great Unconformity in northeastern North China Craton

The Great Unconformity at the Precambrian-Cambrian boundary has been recognized on several continents and may provide critical insights into the environmental context of the Cambrian explosion. However, the geodynamic drivers, geochronological duration, and paleogeographic extent of the Great Unconformity remain unconstrained in many cases. Recently, a major depositional gap of varying magnitudes has been reported around the Precambrian-Cambrian boundary in several regions of North China, leading to the interpretation that the Great Unconformity may have been widespread but diachronous across the North China Craton. However, the magnitude of the Great Unconformity remains unknown in northeastern North China, largely because of the poor age constraints on the thick Proterozoic–Cambrian successions in this region. Here we use biostratigraphic data to constrain the depositional age of Proterozoic strata below the Great Unconformity in northeastern North China. We report a diverse organic-walled microfossil assemblage from the Qinggouzi Formation in southern Jilin Province, northeastern margin of the North China Craton. Typical late Mesoproterozoic to early Neoproterozoic microfossils, including Trachyhystrichosphaera aimika and Proterocladus antiquus, are present in Qinggouzi assemblage, providing a solid biostratigraphic constraint on the Qinggouzi Formation. Given that the overlying Shuidong Formation contains typical early Cambrian small shelly fossils, our new data indicate that the Great Unconformity in northeastern North China represents a major depositional gap of >200 Myr. Thus, the new data, along with other available biostratigraphic and geochronological data from over the world, provide robust constraints on the paleogeographic extent, chronostratigraphic duration, and diachronous nature of the Great Unconformity.

Meteorite impact at Ramgarh, India: Petrographic and geochemical evidence, and new geochronological insights

The impact origin of Ramgarh crater in India has been a topic of debate for several decades due to its conspicuous morphology, with recent studies confirming the structure as a complex impact crater. In this work, we present the results from an integrated petrographic and geochemical study to evaluate the impact origin of the crater, in conjunction with introduction of a new geochronological data for the crater through zircon U Pb systematics. Petrographic studies of the target Vindhyan sedimentary rocks show the presence of shock fabrics such as planar fractures, decorated planar deformation features, brecciation, melted grain boundaries, diaplectic glass, and vitrified matrix. Geochemically, the lithounits have high concentrations of Cr, Ni, Cu, and the corresponding chondrite normalized values show notably elevated levels than crustal average. The elevated levels of Cr, Ni and Cu in the target rocks indicate its interaction with an extra-terrestrial object. The positive correlation between Ni and Co, higher concentration of Cr (9–623.35 ppm), and more importantly the average Ni/Cr (~0.006- ~ 1.3), Ni/Co (~1.8 to ~22) and Cr/Co (~57–~368) ratios in the target lithounits of Ramgarh, point to a differentiated achondrite being the possible impactor. The zircon U Pb geochronological data from two samples in this study do not show significant Pb-loss and U enrichment. However, the relatively younger age of 528–395 Ma, depicted by quartzite sample (AN-4), along with the discordance and distinguishable Pb-loss, might hint that the impact event at Ramgarh have occurred between this timeframe. This age is considerably closer to the Precambrian-Cambrian Boundary (543 Ma) and, it also encompasses the age corresponding to the mid-Ordovician Meteor Event (OME) (467.5 ± 0.28 Ma). As this study infers that the potential impactor at Ramgarh is a differentiated achondrite and not a L-chondrite, the OME age can be ignored, further narrowing the age of Ramgarh impact structure. Our study also confirms the Ramgarh structure as an impact crater, and constrains the possible timing of the impact. • Tracking the impact event at Ramgarh Crater, NW India • Shock features in quartz grains mainly includes decorated PDFs, and melting. • Whole rock, trace and REE geochemistry reveals impact event. • Zircon U Pb ages of 528 to 395 Ma, which is the first convincing age for this crater

Phosphorite generative processes around the Precambrian-Cambrian boundary in South China: An integrated study of Mo and phosphate O isotopic compositions

Large phosphorite deposits in Central Guizhou, China, were formed around the Precambrian/Cambrian boundary (PC/C), including the Ediacaran (Doushantuo stage) and early Cambrian (Gezhongwu stage). Among them, Gezhongwu phosphorite from Zhijin are enriched in rare earth elements (REE) plus yttrium (REY), reaching 3.503 million tons. Although phosphorites have attracted great attention, the specific sources P and REY remained unclear. To determine the P and REY sources and establish a phosphogenic model of PC/C phosphorite, we present an integrated dataset of Mo and phosphate O isotopes for the first time, along with carbonate C and O isotopes, geology, petrology, and geochemistry. In all samples, δ18Op, Y/Ho, and Zr/Hf decreased from the Ediacaran to the early Cambrian, indicating increased terrigenous weathering fluxes while decreased upwelling water input. Furthermore, terrigenous weathering delivery significantly elevated marine REY concentrations in the Cambrian in Zhijin. The Ceanom and δ98/95Mo suggest that seawater was oxidized in the later Ediacaran and became entirely oxic in the early Cambrian. The positive feedback between oxygen levels in atmosphere and primary productivity caused progressive oxygenation in ocean–atmosphere system and enable phosphorites to be formed by different mechanisms. Results show that the Lower Doushantuo consist of abiotic intraclasts and exhibited “seawater-like” REY types, indicating abiological and mechanical reworking phosphogenesis. The Upper Doushantuo and Gezhongwu Formation contained mainly microbial debris and abiogenic intraclasts, and exhibit “hat-shaped” REY plots, suggesting microbially mediated phosphogenesis. Based on this data set, we developed a phosphogenic model illustrating formation of these two phosphorite deposits, wherein the Lower Doushantuo phosphorite formed through the reworking of pre-existing phosphatic sediments in anoxic and abiotic ocean, whereas the Upper Doushantuo and Gezhongwu phosphorite formed via microbial metabolisms in oxic and biotic conditions. Our study has implications on the PC/C phosphorite generative processes, as well as paleoenvironmental conditions.

Late Neoproterozoic – early Paleozoic basin evolution in the Coal Creek inlier of Yukon, Canada: implications for the tectonic evolution of northwestern Laurentia

The age and nature of the Neoproterozoic – early Paleozoic rift–drift transition has been interpreted differently along the length of the North American Cordillera. The Ediacaran “upper” group (herein elevated to the Rackla Group) of the Coal Creek inlier, Yukon, Canada, represents a key succession to reconstruct the sedimentation history of northwestern Laurentia across the Precambrian–Cambrian boundary and elucidate the timing of active tectonism during the protracted breakup of the supercontinent Rodinia. These previously undifferentiated late Neoproterozoic – early Paleozoic map units in the Coal Creek inlier are herein formally defined as the Lone, Cliff Creek, Mount Ina, Last Chance, Shade, and Shell Creek formations. New sedimentological and stratigraphic data from these units is used to reconstruct the depositional setting. In the Last Chance Formation, chemostratigraphic observations indicate a ca. 5‰ δ13Ccarbgradient coincident with the globally recognized ca. 574–567 Ma Shuram carbon isotope excursion. Map and stratigraphic relationships in the overlying Shell Creek Formation provide evidence for latest Ediacaran – middle Cambrian tilting and rift-related sedimentation. This provides evidence for active extension through the Cambrian Miaolingian Series in northwestern Canada, supporting arguments for a multiphase and protracted breakup of Rodinia.

Detrital zircon age and biostratigraphic and chemostratigraphic constraints on the Ediacaran–Cambrian transitional interval in the Irkutsk Cis–Sayans Uplift, southwestern Siberian Platform

AbstractA number of ecological and geochemical transformations occurred during late Ediacaran and early Cambrian time, the effects of which are difficult to overestimate. However, the strong linkage of biostratigraphic and chemostratigraphic methods with lithofacies makes the localization of the Precambrian–Cambrian boundary and its correlation with lithologically contrasting sections highly debatable. We analyse the taxonomy and stratigraphic distribution of small skeletal fossils and trace fossils, the carbonate carbon and oxygen isotope composition, and U–Pb detrital zircon age in the Ediacaran–Cambrian transitional interval of the Irkutsk Cis–Sayans Uplift (southwestern Siberian Platform). This interval (Moty Group) comprises a transgressive succession with red-coloured alluvial to deltaic siliciclastic deposits (Shaman Formation) and overlying shallow-marine carbonates (Irkut Formation). The lower Irkut Formation hosts sporadic and poorly preserved tubularCambrotubulusfossils, which are known from both the terminal Ediacaran Period (c. 550–541 Ma) and the Terreneuvian Epoch (541–521 Ma), and typical Fortunian trace fossils, including an index ichnotaxon of the Cambrian boundaryTreptichnus pedum. The biostratigraphic and carbonate carbon isotope data and U–Pb concordia ages of 531.1 ± 5.2 Ma (mean weighted, 530.6 ± 5.3 Ma) of the five youngest zircon grains from the lower Irkut Formation indicate that at least the shallow-marine carbonates of the upper Moty Group correspond to the Cambrian Stage 2 (c. 529–521 Ma). In the Irkutsk Cis–Sayans Uplift, the Cambrian Period tentatively began before or during the accumulation of the alluvial to deltaic siliciclastic Khuzhir and Shaman formations, and this crucial divide remained unmarked in the palaeontological and isotopic records.

Guía de campo post-congreso, 21-24 de Octubre de 2019: Ediacárico y Terreneuviense en los alrededores del Geoparque de la UNESCO Villuercas-Ibores-Jara

Una de las esquinas de los mapas geográficos que enlazan las provincias de Badajoz, Cáceres y Toledo contiene unos afloramientos claves para entender el tránsito Ediacárico-Cámbrico de la Zona Centroibérica. En los núcleos del Anticlinorio Extremeño y de los Anticlinales de Ibor y Valdelacasa afloran el Supergrupo del Alcudiense inferior-Domo Extremeño (donde destacan las diamictitas de la Formación de Orellana), los arrecifes microbianos más espectaculares con Cloudina de la Formación de Villarta y la base paleoicnológica del Cámbrico en la Formación de Arrocampo (las dos últimas formaciones pertenecen al Grupo de Ibor). Los afloramientos que tradicionalmente se consideraban como representantes del límite Precámbrico-Cámbrico y base del piso regional Cordubiense se sitúan en el miembro inferior de la Formación del Pusa, suprayacentes al Grupo de Ibor y considerados actualmente como intra-terreneuvienses.

Magnesium isotope evidence for enhanced crustal reworking in lowermost Cambrian sedimentary rocks (Kazakhstan)

The transition from the Proterozoic to the Phanerozoic Eon was accompanied by the rise of metazoan life, a key and unique biogeochemical milestone in Earth's history. Concomitant continental re-organization and collision were associated with enhanced continental reworking and changes in global ocean currents, with profound impacts on continental weathering rates, riverine run-off and associated changes in the ocean nutrient budget. The causal relationship between the geological re-organisation of continents and the biologic evolution of marine life, however, remains elusive. In this study, we investigate phosphatic shallow-water sedimentary successions from Kazakhstan, which host key marker horizons from the Precambrian-Cambrian (Pc-C) boundary. We show that a rapid change (over ca. 3 Myrs) towards heavier stable Mg isotope compositions of the phosphatic sedimentary deposits in Kazakhstan, which we consider representative for contemporaneous ocean chemistry, co-varies with changes in radiogenic Sr isotope signatures. We propose that ocean chemistry at the Pc-C boundary, represented through this co-variation, was strongly affected by continental re-organization and associated weathering, which, in analogy, would have affected ocean nutrient levels. A rapid reversal of isotope compositions towards signatures similar to those prior to the isotope excursion likely reflects the fading influence of weathering and a buffering of water-rock interactions during oceanic spreading. We conclude that, based on the positive, coupled 87Sr/86Sr- δ26Mg isotope spike in ocean water chemistry, a link between Gondwana re-organization at the Pc-C boundary and the marked change in marine fauna seems plausible.

Cambrian integrative stratigraphy and timescale of China

The Cambrian Period is the first period of the Phanerozoic Eon and witnessed the explosive appearance of the metazoans, representing the beginning of the modern earth-life system characterized by animals in contrary to the Precambrian earth-life system dominated by microbial life. However, understanding Cambrian earth-life system evolution is hampered by regional and global stratigraphic correlations due to an incomplete chronostratigraphy and consequent absence of a high-resolution timescale. Here we briefly review the historical narrative of the present international chronostratigraphic framework of the Cambrian System and summarize recent advances and problems of the undefined Cambrian stage GSSPs, in particular we challenge the global correlation of the GSSP for the Cambrian base, in addition to Cambrian chemostratigraphy and geochronology. Based on the recent advances of the international Cambrian chronostratigraphy, revisions to the Cambrian chronostratigraphy of China, which are largely based on the stratigraphic record of South China, are suggested, and the Xiaotanian Stage is newly proposed for the Cambrian Stage 2 of China. We further summarize the integrative stratigraphy of South China, North China and Tarim platforms respectively with an emphasis on the facies variations of the Precambrian-Cambrian boundary successions and problems for identification of the Cambrian base in the different facies and areas of China. Moreover, we discuss stratigraphic complications that are introduced by poorly fossiliferous dolomite successions in the upper Cambrian System which are widespread in South China, North China and Tarim platforms.

Reconstructing the Himalayan margin prior to collision with Asia: Proterozoic and lower Paleozoic geology and its implications for Cenozoic tectonics

AbstractReconstructing the stratigraphic architecture of deposits prior to Cenozoic Himalayan uplift is critical for unravelling the structural, metamorphic, depositional and erosional history of the orogen. The nature and distribution of Proterozoic and lower Paleozoic strata have helped elucidate the relationship between lithotectonic zones, as well as the geometries of major bounding faults. Stratigraphic and geochronological work has revealed a uniform and widespread pattern of Paleoproterozoic strata >1.6 Ga that are unconformably overlain by <1.1 Ga rocks. The overlying Neoproterozoic strata record marine sedimentation, including a Cryogenian diamictite, a well-developed carbonate platform succession and condensed fossiliferous Precambrian–Cambrian boundary strata. Palaeontological study of Cambrian units permits correlation from the Indian craton through three Himalayan lithotectonic zones to a precision of within a few million years. Detailed sedimentological and stratigraphic analysis shows the differentiation of a proximal realm of relatively condensed, nearshore, evaporite-rich units to the south and a distal realm of thick, deltaic deposits to the north. Thus, Neoproterozoic and Cambrian strata blanketed the northern Indian craton with an extensive, northward-deepening, succession. Today, these rocks are absent from parts of the inner Lesser Himalaya, and the uplift and erosion of these proximal facies explains a marked change in global seawater isotopic chemistry at 16 Ma.

Systematics of Early Cambrian Paleomagnetic Directions from the Northern and Eastern Regions of the Siberian Platform and the Problem of an Anomalous Geomagnetic Field in the Time Vicinity of the Proterozoic–Phanerozoic Boundary

Representative paleomagnetic collections of Lower Cambrian rocks from the northern and eastern regions of the Siberian platform are studied. New evidence demonstrating the anomalous character of the paleomagnetic record in these rocks is obtained. These data confidently support the hypothesis (Pavlov et al., 2004) that in the substantial part of the Lower Cambrian section of the Siberian platform there are two stable high-temperature magnetization components having significantly different directions, each of which is eligible for being a primary component that was formed, at the latest, in the Early Cambrian. The analysis of the world’s paleomagnetic data for this interval of the geological history shows that the peculiarities observed in Siberia in the paleomagnetic record for the Precambrian–Phanerozoic boundary are global, inconsistent with the traditional notion of a paleomagnetic record as reflecting the predominant axial dipole component of the geomagnetic field, and necessitates the assumption that the geomagnetic field at the Proterozoic–Phanerozoic boundary (Ediacaran–Lower Cambrian) substantially differed from the field of most of the other geological epochs. In order to explain the observed paleomagnetic record, we propose a hypothesis suggesting that the geomagnetic field at the Precambrian–Cambrian boundary had an anomalous character. This field was characterized by the presence of two alternating quasi-stable generation regimes. According to our hypothesis, the magnetic field at the Precambrian–Cambrian boundary can be described by the alternation of long periods dominated by an axial, mainly monopolar dipole field and relatively short epochs, lasting a few hundred kA, with the prevalence of the near-equatorial or midlatitude dipole. The proposed hypothesis agrees with the data obtained from studies of the transitional fields of Paleozoic reversals (Khramov and Iosifidi, 2012) and with the results of geodynamo numerical simulations (Aubert and Wicht, 2004; Glatzmayer and Olson, 2005; Gissinger et al., 2012).

Hydrocarbon generation capability of Sinian–Lower Cambrian shale, mudstone, and carbonate rocks in the Sichuan Basin, southwestern China: Implications for contributions to the giant Sinian Dengying natural gas accumulation

The giant natural gas accumulation recently discovered within the (Neoproterozoic) Dengying Formation in the Sichuan Basin of southwestern China represents a new and important supplement to the ancient Neoproterozoic–Cambrian petroleum systems worldwide. However, the source of this gas is controversial because there are five possibilities based on geology, from bottom to top including the Lower Sinian Doushantuo mudstone, the Upper Sinian Dengying algal dolomite, the mudstone of the third member of the Dengying Formation, the Lower Cambrian Maidiping argillaceous dolomite, and the Lower Cambrian Qiongzhusi shale. To improve the understanding of this issue, 33 samples from the five possible source rock units in the study area were investigated for their character and maturity via petrology, total organic carbon (TOC), pyrobitumen reflectance, kerogen carbon isotope, and biomarker analyses. Based on the results, we address their hydrocarbon generation capabilities and contributions to the giant gas accumulation. Results show that present-day TOC values of the samples range from 0.03% to 2.36% and vary both regionally and stratigraphically, with the Qiongzhusi shales in the central basin and the Weiyuan–Ziyang area ranking the highest. In contrast, the organic matter source and maturity within these rocks are relatively homogenous with slight variation throughout the study area. The organic matter is predominantly derived from algae and bacteria with different compositions deposited in marine reducing environments. The rocks range in thermal maturity from postmature to overmature. These results imply that the generation capability of source rock had been high in the past, and the gas in the study area is most likely originated from oil cracking and the late generation directly from the kerogen of source rocks, with the Qiongzhusi shales being the dominant source rock. Thus, the hydrocarbon migration pattern in the study area is a lateral migration from deep-seated and younger Cambrian source rocks in sags to shallow-seated and older Sinian dolomite reservoirs in uplifts. The migration process occurred in the oil phase with the oil being later cracked. The differences in natural gas geochemistry may be controlled by complex factors, e.g., thermal maturity, the migration–accumulation process, and differing contributions from source rocks besides the dominant Qiongzhusi. Regionally, the central basin and the Weiyuan–Ziyang area have had high hydrocarbon generation capability and thus should be considered as favorable targets for natural gas exploration in the future. This study of China provides an additional example of Neoproterozoic–Cambrian petroleum systems worldwide and thus can help to synthesize the systematics of such systems and understand the sedimentary transition across the Precambrian–Cambrian boundary.

Variations in the Properties of Extractable “Humic Matter” and Associated Kerogen in Sediments through Geologic Time: Their Significance for Precambrian Biological Evolution and Paleoecology

ABSTRACTChemical properties and δ13C values of benzene/methanol-extractable “humic matter” and associated kerogen in a large, diverse collection of Precambrian and Phanerozoic sediments from different parts of the world showed complex systematic variations through geologic time, reflecting major developments in the history of Precambrian life, and different kinds of sediment yielded similar patterns of variation. Moreover, certain data differentiate clearly between glacial and nonglacial detrital sediments, or between lacustrine and marine sediments, and some data suggest the occurrence of Precambrian land life. The abundance of aromatic groups and the proportion of aliphatic to aromatic groups in the extracts showed little variation from the early Archean (ca. 3.3 Ga) to the mid-Proterozoic (ca. 1.6-1.3 or 1.3-1.1 Ga), whereupon they increased sharply, peaked ca. 1.1-0.900 Ga, and then plunged to a minimum in the late Proterozoic (ca. 0.800 Ga) or early Phanerozoic. This is interpreted as indicating that cyanobacteria were the dominant photoautotrophs until the mid-Proterozoic, when algae evolved, proliferating until the late Proterozoic, whereupon their populations were depleted by herbivorous metazoans. Nitrogenous aromatic material increased to a maximum ca. 3.4–3.3 Ga and then decreased steadily to ca. 1.3 Ga, suggesting that early Precambrian cyanobacteria were enriched in photoprotective as well as photosynthetic tetrapyrrole pigments owing to the lack of ultraviolet radiation-shielding atmospheric O2 and O3. The concentration increased again starting ca. 1.3–0.800 Ga, reflecting the rise of algae, peaked ca. 0.680 Ga, and dropped catastrophically to a much lower value in the Cambrian (ca. 0.510 Ga), suggesting mass mortality at the Precambrian-Cambrian boundary.

Origin and the Early Evolution of the Phylum Mollusca

The paper gives an overview of the modern hypotheses on the origin of the phylum Mollusca and the formation of its main classes. The Cambrian stage of molluscan evolution is characterized based on the paleontological material. The doubtfulness of assignment of the Precambrian (Vendian) soft-bodied fossil Kimberella to mollusks is argued. Judging from the interpretation of the morphologically diverse Cambrian fossils, it is suggested that the classes Polyplacophora, Monoplacophora, Gastropoda and Bivalvia formed already near the Precambrian–Cambrian boundary, i.e., from the beginning of the paleontologically documented evolutionary history of the phylum, whereas the assumption of the later origin of these taxa is unconvincing. The remaining classes of mollusks arose later, i.e., Cephalopoda, in the Late Cambrian; Scaphopoda, in the Ordovician; and Aplacophora, in the Silurian.

Organic‐walled microfossils from the Ediacaran–Cambrian boundary stratotype section, Chapel Island and Random formations, Burin Peninsula, Newfoundland, Canada: Global correlation and significance for the evolution of early complex ecosystems

Although a variety of trace and body fossils have been described from the Cambrian strata in the stratotype section (global stratotype section and point) of the Precambrian–Cambrian boundary in the Burin Peninsula, Newfoundland, a detailed analysis of its organic‐walled microfossils has been missing. The basal Cambrian Treptichnus pedum Ichnozone of the Chapel Island Formation is dominated by leiosphaerids and filamentous sheaths. The appearance of Granomarginata approximates the base of the overlying Rusophycus avalonensis Ichnozone. Common process‐bearing acritarchs, represented by small Asteridium and Comasphaeridium, first appear in the middle of the overlying Random Formation, and a more diverse acritarch assemblage at its top. The Random Formation also yields small carbonaceous metazoan fossils, the first report of this type of fossil in this formation. The initial low diversity of phytoplankton in the basal Cambrian strata, a holdover from Ediacaran extinctions, indicated that they have limited potential for precise global correlation of the global stratotype section and point. The pattern of increasing diversity of acritarchs through the lower Fortunian strata lagged behind and was potentially a response to the Cambrian radiation of metazoans, as most clearly represented by ichnofossils. The timing of phytoplankton radiation reflects a dynamic lag driven by metazoan‐induced changes in early Cambrian food webs.

An Australian source for Pacific-Gondwanan zircons: Implications for the assembly of northeastern Gondwana

Detrital zircons in Neoproterozoic–Paleozoic basins of the Pacific-Gondwana (PG) region contain a distinctive 700–500 Ma population conventionally considered to be derived from Antarctica. However, the 700–600 Ma age component of the population predates major peripheral orogenesis (Terra Australis orogen), which began at ca. 580 Ma, and the highly evolved e Hf(t) -in-zircon values (to –40) require an Archean source, which is not proximal to the Terra Australis active margin. Based on similar e Hf(t) arrays defined by Neoproterozoic granites in Western Australia and detrital zircon populations from the surrounding basins, we suggest that PG zircon grains were derived from the >2000-km-long, late Neoproterozoic Paterson-Petermann orogen, which sutured northern and southern Australia at 550–530 Ma. This Himalayan-style orogen was responsible for amalgamating Southeast Asian terranes into northeast Gondwana, thereby constraining the paleogeography of the northern Gondwanan margin at the Precambrian-Cambrian boundary. Remarkable isotopic similarity of zircon grains with the Lhasa terrane of Tibet suggests that the Paterson-Petermann orogen was the eastern sector of the developing circum-Gondwana subduction system from ca. 700 Ma.

Bacterial sulfur disproportionation constrains timing of Neoproterozoic oxygenation

Various geochemical records suggest that atmospheric O 2 increased in the Ediacaran (635–541 Ma), broadly coincident with the emergence and diversification of large animals and increasing marine ecosystem complexity. Furthermore, geochemical proxies indicate that seawater sulfate levels rose at this time too, which has been hypothesized to reflect increased sulfide oxidation in marine sediments caused by sediment mixing of the newly evolved macrofauna. However, the exact timing of oxygenation is not yet understood, and there are claims for significant oxygenation prior to the Ediacaran. Furthermore, recent evidence suggests that physical mixing of sediments did not become important until the late Silurian. Here we report a multiple sulfur isotope record from a ca. 835–630 Ma succession from Svalbard, further supported by data from Proterozoic strata in Canada, Australia, Russia, and the United States, in order to investigate the timing of oxygenation. We present isotopic evidence for onset of globally significant bacterial sulfur disproportionation and reoxidative sulfur cycling following the 635 Ma Marinoan glaciation. Widespread sulfide oxidation helps to explain the observed first-order increase in seawater sulfate concentration from the earliest Ediacaran to the Precambrian-Cambrian boundary by reducing the amount of sulfur buried as pyrite. Expansion of reoxidative sulfur cycling to a global scale also indicates increasing environmental O 2 levels. Thus, our data suggest that increasing atmospheric O 2 levels may have played a role in the emergence of the Ediacaran macrofauna and increasing marine ecosystem complexity.