Pore Water Salinity Research Articles

Comparison of methods measuring electrical conductivity in coastal aquifers

Coastal aquifers, the transition zone between freshwater and saltwater, show large salinity contrasts in the subsurface. Salinity is a key parameter to understand coastal groundwater flow dynamics and consequently also geochemical and microbial processes. For mapping porewater salinity, a variety of methods exists, mainly using electrical conductivity as a proxy. We investigate methods including hydrological/geochemical (well sampling, fluid logger) as well as geophysical method (direct push, geoelectrics) utilising measurements near the high-water line of a high-energy beach at the North Sea island of Spiekeroog. We compare the methods, discuss their benefits and limitations and assess their spatial and temporal resolution. One key to enable a comparison is the estimation of formation factors transforming bulk conductivity measured by geophysical tools in to fluid conductivities obtained from direct measurements. We derive depth-dependent formation factors derived from time-series measurements of fluid loggers and a vertical electrode installation. Using these formation factors, the vertical electrode chain proves to provide reliable salinities at high spatial and temporal dimension. Direct-push profiling data provide the highest vertical resolution. However, a careful calibration is needed to allow for salinity quantification. On the other hand, electrical resistivity tomography (ERT) exhibits the lowest spatial resolution, but can image two-dimensional salinity distributions. We found ERT to fit very well to all other methods, but the data analysis should be aimed at salinities instead of bulk conductivities, i.e. including formation factors and temperature models into the inversion process.

Methane seepage activities in the Qiongdongnan Basin since MIS2

Gas hydrates are globally acknowledged as a significant strategic alternative energy source, and there is a consensus on the necessity to enhance their exploration. However, gas hydrates are highly prone to decomposition under variations in external environmental conditions, which can result in subsea methane seepage activities. Consequently, investigating subsea methane seepage activities holds substantial theoretical and practical significance for exploring gas hydrates. This paper evaluates the history of methane seepage activities in the Qiongdongnan Basin (QDNB) by analyzing the carbon and oxygen isotopic characteristics of benthic foraminifera and the geochemical properties of pore water from gravity sediment cores at sites QH-CL4 and QH-CL40. The results indicate that since the Marine isotope stage2 (MIS2), continuous micro-methane seepage activity has been present in the QDNB, characterized by a slight negative deviation in the carbon isotopes of benthic foraminifera. Methane seepage activity intensified during 14.6 ka BP and between 19.64–23.22 ka BP. This increase is thought to be associated with rising seawater temperature during the Bølling–Allerød interstadial and declining sea level during the Last Glacial Maximum, respectively. Moreover, current geochemical characteristics of pore water reveal strong methane seepage activity, with flux as high as 28.968 mmol·m-²·a-¹. This ongoing activity has led to gas hydrate formation within shallow layers while also causing negative deviations in pore water salinity.

Effects of dry density and porewater salinity on Eu(Ⅲ) diffusion in compacted GMZ bentonite: A perspective from triple pore structure

Compacted bentonite is microscopically characterized by a triple pore structure composed of inter-aggregate pores, inter-particle pores and interlayer pores. These three types of pores are available for diffusive transport of cations through different mechanisms: free water diffusion, surface diffusion, and interlayer diffusion. This study investigated the effects of dry density and porewater salinity on Eu(Ⅲ) diffusion in compacted GMZ bentonite from the perspective of triple pore structure. A series of through-diffusion (TD) experiments were conducted as a function of the density and porewater salinity. Then the triple pore structure was characterized using SEM and MIP tests. On this basis, a mathematical expression about the dependence of Eu(Ⅲ) diffusion on the triple pore structure was developed. Results indicated that increasing dry density inhibited the Eu(Ⅲ) diffusion, as evidenced by decreases in the effective diffusion coefficient De, capacity factor α, and apparent diffusion coefficient Da. This inhibition is attributed to the reduction in inter-aggregate pores, inter-particle pores, and interlayer pores with increased density, thereby suppressing free water diffusion, surface diffusion, and interlayer diffusion. Conversely, increasing porewater salinity facilitated the Eu(Ⅲ) diffusion. This is likely because the relatively high concentration of Eu(Ⅲ) in the TD tests makes free water diffusion as the dominant pathway. Although surface diffusion and interlayer diffusion were inhibited owning to the decrease of inter-particle pores and interlayer pores, their negative effects on total diffusion flux were less than the positive effects of enhanced free water diffusion resulting from the increase of inter-aggregate pores. Finally, by comparing the calculated total diffusion fluxes and experimental values, the applicability of the proposed expression for predicting Eu(Ⅲ) diffusion in compacted bentonite with varying dry densities and salinities was discussed.

Isotropic compression behavior of salinized unsaturated agricultural soil: An experimental and constitutive investigation

Salinity-induced soil degradation is a significant challenge in coastal reclamation areas, impacting agricultural productivity and infrastructure development. Variations in soil compression and deformation caused by changes in salinity warrant further investigation, particularly for agricultural applications. This study explores the relationship between soil pore water salinity and compressibility by conducting isotropic compression tests on salinized unsaturated agricultural soils treated with distilled water, 0.5 mol/L and 1 mol/L sodium chloride (NaCl) and calcium chloride (CaCl2) solutions. The results demonstrate that the type and concentration of salts significantly affect the compression behavior of these soils. The constitutive parameters were calibrated based on the experimental data. To account for osmotic suction, Barcelona Basic Model (BBM) was adjusted. The findings indicate that as pore water salinity increases, soil compressibility decreases, reflected by a compression index (Cc), and higher pre-consolidation stress (py). This modification aimed to quantify the impact of pore water salinity on soil compression. To validate the constitutive model, a numerical analysis of an isotropic compression test was carried out. This study contributes to our understanding of the isotropic compression behavior of coastal saline soil, proposes a constitutive framework for predicting soil responses under different salt conditions, and provides theoretical support for engineering construction in coastal reclamation areas.

Massive Ice Outcrops and Thermokarst Along the Arctic Shelf Edge: By‐Products of Ongoing Groundwater Freezing and Thawing in the Sub‐Surface

AbstractSubstantial seafloor morphological changes are rapidly occurring along the Canadian Arctic shelf edge. Five multibeam bathymetric mapping surveys, each partially covering a 15 km2 study area between 120‐ and 200‐m water depth, were conducted over a 12‐year time period. These surveys reveal that 65 new craters have developed between 2010 and 2022, averaging 6.5 m and reaching up to 30 m deep. Remotely operated vehicle investigations revealed massive ice outcrops exposed on two newly formed crater flanks. This ice is not relict subaerially formed Pleistocene permafrost because it is hosted in sediments which were deposited in a submarine setting post‐deglaciation. Low salinity porewater and sediment core ice samples with depleted oxygen isotopic compositions indicate waters with a meteoric signature are discharging and freezing in this area. These ascending brackish groundwaters are likely derived in part from thawed relict permafrost hundreds of meters under the continental shelf. They refreeze as they approach the −1.4°C seafloor, leading to the development of widespread, near seafloor, sub‐bottom ice layers. Conditions appropriate for ice melting also exist nearby where ice is exposed to seawater or warmed by ascending groundwater. Small variations in temperature and salinity lead to shifts between freezing of ascending brackish groundwater or melting of near seafloor ice layers. These conditions have produced a dramatic submarine thermokarst morphology riddled with multi‐aged depressions. Thermokarst geohazards may exist, unmapped, on other Arctic margins with groundwater channeled toward the shelf edge by a relict permafrost cap, and sufficiently cold shelf edge bottom water temperatures.

Paleo-climatic control on recharge and fresh-salt groundwater distribution in the Red River delta plain, Vietnam

Paleo-climatic induced sedimentation controls present-day recharge and the fresh-salt groundwater distribution in Quaternary delta systems. During sea-level highstands, marine clays with saline pore water were deposited and are interbedded with aquifers of coarse-grained sandy fluvial and shallow marine deposits, laid down during lowstands. The low-permeable marine layers may inhibit recent recharge to deeper aquifers, and thereby limit sustainable use of these freshwater resources. This phenomenon has been investigated in the Red River delta plain, using geophysical borehole logging, transient electromagnetic soundings, groundwater chemistry, stable isotope analysis and 3H and 14C dating of groundwater. Results reveal that marine saline pore water is still present in the Holocene marine clays, implying that fresh water has not entered the clays since their deposition. Therefore, recharge within the delta plain is not occurring and the deeper aquifers are hydraulically disconnected from the upper sandy layers. Today, recharge only occurs from the hinterland. Recharge during the last glacial period has flushed saline pore water from Pleistocene marine clays, but these clays were again affected by saline water during the Holocene transgression. The use of the groundwater resources in the delta plain must be adjusted to the present recharge to be sustainable.

Effect of decrease in pore water salinity induced by hydrate decomposition in clayey silt sediment on the destabilization-migration-clogging characteristics of illite

The clayey silt sediments are characterized by low permeability and high clay content, which makes fines migration not negligible. This work investigated the fines migration characteristics of illite under the condition of pore water salinity decreased, analyzed the effect on reservoir seepage characteristics, and evaluated the fines migration capability. The results show that the rapid decrease in pore water salinity caused by the decomposition of hydrate with high saturation produces higher particle concentration and results in more serious damage. At lower production pressures(0.1 MPa), the stability of illite was directly destroyed and flocculated to form aggregates that directly clogged the pores. The illite still tends to adsorb to the wall at higher production pressure(2.0 MPa), and then destabilizes and segregates under the effect of fluid dynamic. At higher production pressures, suspended particles are less likely to flocculate, which is more likely to block pores through bridging. The evaluation results of fines migration capability further clarified that salinity has a significant effect on fines migration characteristics and reservoir seepage capacity damage under different production pressures. This work demonstrates it is necessary to pay attention to the effect of fines migration on reservoir seepage characteristics when developing hydrate mining strategy.

Net evaporation-induced mangrove area loss across low-lying Caribbean islands

Abstract Although mangroves provide many beneficial ecosystem services, such as blue carbon storage and coastal protection, they are currently under threat due to changes in climate conditions, such as prolonged drought exposure. Under drought conditions, evaporation exceeds precipitation and high soil salinities can lead to stunted growth and die-back. To quantify this interplay, we developed a database for low-lying and uninhabited mangrove islands in the Caribbean under various evaporation and precipitation regimes. We extracted physical and biological information from each island using remote sensing techniques and coupled it with a process-based model. We used this database to develop a model that explains both the spatial variability in vegetated area across the Caribbean—as a function of rates of evaporation and precipitation—and porewater salinity concentration and dispersion from island edge towards the interior of mangrove islands. We then used this validated model to predict mangrove area loss associated with increases in evaporation to precipitation rates by 2100 for different Shared Socioeconomic Pathways (SSP). Less wealthy Caribbean regions such as Belize, Puerto Rico, and Venezuela are disproportionally affected, with mangrove area losses ranging from 3%–7% for SSP 2.6 and 13%–21% for SSP 7.0. Furthermore, foregone carbon sequestration in lost biomass under SSP 4.5 and 7.0 scenarios could compromise the ability of low-lying Caribbean mangrove islands to vertically adjust to sea level rise.

Effects of groundwater pumping on pore water flow and salt transport in tide‐controlled unconfined coastal aquifers

AbstractUnconfined coastal aquifers are a main pathway for land‐sourced solutes to enter the oceans. The migration of these solutes in aquifers is highly affected by the groundwater flow and salt transport processes, which are, to a great extent, controlled by tides. While many studies have examined how tidal oscillations would influence the subsurface hydrodynamics in coastal aquifers, most of them ignored the potential impact of groundwater pumping, a common practice in coastal areas to satisfy the demand for freshwater. This study, by means of laboratory experiments and numerical simulations, explored the combined effects of tides and groundwater pumping on the pore water flow and salinity distributions in an unconfined coastal aquifer. The results show that, in a tide‐controlled aquifer, the addition of groundwater pumping would exacerbate the degree of seawater intrusion and lead to wider spreading and deeper penetration of the upper saline plume. Moreover, groundwater pumping would enhance the tide‐driven circulation in the upper saline plume and weaken the density‐driven circulation in the saltwater wedge, ultimately leading to the reduction in total submarine groundwater discharge. These findings may promote a deep insight into the complex coastal groundwater systems experiencing human activities, and provide guidance for better evaluating the environmental impact of groundwater pumping.

A Fresh Take: Seasonal Changes in Terrestrial Freshwater Inputs Impact Salt Marsh Hydrology and Vegetation Dynamics

Salt marshes exist at the terrestrial-marine interface, providing important ecosystem services such as nutrient cycling and carbon sequestration. Tidal inputs play a dominant role in salt marsh porewater mixing, and terrestrially derived freshwater inputs are increasingly recognized as important sources of water and solutes to intertidal wetlands. However, there remains a critical gap in understanding the role of freshwater inputs on salt marsh hydrology, and how this may impact marsh subsurface salinity and plant productivity. Here, we address this knowledge gap by examining the hydrologic behavior, porewater salinity, and pickleweed (Sarcocornia pacifica also known as Salicornia pacifica) plant productivity along a salt marsh transect in an estuary along the central coast of California. Through the installation of a suite of hydrometric sensors and routine porewater sampling and vegetation surveys, we sought to understand how seasonal changes in terrestrial freshwater inputs impact salt marsh ecohydrologic processes. We found that salt marsh porewater salinity, shallow subsurface saturation, and pickleweed productivity are closely coupled with elevated upland water level during the winter and spring, and more influenced by tidal inputs during the summer and fall. This seasonal response indicates a switch in salt marsh hydrologic connectivity with the terrestrial upland that impacts ecosystem functioning. Through elucidating the interannual impacts of drought on salt marsh hydrology, we found that the severity of drought and historical precipitation can impact contemporary hydrologic behavior and the duration and timing of the upland-marsh hydrologic connectivity. This implies that the sensitivity of salt marshes to climate change involves a complex interaction between sea level rise and freshwater inputs that vary at seasonal to interannual timescales.

Compilation of Consolidation Properties Data of Champlain Sea Clay from Ottawa Region

Estimation of consolidation settlements in fine-grained soils due to various civil infrastructure loads is traditionally based on results derived from consolidation tests performed on undisturbed soil samples, combined with the data of other soil properties. In many geotechnical engineering applications, consolidation settlements are also estimated using empirical consolidation parameters derived from basic soil properties. This approach relies on correlations from the literature to bypass the time-consuming and expensive sampling techniques, laboratory testing, and other associated expenses. However, these correlations may not provide reasonable consolidation settlement estimations as these correlations are typically developed without considering the influence of stress history, geology, salinity of pore water, gradation, soil fabric, and chemical properties of the soils. This is especially true for Champlain Sea clay deposits from Eastern Ontario region of Canada that are typically with heterogeneous site conditions and exhibit spatial variability of soil properties. In this paper, data from the published literature and industrial and government reports on sensitive Champlain Sea clays were gathered for the Ottawa region. The data collection and clean-up methodology towards enhancing the reliability of the gathered data is comprehensively discussed. The summarized data from this study can be used with a greater degree of confidence towards developing reliable correlations in the estimation of consolidation settlements in geotechnical engineering practice.

Characterizing spatial distribution of ice and methane hydrates in sediments using cross-hole electrical resistivity tomography

Electrical resistivity is an essential parameter for assessing the abundance of gas hydrates and predicting their location. However, imaging techniques are poorly developed for detecting the electrical resistivity distribution of hydrate-bearing sediments. In this study, a cross-hole electrical resistivity tomography (CHERT) array was established in the large-scale simulator for characterizing the spatial distribution of the sedimentary system. Ice- and methane hydrate-bearing sediments were investigated respectively using CHERT. The results show that CHERT effectively observed the significant influence of methane hydrate/ice formation and salt drainage on the variations in electrical parameters. Their formation leads to a sustained increase in average resistivity, while salt ion exclusion leads to an increase in pore water salinity, resulting in a decrease in local resistivity. Moreover, CHERT observed a range of resistivities from a few Ω·m to several thousand Ω·m for ice- and methane hydrate-bearing sediments, which is consistent with the resistivity response of hydrate reservoirs in the field. It is suggested that CHERT can be used for hydrate reservoir detection and combined with acoustic imaging to more accurately characterize the spatial distribution of hydrates. These results contribute to advancing the potential application of CHERT technology in multi-method and multi-scale gas hydrate monitoring initiatives.

Unravelling the signatures of submarine groundwater discharge and seawater intrusion along the coastal plains of Odisha, India: a multi-proxy approach.

Submarine Groundwater Discharge (SGD) and Seawater Intrusion (SWI) are two contrary hydrological processes that occur across the land-sea continuum and understanding their nature is essential for management and development of coastal groundwater resource. Present study has attempted to demarcate probable zones of SGD and SWI along highly populated Odisha coastal plains which is water stressed due to indiscriminate-exploitation of groundwater leading to salinization and fresh groundwater loss from the alluvial aquifers. A multi-proxy investigation approach including decadal groundwater leveldynamics, LANDSAT derived sea surface temperature (SST) anomalies and in-situ physicochemical analysis (pH, EC, TDS, salinity and temperature) of porewater, groundwater and seawater were used to locate the SGD and SWI sites. A total of 340 samples for four seasons (85 samples i.e., 30 porewater, 30 seawater and 25 groundwater in each season) were collected and their in-situ parameters were measured at every 1-2km gap along ~ 145km coastline of central Odisha (excluding the estuarine region). Considering high groundwater EC values (> 3000 μS/cm), three probable SWI and low porewater salinities (< 32 ppt in pre- and < 25 ppt in post-monsoons), four probable SGD zones were identified. The identified zones were validated with observed high positive hydraulic gradient (> 10m) at SGD and negative hydraulic gradient (< 0m) at SWI sites along with anomalous SST (colder in pre- and warmer in post-monsoon) near probable SGD locations. This study is first of its kind along the Odisha coast and may act as initial basis for subsequent investigations on fresh-saline interaction along the coastal plains where environmental integrity supports the livelihood of coastal communities and the ecosystem.

Evaluating Hydrogeomorphic Condition Across Ecosystem States in a Non-tidal, Brackish Peat Marsh of the Florida Coastal Everglades, USA

Emergent marsh and open water have been identified as alternate stable states in tidal marshes with large, relative differences in hydrogeomorphic conditions. In the Florida coastal Everglades, concern has been raised regarding the loss of non-tidal, coastal peat marsh via dieback of emergent vegetation and peat collapse. To aid in the identification of alternate stable states, our objective was to characterize the variability of hydrogeomorphic and biologic conditions using a field survey and long-term monitoring of hydrologic and geomorphic conditions across a range of vegetated (emergent, submerged) and unvegetated (open water) communities, which we refer to as “ecosystem states,” in a non-tidal, brackish peat marsh of the coastal Everglades. Results show (1) linear relationships among field-surveyed geomorphic, hydrologic, and biologic variables, with a 35-cm mean difference in soil surface elevation between emergent and open water states, (2) an overall decline in soil elevation in the submerged state that was related to cumulative dry days, and (3) a 2× increase in porewater salinity during the dry season in the emergent state that was also related to the number of dry days. Coupled with findings from previous experiments, we propose a conceptual model that describes how seasonal hydrologic variability may lead to ecosystem state transitions between emergent and open water alternate states. Since vegetative states are only moderately salt tolerant, as sea-level rise pushes the saltwater front inland, the importance of continued progress on Everglades restoration projects, with an aim to increase the volume of freshwater being delivered to coastal wetlands, is the primary management intervention available to mitigate salinization and slow ecosystem state shifts in non-tidal, brackish peat marshes.

Deciphering environmental forcings in the distribution of meiofauna and nematodes in mangroves of the Atlantic-Caribbean-East Pacific and Indo-West Pacific regions

Mangroves develop under environmental conditions and anthropogenic pressures whose impact on benthic meiofauna remains poorly understood. It is unclear how meiofauna communities are structured according to local sedimentary conditions. This study was designed to characterize the community structure of meiofauna and nematodes (dominant taxa) and the associated environmental forcings in intertidal mangrove sediments from Mayotte (Indo-West-Pacific), Martinique and Guadeloupe (Caribbean). Sediment cores were sampled at the end of the dry season at low tide on adult mangrove stands with similar immersion time. In each sediment layer, we analyzed redox potential, pH, porewater salinity, grain size, organic matter, metals, organic contaminants, prokaryotes and meiofauna. Our results show that sediments far from cities and agricultural fields trapped site-specific contaminants due to local water transport processes. Some metals, PAHs or pesticides exceeded toxicity thresholds in most of the studied stations, thus being harmful to benthic fauna. The sedimentary environment acts as a filter selecting specific meiofauna communities at station scale only in the Caribbean. In Mayotte, horizontal homogeneity contrasts with vertical heterogeneity of the sedimentary environment and the meiofauna. Nematode genera showed particular distribution patterns horizontally and vertically, suggesting the presence of sediment patches suitable for a restricted pool of genera on each island. Results in the Caribbean are consistent with nested diversity patterns due to environmental filtering. Conversely, horizontal homogeneity at Mayotte would reflect greater dispersal between stations or more spatially homogeneous anthropogenic pressures. The nematode genera present at depth may not be the most specialized, but the most versatile, capable of thriving in different conditions. Terschellingia and Daptonema showed contrasted responses to environmental forcing, likely due to their versatility, while Desmodora showed uniform responses between study areas, except when toxicity thresholds were exceeded. Our results emphasize that a given genus of nematode may respond differently to sedimentary conditions depending on sites.

Major ion pore-water chemistry evolution in Lake Michigan benthic sediments: Evidence for direct input from Michigan Basin saline groundwater

The Michigan Basin is composed of geological formations that contain brines and evaporites, and solutes from these geological sources have affected benthic sediment pore-water chemistry in Saginaw Bay (Lake Huron). We hypothesize that there exists similar potential for upward solute transport directly from the Michigan Basin into other Great Lakes areas. To test our hypothesis, we present here previously unpublished pore-water chemistry analyses from sediment cores collected during multiple Lake Michigan sampling events (spanning 1991−1999) and a new evaluation of previously published data. In several box cores, pore-water chloride concentrations increase with depth, and Cl:Br ratios are consistent with a geological formation brine source. In all gravity cores we collected from southern Lake Michigan, pore-water sodium concentrations increase with sediment depth. At one sample station, pore-water sodium concentrations exceed 2000 mg L−1 within 2 m of the sediment-water interface. Given the pore-water chemistry changes reported here, combined with information from previous studies of Lake Michigan bedrock geology, a Devonian formation brine is a plausible solute source. The presence of saline pore water within glaciolacustrine sediments underlying Lake Michigan indicates that this solute flux has been active during the past 10 k.y. However, the origins of this solute flux, including timing (onset) and contributions from advective and/or diffusive transport, are unknown. The specific geological source and solute transport process are important to resolve in order to evaluate potential effects of these Michigan Basin solute sources on the Great Lakes’ sediment biogeochemistry and water quality.

Effect of initial pore water content and salinity on the resistivity of methane hydrate-bearing fine sediments

Methane hydrates are widely distributed in the soft silty-clayey soils of continental margin sediments. The resistivity method is generally used to detect their distribution state and monitor their kinetic reaction process. However, there are some major details to be elaborated on as to the occurrence state and the evolution of key characteristic parameters. Based on the kinetic reaction experiment under different lithological conditions (initial water content and pore water salinity), this research records the changing resistance of natural sand porous medium system during the cooling formation of hydrates by in-situ measurement. The Archie formula is further used to study the influencing factors of the resistance of hydrate-bearing sediments and how the resistance changes during hydrate formation. The results demonstrate that these two lithological parameters can significantly affect the resistivity of the hydrate-bearing natural sand porous media system. It is found that within a certain range, NaCl in pore water will inhibit the formation reaction of hydrates, while an increase of initial water content will enhance the hydrate production amount in the system. With the hydrate formation in the pores, the porosity and skeleton composition of the natural sand porous medium change as well, coupled with the salt-removing effect, which further changes the system resistivity. During hydrate formation, the system resistivity changes regularly in the cooling stage, hydrate nucleation stage, and hydrate formation stage. Our study systematically considers the influence of these geological parameters on resistivity characterization at different reaction stages during the formation of natural hydrates. Thus, it can serve as a technical reference for hydrate reservoir logging and other related issues.

Predicting the Electrical Conductivity of Partially Saturated Frozen Porous Media, a Fractal Model for Wide Ranges of Temperature and Salinity

AbstractThe quantitative determination of liquid water content and salinity in soils is crucial for the preservation of hydrological environments and engineering infrastructures, especially in frozen regions. Electrical conductivity, as a fundamental physical parameter in electrical and electromagnetic non‐destructive techniques, varies significantly with the physical and chemical properties, such as pore water conductivity, salinity, water saturation, and temperature. In this study, accounting for pore size and tortuous length following fractal distributions, we develop a new capillary bundle model for variation of electrical conductivity as a function of temperature in broad water saturation and salinity ranges. In this new model, we consider the contributions of bulk and surface conductivities to the total electrical conductivity. To test this model, a series of laboratory experiments were carried out for different initial water saturations and salinities using an electrical resistance apparatus and a nuclear magnetic resonance method. The experimental results show that unfrozen water saturation and ionic concentration affect the electrical conductivity of unsaturated frozen soils. Furthermore, the proposed model is capable of fitting the main trends of the experimental data from the literature and acquired in this study in unfrozen‐frozen conditions for different water contents. Relying on the proposed model, we also determine the expression of the apparent formation factor, which is significantly sensitive to porosity, water saturation, and temperature. The predicted values of the apparent formation factor also agree very well with the experimental data. This new capillary bundle model provides a new perspective in interpreting electrical monitoring to easily deduce changes in key variables in the cryosphere such as liquid water content and moisture gradients.

The effect of salinity on the rigidity and settling behavior of reconstituted water-saturated kaolinite sediments

In sandy sediments, the salinity of the pore water only affects the sound speed of the mixture by way of affecting the sound speed of the pore water. With clay mineral and saltwater mixtures, the intergranular forces that depend on the salinity of the pore water affect the sediment acoustic properties beyond simply affecting the sound speed of the pore water. These dependencies were investigated via image analyses of prepared samples of two kaolinite clay types (Flat DS and RSA) via analyses of their settling dynamics, porosity, and rigidity as a function of pore water salinity. There exists an observable dependence on salinity to mixture porosity and rate of settling. In addition, three regimes of slip-stick dynamics are shown to exist at different salinity ranges: (a) an immediate transition to liquid-like behavior; (b) a viscoelastic transition to liquid-like behavior with long term creep; and (c) a delayed transition to viscoelastic behavior with long term creep. [Work supported by ONR.]

New insights into the flow dynamics of a deep freshwater aquifer in the semi-arid and saline Cuvelai-Etosha Basin, Northern Namibia: Results of a multi-environmental tracer study

Study regionA paleo-megafan system of the Cubango River in the northern parts of the semi-arid Cuvelai-Etosha Basin, shared by Angola and Namibia. It hosts a deep freshwater aquifer, the so-called Kalahari-Ohangwena 2 (KOH-2), with the potential to resolve the imminent regional water supply shortages. Study focusHydrogeochemical and multi-environmental tracer studies incorporating the use of age tracers 14C, 36Cl, 81Kr and 4He to determine the age of groundwater and provide insights into the flow dynamics of the KOH-2. New hydrological insights for the regionStable water isotopes and noble gas thermometry show that in a period with higher rainfall and recharge, temperatures were at least 3 – 4 °C lower than today. Several arguments led to the conclusion that younger groundwater, possibly of an age of 35,000 years, is mixed with ancient saline pore water. These include: 1) the correlation of measured 36Cl and 81Kr ratios, as well as 4He concentrations, using a binary mixing model, and 2) the substantial variation in 81Kr ages, ranging from 40,000 to 170,000 years, over relatively short distances—a phenomenon challenging to explain by advective groundwater flow equations. Consequently, the ages derived from 81Kr measurements serve as indicators of the extent of freshening and therefore describe mixing ages rather than absolute travel times.