Potential Storage Sites Research Articles

A prospective approach to the optimal deployment of a hydrogen supply chain for sustainable mobility in island territories: Application to Corsica

This study develops a framework for designing hydrogen supply chains (HSC) in island territories using Mixed Integer Linear Programming (MILP) with a multi-period approach. The framework minimizes system costs, greenhouse gas emissions, and a risk-based index. Corsica is used as a case study, with a Geographic Information System (GIS) identifying hydrogen demand regions and potential sites for production, storage, and distribution. The results provide an optimal HSC configuration for 2050, specifying the size, location, and technology while accounting for techno-economic factors. This work integrates the unique geographical characteristics of islands using a GIS-based approach, incorporates technology readiness levels, and utilizes renewable electricity from neighboring regions. The model proposes decentralized configurations that avoid hydrogen transport between grids, achieving a levelized cost of hydrogen (LCOH) of €8.54/kg. This approach offers insight into future options and incentive mechanisms to support the development of hydrogen economies in isolated territories.

Risk assessment and management strategy of geologic carbon storage in multi-well site

Many oil and gas production areas may serve as potential geologic carbon storage(GCS) sites, but large-scale CO2 injection in these sites with multiple legacy wells poses a leakage risk. Therefore, it is crucial to analyze the well leakage risk of these GCS sites and develop effective risk management strategies to minimize CO2 and brine leakage. In this study, we hypothesized a GCS site based on the Jingbian area in the Ordos Basin, which has 177 legacy wells. We conducted a three-dimensional geological modeling of the site and simulated the injection and migration of CO2. Using the National Risk Assessment Partnership’s open-source Integrated Assessment toolkit, we outlined a workflow for assessing the risk of CO2 and brine leakage in multi-well site. Simulations of CO2 and brine leakage through 177 existing wells into the USDW or the atmosphere are used as an indicator of potential risk. Finally, we proposed risk management strategies based on well integrity, injection rate, and pollution range, verifying their effectiveness. The results of the 95th percentile (P95) model implementation showed that the leakage risk of GCS sites was low over 150 years, with a CO2 leakage of 15,996.4 tonnes(0.16 % of the 107 t injected). The risk-based strategy outperformed both distance-based strategy and hybrid strategy overall. Reducing injection rates alone proved ineffective as a risk management strategy. Only high-risk wells near the injection zone may cause pollution to USDW. Meanwhile, legacy wells have negligible impact on atmospheric pollution. The management strategy based on pollution range can be used as a supplement to the risk-based strategy in practical engineering.

Structural and Reservoir Characteristics of Potential Carbon Dioxide Storage Sites in the Northern South Yellow Sea Basin, Offshore Eastern China

The geological storage of carbon dioxide (CO2) in offshore saline aquifers stands as a primary option for reducing CO2 emissions in coastal regions. China’s coastal regions, particularly Shandong and Jiangsu provinces, face significant challenges in CO2 reduction. Therefore, evaluating the feasibility of CO2 geological storage in the adjacent seas is critical. To assess the suitability of a CO2 storage site, understanding its structural and reservoir characteristics is essential to mitigate injection and storage risks. In this study, we analyzed the structural characteristics and potential traps of the Yantai Depression in the South Yellow Sea Basin based on seismic data interpretation. We further conducted well logging analysis and post-stack seismic inversion to obtain lithological data, including acoustic impedance and sandstone content percentages from the Cenozoic Funing Formation, Dainan–Sanduo Formation, and Yancheng Formation. Our findings highlight that the Yantai Depression in the South Yellow Sea Basin exhibits diverse structural traps and favorable reservoir–caprock combinations, suggesting promising geological conditions for CO2 storage. This area emerges as a suitable candidate for implementing CO2 geological storage initiatives.

The role of the Messinian evaporites in the identification of potential gas storage sites: A review of the Adriatic foreland basin system (Italy)

AbstractFocusing on the late Miocene succession stratigraphic successions including the evaporite deposits from the Messinian salinity crisis (MSC) of the Adriatic foreland basin, a revision of available boreholes and seismic data allowed us to recognize the presence of reservoirs and seals systems that can be considered of potential interest for the storage of natural and synthetic gas. Potentially good reservoir sites can be found where porous rocks referable to siliciclastic turbiditites (Marnoso‐arenacea and Laga Fms) or shallow‐water carbonates (Bolognano Fm) preferentially involved in anticlinal structures and covered by thick MSC evaporites, which may represent effective reservoir seals. The integrated reconstruction of porous rocks distribution and facies, thickness, and lateral continuity of the overlying evaporites, allows the identification and zonation of geological settings in the Adriatic foredeep, backbulge and foreland with peculiar stratigraphy and deformations, only partially considered before, that may deserve consideration in the research of potential gas storage sites.

In-situ study of CO2-saturated brine reactive transport in carbonates considering the efficiency of wormhole propagation

Deep limestone aquifers are potential CO2 storage sites, but CO2-saturated brine reacts with the carbonate rock, changing its transport and storage properties. This study provided a preliminary investigation of the optimal injection rate of CO2-saturated brine in carbonate rocks. Indiana limestone cores were subjected to CO2-saturated brine injection at varied rates using an HPHT coreflooding setup with X-ray CT monitoring. The samples were characterized pre- and post-treatment in terms of porosity and pore size distribution using a gas porosimeter and NMR T2 measurements. Moreover, the reaction was evaluated by measuring the aqueous effluent calcium ions concentration as a function of throughput using ICP-OES analysis. A high-resolution micro-CT scan was used to capture the dissolution post-treatments and characterize the wormhole's size and patterns. Results showed that the wormholes broke through to the sample exit face after injecting 160, 48, and 36 pore volumes at 0.5, 1, and 2 cm3/min, respectively thereby revealing the importance of injection velocity. The ICP-OES analysis revealed that a larger dissolution rate was achieved at 2 cm3/min, which explained the fast wormhole propagation. An increase in rock porosity and the pore-size distributions was observed after coreflooding on all samples with minimum precipitation, as concluded from the NMR T2 relaxation time. A universal optimum Damköhler number can be obtained that enables calculating the optimum injection rate of CO2-saturated brine at different rock and fluid conditions. We speculated that the optimum Damköhler number could be different from the value of 0.29 proposed by Fredd and Fogler (1998). This study provides a preliminary understanding of the optimal CO2-saturated brine injection velocity that has an application for CO2 storage, water alternating gas (WAG) operations, and acid stimulation of carbonate formations.

Design Insights for Industrial CO2 Capture, Transport, and Storage Systems.

We present methods and insights for the design of CO2 capture, transport, and storage systems for industrial facilities with a case study focus on Louisiana. Our analytical framework includes (1) evaluating the scale and concentration of capturable CO2 emissions at individual facilities for the purpose of estimating the cost of CO2 capture retrofits that utilize various energy supply sources to meet parasitic demands; (2) screening to identify potential CO2 storage sites and estimate their capacities, injectivities, and costs; and (3) designing cost-minimized trucking or pipeline infrastructure connecting CO2 capture plants with storage sites, considering existing land uses, demographics, and a variety of social and environmental justice factors. Estimated levelized costs of capture at Louisiana's 190 industrial facilities range from below $50/tCO2 to above $500/tCO2, depending on facility-specific features. We identified 98 potential storage sites with storage costs ranging from $8 to $17/tCO2. We find that in most situations, pipelines are the least-costly mode of CO2 transport. When industrial facilities in a region share pipelines, aggregate pipeline mileage and average transport costs are dramatically lower than without sharing. Shared pipeline networks designed to avoid disadvantaged communities require right-of-way areas compared to those for networks that transect such communities, but result in 25% higher average per-tonne transport cost.

Key indicators of caprock sealing assessment with consideration of faults in potential CO2 geological storage sites in Subei Basin, China

Good caprock sealing is crucial for ensuring the long-term safety and security of carbon dioxide (CO2) geological storage. However, concealed faults within caprocks and reservoirs can impact the transport and accumulation of CO2 plumes. Due to the uncertainties associated with the geometric structure, physical properties, and combined relationships among reservoir, caprock and fault, accurately evaluating caprock sealing is challenging. To address the challenge of identifying key indicators for caprock sealing considering faults, this study focuses on the one potential CO2 geological storage field in the Subei Basin, China. First, this study establishes a hydraulic-mechanical (HM) coupled finite element model considering a combination of caprock, reservoir and fault. Then, 22 research indicators, including fault offset, fault dip, caprock thickness, burial depth, permeability and mechanical properties, are analysed to evaluate their influence on caprock sealing via the tornado analysis and response surface methods. Finally, key indicators are determined based on evaluation criteria, such as pore pressure increment (ΔPP) and Coulomb failure stress (CFS), in the fault plane. The research results indicate that fault dip, fault offset, fault permeability, burial depth, and reservoir permeability are key indicators. The caprock thickness, caprock permeability, and caprock Young's modulus significantly influence the caprock sealing capacity. The ΔPP and CFS increase with increasing fault dip and offset. When the fault dip exceeds 45°, the ΔPP and CFS reach maximum values at the interface between the reservoir and caprock. Fault permeability has a greater impact than reservoir permeability and caprock permeability. The research results may provide guidance for the evaluation of caprock sealing capacity for CO2 geological storage.

Public perception and acceptance of CCUS: preliminary findings of a qualitative case study in Greece.

The development and implementation of carbon capture, utilisation and storage (CCUS) technologies plays an increasingly important part in European Union (EU) countries' decarbonisation policies and strategies. Several studies have shown the important role social acceptance plays in determining the outcomes of CCUS projects and how social acceptance is shaped by the national and local contexts. Yet most studies on CCUS and social acceptance have focused on a few northern European countries despite the increasing numbers of CCUS projects across the European Union. This study seeks to help address this gap by conducting a case study on how local dynamics shaped people's acceptance and awareness of CCUS in two separate Greek communities. Based on semi-structured interviews with community members near a CCUS pilot plant, and a focus group with community members from a potential storage site, this single case study explores the factors and dynamics that shaped the participants' perceptions of CCUS technologies. Our findings indicate that, despite the low level of awareness of CCUS technologies, participants could draw on their situated knowledge to identify potential drawbacks with their application. We identified scepticism regarding the adoption of new technologies and the organisations involved based on past experiences, and a notable lack of provision of technology and location-specific information as well as public engagement by the project consortium. Our recommendations for future projects and community engagement include the early involvement of the public in project development, location-based transparent information, appropriate channels to facilitate knowledge exchange, and educational initiatives to build communities' capability to influence projects.

Laboratory Experiments and Geochemical Modeling of Gas–Water–Rock Interactions for a CO2 Storage Pilot Project in a Carbonate Reservoir in the Czech Republic

The aim of this study was to characterize the influence of CO2 in geological structures on mineralogical changes in rocks and assess the sequestration capacity in mineral form and solution of a potential pilot storage site in the Czech Republic. Rock samples from a dolomite reservoir and the overburden level, as well as the corresponding pore water, were used. The most important chemical process occurring in the reservoir rock is the dissolution of carbonate minerals and feldspars during the injection of CO2 into the structure, which increases the porosity of the structure by approximately 0.25 percentage points and affects the sequestration capacity of the reservoir rock. According to the results of geochemical modeling, the secondary carbonate minerals (dolomite, siderite, and ephemeral dawsonite) were present only during the first 50 years of storage, and the porosity at this stage decreased by 1.20 pp. In the caprocks, the decomposition of K-feldspar and calcite resulted in an increase in porosity by 0.15 percentage points at the injection stage only, while no changes in porosity were noted during storage. This suggests that their insulation efficiency can be maintained during the injection and post-injection periods. However, further experimental research is needed to support this observation. The results of this study indicate that the analyzed formation has a low potential for CO2 sequestration in mineral form and solution over 10,000 years of storage, amounting to 5.50 kg CO2/m3 for reservoir rocks (4.37 kg CO2/m3 in mineral form and 1.13 kg CO2/m3 in dissolved form) and 3.22 kg CO2/m3 for caprock rocks (3.01 kg CO2/m3 in mineral form and 0.21 kg CO2/m3 in dissolved form). These values are lower than in the case of the depleted Brodské oil field, which is a porous reservoir located in the Moravian part of the Vienna Basin.

Generalized functionals for qualification of geological carbon storage injection sites

Many nations have pledged to reach carbon neutrality by 2050. Embarking on the decarbonization journey, they posited geological carbon storage (GCS) as a pivotal technology within the carbon capture, utilization, and storage (CCUS) framework. The CCUS chain operates to reduce “hard-to-abate” emissions at key sectors by capturing carbon dioxide (CO2), reusing it, transporting it, or disposing of it via injection into underground geological formations for permanent storage. Despite the global success of GCS ventures, mainly driven by the oil and gas industry, GCS initiatives are still in their early stages in several developing countries. In Brazil, for instance, a full setup covering precise storage capacity databases, potential CCUS clusters, national regulatory structure, and auxiliary computer-aided engineering is underway. Intended to push the frontier in the latter subject, this paper introduces mathematical models for qualifying underground CO2 storage sites. Our research explores a family of multivariate functionals endowed with underlying reservoir features and distinct weighting functions, thus envisioning two primary objectives. Firstly, it clarifies non-linear interactions between rock and fluid properties using quality indicators. Secondly, it evaluates geographical regions considering structural traps/caprocks settings. Backed by the Matlab Reservoir Simulation Toolbox (MRST) capabilities, the methodology is a subsidiary resource for identifying suitable injection and storage sites. A case study using the UNISIM-I-D model generated dozens of volumetric quality maps that point to unique potential storage sites. Numerical simulation experiments of injection comparing legacy and novel wells reveal storage surpluses improved by up to 50%. The paper seeks to establish foundational knowledge in GCS efficiency for general underground settings. One expects that these outcomes leverage well-repurposing perspectives and stimulate field appraisal actions to scale up GCS projects both in Brazil and worldwide.

A one-dimensional diffusive transport model to evaluate H2S generation in salt caverns hydrogen storage sites

Salt caverns are considered a potential hydrogen storage site given the ductility, tightness, and chemical inertness of halite. In addition, unlike porous media, salt caverns require less cushion gas and allow more cycles of injection and production within a year. However, hydrogen is an electron donor for many hydrogenotrophic microorganisms including halophilic sulfate-reducing microbes (SRM) and hydrogen sulfide (H2S) can be generated in a cavern once sulfate and hydrogen become available in the aqueous phase. As salt deposits are often associated with large amounts of impurities such as anhydrite and gypsum, their dissolution during the leaching phase can release the required sulfate ions for SRMs to produce H2S once hydrogen diffuses and dissolves in the brine at the bottom of the cavern. In this study, a one-dimensional diffusive transport model was developed using PHREEQC to simulate sulfate reduction and H2S generation in a cavern at the gas-brine interface. The solution of Fick's diffusion equation was used to calculate the hydrogen concentration at each level of the 1D model while the kinetic rates of reactions were derived from reported experimental and field site observations of brine samples taken from salt caverns. The results obtained indicated that hydrogen consumption at the gas-brine interface can trigger H2S and methane formations. This is followed by a reduction in sulfate and carbonate concentration and a slight increase in pH due to the reduction of protons in the solution. It was also observed that the presence of Fe2+ ions can reduce the amount of the hydrogen sulfide production while Ca2+ ions slightly favour sulfate reduction due to the production of methane. Although the kinetic reaction rate of the reactions in the model is subject to a certain degree of uncertainty, the workflow and results this study can serve as a guide for the future storage of hydrogen in salt caverns.

New Uses for Coal Mines as Potential Power Generators and Storage Sites

New Uses for Coal Mines as Potential Power Generators and Storage Sites

Interactions at the interfaces of the H2-brine-cement systems at elevated pressures for H2 storage

There is a global demand on assessment of potential subsurface gas storage sites in view of safely injecting hydrogen or carbon dioxide. One relevant aspect that has already been subject to thorough investigation is the mutual interaction of all participating compounds in terms of the wetting behaviour that on its turn is directly related to the predominating capture mechanisms. Given the diversity of the geophysical and geochemical circumstances, transferability of results from work conducted on one geological site to another location is limited. For instance, there is a large number of publications on wettability of many different rock types in hydrogen atmosphere that are partly controversal and strictly applicable only to the respective reported system. Hence, there is a gap in finding general model approaches that serve for a holistic understanding of predominating mechanisms and building the fundamentals for predicting the behaviour of systems that have not been studied so far. The presented work addresses this gap by quantifying mutual interactions of the participating phases in a solid-liquid-gas systems and determining the respective interfacial tensions, γSV (solid-vapor), γLV, (liquid-vapor) and γSL (solid-liquid).Neumann and Good demonstrated how to determine the solid-fluid interfacial tension based on the contact angle and the liquid-gas interfacial tension by calculating a so-called molecular interaction parameter. Up to date, this method has been applied, among others, for systems containing CO2 and solids such a teflon, glass, and steel. The methodology could be confirmed by testing systems comprising steel - H2O - CH4 /H2 and comparing the results to the aforementioned literature data.As one of the critical parts in H2 underground storage, the completion system containing a common well cement, H2 and brine was subject to this work. The interfacial tension between H2 and brine as well as the contact angle between the fluid phases and the cement were investigated experimentally up to 20 MPa, temperatures from 313.15 to 353.15 K and NaCl – concentrations of up to 10% wt. As a theoretical approach, the interfacial tension of the system H2O+H2 was investigated using the density gradient theory (DGT) in combination with the perturbed chain statistical associating fluid theory equation of state (PC-SAFT). Finally, the H2-cement interfacial tension is determined through the calculation of a so-called molecular interaction parameter. The interfacial tension data of H2O+H2 experimentally and theoretically determined in this work agree among each other as well as with previous literature data. Likewise, agreement was found between the brine+H2 interfacial tension and previous studies. The contact angle appears to be influenced mostly by pressure, producing a less H2O/brine-wet system as pressure increases. The H2-cement interfacial tension decreases from approximately 150 mN/m down to 100 mN/m, as the pressure increases from 0.1 to 20 MPa. The presented data suggest H2 to be slightly adsorbed on the one hand but the capillary entry pressure to decrease on the other, causing concerns regarding the integrity of the completion system.

Research on the helium seepage mechanism in the strata surrounding bedded salt cavern helium storage and its tightness evaluation

To improve the safety and scale of helium storage, large-scale or strategic helium storage in underground salt caverns can be implemented. Salt caverns leached from bedded salt formations have been considered as potential underground storage sites for helium in China. However, the salt formations are typical lacustrine sedimentary rocks with an interbedded structure, thus the sealing feasibility of such salt caverns must be evaluated before they can be used. To this end, the helium seepage equation in deep strata and permeability evolution function are derived with the help of experimental results and theoretical analysis. Based on these, a helium seepage model considering slippage effect and threshold pressure gradient is proposed to evaluate the sealing properties of salt caverns for helium storage. The analysis results indicate that it is feasible to use bedded salt mine formations for helium storage when the formations permeability parameters and reservoir design parameters meet the long-term tightness evaluation criteria, including permeability, porosity, salt pillar width, salt roof thickness and operating pressure and duration. More importantly, specific recommendations are provided for the operation parameters, design parameters and formation permeability thresholds of salt caverns for ensuring helium storage safety while maintaining stable cavern operations. The threshold permeability of the target salt formations should be approximately 1 × 10−18 m2 to ensure tightness. The minimum and maximum operating pressure are recommended to be 10 MPa and 18 MPa respectively for 50 years of this helium storage. The salt pillar width should be 300 m, and the salt roof thickness should be 40 m.

Strategic Qualitative Risk Assessment of Thousands of Legacy Wells within the Area of Review (AoR) of a Potential CO2 Storage Site

The subsurface confinement of anthropogenic carbon dioxide (CO2) demands robust risk assessment methodologies to identify potential leakage pathways. Legacy wells within the Area of Review (AoR) represent one potential leakage pathway. Robust methodologies require enormous amounts of data, which are not available for many old legacy wells. This study strategically categorizes 4386 legacy wells within the AoR of a potential CO2 storage site in the Illinois basin and identifies the high-risk wells by leveraging publicly available data—reports and well logs submitted to state regulatory agencies. Wells were categorized based on their proximity to the injection well location, depth, the mechanical integrity of well barriers, and the accessibility to these wells throughout the project lifecycle. Wells posing immediate risks were identified, guiding prioritized corrective actions and monitoring plans. Out of 4386 wells, 54 have high priority for corrective action, 10 have medium priority, and the remainder are of low priority. Case study results from the Illinois basin demonstrate the effectiveness and applicability of this approach, to assess the risk associated with legacy wells within the AoR of potential CO2 storage site, strategically categorizing over 4000 such wells despite data limitations.

Reservoir Static Modelling towards Safe CO2 Storage in Depleted Oil Reservoirs of ‘CRK’ Field, Niger Delta, Nigeria

Geological carbon storage (GCS) is gradually gaining acceptance as the technology of highest repute for the mitigation against greenhouse gas effect. This involves the injection and long-term or permanent storage of carbon dioxide (CO2) in subsurface geological formations. The development of a robust 3D reservoir model then becomes necessary to understand the facies changes and the petrophysical properties distribution of candidate CO2 storage reservoirs. This study attempts the use of static modelling technique to investigate the depleted oil and gas reservoirs of ‘CRK’ field in the Niger Delta sedimentary Basin as a potential CO2 storage site. Using an integrated approach of 3D seismic and a suit of well logs from the study area, two reservoir sands (D10C0 and D6200) were mapped. 3D static modelling of discrete and continuous property distribution of the reservoirs revealed the reservoirs are composed majorly of clean sands with water saturation ranging from 8 to 75%. The average porosity and permeability values are between 20 to 29% and 250 to 890mD respectively. A theoretical storage capacity of 24.85Mt is estimated for the two reservoirs combined, while the median effective storage capacity is 6.22Mt. Comparison of the results obtained in the study with recommended standard values show the reservoirs are suitable for CO2 storage. The property models constructed can serve as primary input for dynamic simulation of the oilfield in future studies.

The architecture of basalt reservoirs in the North Atlantic Igneous Province with implications for basalt carbon sequestration

Abstract Offshore CO 2 sequestration in basaltic formations of the North Atlantic Igneous Province may allow permanent storage of large volumes of CO 2 through rapid carbonate mineralization. Characterizing the internal architecture of such reservoirs is key to assessing the storage potential. In this study, six photogrammetry models and three boreholes on the Faroe Islands have been used to characterize the internal lava sequence architectures as a direct analogue to potential offshore North Atlantic Igneous Province storage sites. The studied formations are dominated by c. 5 to 50 m thick simple and compound lava flows, with drill core observations documenting a transition from pāhoehoe moving towards ‘a’ā lava flow types interbedded with thin (<5 m thick) volcaniclastic rock units. The identification of flow margin breccias is potentially important as these units form excellent reservoirs in several other localities globally. Stacked, thick simple flows may present sealing units associated with dense flow interiors. Connected porous and permeable lava flow crusts present potential reservoirs; however, the degree of secondary mineralization and alteration can alter initially good reservoir units to impermeable barriers for fluid flow. Large-scale reservoir volumes may be present mainly within both vesicular, fractured pāhoehoe and brecciated flow margins of transitional simple lava flows.

Artificial intelligence-based prediction of hydrogen adsorption in various kerogen types: Implications for underground hydrogen storage and cleaner production

Hydrogen offers significant potential as a sustainable energy source. However, its storage and transportation pose challenges due to its volatility and low density. Subsurface geological formations, such as shale, sandstone, and coal, have been investigated as potential storage sites for hydrogen. Precise estimation of hydrogen adsorption in these formations necessitates a thorough understanding of kerogens, organic-rich sedimentary rocks prevalent in unconventional formations. In this study, we introduce a novel approach employing Extreme Gradient Boosting (XGBoost), Random forest (RF), Light gradient Boosting (LGBM), and Natural gradient boosting (NGBM) algorithms to intelligently predict hydrogen adsorption in various kerogen types. Among these, the NGBM algorithm, utilizing three input features (temperature, pressure, and kerogen types), demonstrated the highest predictive accuracy, achieving an R2 value of 0.989, RMSE of 0.062, and MAE of 0.037 for all data samples. SHAP diagram analysis identified kerogen types as the most influential parameter within the NGBM model. The presented approach has implications beyond energy storage, highlighting the significance of advanced technologies in addressing complex energy challenges. Precise hydrogen adsorption estimation in subsurface formations is vital for developing sustainable energy solutions, and our approach has the potential to expedite progress in this field. Interdisciplinary collaboration among geologists, chemists, and data scientists is crucial for devising innovative solutions for sustainable energy.

Geomechanical Assessment of Potential Co2 Storage Sites in the Us Shallow Water Gulf Coast

Geomechanical Assessment of Potential Co2 Storage Sites in the Us Shallow Water Gulf Coast

Influence mechanism of interfacial organic matter and salt system on carbon dioxide hydrate nucleation in porous media

CO2 carbon sequestration in marine gas hydrate occurrence areas is a potential way to mitigate the continued growth of CO2 in the atmosphere. The organic matters of marine sediment can affect the phase equilibrium conditions of CO2 hydrate in salt system, and the organic salt system in pore medium has effect on the nucleation growth of CO2 hydrate. The organic matters on the surface of the sediment is mainly composed of lipids, proteins, carbohydrates, and unsaturated hydrocarbon organic compounds, and these polar functional groups weaken the inhibitory effect of salt ions on hydrates through coordination bonds and Ca ion complexation. The nucleation kinetics of CO2 hydrate under organic salt system in pore medium in marine environment is an important parameter determining the carbon sequestration of hydrate. In addition, experimental results show that clay surface organic matters (CSOM) can reduce the surface tension of pore water, and thus pore water migration occurs during hydrate growth and expansion. The basic background in our findings will bring a much better recognition of phase equilibrium conditions among the offshore marine sediment CO2 sequestration process and further assess the location of potential marine CO2 storage sites.