The Ca(OH)2/CaO reaction system presents broad development prospects for thermochemical heat storage. However, the poor thermal conductivity of heat storage material and the complex internal flow limit the performance of the reactor. To improve the performance of the reactor, this work designs a new improved fixed bed reactor with baffle. The comparison with and without baffle, as well as the effects of operation conditions and structural parameters of the improved reactor on heat storage and release performance, are numerically investigated. The results show that the improved reactor can enhance heat transfer and flow inside the reactor, resulting in performance improvement. After baffle installation, there is a 64% decrease in the pressure drop, a 29.14% reduction in the heat storage time, and a 35.45% reduction in the heat release time. Besides that, the improved reactor can maintain the high temperature for longer at the outlet during heat release. The orthogonal test design analysis reveals that the inlet velocity of direct heat transfer fluid has the greatest impact on heat storage, while the inlet velocity of indirect heat transfer fluid has the smallest impact, and the same applies to heat release. The thermal conductivity and permeability of the porous baffle have minor impacts, but the air distribution chamber has a noticeable influence. This work can guide the optimization design and operation adjustment of the reactor.
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