A small amount of the conductive carbon agent in lithium-ion battery (LIB) formulation has a significantly impact on the rate capability performance of battery but the distribution problem of the carbon conductive material is issued in the electrode slurry due to its hydrophobic and inert characteristics. To overcome this problem, the use of dispersant agent was proposed in the electrode fabrication process.In this study, the grafting of adhesive acrylamide monomer (AM) and a long-chain alkyl monomer onto carboxymethyl cellulose (CMC) is applied to binder to improve the conductive agent distribution in a high-capacity SiOx/C anode. The long alkyl chain in the monomer of the graft copolymer binder exhibits good dispersibility of the carbon agent and improved conductive matrix compared to the binder with no alkyl monomer. This may be explained by CH-π integration between the alkyl monomer in graft polymer and carbon agent. The high-capacity SiOx/C anode with the long-alkyl chain introduced graft binder is examined in the slurry level with rheology and dispersion stability, in the electrode sheet level with electric resistance, peel-off, and coin-cell level with various electrochemical performance, charge/discharge performance. Keywords: Silicon oxide; Graphite; Carbon agent distribution, long-chain alkyl monomer; Acrylamide; Graft copolymer Figure 1