Poly Butylene Succinate Nanocomposites Research Articles

Mechanical, Crystallization, Rheological, and Supercritical CO2 Foaming Properties of Polybutylene Succinate Nanocomposites: Impact of Carbon Nanofiber Content.

As a substitute for conventional polymers for the preparation of biodegradable microcellular polymeric foams, polybutylene succinate (PBS) presents one of the most promising alternatives. However, the low melt strength of PBS makes it difficult to produce high-performance microcellular foams. This study aimed to improve the melt strength of PBS and explore the mechanical, thermal, crystalline, rheological, and supercritical CO2 foaming properties of PBS nanocomposites by using carbon nanofibers (CNFs). This study found that nanocomposites containing 7 wt% CNF exhibited the highest tensile strength, Young's modulus, and bending strength. Moreover, the CNF nanofillers were well dispersed in the PBS matrix without significant agglomeration, even at high filler concentrations. Furthermore, the nanocomposites demonstrated improved melting temperature and crystallinity compared with pure PBS. The rheological analysis showed that the addition of CNFs significantly increased PBS viscosity at low frequencies due to the interaction between the PBS molecular chains and CNFs and the entanglement of CNFs, resulting in a more complete physical network formation when the CNF content reached above 3 wt%. During the supercritical CO2 foaming process, the addition of CNFs resulted in increased cell density, smaller cells, and thicker cell walls, with good laps formed between the fibers on the cell walls of nanocomposite foams. Moreover, the electrical conductivity and electromagnetic interference (EMI) shielding properties of the foamed material were studied, and a nanocomposite foam containing 7 wt% CNF showed good electrical conductivity (4.5 × 10-3 S/m) and specific EMI shielding effectiveness (EMI SE) (34.7 dB/g·cm-1). Additionally, the nanocomposite foam with 7 wt% CNF also exhibited good compression properties (21.7 MPa). Overall, this work has successfully developed a high-performance, multifunctional PBS-based nanocomposite foam, making it suitable for applications in various fields.

Temperature effects on electric charge transport processes and electron emission in PBS–clay nanocomposites submitted to electron bombardment

The effects of isothermal conditions on the charge transport processes and electron emission properties of polybutylene succinate (PBS) nanocomposites with different nanoclay content are investigated. The temperature range used (20 °C–80 °C) is close to the working conditions of materials used in many applications (insulation, sensors). These effects are highlighted using an appropriate device placed in a scanning electron microscope, allowing measurement of induced current in an electron-irradiated specimen. The experimental results show that the rise in temperature involves a decrease in the charging ability and an increase in the conductivity of PBS nanocomposites. The mobility of charge carriers and its thermal dependency deduced during the discharge step were found to be lower for the nanocomposites. A qualitative analysis, expressed to understand these observations, is based on the determination of the electron trap energy distribution (i.e. density of occupied states). Secondary electron emission yield decreased with increasing temperature. The results help us envision a new class of insulators with improved electrical performance. The operating thermal stress, combined with the absence of trapped charges, allows a reduction of electrical and thermal aging and consequently ensures the long-term reliability of the insulators (for instance under High Voltage).

Outstanding chain-extension effect and high UV resistance of polybutylene succinate containing amino-acid-modified layered double hydroxides.

Polybutylene succinate (PBS) nanocomposite materials were prepared using a melt compounding process. The Mg2Al-based PBS nanocomposites, dispersed with inorganic–organic hybrid materials (layered double hydroxides, LDHs), were functionalized with the amino acids L-histidine (HIS) and L-phenylalanine (PHE). The rheological and anti-ultraviolet (anti-UV) properties were investigated and compared to filler-free PBS as well as LDH Mg2Al/nitrate as references. Both organo-modified LDHs exhibited a remarkable chain-extension effect for PBS with an outstanding increase in the zero-shear viscosity η0 for PBS–Mg2Al/PHE (two order of magnitude increase as compared to filler-free PBS). These results were compared to data found in the literature. Moreover, HIS and PHE anions embedded into the LDH structure can successfully prevent the chain scission reactions that usually occur during photo-ageing of PBS under UV radiation exposure. This highlights the outstanding performance of the LDH hybrid materials, and in particular, their application as a polymer chain extender and UV stabilizer for PBS, which can likely be extended to other biodegradable polymers.