Pozzolanic Materials Research Articles

MECHANICAL PROPERTIES AND MICROSTRUCTURE OF CONCRETE INCORPORATING SYNTHETIC ZEOLITE

The effect of natural and synthetic zeolite on the microstructure of cement matrix and mechanical properties of concretes was studied in the article. Results show that the addition of these pozzolanic materials results in the increase both compressive and flexural strength after 28 days of hardening. The concrete incorporating 10 mass.% of synthetic zeolite Na-P1 characterizes the highest compressive and flexural strength that reaches 53.5 and 7.8 MPa and exceeds the strength of reference concrete by 18 and 24%, respectively. This increase is the result of the improvement of the concrete on the microstructural level due to the formation of the additional amount of fibre-like crystals of hydrosilicates in the non-clinker part of the cement matrix providing its self-reinforcement.

Synergistic effects of nano titanium dioxide and waste glass powder on the mechanical and durability properties of concrete.

This study investigates the combined use of waste glass powder and nano titanium dioxide (TiO2) on the mechanical and durability properties of the concrete. Waste glass being one of the major municipal wastes going into the landfill sites can be used as a pozzolanic material in the concrete, in this study cement is replaced with waste glass powder by 10% along with nano TiO2, it is used as an addition to cementitious material by 0.5%, 1% and 1.5%. Fresh and mechanical properties like setting time, workability, compressive strength and flexural strength is evaluated along with durability properties such as sorptivity, acid, sulphate and chloride attacks, elevated temperature test. Scanning electron microscope is done to understand the morphology of the blended concrete. Combined use of glass powder and nano TiO2 is found beneficial in mechanical and durability parameters whereas addition of nano TiO2 has resulted in decreased workability of the concrete.

Experimental Study of Sugarcane Bagasse Ash as Partial Replacement of Cement Based on SEM and XRF Analysis

This research aims to identify chemical composition and it’s leaching from concrete mixed with sugarcane bagasse ash. By manipulating percent of slump flow at 110±5%, sugarcane bagasse ash was employed as a pozzolanic material to partially replace cement at 0, 10, 20, 30, 40, and 50 percent by weight of binder in concrete. Cube specimens were cast and cured in water for 3, 7, 14 and, 28 days, respectively. The patterns of sugarcane bagasse ash morphology were performed by using Scanning Electron Microscope (SEM) to analyze physicochemical characteristics. Results of tests on the X-ray fluorescence (XRF) analysis from the ash and curing water at various times revealed that SiO2 made up half of the components in sugarcane bagasse ash. Al2O3, CaO, Fe2O3, K2O, P2O5, and MgO were the minor components. The calcium content from the 14-day period at 50% by weight of the sugarcane bagasse ash binder was higher than that of the other elements, according to the results of curing water. According to the results of 28-day water curing, potassium outnumbered all other elements in the replacement of sugarcane bagasse ash in every ratio.

Preliminary investigation of the effects of high-temperature thermal activation on the activity of graphite tailings and the mechanical properties of graphite tailings mortar

The disposal of graphite tailings, a byproduct of graphite mining, poses significant recycling challenges. This study explores eco-friendly cement mortar by partially replacing sand with activated graphite tailings, focusing on waste utilization. Activating the pozzolanic properties of graphite tailings at various thermal activation temperatures converts them into high-quality binder materials. Quantitative assessments of graphite tailings' activity, conducted through ion leaching tests and raw material diffraction analysis, produce an activity index Ka, evaluating their performance under different thermal activation temperatures. Variable testing of substitution rates and activation temperatures examines changes in mechanical properties, microstructure, and pore distribution of the graphite tailings mortar. Optimum results reveal a 30 % substitution rate and a 750°C activation temperature. Graphite tailings, as pozzolanic binder materials, enhance mortar strength by improving particle size distribution, reducing "micro-area bleeding" and "boundary effects". After thermal activation, reactive minerals on the tailings' surface undergo secondary hydration reactions with cementitious products, modifying chemical structures and micro-morphology at the interface. Semi-quantitative XRD analysis and FT-IR spectroscopy characterize the ensuing chemical reactions, unveiling molecular bond and functional group changes. The superior performance of thermally activated graphite tailings primarily stems from increased active SiO2 and Al2O3 post-activation. The active SiO2 and Al2O3 reacts with cementitious products to form C-(A)-S-H gels, filling micro-pores at the tailings-mortar interface, which is the key characteristic that enables graphite tailings to serve as high-quality pozzolanic binder aggregates. A predictive model for compressive strength, utilizing reference models from solid waste mortar concrete, quantifies the positive impact of chemical activation. The theoretical results obtained from this predictive model closely align with the experimental findings.

Investigating chloride-induced corrosion in reinforced concrete structures using Laser-Induced Breakdown Spectroscopy

Reinforced concrete structures face significant annual expenditures in combating rebar corrosion, with chloride penetration identified as a major contributor. This study employs laser-induced breakdown spectroscopy (LIBS) to quantitatively predict the chloride-induced corrosion rate in such structures. Eighty samples, characterized by known chloride content (ranging from 0% to 1.0%), underwent controlled corrosion processes with predetermined degrees measured as bar weight loss. The investigation included two cement types, Type I and Type V, along with samples incorporating pozzolanic materials (FA, SF, and GGBFS,) in addition to plain OPC samples. LIBS was subsequently employed to detect chlorine presence in each concrete sample, recording the corresponding intensity of the chlorine line. After the initial data acquisition, peak analysis was performed to identify the dominant spectral peaks, ensuring that the most relevant signals were isolated. Following this, the intensity of the chloride emission line from the LIBS spectrum was recorded and correlated with its corresponding chloride signal, establishing a quantitative relationship between the LIBS output and chloride presence. A model was then developed to link the LIBS signal intensity to its corresponding chloride concentration in the sample. In parallel, the corrosion rate associated with each specific chloride concentration was measured and then linked to the LIBS-derived chloride concentrations, creating a framework that ties the LIBS output to the actual rebar degradation within the concrete. Comparisons with previous studies demonstrated superior conformity of the developed models. The study also presents optimized parameters for the LIBS setup. Notably, results indicated a high correlation between LIBS intensity and chloride concentration, with the developed model accurately predicting the degree of corrosion.

Physical, Mechanical and Durability Properties of Eco-Friendly Engineered Geopolymer Composites

Engineered geopolymer composite (EGC) is a high-performance material with enhanced mechanical and durability capabilities. Ground granulated blast furnace slag (GGBFS) and silica fume (SF) are common binder materials in producing EGC. However, due to the scarcity and high cost of these materials in some countries, sustainable alternatives are needed. This research focused on producing eco-friendly EGC made of cheaper and more common pozzolanic waste materials that are rich in aluminum and silicon. Rice husk ash (RHA), granite waste powder (GWP), and volcanic pumice powder (VPP) were used as partial substitutions (10–50%) of GGBFS in EGC. The effects of these wastes on workability, unit weight, compressive strength, tensile strength, flexural strength, water absorption, and porosity of EGC were examined. The residual compressive strength of the proposed EGC mixtures at high elevated temperatures (200, 400, and 600 °C) was also evaluated. Additionally, scanning electron microscope (SEM) was employed to analyze the EGC microstructure characteristics. The experimental results demonstrated that replacing GGBFS with RHA and GWP at high replacement ratios decreased EGC workability by up to 23.1% and 30.8%, respectively, while 50% VPP improved EGC workability by up to 38.5%. EGC mixtures made with 30% RHA, 20% GWP, or 10% VPP showed the optimal results in which they exhibited the highest compressive, tensile, and flexural strengths, as well as the highest residual compressive strength when exposed to high elevated temperatures. The water absorption and porosity increased by up to 106.1% and 75.1%, respectively, when using RHA; increased by up to 23.2% and 18.6%, respectively, when using GWP; and decreased by up to 24.7% and 22.6%, respectively, when using VPP in EGC.

Assessment of possibility of decreasing alkali reactivity of aggregates by using pozzolanic materials

Assessment of possibility of decreasing alkali reactivity of aggregates by using pozzolanic materials

A Comparative Evaluation of Embodied Environmental Impacts of Channel Stabilisation Using Concrete Lining and Alternative Pozzolanic Materials

Channel stabilisation with the lining of bed/ banks using cement-concrete (with/ without steel reinforcement as per the size, depth, and capacity), geomembrane, polymers, canvas, ramped earth, vegetation, gravel/ stone pitching, and brick blast is a common practice worldwide to save the adjacent flood plain areas from bank overflowing, seepage, water logging/ salinity, loss of water in irrigation channels, maintaining required water levels and strengthening of channels to be used as transportation means. A trapezoidal channel of cross-section 165 m2 and a lined perimeter of 42m was proposed to accommodate a super flood of 360 m3/sec discharge for a catchment area of 1446 km2 and 118 km length, using a projected heavy flood event of 6 cm precipitation in 8 hours for Swale River to ascertain the material calculation and its environmental impact. This concrete lining would likely produce an equivalent global warming potential/ embodied carbon dioxide (CO2) of 284 million kgCO2eq (kilogram CO2 equivalent) with the projected use of around 271 million kg of cement concrete and 78 million kg of steel. The enormous amount of embodied CO2 emissions from this projected lining project suggested using natural means of flood/ channel protection if feasible, or alternative supplementary cementitious materials with fibres should be used to minimise the environmental impacts.

Stress-Strain Behavior of Soft Soil Stabilized with Nickel Slag, Limestone, and Aluminum Hydroxide

Soil stabilization by combining several minerals is a form of material engineering aimed at increasing the bearing capacity of the soil to a higher level. The development of waste-based materials and the utilization of local potential are part of environmentally conscious construction. This study aims to analyses the mechanical behaviour of soil stabilized with several pozzolanic materials derived from nickel processing waste and limestone, which are local materials with very large deposits. ASTM standards were used in this study for both physical and mechanical testing. Unconfined compressive strength (UCS) tests were conducted to compare the mechanical behaviour of stabilized soil with that of natural soil. The test samples used were cylindrical with a diameter of 35 mm and a height of 70 mm. The binding materials consisted of nickel slag, aluminium hydroxide, and limestone, with the amount of each material based on the dry soil weight (γdry). The addition of lime in this study was varied at 2%, 4%, and 6%. The test results generally show that lime variations and curing time affect the increase in unconfined compressive strength (qu), with the highest value of 30.91 kg/cm² observed at 6% lime content after 28 days of curing.

SUGAR CANE BAGASSE ASH IN CONCRETE: A REVIEW

Sugarcane bagasse ash (SCBA), a by product of sugarcane processing, has shown great potential as a supplementary material in concrete production. A review of its application in concrete highlights its benefits, including improved mechanical properties, durability, and sustainability. SCBA contains high levels of silica, which can act as a pozzolanic material, enhancing the compressive strength and reducing the permeability of concrete. Incorporating SCBA also lowers the carbon footprint of concrete, contributing to greener construction practices by partially replacing cement. However, challenges remain, such as the variability in ash quality, proper ash treatment, and optimal blending ratios. Ongoing research focuses on refining these aspects to maximize the benefits of the SCBA in concrete, making it a promising alternative in the construction industry for sustainable development. Keyword - Sugarcane bagasse ash, Compression strength, Percentage strength, Sugarcane Workability, Slump test.

Strength, durability, and heat development characteristics of high-performance concrete containing ground coal bottom ash with low and high calcium

Currently, the availability of fly ash has reduced continuously due to the shutdowns of coal-fired power generating plant as climate change concerns have increased. Therefore, the aim of this paper is to find an alternative pozzolan by examining the employment of low- and high-calcium oxide (CaO) ground bottom ash which has been abandoned rather using in concrete production. The bottom ashes were blended with fly ash as a partial substitution of cement (OPC) by observing their generic effects on the compressive strength, cumulative heat generation, chloride ion penetration, and water sorptivity of high-performance concrete. The samples of bottom ash were prepared by oven drying, particle size cutting, and grinding to enhance the reactivity and consistency. High-performance concretes were made at a water-to-binder (W/B) ratio of 0.27 and partial replacement of OPC up to 50 % by weight of the binder. The results indicated that the concretes with 28-day compressive strengths of 101.0 and 109.0 MPa (21.6 % and 28.2 % stronger than OPC concrete) were produced with 50 wt% OPC replacement with high- and low-calcium ground coal bottom ashes (HCBA and LCBA), respectively. These findings suggest that HCBA and LCBA have high pozzolanic reactivity and high possibility for utilization as pozzolan or supplementary cementitious materials in concrete. In addition, the binary blended binders (OPC-HCBA and OPC-LCBA) and ternary blended binders (OPC-HCBA-FA and OPC-LCBA-FA) produced had better chloride ion penetration resistance, less cumulative heat evolution, and lower water sorptivity than 100 % OPC as a cementitious material. Partial OPC replacement by HCBA and LCBA improved the chloride ion penetrability class of OPC concrete from “very low” to “negligible.” The cumulative heat generation due to the pozzolanic reaction of HCBA and LCBA from the partial replacement of OPC up to 50 % reduced 30–44 % relative to the OPC-based mixture throughout during 72 hours after mixing. The CaO content strongly influenced early compressive strength development and cumulative heat evolution but had less impact on chloride ion penetration resistance and water sorptivity.

Modeling and Optimization of Sisal Fiber Degradation Treatment by Calcined Bentonite for Cement Composite Materials

ABSTRACT The treatment of sisal fiber by pozzolanic materials like kaolin and silica-fume has been explored; however, no study has modeled and optimized the effect of sisal fiber degradation treatment using calcined bentonite. Therefore, the present study investigate the effects of treating sisal fiber with different doses of calcined bentonite, bentonite calcination temperatures, and times on fiber breaking load, degradation resistance, and water absorption using the central composite design-response surface method (CCD-RSM). The best performance of the optimum treated sisal fiber selected from the CCD-RSM based on the established goal of maximizing breaking load and degradation resistance with minimum water absorption, it was obtained a calcined bentonite dose of 30.067%, a bentonite calcination temperature of 800°C, and a calcination time of 179.99 min. Based on these factors, experimentally found sisal fiber breaking load 12.87 N, degradation resistance 98.44%, and water absorption 39.05%, all are within the 95% confidence level compared to the optimum numerical suggested values. Hence, the optimum treated sisal fiber improved breaking load by 33.37% and degradation resistance by 98%, while it reduced water absorption by 60.95%, compared to raw sisal fiber. Besides these, the optimum treated sisal fiber exhibits higher surface roughness and lower porosity than the raw sisal fiber.

Waste paper sludge ash as a pozzolanic material: Enhancing concrete performance and sustainability

Waste paper sludge ash as a pozzolanic material: Enhancing concrete performance and sustainability

Comparative Study of Mechanical Properties of Self Compacting Concrete Using Binary Pozzolanic Materials

Abstract: The study examined the viability of using waste supplementary cementing materials (SCMs), such as fly ash (FA) and silica fume (SF), as partial replacement of Ordinary Portland cement. The way SCC's fresh properties and hardened were impacted by FA and SF. The study examined the fresh characteristics and hardened characteristics of various distinct SCC mixes using SCC with partial replacement of Ordinary Portland Cement with FA (class F) and SF. First, the cement was replaced by percentages in the mixes 0%, 10%, 15%, 20%, 25%, and 30% by FA and constant replacement of 10% by SF. Then cement was replaced by percentages in the mix with 25% FA constant and 4%, 6%, 8%, 10%, and 12% by SF. For every combination, the water/binder (w/b) ratio was set at 0.43. The EFNARC (Specification and Guidelines for Self-Compacting Concrete) standards were met by the slump flow, T50, and viscosity of the SCC. After 28 days of curing, the blend consisting of 65% PC, 25% FA, and 10% SF had a maximum compressive strength of 41.22 MPa which is 12.07% greater than the compressive strength of the control specimen which is 36.78 MPa. The Split Tensile Strength of the same blend is 4.37% is greater than the control specimen. Non-destructive tests were also performed after 28 days of curing and the regression equations give the excellent relationship between Rebound Number, Ultrasonic Pulse Velocity, and Compressive Strength. This is due to the formation of the proper matrix as the particle size of SF and FA is less than that of cement and the free lime of cement reacts with FA and SF to form C-S-H gel which provides strength.

Hybrid Effect of Metakaolin and Nano-Silica on Mechanical and Durability Parameters of Mortar

The incorporation of pozzolanic materials such as nano silica and metakaolin in cementitious materials has gained significant attention in recent years due to their potential to improve the mechanical and durability properties of cement-based composites. This thesis investigates the hybrid effect of nano silica and metakaolin on the mechanical and durability properties of cement mortar. The research work involved the preparation of cement mortar specimens with varying proportions of nano silica and metakaolin, which were then subjected to a series of mechanical and durability tests. The mechanical tests included compressive strength, while the durability tests included water absorption and elevated temperature test. The study showed that the addition of both nano silica and metakaolin to cement mortar resulted in a significant improvement in the mechanical properties of the mortar. Additionally, the hybrid effect of nano silica and metakaolin resulted in enhanced durability of the cement mortar, with a significant reduction in water absorption and improved temperature resistance. The findings of this study will have significant implications for the development of sustainable and durable cementitious materials. The use of pozzolanic materials such as nano silica and metakaolin can reduce the consumption of cement and the associated carbon footprint while also improving the durability and long-term performance of cement-based composites. Overall, this study suggests that the incorporation of nano silica and metakaolin can lead to significant improvements in the mechanical and durability properties of cement mortar, making it a promising material for use in various construction applications.

Investigation of self-compacting concrete utilizing different supplementary pozzolanic materials for cement replacement

This study enhances self-compacting concrete (SCC) properties by adjusting the mix design, reducing the water-to-cement ratio, and adding permeability-reducing admixtures (GGBS, fly ash, silica fume, bentonite). Different admixture proportions were tested to improve mechanical characteristics. Four SCC mixtures were formulated, varying GGBS and fly ash (0-70%) and silica fume and bentonite (0-20%). Auromix 300 plus (0.6% by weight of cement) was used as a chemical admixture. Strength properties (compressive, flexural, split tensile, elastic modulus) were evaluated on specimens cured normally for 28 days, then in NaCl for 56-112 days. Optimal mixtures were found: GGBS 30% for compressive strength, bentonite 10% for flexural and split tensile strength. Results indicate increased strength and reduced porosity by incorporating these materials.

Investigation of Sugarcane Bagasse Ash (SBA)-Based Engineered Geopolymer Mortar Reinforced with Coconut Fibre for Engineered Geopolymer Composites

In recent years, there have been growing demand for fibre-reinforced cementitious composites using materials wastes to reduce cost and cement usage in concrete production. Therefore, this study aims to prepare sugarcane bagasse ash (SBA)-based geopolymer reinforced with coconut fibre as a material suitability evaluation for engineered geopolymer composites. The sugarcane baggase ash was characterised for its physical and chemical properties using scanning electron microscopy (SEM), Energy dispersive X-ray spectroscopy (EDS), X-ray powder diffraction (XRD). The coconut fibres was added at 0%, 1%, 2%, and 3%, while the plain cement mortar was used as the control mix. Both destructive (compressive and tensile strength) and non- destructive test (water absorption, and ultrasonic pulse velocity test) were conducted on the resulting geopolymer mortar. The result of the SBA characterisation showed that the SBA met the ASTM C618 requirement for a pozzolanic material. The addition of 1% fibre to the geopolymer composite resulted in enhanced durability property than the plain cement mortar. The ultrasonic pulse velocity test demonstrated that bagasse ash-based geopolymer composites can be classified as a excellent cementitious material. The study also found the engineered cementitious composite showed better compressive and tensile strength than the plain concrete mortar, while the addition of fibre provided a denser microstructure for additional strength. The optimum fibre content was found at 1% for improved water absorption performance, UPV, and compressive strength. The study concludes that SBA composite reinforced with coconut fibre can provide better alternatives to achieve sustainability in engineered geopolymer concrete applications.

Prediction of strength activity index using chemical and physical properties of pozzolans

Reductions in cement use have essential benefits in reducing the embodied energy in concrete and CO2 emissions. Hence, effective assessment of potential pozzolanic materials is highly desirable to facilitate usage as sustainable supplementary cementitious materials (SCMs). However, assessment of pozzolanic reactivity using conventional experimental tests is typically time-consuming and expensive. Pozzolanic reactivity is mainly related to the chemical and physical characteristics of various pozzolans, such as amorphous silica and alumina contents and specific surface area. This study develops and presents an equation that can predict the strength activity index (SAI) as an indirect method for the assessment of potential pozzolans and their strength outcome using their chemical and physical properties. The development of a prediction equation not only saves time and resources but also helps with designing optimized and improved pozzolanic SCMs. The strength activity index (SAI) of seven different materials with varying pozzolanic properties was measured at an age of 90 days. The powdered test materials included pottery cull, brick powder, lightweight aggregate fines, glass powder, silica fume, dolostone, and Class C fly ash. In the second stage, correlation analyses were performed to find parameters (based on chemical and physical properties) that were highly correlated with SAI. An equation was then developed as a function of the chemical and physical properties of raw pozzolanic materials using an optimization tool. Consequently, an equation predicting SAI was derived which had a high degree of correlation (R = 0.972) with measured SAI.

A Short Review on the Utilization of Pozzolan Material in Concrete

A Short Review on the Utilization of Pozzolan Material in Concrete

The influence of sugarcane bagasse ash on the microstructure of autoclaved cementitious material: Comparative study with amorphous and crystalline silica

This study aimed to investigate the effects of a partial replacement (25 wt%) of Portland cement with sugarcane bagasse ash (SCBA) on the microstructure of cement pastes. The effects were compared with those of pastes containing amorphous (silica fume) or crystalline (crushed quartz) silica. Two curing methods were used for the pastes: conventional curing (25 °C and RH > 95%) and autoclave curing (220 °C under 2.1 MPa for 8 h). The microstructure of the pastes was characterized by XRD, SEM, FTIR, and the hardness and elastic modulus of their C–S–H regions. The results showed that the pastes cured at room temperature exhibited similar microstructure development, showing little or no reaction, even though silica fume is a highly reactive pozzolanic material. Differently, the hardness of the pastes containing silica fume, SBCA and crushed quartz replacement for cement increased approximately threefold after autoclave curing, while, in contrast, the reference sample, no cement replacement, showed no improvement. This is attributed to the formation of tobermorite and xonotlite. The presence of Al in the SCBA allowed the formation of tobermorite under the autoclave curing conditions (220 °C, 2.1 MPa for 8 h), and in this case, the SCBA exhibited behavior between silica fume and fine quartz.