Porous Media Grain Research Articles

Physical experiment and pore-scale investigation of the clogging of polydisperse particles in saturated porous media during artificial groundwater recharge

Groundwater recharge engineering practices are usually accompanied by the migration and deposition of polydisperse particles. Solid particles may be retained in the pore space leading to clogging of the porous media and reducing groundwater recharge efficiency. However, the mechanism behind this clogging phenomenon remains poorly understood. Specifically, the relation of particle clogging at pore-scale and macroscale is unclear. Here, the influence of polydisperse particle size on clogging development patterns was studied utilizing a series of laboratory-scale column experiments in conjunction with pore-scale scanning electron microscopy (SEM) experiments. Particles with median particle sizes (dp50) of 0.66, 4.05, 11.83 μm were injected separately into the sand column to simulate particle clogging that occurs during groundwater recharge. SEM was used to directly observe particles deposition on porous media grain surface after the column experiments. By counting the size distribution of the particles on the media grain surface, the response of the particle deposition to the surface morphology of the media grains was analysed. Compared to dp50 of 4.05 and 11.83 μm, the spatial distribution of particles deposited in the sand column was more uniform at dp50 of 0.66 μm. The smallest particles (dp50 = 0.66 μm) used in the experiments ultimately formed mixed clogging, which was the result of the combined effects of particle deposition and aggregation. The particle deposition with dp50 = 4.05 and 11.83 μm ultimately exhibited hyper-exponential distribution and formed mixed and superficial clogging, respectively. At the same time, the concave region of the media grain surface played a dominant role in particle deposition. For dp50 = 4.05 μm, 69.41 % of the particles were deposited in the concave region, and for dp50 = 11.83 μm, the proportion was 90.1 %. The results help to better manage particle clogging in groundwater recharge and other engineering applications (e.g., groundwater source heat pump, and filtration project). In addition, these findings provide a theoretical reference for the development of numerical models to help recognize the probability of particles of different sizes to be captured in porous media.

Experimental study and modeling permeability damage in porous media due to asphaltene deposition

Asphaltene deposition in porous media has a destructive effect on well productivity during primary and secondary oil recovery. Previous research studies have presented models for permeability reduction due to particle deposition in porous media. In this study, a semi-experimental model was modified and a new model was introduced to predict permeability changes due to asphaltene retention in early times of precipitation. The modified model unlike common models considers the size of asphaltene particles, porous media grain size, fluid flow properties and precipitation in pore throat. A set of experiments are done to obtain the parameters needed for modeling and check the validity of model. Crude oil is used as fluid sample and a sand pack filled with glass beads is used as an artificial porous media in flood tests. To identify the size of asphaltene particles, microscopic technique is used. The results of experiments are used to investigate asphaltene deposition in porous media and evaluate model prediction. A new procedure based on the modified model is applied to obtain model parameters and simplify the calculations. The new model can eliminate the deficiencies in previous models for prediction of asphaltene deposition in early stages of particle retention. The model also is validated by experimental results that were reported in the literature before. The results show rational accommodation with experimental data.

Reversible and irreversible adsorption of bare and hybrid silica nanoparticles onto carbonate surface at reservoir condition

Realistic implementation of nanofluids in subsurface projects including carbon geosequestration and enhanced oil recovery requires full understanding of nanoparticles (NPs) adsorption behaviour in the porous media. The physicochemical interactions between NPs and between the NP and the porous media grain surface control the adsorption behavior of NPs. This study investigates the reversible and irreversible adsorption of silica NPs onto oil-wet and water-wet carbonate surfaces at reservoir conditions. Each carbonate sample was treated with different concentrations of silica nanofluid to investigate NP adsorption in terms of nanoparticles initial size and hydrophobicity at different temperatures, and pressures. Aggregation behaviour and the reversibility of NP adsorption onto carbonate surfaces was measured using dynamic light scattering (DLS), scanning electron microscope (SEM) images, energy dispersive X-ray spectroscope (EDS), and atomic force microscope (AFM) measurement. Results show that the initial hydrophilicity of the NP and the carbonate rock surface can influence the NPs adsorption onto the rock surfaces. Typically, oppositely charged NP and rock surface are attracted to each other, forming a mono or multilayers of NPs on the rock. Operation conditions including pressure and temperature have shown minor influence on nano-treatment efficiency. Moreover, DLS measurement proved the impact of hydrophilicity on the stability and adsorption trend of NPs. This was also confirmed by SEM images. Further, AFM results indicated that a wide-ranging adsorption scenario of NPs on the carbonate surface exists. Similar results were obtained from the EDS measurements. This study thus gives the first insight into NPs adsorption onto carbonate surfaces at reservoirs conditions. High pressure/temperature cell for surface treatment with nanoparticles (nanofluid) at reservoir condition.

Removal of NAPL from columns by oxidation, sparging, surfactant and thermal treatment

In this paper, four treatment techniques commonly applied to Volatile Organic Compounds (VOC) removal from soil are compared in column experiments with pure sand containing a residual Light Non-Aqueous Phase Liquid (L-NAPL) contamination. Oxidation is tested through the injection of Fenton reagent, with persulfate, and combined with sparging with the injection of ozone. Surfactant treatment was conducted at low flow rates with Tween®80. Sparging was conducted by air injection but at a low flow rate of 1 mL min−1. Finally several columns were thermally treated at a temperature of 80 °C. The results showed high removal (>90%) for all techniques used, although only thermal treatment on BTEX (Benzene, Toluene, Ethylbenzene and Xylenes) reached 100% efficiency. The main limiting factors of each technique were: (i) for oxidation, the solubility of the substance limited the removal; (ii) for surfactant both the solubility in the surfactant and the type of surfactant are important; (iii) for sparging, the main factors are contaminant vapor pressure and porous media grain size; (iv) for thermal treatment, the limitation arises from the contaminant vapor pressure and the medium hydraulic conductivity. A comparison with literature data shows that the results are consistent with most of the studies conducted on one technique.

Transport and retention of carbon dots (CDs) in saturated and unsaturated porous media: Role of ionic strength, pH, and collector grain size

Carbon-based engineered nanoparticles (ENPs) are widely used in consumer products due to their small size and unique physicochemical properties. Therefore, their release and distribution into the surface and subsurface environment is a subject of concern. Several studies have evaluated the transport and retention of carbon nanotubes and fullerenes, but none investigated the transport and retention of carbon dots (CDs). The aim of this research is to fill this knowledge gap by evaluating the transport and retention of CDs in saturated and unsaturated porous medium. Here, we investigate the effects of solution ionic strength (IS, 1–700 mM NaCl) and pH (4–9), the initial concentration of CDs (50–200 mg L−1), and porous media grain size (0.20–0.50 mm, 0.50–1 mm, 1–1.5 mm and 1.5–2 mm grain diameters) on the transport and retention of CDs in saturated (upward flow) and unsaturated (downward flow) quartz porous media. A mathematical model based on the advection-dispersion equation coupled with the second-order kinetics was used to fit the breakthrough curves and to calculate the attachment and straining rates under the different experimental conditions. These analyses were underpinned by characterization of CD surface functional groups, surface charge and aggregation under the different experimental conditions, calculation of CD-CD and CD-quartz sand interaction potential according to DLVO theory.Transport and retention of CDs in quartz porous media are consistent with those observed for other types of carbon-based ENPs such as fullerenes and carbon nanotubes. Mobility of CDs in both saturated and unsaturated porous media increases with the decrease in ionic strength, increase in pH, and increase in collector grain size. Retention of CDs increases with the increase in IS, decrease in pH and decrease in grain size. Generally, CDs mobility was higher under saturated than under unsaturated flow conditions, for the same experimental conditions. Overall, CDs tend to be highly mobile and could travel for long distances at a wide range of environmental conditions.

Porous media grain size distribution and hydrodynamic forces effects on transport and deposition of suspended particles

The effects of porous media grain size distribution on the transport and deposition of polydisperse suspended particles under different flow velocities were investigated. Selected Kaolinite particles (2–30μm) and Fluorescein (dissolved tracer) were injected in the porous media by step input injection technique. Three sands filled columns were used: Fine sand, Coarse sand, and a third sand (Mixture) obtained by mixing the two last sands in equal weight proportion. The porous media performance on the particle removal was evaluated by analysing particles breakthrough curves, hydro-dispersive parameters determined using the analytical solution of convection–dispersion equation with a first order deposition kinetics, particles deposition profiles, and particle-size distribution of the recovered and the deposited particles. The deposition kinetics and the longitudinal hydrodynamic dispersion coefficients are controlled by the porous media grain size distribution. Mixture sand is more dispersive than Fine and Coarse sands. More the uniformity coefficient of the porous medium is large, higher is the filtration efficiency. At low velocities, porous media capture all sizes of suspended particles injected with larger ones mainly captured at the entrance. A high flow velocity carries the particles deeper into the porous media, producing more gradual changes in the deposition profile. The median diameter of the deposited particles at different depth increases with flow velocity. The large grain size distribution leads to build narrow pores enhancing the deposition of the particles by straining.

Bacteria cell properties and grain size impact on bacteria transport and deposition in porous media

The simultaneous role of bacteria cell properties and porous media grain size on bacteria transport and deposition behavior was investigated in this study. Transport column experiments and numerical HYDRUS-1D simulations of three bacteria with different cell properties (Escherichia coli, Klebsiella oxytoca, and Rhodococcus rhodochrous) were carried out on two sandy media with different grain sizes, under saturated steady state flow conditions. Each bacterium was characterized by cell size and shape, cell motility, electrophoretic mobility, zeta potential, hydrophobicity and potential of interaction with the sand surface. Cell characteristics affected bacteria transport behavior in the fine sand, but similar bacteria breakthroughs and retardation factors observed in the coarse sand, indicated that bacteria transport was more depended on grain size than on bacteria cell properties. Retention decreased with increasing hydrophobicity and increased with increasing electrophoretic mobility of bacteria for both sand. The increasing sand grain size resulted in a decrease of bacteria retention, except for the motile E. coli, indicating that retention of this strain was more dependent on cell motility than on the sand grain size. Bacteria deposition coefficients obtained from numerical simulations of the retention profiles indicated that straining was an important mechanism affecting bacteria deposition of E. coli and Klebsiella sp., in the fine sand, but the attachment had the same importance as straining for R. rhodochrous. The results obtained in the coarse sand did not permit to discriminate the predominant mechanism of bacteria deposition and the relative implication of bacteria cell properties of this process.

Prediction of permeability from reservoir main properties using neural network

Prediction on permeability is an essential task in reservoir engineering as it has great influences on oil and gas production, while porous media grain size, sorting, cementing, porosity, specific surface area, direction and location of grain and irreduction water saturation have effects on permeability. In this project we studied the effect of porosity, specific surface area and irreduction water saturation as main parameters on permeability distribution in the reservoir; the main goal of this research was permeability prediction in carbonat reservoir using neural network approach. Our studies showed a good agreement between our neural network model prediction and lab data or core analysis. This approach can be a useful tool for prediction permeability when core tests are not available. Key words: Permeability prediction, neural network, specific surface area, irreducible water saturation, porosity.

Impact of Porous Media Grain Size on the Transport of Multi-walled Carbon Nanotubes

Nanoparticles possess unique physical, electrical, and chemical properties which make them attractive for use in a wide range of consumer products. Through their manufacturing, usage, and eventual disposal, nanoparticles are expected to ultimately be released to the environment after which point they may pose environmental and human health risks. One critical component of understanding and modeling those potential risks is their transport in the subsurface environment. This study investigates the mobility of one important nanoparticle (multi-walled carbon nanotubes or MWCNTs) through porous media, and makes the first measurements on the impact of mean collector grain size (d(50)) on MWCNT retention. Results from one-dimensional column experiments conducted under various physical and chemical conditions coupled with results of numerical modeling assessed the suitability of traditional transport models to predict MWCNT mobility. Findings suggest that a dual deposition model coupled with site blocking greatly improves model fits compared to traditional colloid filtration theory. Of particular note is that the MWCNTs traveled through porous media ranging in size from fine sand to silt resulting in normalized concentrations of MWCNTs in the effluent in excess of 60% of the influent concentration.

Experimental measurements of saturation overshoot on infiltration

Gravity‐driven fingers in uniform porous medium are known to have a distinctive nonmonotonic saturation profile, with saturated (or nearly so) tips and much less saturation in the tails. In this work, constant‐flux infiltrations into confined porous media (laterally smaller than the finger diameter, thus essentially one‐dimensional) are found to produce saturation overshoot identical to that found in gravity‐driven fingers. Light transmission is used to measure the saturation profiles as a function of infiltrating flux, porous media grain size, grain sphericity, and initial water saturation. Saturation overshoot is found to cease below a certain minimum infiltrating flux. This minimum flux depends greatly on the grain sphericity and initial water content of the media and slightly on the mean grain size. The observed saturation overshoot is inconsistent with a continuum description of porous media but qualitatively matches well observations and predictions from discrete pore‐filling mechanisms. This suggests that pore‐scale physics controls saturation overshoot and in turn gravity‐driven fingering.

An Experimental Investigation of Rate‐Limited Nonaqueous Phase Liquid Volatilization in Unsaturated Porous Media: Steady State Mass Transfer

Results of one‐dimensional soil column experiments are presented to evaluate the factors influencing volatilization of entrapped nonaqueous phase liquids (NAPLs) in unsaturated sandy porous media. Three‐phase fluid saturations measured in Ottawa and Wagner sands were found to depend upon porous media grain size and distribution, with residual water and NAPL saturations ranging from 8 to 16% and 4 to 10%, respectively. In general, residual NAPL saturations were 2–3 times less than NAPL entrapped in similar two‐phase (organic‐water) systems. During volatilization of three single‐component NAPLs (styrene, toluene, and tetrachloroethylene), contaminant vapor phase effluent concentrations deviated from local equilibrium values by 10–40% for pore velocities ranging from 0.25 to 1.5 cm/s. In contrast to NAPL dissolution, mass transfer rates were found to decrease with decreasing soil mean grain size. An empirical correlation based on the modified Sherwood number and Peclet number was developed which incorporates the soil mean grain size as a surrogate measure of NAPL distribution. The utility of this model is demonstrated for the prediction of steady state volatilization rates in independent NAPL‐porous media systems.

Fingering of Dense Nonaqueous Phase Liquids in Porous Media: 1. Experimental Investigation

The propagation of dense nonaqueous phase liquids (DNAPLs) in water‐saturated, homogeneous porous media was investigated. The static distribution of DNAPL after gravity‐driven displacement was studied using a number of three‐dimensional spill experiments. Fingering intrinsic to the displacement systems was observed in all experiments. The effects of physical and chemical parameters on flow instability were examined for a range of sand grain sizes (fine, medium, and very coarse) and for different DNAPLs (trichloroethylene, trichloroethane, and dibutyl phthalate). Gravitational, viscous, and capillary forces were observed to have a varied influence on the flow behavior in these experiments. Our observations show that the development of finger patterns is sensitive to the porous media grain size, properties of the DNAPL, and spill conditions. By controlling experimental parameters, results are reproducible and yield insight into finger formation and preferential DNAPL flow in homogeneous aquifer materials. This paper discusses the experimental results qualitatively; a companion paper discusses their quantification with fractal concepts.