This study introduces a mathematical coupling model within the Euler-Lagrange framework to conduct numerical simulations for supersonic gas-particles flow. After validating the model, the gas flow characteristics and particle dynamics within supersonic gas-particle flow under various nozzle configurations are investigated. The findings are as follows: (1) A Laval nozzle with a smoothly connected throat suppresses the generation of fan-shaped Prandtl-Meyer expansion waves and other complex wave systems, effectively mitigating significant changes in gas pressure at the throat and enhancing the stability of supersonic jets. (2) The presence of a particle-free zone in the nozzle divergent segment reduces the collision frequency between particles and the walls, thereby restricting the radial expansion of particles. (3) Utilizing an internally smooth-lined nozzle and expanding the radial divergence angle to 2.5–2.8 times, while ensuring particles maintain consistent axial penetration performance, increases the reflective contact area. This leads to an improvement in the utilization efficiency of particles. These findings provide valuable insights for optimizing nozzle configurations and enhancing the performance of supersonic gas-particle systems.