Fraction Of Pores Research Articles

Enhancing geothermal petrography with convolutional neural networks

The qualitative assessment of a geothermal reservoir using petrography is often conducted during drilling to assess the permeability, porosity, and mineral geothermometry of the reservoir rocks especially when little is known about the subsurface during the exploration stage. The petrographic analysis includes visually estimating pore and vein fractions, identifying rock textures, describing the degree of alteration, recognizing the hydrothermal alteration minerals and indicated temperature, and noting the presence of shearing and various porosity types. This traditional method of visual estimation and assessment is prone to errors when averaging fields of view and can be labor-intensive, especially during time-sensitive drilling operations when a geologist must analyze hundreds of thin sections per well under a polarizing light microscope. In this study, indicated porosity levels were assigned to 103 geothermal core thin sections based on the grouping of the rock parameters as observed under a polarizing light microscope. To enhance the traditional visual assessment in petrography, this study trained and validated convolutional neural networks (CNNs) in the automatic rating of porosity based on these parameters and in the detection of epidote, a key production marker in high-temperature magmatic-intrusive geothermal systems. Photomicrographs of the geothermal well core thin sections were utilized as input data for training and validating the ResNet, AlexNet, and VGGNet architectures. The three CNN architectures achieved porosity classification precision ranging from 0.74 to 0.84, and epidote detection precision between 0.90 and 1.0 in plane-polarized light (PPL) photomicrographs. The results demonstrate that CNNs can significantly augment traditional petrography in evaluating geothermal well samples.

Improving the performance of crumb rubber concrete using waste ultrafine glass powder

Due to its superior toughness and environmental benefits over traditional concrete, crumb rubber (CR) concrete (CRC) gained considerable attention in both research and practical engineering fields. However, the static mechanical characteristics of CRC exhibit a certain level of decline as CR demonstrates a lower elastic modulus and less effective bonding capabilities with mortar when compared to natural aggregates. Consequently, this study explores the potential of substituting cement with ultra-fine waste glass powder (WGP) to enhance the mechanical characteristics and microstructure of CRC. The impact of varying WGP substitution rates on workability, wet packing density (WPD) in the fresh phase is examined. Moreover, analyses on compressive strength, flexural-tensile strength, ductility index, dynamic elastic modulus, damping ratio, and impermeability post-hardening are presented. The use of scanning electron microscopy (SEM), X-ray diffraction (X-RD), and mercury intrusion piezometry (MIP) provided insights into the influence of WGP on the micromorphology, mineral composition, and pore structure characteristics. The results revealed that WGP introduction enhanced the fresh properties of CRC, notably in terms of workability and WPD. The slump and slump-flow increased to 270 mm and 630 mm for WGP dosing increased to 30 %. A gradual enhancement in strength, dynamic elastic modulus, and impermeability was observed with increased WGP content, alongside a significant improvement in toughness. The compressive and flexural strengths of 30 % WGP were mentioned to be about 11 % and 62 %, respectively, and the permeability coefficient was reduced to 0.78 × 10−12 m2/s. The damping ratio initially decreases, then rises to a peak of 1.6 % at a WGP content of 30 %. Integration of WGP resulted in a progressive decrease in interfacial frictional zone width, average pore diameter, and porosity, while the fraction of harmless pores increased, likely aiding the strength and dynamic elastic modulus.

Reduction of oil absorption and acrylamide content in banana slices by infrared frying

AbstractBackgroundThe crust characteristics of fried crisps determine their oil absorption. Starch structures, as the main components of fried starchy fruits and vegetables, influence their crust formation and properties. This study investigated the reduction of oil uptake and acrylamide content in infrared‐fried (IF) banana slices by modifying starch structures at varying infrared power levels.ResultsInfrared heating improved heat transfer and surface moisture removal in fried banana slices. It facilitated crust formation in the IF samples and produced increased crust uniformity, crust ratio, and hardness. Analysis of the porous properties showed that the volume fraction of pores sized 100–250 μm was reduced in IF samples but the proportion of pores with a diameter ranging from 0.02 to 10 μm was increased. Infrared frying reduced the total oil uptake, surface oil, and structural oil content in banana slices, and each of these measures decreased as infrared power levels increased. Characterization of the starch structures suggested that the damage to the crystalline structure was increased in IF samples and more starch‐lipid complexes were generated, which would be responsible for the formation of a denser and thicker crust. The acrylamide content in the IF sample was reduced, as determined by liquid chromatography–tandem mass spectrometry (LC–MS/MS).ConclusionModifications to starch structures (crystalline structures and chemical structures) play a crucial role in oil absorption in fried starchy fruits and vegetables. Infrared frying can be used as an alternative method to produce low‐fat fruits and vegetable crisps with reduced acrylamide content. © 2024 Society of Chemical Industry.

Effect of carbonation curing regime on 3D printed concrete: Compressive strength, CO2 uptake, and characterization

Carbonation curing is a promising method to improve the mechanical strength and reduce the carbon emissions of 3D printed concrete (3DPC). To avoid the adverse impacts of excessive CO2 exposure, the effect of carbonation curing regimes on 3DPC was investigated in this study. The CO2 uptake and compressive strength of 3DPC with different pre-curing and carbonation durations were determined. The prolonged pre-curing and carbonation duration led to increased CO2 uptake of 3DPC, while its compressive strength reached the highest for 10–17.5-h pre-curing and 12 ∼16-h carbonation. The water loss rate, as an important factor for determining the pre-curing duration of 3DPC, is optimal at 20 %. The appropriate carbonation curing can lead to 39.9 % increase in 3-day compressive strength, but the effect on the later-age strength is weakened. Carbonation curing can improve the pore structure of 3DPC by reducing the porosity and volume fraction of harmful pores. In addition, the prolonged pre-curing and carbonation may result in excessive consumption of C3S and C2S and water loss, adversely affecting the subsequent hydration reactions and decreasing the compressive strength of 3DPC. Hence, suitable pre-curing and carbonation duration should be determined by considering the balance of mechanical strength and CO2 uptake of 3DPC.

An innovative method for mesoscale modelling of moisture diffusion in concrete

Moisture diffusion influences the durability and long-term performance of concrete and whilst it predominantly occurs via the cement matrix and Interfacial Transition Zone, most existing models consider concrete to be homogeneous. This paper introduces a novel micro-meso model that employs random packing and Voronoi tessellation. Rayleigh-Ritz pore distribution and Brunauer-Skalny-Bodor models are combined to determine the radius and fraction of various pores. The results indicate that relative humidity diffuses faster with increasing temperature, decreasing ambient relative humidity and tortuosity. Ambient relative humidity has a greater influence on diffusion compared to temperature and tortuosity. Numerical and experimental comparisons demonstrate that the proposed methodology effectively captures relative humidity distribution across various scenarios. Furthermore, explicit pore network modelling incorporates key parameters for a more accurate analysis. Integrating the proposed methodology into a fully coupled hygro-mechanical framework can potentially yield more accurate predictions of mechanical behaviour; enhancing the reliability of long-term performance assessments and enabling more durable concrete design.

Anti-Corrosion Performance of Magnesium Potassium Phosphate Cement Coating on Steel Reinforcement: The Effect of Boric Acid.

It has recently been found that magnesium potassium phosphate cement (MKPC) paste coating applied on the surface of steel reinforcement can effectively retard the onset of corrosion and suppress corrosion reactions. However, the fast-setting nature of MKPC-which is a merit in repair-can be problematic in a practical engineering process of coating the steel reinforcement with MKPC paste. To address this problem, boric acid (H3BO3) was added as a retarder in an MKPC formulation to prolong the setting time. This work investigated the impact of boric acid (at 5% by weight of MgO) on the anti-corrosion performance of MKPC paste coating through a series of electrochemical (EC) tests. The results showed that the anti-corrosion performance of MKPC paste coating for a mild steel bar could be interfered with by the presence of boric acid. In the same testing situation (immersed in 3.5 wt.% NaCl corrosion solution), the polarization resistance and corrosion current density of the group including boric acid were inferior and exceeded the corrosion thresholds prior to the control group without boric acid. Meanwhile, the time constant phase in the frequency range from 1 Hz to 10 kHz was rarely observed, implying that the presence of boric acid probably impaired the formation of the passivation layer. This decrease in anti-corrosion performance of MKPC paste coating could be related to the larger volume fraction of pores in the range from 0.1 to 10 µm that are formed during the initial stage of coating formation.

Numerical Simulation on the Electrical Conductivity of Ternary Mixtures Containing NaCl Solution, Quartz, and Smectite

AbstractWhile the electrical conductivity of smectite‐rich rocks is high, previous studies have only partially revealed its dependence on temperature, salinity, and porosity. This knowledge gap mainly arises from challenges in controlling various experimental conditions when measuring the conductivity of real smectite‐bearing rock samples and quantifying the smectite content. To mimic conductivity measurements under ideal conditions, this study aimed to develop a simulator capable of accurately configuring the conditions to predict the direct‐current conductivity of saturated rocks composed of an aqueous NaCl solution, quartz, and smectite under various temperatures (20°C–200°C), salinities (10−4–5 mol kg−1), porosities (0–1), and smectite fractions (0–1). The simulator reproduced the experimental conductivity measurements from drilled core samples by giving the anisotropy of those components' distribution. In addition, simulations with randomly assigned components revealed that when rocks contain abundant smectite, the bulk conductivity partially decreases with increasing NaCl solution's salinity or volume fraction. These negative slopes were approximated using empirical equations derived from previous studies. Percolation analysis further revealed that when the components are randomly assigned, conductive paths begin to form between the ends of the modeled sample once the sum of the volume fraction of bulk pore and smectite reaches 0.1.

Correlative X-ray micro-nanotomography with scanning electron microscopy at the Advanced Light Source.

Geological samples are inherently multi-scale. Understanding their bulk physical and chemical properties requires characterization down to the nano-scale. A powerful technique to study the three-dimensional microstructure is X-ray tomography, but it lacks information about the chemistry of samples. To develop a methodology for measuring the multi-scale 3D microstructure of geological samples, correlative X-ray micro- and nanotomography were performed on two rocks followed by scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS) analysis. The study was performed in five steps: (i) micro X-ray tomography was performed on rock sample cores, (ii) samples for nanotomography were prepared using laser milling, (iii) nanotomography was performed on the milled sub-samples, (iv) samples were mounted and polished for SEM analysis and (v) SEM imaging and compositional mapping was performed on micro and nanotomography samples for complimentary information. Correlative study performed on samples of serpentine and basalt revealed multiscale 3D structures involving both solid mineral phases and pore networks. Significant differences in the volume fraction of pores and mineral phases were also observed dependent on the imaging spatial resolution employed. This highlights the necessity for the application of such a multiscale approach for the characterization of complex aggregates such as rocks. Information acquired from the chemical mapping of different phases was also helpful in segmentation of phases that did not exhibit significant contrast in X-ray imaging. Adoption of the protocol used in this study can be broadly applied to 3D imaging studies being performed at the Advanced Light Source and other user facilities.

Tuning porosity of macroporous hydrogels enables rapid rates of stress relaxation and promotes cell expansion and migration

Extracellular matrix (ECM) viscoelasticity broadly regulates cell behavior. While hydrogels can approximate the viscoelasticity of native ECM, it remains challenging to recapitulate the rapid stress relaxation observed in many tissues without limiting the mechanical stability of the hydrogel. Here, we develop macroporous alginate hydrogels that have an order of magnitude increase in the rate of stress relaxation as compared to bulk hydrogels. The increased rate of stress relaxation occurs across a wide range of polymer molecular weights (MWs), which enables the use of high MW polymer for improved mechanical stability of the hydrogel. The rate of stress relaxation in macroporous hydrogels depends on the volume fraction of pores and the concentration of bovine serum albumin, which is added to the hydrogels to stabilize the macroporous structure during gelation. Relative to cell spheroids encapsulated in bulk hydrogels, spheroids in macroporous hydrogels have a significantly larger area and smaller circularity because of increased cell migration. A computational model provides a framework for the relationship between the macroporous architecture and morphogenesis of encapsulated spheroids that is consistent with experimental observations. Taken together, these findings elucidate the relationship between macroporous hydrogel architecture and stress relaxation and help to inform the design of macroporous hydrogels for materials-based cell therapies.

Reducing the oil absorption and oil deterioration in fried apple slices by ultrasound integrated in infrared frying

The effects of integrated ultrasonic infrared frying (USIF) on the oil absorption of apple slices and the oil deterioration were studied with frequency of 28 and 40 kHz, respectively. Results showed that the heat transfer and moisture migration was accelerated by the integrated ultrasound in IF. The soluble Gal-A content and esterification degree of pectin was increased, the damages of pectin crystal structure and chemical structure in side chain was aggravated. These damages to pectin were intensified with higher frequency (40 kHz) of ultrasound. Lower retention of phenols was found in USIF apple slices, but the flavonoids content had no significant change compared to CF samples. USIF samples showed a smoother morphology, and the pore volume and porosity were reduced by ultrasonication applied with 28 kHz but increased with 40 kHz. The largest volume fraction of pores was changed from 100-250 μm in IF to 0.02–10 μm and 10–100 μm by the integrated ultrasound at 28 kHz and 40 kHz samples, respectively. The total oil uptake in USIF samples was reduced by 24.9 %–33.2 % compared to the conventional fried (CF) samples, and achieved the lowest with the frequency of 40 kHz. The surficial and structural oil were also decreased by 39.2 %-51.3 % and 20.9 %–32.3 %, respectively. The peroxide value, acid value, carbonyl value, polar component, and the saturated fatty acids ratio of oil in repeated frying for 16 h was reduced in USIF, especially with ultrasonication 40 kHz. These results indicate that USIF is a promising method for producing novel low-oil apple fries.

Fabrication of porous Ni-Ti shape memory alloy via binder jet additive manufacturing and solid-state sintering

This paper explores the additive manufacturing of nickel-titanium (Ni-Ti) shape memory alloys (SMAs) using binder jetting and subsequent solid-state sintering under an Ar atmosphere. The consolidated 3D-printed Ni-Ti parts exhibit a correlation between pore morphology, pore fraction, and phase formation at different solid-state sintering temperatures. At a sintering temperature of 1175 °C, NiTi grains with TiC precipitates along grain boundaries are observed, accompanied by irregular, interconnected pores constituting ∼15 % of the volume. Increasing the sintering temperature to 1185 °C leads to the formation of a minor phase of Ni4Ti3 within NiTi grains, along with grain boundary TiC precipitates, and isolated pores with a volume fraction of ∼5 %. The higher sintering temperature corresponds to a higher average nanohardness value (8.1 GPa or 763 Hv compared to 6.9 GPa or 654 Hv), indicating the presence of a greater abundance of secondary phases and higher densification at the elevated sintering temperature. While the transformation temperatures (TTs) were undetectable in the bulk-printed samples, a different structure featuring designed channels and thin struts, sintered under similar conditions, exhibited detectable TTs, with a martensite start temperature of 34 °C. Biocompatibility tests demonstrated cell spreading and attachment on both sintered Ni-Ti samples. These findings offer valuable insights into the potential use of binder jetted Ni-Ti for medical implants and tissue engineering applications.

Very fine roots differ among switchgrass (Panicum virgatum L.) cultivars and differentially affect soil pores and carbon processes

Switchgrass (Panicum virgatum L.) is a promising feedstock for biofuel production, with diverse cultivars representing several ecotypes adapted to different environmental conditions within the contiguous USA. Multiple field studies have demonstrated that monoculture switchgrass cultivation leads to slow to negligible soil carbon (C) gains, an outcome unexpected for such a deep-rooted perennial. We hypothesize that different switchgrass cultivars have disparate impacts on soil C gains, and one of the reasons is variations in physical characteristics of their roots, where roots directly and indirectly influence formation of soil pores. We tested this hypothesis at Great Lakes Bioenergy Research Center's research site in Michigan using two lowland cultivars (Alamo and Kanlow) and four upland cultivars (Southlow, Cave-in-Rock, Blackwell, and Trailblazer). Three types of soil samples were collected: 20 cm diameter (Ø) intact cores used for root analyses; 5 cm Ø intact cores subjected to X-ray computed tomography scanning used for pore characterization; and disturbed soil samples used for microbial biomass C (MBC) and soil C measurements. Path analysis was used to explore interactive relationships among roots, soil pores, and their impact on MBC, and ultimately, on soil C contents across six cultivars. The abundance of very fine roots (<200 μm Ø) was positively associated with fractions of pores in the same size range, but negatively with distances to pores and particulate organic matter. Higher abundance of such roots also led to greater MBC, while greater volumes of medium pores (50–200 μm Ø) and shorter distances to pores increased MBC. Results suggest that the greater proportion of very fine roots is a trait that can potentially stimulate soil C gains, with pore characteristics serving as links for the relationship between such roots and C gains. However, at present, ten years of cultivation generated no differences in soil C among the studied cultivars.

Carbonation resistance of fly ash/slag based engineering geopolymer composites

Engineering geopolymer composites (EGC) are promising environmentally friendly building materials with excellent mechanical properties. However, the durability of EGC is compromised by gradual carbonation from atmospheric exposure. For the first time, this study provided an insight of the carbonation of EGC by comprehensively investigating the effect of mix design, such as fly ash/ground granulated blast furnace slag ratio (FA/GGBS ratio), alkali content, water/binder ratio (W/B ratio) and polyethylene (PE) fibre content, on its carbonation resistance. Our results showed the components in EGC affected the carbonation through the alternation of microstructures. An increase of FA content and W/B ratio significantly increased the carbonation depth by 206.6 % and 116.3 % respectively due to the increased porosity and transition pore fraction, resulting in more than 30 % reduction in tensile strength and 15 % reduction in compressive strength. However, increased alkali and fibre content prevent carbonation with around 60 % and 26 % decrease of the carbonation depth, leading to a less loss of the mechanical properties. Furthermore, we tested the pH values of the EGC along the carbonation depth, proposing a novel approach to assess the carbonation degree by dividing the area into completely carbonated area (pH around 9.21–10.44) and non-carbonated area (pH around 12.58–13.37). These findings provide insights for mitigating carbonation effects in EGC and facilitate the widespread use of this sustainable material in construction applications, ensuring long-term durability and reliability.

Enhancing Capillary Pressure of Porous Aluminum Wicks by Controlling Bi-Porous Structure Using Different-Sized NaCl Space Holders.

Capillary pressure and permeability of porous media are important for heat transfer devices, including loop heat pipes. In general, smaller pore sizes enhance capillary pressure but decrease permeability. Introducing a bi-porous structure is promising for solving this trade-off relation. In this study, the bi-porous aluminum was fabricated by the space holder method using two different-sized NaCl particles (approximately 400 and 40 μm). The capillary pressure and permeability of the bi-porous Al were evaluated and compared with those of mono-porous Al fabricated by the space holder method. Increasing the porosity of the mono-porous Al improved the permeability but reduced the capillary pressure because of better-connected pores and increased effective pore size. The fraction of large and small pores in the bi-porous Al was successfully controlled under a constant porosity of 70%. The capillary pressure of the bi-porous Al with 40% large and 30% small pores was higher than the mono-porous Al with 70% porosity without sacrificing the permeability. However, the bi-porous Al with other fractions of large and small pores did not exhibit properties superior to the mono-porous Al. Thus, accurately controlling the fractions of large and small pores is required to enhance the capillary performance by introducing the bi-porous structure.

Feasibility study on the preparation of ternary blended cements with low-kaolinite calcined coal gangue and limestone

This paper presents a feasibility study on the production of ternary blended cements with low-kaolinite calcined coal gangue (CCG) and limestone, considering kaolinite contents varying from 11.7 % to 40.6 % in coal gangue (CG). The ternary systems were designed with 15 %, 30 %, 45 % and 60 % by mass of cement replaced by CCG and limestone with a fixed mass ratio of 2:1. The fluidity and compressive strength of the mortars were measured, followed by the strength efficiency analysis combined with CO2 emission. The potential hydration mechanism was revealed by analysing the hydration kinetics, hydrates and microstructural evolution of these ternary pastes. The results showed that it is possible to use low-kaolinite CCG and limestone to prepare ternary blended cements with adequate mechanical strength that can fulfill the 28-day strength requirement of 32.5 or 42.5 grade cement. In addition, Increasing the kaolinite content in CG can increase the substitution of cement up to 60 %. Microstructural studies indicated that the compressive strength of these ternary mortars at 3 and 7 days was mainly dominated by cement hydration and the pozzolanic reaction between CCG and portlandite (CH), respectively. The precipitation of carboaluminates from the synergy of CCG and limestone significantly reduced critical pore size and increased the volume fraction of fine capillary pores from 7 days, well supporting the strength development of the ternary mortar. The findings of this work underscores the potential of using low-kaolinite CCG as a supplementary cementitious material (SCM) to reduce carbon footprint in the field of construction, and also in contributing to a high-value green utilization of solid waste.

Salt weathering resilience in masonry: An accelerated laboratory study involving wind-induced variations

Salt weathering resistance is a critical parameter governing the durability of coastal masonry units and mortars. Accelerated weathering cycles are employed at the laboratory to investigate the responses of substrates and mortars upon exposure to salt, moisture, temperature fluctuations and humidity. In this paper, the individual and synergistic performances of bricks and mortar formulations when exposed to accelerated salt weathering cycles are investigated, incorporating the influence of wind on their resilience. The study examines the behaviour of brick-mortar sandwich specimens and separate specimens of bricks and mortar mixtures comprising cement, dry hydrated lime, fly ash, and limestone. These specimens are exposed to repeated weathering cycles in a 5 % sodium sulphate solution. Along with the mass variations during each weathering cycle, physicomechanical, microstructural, mineralogical and morphological characterization of the specimens are used to compare their salt weathering resistance. The results highlight that the responses of individual masonry components might not collectively translate to the overall performance of the combined system due to hygric resistance, which is minimal when the components have comparable pore size distribution. Higher microporosity (pores of diameter between 0.1 μm and 10 μm) and mechanical strength enough to resist the crystallization stresses together provide better resistance to salt weathering to the individual mortars. However, pore structure compatibility and pore fraction similarity between the components govern the behaviour of the combined system and, therefore, reflect the better performance of sandwich specimens with brick and lime mortars. The study demonstrated that wind accelerates material degradation during salt weathering through progressive erosion, accelerated evaporation and subsequent formation of isolated thenardite.

Effect of Laser Parameters on Fracture Properties of Laser-Repaired Cracks with Micro/NanoMaterial Addition: Multiscale Analysis.

In laser crack repair processes, laser parameters have significant influence on repair quality. Improper combination of laser process parameters may result in defects-such as porosity, ablation, and coarse grain size-in remelted zones. A trans-scale computational model is established by combining crystal plasticity finite elements and variable-node finite elements. The influence of microstructure characteristics such as grain size and porosity of the repair layer on the cumulative plastic slip (CPS) on the dominant slip system at the meso-scale and the J-integral at the macro-scale is studied to explore the effect of laser process parameters on repair quality. The results show that when the laser power is 1800 W and the heating time is 0.5 s, the grain size and porosity of the repaired specimen are the smallest. The J-integral of the repaired specimen is more than 8% smaller than that of the unrepaired specimen and about 3% smaller than that of the repaired specimen, with a laser power of 2000 W and a heating time of 1 s. Pores increase the CPS of the crystal around the pores, especially when a pore have sharp corners. Selecting appropriate laser process parameters can not only refine grain size but also reduce the volume fraction of pores and thus reduce the J-integral and eventually improve repair quality of repaired specimens. The study investigates the relationship of process parameter-microstructure-repair quality in the laser repair process and provides a method for studying the mechanical behavior of materials at macro and micro scales.

Enhancements of magnetic properties and compacted density for Fe-based amorphous soft magnetic composites via hot compacting under an ultra-low pressure

Amorphous FeSiBCCr soft magnetic composites (FeSiBCCr-SMCs) with high compacted density (ρc) and excellent magnetic properties has been successfully hot-compacted under an ultra-low pressure of 160 MPa. The thermoplastic deformation of amorphous powders within the supercooled liquid region can give rise to the increase of ρc and the reduction of non-magnetic pores fraction for the SMCs. This situation is conductive to the decrease in resistance of domain wall motion during magnetization process of SMCs, and finally contributes to the improvement of SMCs’ soft magnetic properties. Under the recommended conditions with the compaction temperature (Tc) of 475 ℃, the pressure holding time (th) of 6 min, and the molding pressure (Pm) of 160 MPa, the FeSiBCCr-SMCs’ ρc increases by 28.8 % to 6.53 g/cm3, the corresponding effective permeability (μe) increases by 3.39 times to 73.1, while its total core loss (Pcv) reduces by 57.4 % to 275.3 kW/m3 at 100 kHz, 0.05 T compared with those of the SMCs prepared at Pm=600 MPa, Tc=25 ℃.

Effect of wall thickness on the microstructure and properties of a fourth-generation single crystal superalloy

This study investigated the effect of various thicknesses (0.3–1.5 mm) on the as-cast and heat-treated microstructures of the fourth-generation single crystal superalloy. The microstructures and fracture characteristics of samples with various thicknesses were analyzed after high-temperature stress rupture tests at 1100 ℃/137 MPa. The results showed that as the alloy thickness increased from 0.3 mm to 1.5 mm, the degree of segregation between dendritic core and inter-dendritic significantly increased. The increased segregation was attributed to the slower solidification rate of the 1.5 mm-thick sample compared to the 0.3 mm-thick sample. Lower solidification rates and higher degrees of dendritic segregation enhanced the area fraction of eutectics, the primary dendrite arm spacing (PDAS), the and area fraction of pores. After stress rupture tests, the rupture life of the alloy increased from 81 h to 333 h. It was observed that in the 0.3 mm-thick sample, microcracks initiated at the surface and extended into the matrix. On the contrary, as for the 1.5 mm-thick sample, microcracks initiated at the matrix and propagated towards the surface. To evaluate the influence of oxidation, interrupted stress rupture tests were conducted in air atmosphere to investigate the thickness debit effect. Surface oxidation led to the initiation of microcracks on the surface and change the morphology and area fraction of the internal γ′ phase, as well as the effective load-bearing area of the samples. TEM and EBSD were employed to characterize the deformation characteristics of samples with various thicknesses, and the influence of thickness on deformation mechanisms was discussed as well.

Revealing the role of multi-scale fibers in the compressive behavior of a novel ultra-high performance concrete subjected to elevated temperatures

Ultra-high performance concrete has received widespread attention due to its excellent performance. However, the mechanical properties can seriously degrade at high temperatures. To improve the thermal resistance, cenospheres and multi-scale fibers such as polyethylene fiber, steel fiber, calcium sulfate whisker, carbon fiber, and carbon nanotubes, are added to develop a type of ultra-high performance (MSFUHPC) in this work. The effects of cenospheres and multi-scale fibers on peak strain, compressive strength, Young's modulus, specific toughness and stress-strain curve are studied at various temperatures (25 °C, 200 °C, 400 °C, 600 °C, and 800 °C) through uniaxial compression tests. Additionally, mercury intrusion porosimetry tests and scanning electron microscope tests are used to discuss the effect of cenospheres and multi-scale fibers on the microstructure. The results demonstrate that both CE and multi-scale fiber can reduce the thermal damage of MSFUHPC. The multi-scale fiber can significantly improve the mechanical strength of the material, while CE has the opposite effect. It is found that microscale and nanoscale fibers have negligible effect on the specific toughness, while the effect of CE on specific toughness depends on the temperature and its content. Results show that the incorporation of multi-scale fibers effectively decreases the fraction of large pores while simultaneously refining the pore structure and enhancing the proportion of gel pores. Furthermore, the stress-strain relationship of MSFUHPC is established by considering the influence of multi-scale fiber content and high temperature.