I–III–VI2-semiconductor-based nanocrystals of ZnSe–AgInSe2 solid solution ((AgIn)xZn2(1-x)Se2, ZAISe) with average sizes of 3.5–6.2 nm were successfully synthesized through thermal reaction of corresponding metal acetates and selenourea in a hot oleylamine solution. The optical property of ZAISe solid solution nanocrystals was tunable in a broad wavelength region from visible to near-infrared light by changing the composition of solid solution, where the energy gap of ZAISe nanocrystals was enlarged from 1.44 to 3.00 eV with an increase in the fraction of ZnSe in ZAISe, that is, with a decrease in x from 1.0 to 0. Both levels of conduction band and valence band edges, determined by photoelectron spectroscopy in air, were monotonously shifted to higher levels with an increase in the fraction of ZnSe. Quantum-dot-sensitized solar cells were fabricated with porous TiO2 film electrodes immobilized with ZAISe nanocrystals using 3-mercaptopropionic acid as a cross-linking agent. The light conversion efficiency ...