Microwave absorbing properties of polymer composites based on core-shell fillers with ultra-high molecular weight polyethylene core and GNP-carbonyl iron, GNP-cobalt oxide Co3O4, GNP-micro-sized MoS2, and GNP-barium hexaferrite BaFe12O19 hybrid shells were investigated in the frequency range of 40–60 GHz. Scanning electron microscopy sizing of the constituent particles in the composites showed the characteristic dimension of micron for Fe particles while Co3O4 and BaFe12O19 particles are found to be much smaller (nanometer-sized); MoS2 particles mostly form agglomerates and have diverse shapes and varying from 70 nm to 3–4 μm sizes. The shielding properties of composite materials (CMs) with 30 wt % Fe (Co3O4,MoS2, BaFe12O19) + C wt. % GNP/PEwith the GNP concentration c in the range of 1–5 wt% of nanocarbon are weakly frequency dependent. But the analyzed composites interaction with the electromagnetic radiation reveals significant influence of both the nanocarbon content and the additional dielectric or magnetic component type in the shell materials on the shielding parameters. The calculated values of the effective absorption coefficients Aeff for the investigated composites with different hybrid shells have shown that at 3 wt % GNP in the composite with 30 % Co3O4Aeff increases greatly and reaches 0.75, exceeding the correspondent values for the 30%BaFe12O19+GNP system. The primary contribution of absorption to the shielding characteristics of the investigated polymer CMs based on core-shell fillers with hybrid shells constitutes good prospects of applications.
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