Cement-soil can effectively improve the mechanical characteristics of soft soil and reduce the deformation of foundations through the physical and chemical processes of cement hydration. After mixing cement with soft soil, the hydration reaction of cement consumes a certain amount of water, which leads to a decrease in the water content. The early strength of cement-soil refers to the undrained shear strength within a few hours of mixing. The initial setting time of cement-soil can reflect its early strength development. In this study, polymer optical fibre (POF) sensors are used to visually monitor the early strength of cement-soil with different cement contents; the monitoring results show that the POF sensor can effectively visualize the hydration process of cemented soil. The cement-soil hydration process is divided into three stages: the initial setting time of the cement-soil is 13-15 h, and the final is 33-41 h. Furthermore, the cement content significantly influences the initial and final setting times of cement-reinforced soil. As the cement content increases, the initial and final setting times of the cement–soil decrease. This study proposes a new method for monitoring the strength of cement-reinforced soils.