Porous Composition Research Articles

Extraction of nickel ions using nanoporous adsorbent material from waste glass

This study aims to create a porous glass adsorbent from waste glass to extraction nickel ions from its aqueous solution. The process involves converting waste glass to porous glass using 1:1:1:1 lime, sodium chloride, and sodium bicarbonate, followed by reacting with waste glass at 800 ˚C. The porous glass surface morphology, elemental composition, and functional groups, were analyzed using SEM, EDS, and FT-IR techniques.The outcome parameters used in this study are adsorbent dosage (10 g), contact time (150 min), heavy metal ion concentration (100 mg/l), and pH of 6. The adsorption capacity resulting from these parameters is 9.28 mg/g using the porous extract adsorbent for the extraction of nickel ions from its solutions. According to the findings. The proportion of Ni (II) ions extracted increased, coupled with a rise in the adsorbent dosage, heavy metal ion concentration, contact time, and pH. In addition, the Langmuir isotherm (R2 = 0.98,KL=0.072) has shown better performance than the Freundlich adsorption isotherm (R2 = 0.93,N=1.598) for the adsorption of the Ni(II) in this study.

Excellent C-band microwave absorption properties of Ni@nitrogen-doped porous carbon nanocomposite via polymer bubbling technique

Nitrogen-doped porous carbon nanocomposites are highly sought-after materials for electromagnetic wave absorption due to their unique combination of electrical and magnetic properties. However, achieving optimal absorption performance within the critical C-band (4–8 GHz) frequency range remains a significant challenge. Ni@NPC nanocomposites, synthesized through the polymer bubbling technique, demonstrated exceptional microwave absorption (MWA) performance in the C-band. These materials exhibited a reflection loss (RL) of −65.20 dB at a thickness of 4.8 mm. When carbonized at 600 °C, a thickness of 2.0 mm achieved an effective absorption bandwidth (EAB) of 5.74 GHz. The remarkable absorption performance is ascribed to the combined effect of their porous composition and the addition of nitrogen dopants, which efficiently foster various microwave attenuation processes. Furthermore, the material’s effectiveness in real-world applications was evaluated using computer simulation technology (CST). This work highlights the potential of the one-pot fabrication method for developing high-performance MWA materials with practical applications.

Sustainable castor oil-based microcellular polyurethane foam with desirable flame retardancy, vibration damping performance and recyclability

Microcellular polyurethane foam (MPUF) is extensively utilized as a vibration dampening material. However, its long chain and porous composition render it highly susceptible to combustion. Herein, we grafted the flame retardant 9,10-dihydro-9-oxa-10-phospha-phenanthrene-10-oxide (DOPO) onto the castor oil by a simple method to obtain a bio-based flame-retardant polyester polyol (COBH). Then, a bio-based flame-retardant MPUF was synthesized by one-pot synthesis of COBH, polyether polyol, and isocyanate. The target MPUF exhibits excellent flame retardancy, with the limiting oxygen index (LOI) sharply increasing from 19.3 % to 27.6 % and the peak of heat release rate (PHRR) decreasing significantly by 60.1 % as compared to MPUF prepared using unmodified castor oil. In addition, the MPUF shows good vibration dampening performance with a maximum loss factor of 5.2 and a maximum Sc-factor of 250. Moreover, the MPUF can be processed into MPU film by compression molding. The MPU film has adjustable mechanical properties and reusability. This study provides a feasible method for the preparation of flame-retardant, recyclable, bio-based MPUF with good vibration damping properties, thus expanding the practical applications of MPUF in the automotive, aerospace, and packaging and transportation industries.

Porous Polymer Compositions Based on Mixed Colloidal Suspensions Under Ultrasonic Dispersion and Microwave Heating

Porous Polymer Compositions Based on Mixed Colloidal Suspensions Under Ultrasonic Dispersion and Microwave Heating

Study on the influence of aggregate on rheological properties of recycled aggregate asphalt mixture using microstructural quantification

Recycled aggregate (RA) is generated through the crushing process of Construction and Demolition Waste (CDW). Although there has been extensive research on the mechanical properties of recycled aggregate asphalt mixture (RAAM), the impact of recycled aggregate (RA) on its rheological characteristics remains underexplored. This paper aims to assess the rheological properties of recycled aggregate asphalt mixture (RAAM) during the processes of mixing and compaction. Firstly, different percentages of recycled aggregate (RA) were utilized in the design of the recycled aggregate asphalt mixture (RAAM), and rheological behaviors of RAAM during the mixing and compaction stage were characterized by mixing torque and compaction energy, respectively. Then, high-precision three-dimensional models of RA were reconstructed utilizing CT images, and four indices were established to quantitatively assess the macro shape and micro-morphology of RA particles, utilizing the spatial model data for precise measurements. Finally, a correlation was found between rheological properties of RAAM and RA morphology through a comprehensive analysis of laboratory test results and spatial model indicators. Results show that aggregate particles’ microstructural morphology significantly influences asphalt mixture’s rheological behavior during mixing and compaction. Additionally, the 3D spherical degree and Needle-flake index performed more significant correlations with mixing and compaction than the 3D angular index and 3D texture index. As opposed to natural aggregate, RA exhibits more intricate morphological characteristics stemming from its porous cement mortar composition. Increasing the RA content causes more energy consumption and increases the thickness of asphalt mortar film during the compaction process. In general, methods established in this study offer an efficient mean of quantifying the morphological characteristics of aggregate particles, thereby enabling the assessment of the impact of RA on the rheological properties of asphalt mixtures.

A sensitive NH3 chemiresistive sensor with wide detection range: Employing a MOF-derived mesoporous carbon composite with polyaniline

Designing sensing materials with effective porous structure and compositions is a crucial strategy for constructing high-performance gas-sensitive devices. Herein, a dodecahedral mesoporous carbon derived from metal-organic frameworks (CMOF), e.g. Zeolitic Imidazolate Framework-8 (ZIF-8) derived porous carbon (ZIF-8-C) was prepared, and subsequently, three-dimensional (3D) hollow dodecahedral ZIF-derived carbon-polyaniline (PANI) based (ZCPx, x representing the mass fraction of ZIF-derived carbon) hierarchical hybrid materials were constructed by introducing protonated polyaniline on the surface of MOF carbon via in-situ oxidative polymerization. The MOF-derived structure provides a substantial interface surface area for the hybrid material, enabling rapid adsorption and charge transfer, along with essential structural stability. The 3D hollow ZCP50 hybrid material prepared exhibits a wide detection range (0.1–500 ppm), repeatability, acceptable long-term stability, and an 8.3 times response enhancement versus PANI. The above performance is attributed to the significant synergistic effect between ZIF-8-C and PANI. The unique design of this 3D framework holds promising potential for the commercial application of room-temperature gas sensors.

Multifunctional tri-layer aramid nanofiber composite separators for high-energy-density lithium-sulfur batteries

Lithium-sulfur (Li-S) battery has attracted much attention due to their high theoretical energy density. However, severe shuttling effect, sluggish reaction kinetics and uncontrolled dendrite formation of Li anode greatly deter their practical applications. Different to conventional separator engineering strategies that are always focused on surface coating of functional interlayer on commercial polyolefin separators, herein, we proposed a structural engineering tactic by rationally tuning the porous structure and composition of the p-aramid nanofiber (ANF) composite separator to address simultaneously the above problems. A two-step film-casting process combined with a phase inversion approach was developed to fabricate a multifunctional tri-layer ANF composite separator. This innovative separator was especially engineered to comprise a conductive and catalytic NiFe2O4 modified multi-walled carbon nanotubes/ANF layer for rapid and efficient conversion of lithium polysulfides, a microporous ANF layer for fast ion transport, and a dense nanoporous ANF layer for lithium dendrite inhibition. This tri-layer ANF-based separator possessed high porosity, excellent thermal stability, and superb electrolyte wettability. Batteries with the tri-layer ANF- based separator exhibited outstanding cyclic stability with high capacity of >3 mAh cm−2 at high sulfur loading (4 mg cm−2) and high current density (4 mA cm−2). This work opens up new opportunities for design of functional separators based on high performance polymers using the structural engineering strategy.

Characterization of wheat husk-derived holey carbon/(RGO) x /CoFe2O4/PVA nanocomposites: insights into structural, optical, magnetic, and dielectric properties

In this particular study, an uncomplicated method involving chemical co-precipitation was employed to create nanocomposites known as wheat husk-derived holey carbon/reduced graphene oxide/cobalt ferrite/polyvinyl alcohol (WHHC/(RGO) x /CF/PVA). The utilization of biomass materials is a noteworthy aspect that has caught the attention of researchers in this field. It is worth mentioning that the characteristics related to both magnetism and dielectricity in the flexible WHHC/(RGO) x /CF/PVA nanocomposites can be controlled by adjusting the amount of RGO present in the composition. To explore the composite’s absorption properties, the influence of RGO content was investigated, and it was found that there is a direct correlation between higher RGO content and increased absorption. The WHHC/(RGO) x /CF/PVA structure exhibits an enhanced impedance matching due to the strong interfacial interaction between RGO and cobalt ferrite nanoparticles. This porous composition possesses an optimal structure for capturing and collecting light effectively. Moreover, the WHHC/(RGO) x /CF/PVA nanocomposites have exhibited great potential in manufacturing flexible electronic devices such as light-dependent resistors, when employed as an electronic material. Their lightweight characteristics and flexibility are key contributors to the success achieved in this aspect. However, it is important to note that their overall shape tends to resemble that of traditional absorber equipment commonly used in the field.

Enhancing the supercapacitive performance of a carbon-based electrode through a balanced strategy for porous structure, graphitization degree and N,B co-doping

Regarding carbon-based electrodes, simultaneously establishing a well-defined meso-porous architecture, introducing abundant hetero-atoms and improving the graphitization degree can effectively enhance their capacitive performance. However, it remains a significant challenge to achieve a good balance between defects and graphitization degree. In this study, the porous structure and composition of carbon materials are co-optimised through a ‘dual-function’ strategy. Briefly, K3Fe(C2O4)3 and H3BO3 were hybridised with a gelatin aqueous solution to form a homogeneous composite hydrogel, followed by lyophilisation and carbonisation. Owing to the dual functionality of raw materials, the graphitization, activation and hetero-atom doping processes can occur simultaneously during a one-step high-temperature treatment. The resultant carbon material exhibits a high graphitization degree (ID/IG = 0.9 ± 0.1), high hetero-atom content (N: 9.0 ± 0.3 at.%, B: 6.9 ± 0.5 at.%) and a large specific area (1754 ± 58 m2/g). The as-prepared electrode demonstrates a superior capacitance of 383 ± 1F g−1 at 1 A/g. Interestingly, the cyclic voltammetry (CV) curves exhibit a distinctive pair of broad redox peaks, which is uncommon in KOH electrolyte. Experiment data and density functional theory (DFT) simulation verify that N-5, B co-doping enhances the activity of the faradic reaction of carbon electrodes in KOH electrolyte. Furthermore, the fabricated Zn-ion hybrid supercapacitor (ZHSC) based on this carbon electrode delivers a high-energy density of 140.7 W h kg−1 at a power density of 840 W kg−1.

FeNi alloys incorporated N-doped carbon nanotubes as efficient bifunctional electrocatalyst with phase-dependent activity for oxygen and hydrogen evolution reactions

Electrochemical oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) are two important half-cell reactions for overall water splitting. The rational design and fabrication of efficient electrocatalysts involving nonprecious-metals and carbon matrix is highly attractive. Herein, a series of N-doped carbon nanotubes encapsulated FeNi alloy nanoparticles (FeNi@NCNTs) are synthesized via a simple pyrolysis treatment of Fe-doped Ni(OH)2 precursors under the assistance of dicyandiamine source. The results reveal that the Fe/Ni ratio has an obvious influence on the morphology and phase composition of FeNi@NCNTs series, thus affecting the electrocatalytic performance. The highest electrocatalytic activity is achieved for the Fe1Ni4@NCNTs product with a Fe/Ni molar ratio of 1:4, which delivers low overpotentials of 278 and 279 mV for OER and HER at 10 mA cm−2 in 1.0 mol/L KOH, respectively. The intriguing electrocatalytic performance is mainly ascribed to the advantageous integration of rambutan-like hierarchically porous structure and composition optimization, significantly facilitating the fast mass/charge transfer as well as promoting the adsorption ability for intermediates. The present method may open a facile avenue for developing cost-effective, high-activity, and stable electrocatalysts for the application of overall water splitting.

Copper oxides supported sulfur-doped porous carbon material as a remarkable catalyst for reduction of aromatic nitro compounds

Synthesis and manufacturing of metal–organic framework derived carbon/metal oxide nanomaterials with an advisable porous structure and composition are essential as catalysts in various organic transformation processes for the preparation of environmentally friendly catalysts. In this work, we report a scalable synthesis of sulfur-doped porous carbon-containing copper oxide nanoparticles (marked CuxO@CS-400) via direct pyrolysis of a mixture of metal–organic framework precursor called HKUST-1 and diphenyl disulfide for aromatic nitro compounds reduction. X-ray diffraction, surface area analysis (BET), X-ray energy diffraction (EDX) spectroscopy, thermal gravimetric analysis, elemental mapping, infrared spectroscopy (FT-IR), transmission electron microscope, and scanning electron microscope (FE-SEM) analysis were accomplished to acknowledge and investigate the effect of S and CuxO as active sites in heterogeneous catalyst to perform the reduction-nitro aromatic compounds reaction in the presence of CuxO@CS-400 as an effective heterogeneous catalyst. The studies showed that doping sulfur in the resulting carbon/metal oxide substrate increased the catalytic activity compared to the material without sulfur doping.

"Exploring Aerated Autoclaved Concrete (AAC) Acoustic Properties Across Diverse Frequency Bands"

Aerated Autoclaved Concrete (AAC) stands out as an environmentally friendly and lightweight construction material. Known for its durability, load-bearing capacity, and excellent insulation, AAC surpasses traditional concrete blocks and red bricks in construction preferences. Its suitability as a wood alternative is evident, given its resistance to decay and comparable lightweight characteristics. Comprising a blend of cement, fly ash, limestone, and gypsum in an 8:69:20:3 ratio, with aluminum powder as the expansion agent, AAC serves as a versatile building material. In addition to its various attributes, understanding the acoustic properties of AAC is essential. Structures such as schools, hospitals, hotels, offices, and multi-family housing demand effective sound insulation, necessitating the use of materials with favorable sound absorption coefficients and minimal sound reflection coefficients. Due to its porous composition, Aerated Autoclaved Concrete exhibits notable sound absorption coefficients, making it ideal for applications in environments like schools and hospitals. This research delves into the determination of AAC's sound absorption coefficient and sound reflection coefficient across a spectrum of frequencies ranging from 1 kHz to 10 kHz. The analysis extends beyond frequency variations to encompass different sound intensities, offering a comprehensive exploration of AAC's acoustic characteristics.

Ordered Mesoporous Crystalline Frameworks Toward Promising Energy Applications.

Ordered mesoporous crystalline frameworks (MCFs), which possess both functional frameworks and well-defined porosity, receive considerable attention because of their unique properties including high surface areas, large pore sizes, tailored porous structures, and compositions. Construction of novel crystalline mesoporous architectures that allows for rich accessible active sites and efficient mass transfer is envisaged to offer ample opportunities for potential energy-related applications. In this review, the rational synthesis, unique structures, and energy applications of MCFs are the main focus. After summarizing the synthetic approaches, an emphasis is placed on the delicate control of crystallites, mesophases, and nano-architectures by concluding basic principles and showing representative examples. Afterward, the currently fabricated components of MCFs such as metals, metal oxides, metal sulfides, and metal-organic frameworks are described in sequence. Further, typical applications of MCFs in rechargeable batteries, supercapacitors, electrocatalysis, and photocatalysis are highlighted. This review ends with the possible development and synthetic challenges of MCFs as well as a future prospect for high-efficiency energy applications, which underscores a pathway for developing advanced materials.

Microstructure Analysis and Permanent Deformation of Porous Asphalt incorporating Steel Fiber

Porous asphalt composition is frequently used for the surface extraction layer of pavements because to its open structure and high air void percentage, which lessens disturbance and offers protection during precipitation. Porous asphalt composition has a high air void percentage. This would make it possible for water to be stored horizontally inside the pavement layer as well as moved about within that layer. It is possible that this may lessen the impacts of splash and spray, hence improving drivers’ sight during rainstorms. On the other hand, because to the large percentage of air voids contained inside it, the porous asphalt would be prone to rutting, cracking, and peeling. The goal of this research is to explore the microstructure of porous asphalt that has been mixed with steel fibers in proportions ranging from 0 percent to 0.3 percent. The second objective was to analyze the long-term deformation of porous asphalt that had either 0 or 0.3 percent steel fiber content. In this study, a porous asphalt composition was developed with the help of Marshall mix design. Using sieve analysis, the whole mixture of coarse, fine, filler, bituminous binder, and a range of aggregate sizes was separated into its component parts. Pictures taken using a scanning electron microscope (SEM), an energy dispersive x-ray (EDX), an x-ray diffractometer (XRD), and a fourier transform infrared spectrometer (FTIR) are being used in this inquiry (FTIR). The findings point to the possibility that the performance of porous asphalt mixture might be greatly improved by the addition of steel fiber. Additionally, one may make the case that steel fiber has a longer lifespan than the several other forms of fiber that are used in porous asphalt pavement.

Bioderived silicon nano-quills: synthesis, structure and performance in lithium-ion battery anodes

Water-dispersible silicon nano-quills (SiNQs) with unique porous morphology and composition promote the advancement of high-Si-content anodes with fast charging/discharging capabilities.

Star-PCL shape memory polymer (SMP) scaffolds with tunable transition temperatures for enhanced utility.

Thermoresponsive shape memory polymers (SMPs) prepared from UV-curable poly(ε-caprolactone) (PCL) macromers have the potential to create self-fitting bone scaffolds, self-expanding vaginal stents, and other shape-shifting devices. To ensure tissue safety during deployment, the shape actuation temperature (i.e., the melt transition temperature or Tm of PCL) must be reduced from ∼55 °C that is observed for scaffolds prepared from linear-PCL-DA (Mn ∼ 10 kg mol-1). Moreover, increasing the rate of biodegradation would be advantageous, facilitating bone tissue healing and potentially eliminating the need for stent retrieval. Herein, a series of six UV-curable PCL macromers were prepared with linear or 4-arm star architectures and with Mns of 10, 7.5, and 5 kg mol-1, and subsequently fabricated into six porous scaffold compositions (10k, 7.5k, 5k, 10k★, 7.5k★, and 5k★) via solvent casting particulate leaching (SCPL). Scaffolds produced from star-PCL-tetraacrylate (star-PCL-TA) macromers produced pronounced reductions in Tm with decreased Mnversus those formed with the corresponding linear-PCL-diacrylate (linear-PCL-DA) macromers. Scaffolds were produced with the desired reduced Tm profiles: 37 °C < Tm < 55 °C (self-fitting bone scaffold), and Tm ≤ 37 °C (self-expanding stent). As macromer Mn decreased, crosslink density increased while % crystallinity decreased, particularly for scaffolds prepared from star-PCL-TA macromers. While shape memory behavior was retained and radial expansion pressure increased, this imparted a reduction in modulus but with an increase in the rate of degradation.

Modification and Application of Bamboo-Based Materials: A Review—Part II: Application of Bamboo-Based Materials

Bamboo, with its inherently porous composition and exceptional renewability, stands as a symbolic embodiment of sustainability. The imperative to fortify the utilization of bamboo-based materials becomes paramount for future developments. These materials not only find direct applications in the construction and furniture sectors but also exhibit versatility in burgeoning domains such as adsorption materials and electrode components, thereby expanding their consequential influence. This comprehensive review meticulously delves into both their explicit applications and the nuanced panorama of derived uses, thereby illuminating the multifaceted nature of bamboo-based materials. Beyond their current roles, these materials hold promise for addressing environmental challenges and serving as eco-friendly alternatives across diverse industries. Lastly, we provide some insights into the future prospects of bamboo-based materials, which are poised to lead the way in further development. In conclusion, bamboo-based materials hold immense potential across diverse domains and are set to play an increasingly pivotal role in sustainable development.

Synergistic effects of nitrogen-doped carbon and praseodymium oxide in electrochemical water splitting

Hybrid materials featuring perovskite-type metal oxide in conjunction with heteroatom-doped graphene hold immense promise as alternatives to costly noble metal catalysts for electrochemical water splitting, facilitating the generation of environmentally friendly hydrogen. In this study, perovskite-type oxide containing praseodymium, barium, strontium, cobalt, and iron atoms dispersed in a carbon matrix as a catalyst is synthesized via annealing of the carbon material with substrates for the preparation of perovskite oxide. The mass ratio of reagents regulates the porous structure and elemental composition. The result of the hydrogen evolution reaction (HER), suggests that the hybrid catalysts exhibit intermediate HER kinetics compared to the commercial Pt/C and the catalyst without carbon. The Tafel slope for HER is lower for materials containing carbon, because of the improved reaction kinetics, facilitated proton transfer, and enhanced electrochemical surface area. Therefore, the study provides an effective strategy for the preparation of catalyst and their use as the active catalyst of water splitting.

Preparation of porous ceramsite from municipal sludge and its structure characteristics

ABSTRACT In this paper, the municipal sludge was used as the main raw material to prepare a kind of porous ceramsite. The porous ceramsite composition of 50 wt-% of municipal sludge, 10 wt-% of municipal solid waste incineration bottom ash, 45 wt-% of waste glass powders, sintering temperature of 900°C and holding duration of 30 min. The best of the ceramsite synthesised had 1-h water absorption capacity of 51.53%, apparent porosity of 64.14% and pore volume 0.671 mL g−1. During the sintering process, the waste glass powders generated a large amount of liquid phase, wrapt the gas produced by organic matter, and formed a porous structure inside the ceramic particles. At the same time, the silica and aluminium were combined to form Kyanite, which constitutes the basic skeleton of the ceramic particles showing a certain strength. Besides, silicon oxide and calcium silicate generated Wollastonite improving the corrosion resistance of ceramic particles as well. The adsorption capacity of the prepared porous ceramsite modified by acid combined with sodium citrate was 3.1 mg g−1 using the prepared porous ceramsite as substrate. The adsorption kinetics of ammonia nitrogen by porous ceramics conforms to the quasi-second-order kinetic model, and the adsorption isotherm model conforms to the Langmuir model. The findings lay a theoretical foundation for the integration of resource utilisation of solid waste and later application.

Reduced graphene Oxide-Ni@Multiscale carbon nanofibers with Core-Shell porous structure for microwave absorption performance

Microwave absorbing materials is an important area of research in the field of electromagnetic protection. In particular, the organic combination of composition and structure is a practical approach to improving the performance of microwave absorbing materials. In this study, [email protected] nanofibres were coated with graphene [email protected] fibres using electrostatic spinning technology to obtain core-shell porous structure reduced graphene [email protected] carbon nanofibres ([email protected]). The advantages of the core-shell porous structure and composition were fully exploited, and the organic combination of the two resulted in excellent microwave absorption properties of [email protected] The minimum reflection loss is -54.16 dB at 16.8 GHz, and the effective absorption bandwidth reaches 9.71 GHz at a thickness of 3.29 mm. [email protected] also exhibit high moisture resistance and thermal infrared stealth properties. These results indicate that [email protected] are of great value in the synthesis and application of microwave absorbing materials.