Polycyclic Aromatic Hydrocarbons Pollution Levels Research Articles

Environmental profile, potential sources, and ecological risk of polycyclic aromatic hydrocarbons in a typical coastal bay and outer bay area.

As a class of persistent organic pollutants, polycyclic aromatic hydrocarbons (PAHs) are widely present and accumulate in multimedia environments. The pollution characteristics, spatiotemporal distribution, potential sources, influencing factors, and ecological risks of 16 PAHs were investigated in the water-sediment system of the Hangzhou Bay and outer bay area (HZB and OBA, respectively). The total concentrations of 16 PAHs (∑PAHs) were 220 ± 97.0 and 130 ± 36.0ng/L in the seawater and 343 ± 179 and 505 ± 415μg/kg (dry weight) in the sediments of the HZB and OBA, respectively. The pollution level of PAHs in the HZB seawater was higher than that in the OBA seawater, but the opposite result was found in the sediments. Moreover, ∑PAHs exhibited high temporal variability in the HZB seawater (rainy season > dry season), whereas ∑PAHs in the sediments showed no significant difference between seasons. The molecular diagnostic ratio method was used to identify pollution sources and showed that the PAHs in seawater came from different pollution sources (fuel combustion and petroleum), whereas the PAHs in the sediments originated from coincident sources (mixed combustion). Correlation analysis revealed that temperature was positively related to ∑PAHs, whereas salinity was negatively related to seawater ∑PAHs values. Ecological risk assessment demonstrated that the potential for adverse ecological effects was low to moderate in seawater but moderate to high in the sediments.

Insights into the mechanisms underlying the biodegradation of phenanthrene in biochar-amended soil: from bioavailability to soil microbial communities

The dynamic effect of biochar amendment in contaminated soil on the bioavailability of polycyclic aromatic hydrocarbons (PAHs) and microbial communities and how it comprehensively affects PAH biodegradation remain unclear. This study investigated the effects of wheat straw-derived biochars obtained at 300 and 500 °C at different amendment levels (0.03% and 0.3%) on the mineralization kinetics of phenanthrene with different initial concentrations (2 and 20 mg kg−1) in soil by indigenous microorganisms. The results revealed that the addition of biochar inhibited both the rates and extents of mineralization in low-concentration phenanthrene-contaminated soil (PLS) by 38.9–78.3% and 23.9–53.6%, respectively. This was because biochar amendment in the PLS greatly reduced the bioavailable fraction of phenanthrene for degradation owing to its strong sorption and also decreased that to specific degrading bacterial genera, which hindered their growth and reduced their abundances by 1.37–36.6%. However, biochar addition into the soil contaminated with high concentrations of phenanthrene (PHS) resulted in its effective mineralization and enhanced mineralization rates and extents at high amendment levels by 32.4–86.7% and 32.0–44.7%, respectively. This was because biochar amendment in the PHS significantly promoted the abundances of the total bacterial communities (29.9–80.4%) and potential degrading genera (1.89–25.9%) by providing nutrients and stimulated the specific PAH-degradative nidA gene abundance by 1–2 times. These findings will guide the use of biochar to remediate soils with different PAH pollution levels based on the two roles that they play (i.e., immobilizing PAHs or facilitating PAH degradation).Graphical

Health Risk Assessment of PAHs from Estuarine Sediments in the South of Italy

Increased concerns about the toxicities of Polycyclic Aromatic Hydrocarbons (PAHs), ubiquitous and persistent compounds, as well as the associated ecotoxicology issue in estuarine sediments, have drawn attention worldwide in the last few years. The levels of PAHs in the Sele, Sarno, and Volturno Rivers sediments were evaluated. Moreover, the cancerogenic risk resulting from dermal and ingestion exposure to PAHs was estimated using the incremental lifetime cancer risk (ILCR) assessment and the toxic equivalent concentration (TEQBaP). For Sele River, the results showed that the total PAH concentration ranged from 632.42 to 844.93 ng g-1 dw, with an average value of 738.68 ng g-1 dw. ∑PAHs were in the range of 5.2-678.6 ng g-1 dw and 434.8-872.1 ng g-1 dw for the Sarno and Volturno River sediments, respectively. The cancerogenic risk from the accidental ingestion of PAHs in estuarine sediments was low at all sampling sites. However, based on the ILCRdermal values obtained, the risk of cancer associated with exposure by dermal contact with the PAHs present in the sediments was moderate, with a mean ILCRdermal value of 2.77 × 10-6. This study revealed the pollution levels of PAHs across the South of Italy and provided a scientific basis for PAH pollution control and environmental protection.

Historical evolution of polycyclic aromatic hydrocarbon pollution in Chaihe Reservoir from 1863 to 2018

Pollution from polycyclic aromatic hydrocarbons (PAHs) spreads and changes worldwide. The pollution evolution in the regional water environment evolves in response to multiple factors, requiring considerable attention. PAH heterogeneity in the sediment core from Chaihe Reservoir was investigated to indicate dynamic changes in PAH pollution levels and sources and propose recommendations for controlling PAHs. Dynamic PAH patterns showed that the overall decline in PAH pollution was in association with local anthropogenic activities, temperature, and precipitation over the period 1863–2018. Nevertheless, coal, oil, and natural gas consumptions still played significant roles in transferring PAHs to the reservoir. Meanwhile, there were dominant local origins, including grass, wood, and coal combustion. The results highlight that the joint action of natural and anthropogenic interventions mitigated PAH pollution in the reservoir. Promoting improved fuels, new energy vehicles, and cleaner energy may further lower PAH pollution.

Identifying and Characterizing Critical Source Areas of Organic and Inorganic Pollutants in Urban Agglomeration in Lake Baikal Watershed

Critical source areas (CSAs) are the areas prone to generating runoff and are characterized by a high level of soil pollution. CSAs may accumulate and release soil pollutants emitted by primary emission sources (industrial and municipal enterprises) into the surface water during storm events. The aim of this study was to identify CSAs and their pollution sources and to assess the level of soil pollution in CSAs with polycyclic aromatic hydrocarbons (PAH) and trace metals (TM). CSAs were identified using a geospatial data model (GIS), and primary emission sources were identified using a positive matrix factorization (PMF) model. It was found that the soils of CSAs were characterized by higher pollution levels than soils outside the CSAs. Pollution levels were highly variable among the identified CSAs due to the different capacities of the plants located in those areas. Due to high variability of TM concentrations in preindustrial soils, the pollution level of PAHs and the pollution level of TMs in CSA soils did not correlate with each other. The PAH composition of bottom sediments was different from that of soils, whereas the TM compositions of the soils and bottom sediments were similar. It was proved that the main sources of PAHs and TMs in CSA soils were traffic emissions and central heating boilers.

Concentration, Source, and Health Risk Assessment of Polycyclic Aromatic Hydrocarbons: A Pilot Study in the Xuanwei Lung Cancer Epidemic Area, Yunnan Province, China

Polycyclic aromatic hydrocarbons (PAHs) are toxic and hazardous volatile environmental pollutants that have been studied as possible major causative agents of lung cancer in Xuanwei. In this paper, indoor and outdoor PM2.5 samples were collected from two homes at different time periods in Hutou, the lung cancer epidemic area in Xuanwei. The results showed that PAH pollution levels from coal combustion in Xuanwei lung cancer epidemic area were significant. The mass concentrations of total PAHs, major carcinogenic compounds, and benzo[a]pyrene-based equivalent concentration (BaPeq) were significantly higher in the coal-using home than in the electricity-using home. For the coal-using home, the PAHs were mainly derived from coal combustion. For the electricity-using home, the PAHs might have been a combination of traffic and coal combustion sources. The human health risk due to inhalation exposure to the PAHs was represented by the incremental lifetime cancer risk (ILCR) of the inhalation exposure. The results showed that the indoor cancer risk for the coal-using home in Xuanwei is higher than that of the electricity-using home and much higher than that of Chinese megacities such as Beijing and Tianjin. Long-term exposure to indoor coal-burning environments containing high levels of PAHs may be one of the main reasons for the high incidence of lung cancer in Xuanwei.

Characteristics of indoor and outdoor Polycyclic Aromatic Hydrocarbons (PAHs) pollution in TSP in rural Northeast China: A case study of heating and non-heating periods.

Approximately 91% of the world's population lives in an air-polluted environment, and environmental pollution has become a widespread concern. Urban indoor and outdoor air pollution has been fully researched and effective control measures have been proposed. However, the issue of air pollution in rural areas has not been explored in depth. Compared to urban air pollution, the rural air pollution problem is more complex and urgent. Due to climatic factors and economic conditions in rural Northeast China, most households use solid fuels such as biomass straw and coal as domestic energy during the heating period, which will cause serious pollution problems of Total Suspended Particulate (TSP) and Polycyclic Aromatic Hydrocarbons (PAHs). To investigate the pollution characteristics of PAHs in indoor and outdoor TSP in rural Northeast China during the heating and non-heating periods, a medium-sized particulate matter collector 1108A was used to collect TSP for 7days, and GC-MS was used to detect PAHs. The results showed that indoor TSP and PAHs pollution levels were the highest during the heating period. PAHs source analysis by Diagnostic Ratio (DR) and Principal Component Analysis (PCA) indicated that the main sources were biomass and coal combustion, vehicle emissions, and domestic waste incineration. According to the results of carcinogenic risk model calculations, there is a potential carcinogenic risk to the population in the Northeast rural living area. This study reflects the pollution characteristics and sources of indoor and outdoor TSP and PAHs in rural Northeast China during heating and non-heating periods, and provides a reference for further prevention and control of air pollution in rural areas, which is conducive to improving the living environment and improving human health.

Environmental Risk Assessment of Polycyclic Aromatic Hydrocarbons in Farmland Soils near Highways: A Case Study of Guangzhou, China.

Recently, the rapid growth in vehicle activity in rapidly urbanized areas has led to the discharge of large amounts of polycyclic aromatic hydrocarbons (PAHs) into roadside soils and these compounds have gradually accumulated in the soil, which poses a serious threat to national food security and public health. However, previous studies did not clearly investigate the seasonal differences in PAH pollution of roadside soil by different highways. Therefore, based on field investigations, this study collected 84 soil surface samples to compare the pollution characteristics of 16 PAHs in farmland soils located near different roads in different seasons in Guangzhou, China. The results showed that the concentration of Σ16PAHs in farmland soils in spring (with a mean value of 258.604 μg/kg) was much higher than that in autumn (with a mean value of 157.531 μg/kg). There are differences in the PAH compositions in spring (4 ring > 3 ring > 5 ring > 6 ring) and autumn (4 ring > 5 ring > 6 ring > 3 ring). The proportion of 4–6 ring PAHs was much higher than 2–3 ring PAHs in both seasons. The spatial differences were significant. The sampling areas with higher concentrations of 16 PAHs were Tanbu Town, Huadu District (TB), Shitan Town, Zengcheng District (ST), and Huashan Town, Huadu District (HS), while the lowest concentration was in Lanhe Town, Nansha District (LH). The results of the diagnostic ratios showed that the main source of soil PAHs consists of a mixed source from petroleum and biomass combustion. The results from the total pollution assessment method and Nemerow index method indicated that the pollution levels of PAHs in the farmland soils indicated weak contamination. Our study provides a scientific basis for the prevention and control of soil pollution in farmlands near highways.

Spatiotemporal Distribution and Source Apportionment of Suspended Polycyclic Aromatic Hydrocarbons in Surface Water

Polycyclic aromatic hydrocarbons (PAHs) are a type of typical environmental pollutant with carcinogenic effects and high ecological risk. With the development of industry, surface water acts as a primary sink for PAHs. Owing to their low solubility, a significant amount of PAHs are adsorbed onto suspended particulate matter in surface water, which presents a serious risk to human health and the ecological environment. To protect human health and aquatic organisms, a systematic assessment of the trends in PAHs exposure risk is essential. Based on long-term monitoring data from 2002 to 2016, this study systematically evaluated the spatiotemporal distribution and source apportionment of PAHs adsorbed on suspended particulate matter in surface water. The results of the Mann-Kendall test indicated that pollution levels of PAHs decreased from 2012 to 2016. The maximum average content was 6239 μg·kg-1, and the minimum was 2760 μg·kg-1. Benzo(b)fluoranthene, benzo(k)fluoranthene, chrysene, and benzo(a)anthracene showed significant declines from 2002-2016 (P<0.05). Levels of benzo(a)pyrene, dibenzo(a,h)anthracene, and indeno(1,2,3-cd)pyrene were steady. Wavelet analysis showed that the pollution level of PAHs had significant periodic oscillations for surface water. Midstream and downstream Σ16PAHs showed significant declines from 2002-2016 (P<0.05), whereas upstream Σ16PAHs were steady. ANOVA analysis showed that the spatial difference was significant and occurred in the following order:midstream (6168 μg·kg-1)>upstream (5407 μg·kg-1)>downstream (3412 μg·kg-1). Diagnostic ratio analysis and the positive matrix factorization model suggested that the major sources of PAHs were traffic sources, coal burning sources, and biomass combustion sources, which accounted for 40.9%, 33.7%, and 25.4%, respectively. The contribution of traffic sources decreased by 25.9%. The contributions of coal burning sources and biomass combustion sources increased by 4.8% and 21.1% from 2002-2009 to 2010-2016, respectively. These results provide scientific reference for risk analysis and the control of PAHs pollution in surface water.

Pollution Characteristics and Risks of Polycyclic Aromatic Hydrocarbons in Underground and Surface Drinking Water Sources in Northeast Inner Mongolia

Polycyclic aromatic hydrocarbons (PAHs) are hazardous and ubiquitous pollutants in the aquatic environment, and understanding the pollution characteristics and risk levels of PAHs is of great significance to the sustainable development of drinking water sources and drinking water safety. Hence, PAHs residues were measured qualitatively and quantitatively with solid-phase extraction-gas chromatography-mass spectrometry (SPE-GC-MS) in 33 water samples (including 22 groundwater and 11 surface water samples) of the drinking water sources in the Manzhouli and Xinyouqi areas of northeast Inner Mongolia, and assessments of the pollution level of PAHs and the health and ecological risks were carried out. The results showed that PAHs were detected in all 33 sampling points of Manzhouli drinking water sources, except for benzo[k] fluoranthene, benzo[a] pyrene, and dibenzo[a,h] anthracene, with detection rates ranging from 36.36% to 95.45%; the detection rates of the other 13 PAHs monomers were 100%. The detection range of ρ（ΣPAHs） was 42.76-164.50 ng·L-1, and the mean value was 90.82 ng·L-1. The detection ranges of ρ（ΣPAHs） in surface water and groundwater were 66.39-164.50 ng·L-1 and 42.76-147.70 ng·L-1, respectively. The concentration of the detected naphthalene was the highest, with a mean value of 36.91 ng·L-1, and the concentration of anthracene was the lowest, with a mean value of 0.81 ng·L-1; there were no significant differences among the concentrations of all the PAHs monomers of the surface and groundwater (P>0.05). The pollution of PAHs was at a median level in China and abroad, mainly in the middle and low loops (3-4 loops). The analysis of the sources of PAHs in groundwater and surface water in Manzhouli using the ratio feature method and principal component analysis showed that the PAHs in the drinking water source water bodies in the Manzhouli area were mainly affected by the combustion of coal and biomass and oil, and some surface water sources were affected by the oil source. The human health and ecological risk assessment results showed that the water body of drinking water would not cause health risks to the human body, and the ecological risk was at a medium level; however, the high risk of benzo[b] fluoranthene (BbF) monomer production should be continuous cause for concern. From the perspective of the sustainable development of drinking water sources and drinking water safety, the necessary supervision and protection measures should be considered to prevent further pollution. The results of this research provide a scientific basis for the pollution control and prevention and control of PAHs in drinking water sources.

Influence of Source Apportionment of PAHs Occurrence in Aquatic Suspended Particulate Matter at a Typical Post-Industrial City: A Case Study of Freiberger Mulde River

Polycyclic aromatic hydrocarbons (PAHs) have received extensive attention because of their widespread presence in various environmental media and their high environmental toxicity. Thus, figuring out the long-term variances of their occurrence and driving force in the environment is helpful for environmental pollution control. This study investigates the concentration levels, spatial variance, and source apportionment of PAHs in suspended particulate matter of Freiberger Mulde river, Germany. Results show that the concentrations of the 16 priority PAHs suggested by USEPA (Σ16PAHs) were in the range of 707.0–17,243.0 μg kg−1 with a mean value of 5258.0 ± 2569.2 μg kg−1 from 2002 to 2016. The relatively high average concentrations of Σ16PAHs were found in the midstream and upstream stations of the given river (7297.5 and 6096.9 μg kg−1 in Halsbrucke and Hilbersdorf, respectively). In addition, the annual average concentration of Σ16PAHs showed an obvious decreasing pattern with time. Positive Matrix Factorization (PMF) receptor model identified three potential sources: coke ovens (7.6–23.0%), vehicle emissions (35.9–47.7%), and coal and wood combustion (34.5–47.3%). The source intensity variation and wavelet coherence analysis indicated that the use of clean energy played a key role in reducing PAHs pollution levels in suspended sediments. The risk assessment of ecosystem and human health suggested that the Σ16PAHs in the given area posed a non-negligible threat to aquatic organisms and humans. The data provided herein could assist the subsequent management of PAHs in the aquatic environment.

Accumulation of polycyclic aromatic hydrocarbons in the road green infrastructures of sponge city in Northwestern China: Distribution, risk assessments and microbial community impacts

The construction of “sponge city” made the belts on both roadsides be built in the form of bioretention tanks, resulting in runoff pollutants were accumulated in the bioretention tanks. To identify the pollution level and source of polycyclic aromatic hydrocarbons (PAHs) in the bioretention tanks, the soil samples were collected on the eight typical roads of the sponge city. The total contents of ∑PAHs in the bioretention tanks were 10,524–20,462 μg/kg (mean 15,029 μg/kg), and the pollution level of PAHs in the non-flood season was significantly higher than that in the flood season. The PAHs in bioretention tanks were dominated by 4-ring PAHs, with a proportion of 39.36%. The characteristic ratio method was proposed to identify the chemical source of PAHs, and the results indicated that PAHs in the bioretention tanks were mainly supplied by the combustion source and petroleum source. The ecological risk quotient (RQ) values showed that the accumulation of PAHs in the bioretention tank had certain potential ecological risks, and the RQ values of pyrene (PYR) were the highest. Incremental lifetime cancer risks (ILCR) indicated that PAHs in soil posed negligible cancer risks by inhalation way, but much stronger risks by dermal and ingestion ways. The roads with the highest and lowest PAHs content were selected for microbial ecology analysis, and the microbial abundances showed significant decreasing trends from the flood season to the non-flood season. The PAHs accumulated in the bioretention tanks had significant impacts on the microbial community, which made the microorganisms tend to PAHs-degrading bacteria.

Distribution, Composition, Sources, and Potential Ecological Risks of PAHs in the Sediments of the Lanzhou Reach of the Yellow River, China.

The distribution, composition, sources, and potential ecological risks of polycyclic aromatic hydrocarbons (PAHs) in the sediments of the Lanzhou Reach of the Yellow River, China were investigated. The total concentration of the 18 individual PAHs (∑18PAHs) in the sediments ranged from 638 to 1620ng/g, with a mean value of 901ng/g. The pollution level of PAHs in the sediments was low to moderate. Spatially, the distribution of PAHs in the sediments showed an increasing trend along the direction of water flow. ∑18PAHs predominantly consisted of low molecular weight PAHs. The principal component analysis and isomer ratios of PAHs suggested the mixed sources of petroleum and those from the combustion of petroleum, coal, and biomass. The results showed that the PAHs in the sediments of the Lanzhou Reach of the Yellow River have a low ecological risk. However, the BaP equivalent exposure values suggested a potential cancer risk.

Composition, content, source, and risk assessment of PAHs in intertidal sediment in Shilaoren Bay, Qingdao, China

Intertidal sediment samples from Shilaoren Bay, Qingdao, China, were collected to determine the concentrations and compositions of 16 polycyclic aromatic hydrocarbons (PAHs). The sources of PAHs were analyzed, and risk assessment was performed. Results show that the pollution level of PAHs in the investigated area was low. The majority of PAHs are four-ring PAHs. The PAHs in this region were mainly derived from combustion sources, including the incomplete combustion of petroleum, coal, and biomass, such as vegetation, which were affected to some extent by petroleum sources. The highest concentration of PAHs in all sampling sites was lower than that of effects range low, and the mean effects range median quotient was low. Therefore, the PAHs in the study area did not have toxic and side effects on the ecological environment, and ecological risk was low.

The occurrence and levels of polycyclic aromatic hydrocarbons (PAHs) in African environments-a systematic review.

In the African continent, several studies have been conducted to determine PAH pollution levels with their associated health risks in the environment. However, these studies are very much disconnected. The objective of this study is to conduct a systematic review that serves as a comprehensive report on the PAH-related studies conducted in the African continent. Data sources are from Google Scholar and PubMed. English language studies that reported on PAH levels in smoked fish and meat, soils and dust, aquatic environments, indoor and outdoor air, and ready-to-eat food items were selected. Specific PAHs included the following: 33 PAHs comprising ofthe 16 USEPA PAHs, non-alkylated PAHs, non-alkylated PAHs, oxygenated PAHs (OPAHs), and azaarenes (AZAs). Study appraisal and synthesis methods: The Newcastle-Ottawa Scale (NOS) was adapted to assess the quality of the selected studies basing on their sampling methods, analytical techniques, and results. A total of 121 studies were reviewed, with the majority (56) being from Nigeria. PAH levels in smoked fish and meat, soils and dust, aquatic environments, indoor and outdoor air, and ready-to-eat food items recorded total concentrations of PAHs ranging from 5 to 3585 μg/kg, BDL to 6,950,000 μg/kg, 0 to 10,469,000 μg/kg, 0 to 7.82 ± 0.85 μg/m3, and 2.5 to 7889 ± 730 μg/kg respectively. Carcinogenic risk assessment for children and adults ranged from very low to very high levels when compared to the ILCR range (10-6 to 10-4) defined by the USEPA. Out of 54 African countries, only 19 were represented. The majority of selected studies failed to apply any standard protocols for sample collection and analysis. The low to very high PAH levels reported in studies calls for effective actions on environmental health. Similar systematic reviews are expected to be performed in other continents for a global assessment of PAH pollution.

Effect of anthropogenic activities on the occurrence of polycyclic aromatic hydrocarbons in aquatic suspended particulate matter: Evidence from Rhine and Elbe Rivers

As carcinogenic and pervasive pollutants, polycyclic aromatic hydrocarbons (PAHs) in surface water are crucial to environmental policies, and the understanding of their trends and influencing factors is critical for achieving a good chemical and ecological status of water bodies. Based on long-term monitoring data from 1998 to 2017, this study systematically evaluated the spatiotemporal distribution, multimedia transport, fate, and source apportionment of PAHs adsorbed on suspended particulate matter (SPM) in Rhine and Elbe Rivers. The results of the Mann-Kendall test indicated that pollution levels of PAHs decreased from 2.81×105μg⋅s−1 to 9.80×104μg⋅s−1 on average in the Rhine and from 1.60×105 μg⋅s−1 to 5.21×104 μg⋅s−1 in the Elbe in the last 20 years. Spatially, SPM near urban areas had higher PAH mass fluxes (Rhine:3.07×105μg⋅s−1, Elbe: 1.73×105μg⋅s−1) and greater rates of decrease (slopes for Rhine and Elbe: −409, −323) than those near rural areas (Rhine:1.41×105 μg⋅s−1, Elbe: 9.35×104μg⋅s−1; slopes for Rhine and Elbe: −128, −89), indicating the significant influence of anthropogenic activities. Wavelet analysis showed that the pollution level of PAH had significant periodic oscillations for the Rhine and Elbe, and revealed several abrupt change points for the two rivers. A multimedia fugacity model demonstrated that impervious surfaces had the highest concentration (Rhine: 1.84g⋅m−3, Elbe: 0.15g⋅m−3), while soil (Rhine: 8.33×107g, Elbe: 2.53×106g) and sediments (Rhine: 4.85×106g, Elbe: 1.31×106g) had higher masses of PAHs. Furthermore, source apportionment computed using a self-organizing map and positive matrix factorization model suggested that the major sources of PAHs were vehicular emissions and coal combustion, which accounted for 51.86% of the total mass in the Rhine and 62.92% in the Elbe. The data revealed that the long-term trends of PAH variation were associated with changes in energy consumption and the implementation of vehicular emission standards. Therefore, the substitution of coal and petroleum with renewable energies could assist strategies of PAH mitigation in the environment and gradual reduction of pollution levels.

Assessment of Polycyclic Aromatic Hydrocarbons Pollution in Lake and Reservoir Sediments in Korea

Polycyclic aromatic hydrocarbons (PAHs) are pollutants that require management as they are continuously formed by natural and anthropogenic processes. We assessed PAH pollution in freshwater sediment in major lakes and reservoirs of Korea. We collected samples of surface sediment in spring 2018; these were sieved to obtain sand, silt and clay (<2 mm). We extracted dry sediment using Hexane:Acetone(1:1) and analyzed the concentration of 16 PAHs by GC-MS. Measured concentration of PAHs was compared with threshold effect concentration(TEC) and probable effect concentration (PEC), and concentration ratio of chemical species was analyzed to track source. PAH concentrations ranged from 13 ng/g-dw to 1 337 ng/g-dw, (median 123 ± 204 ng/g-dw),which are below TEC and are similar or slightly lower than those reported by previous studies. At most sites, the dominant PAH source was natural combustion such as forest fires rather than anthropogenic such as petroleum. In contrast, the site with the highest PAH concentration (1 337 ng/g-dw) in Dae-am reservoir indicated natural and anthropogenic sources. Pollution levels of PAHs in reservoirs and lakes in Korea is not of concern in general. However, some sites with PAHs from anthropogenic sources need to be monitored to investigate possible increase in PAH concentrations in future. Key Words: PAHs, Sediment, Pollution assessment, Pollution evaluation guideline, Composition ratio of 16 PAHs

Polycyclic aromatic hydrocarbons (PAHs) in water and sediment of Hoor Al-Azim wetland, Iran: a focus on source apportionment, environmental risk assessment, and sediment-water partitioning.

The concentration, source, and ecological risk of 16 polycyclic aromatic hydrocarbons (PAHs) in water and sediment samples in Hoor Al-Azim wetland, a significant freshwater wetland in Lower Mesopotamia, were evaluated. Total PAHs concentrations varied from 15.3 to 160.15ng/L, and 15.78 to 410.2μg/Kg in water and sediment, respectively. PAHs pollution levels in sediments compared with sediment quality guidelines (SQG) were found to be moderate in two stations and low in water and the rest of sediment stations. Based on the diagnostic ratio analysis, cluster analysis (CA), and principal component analysis-multiple linear regression (PCA-MLR), the mean percentage contributions were 62.62% for mixed pyrogenic and petrogenic sources (e.g., unburned and combusted fossil fuels from fishing boats and vehicle engines, incomplete combustion, oil leakage), 20.68% for auto emission, and 16.7% for pyrogenic sources (fossil fuels and biomass combustion). According to the sediment risk assessment indices such as mean effects range-median quotient (M-ERM-Q), the ecological risk of multiple PAHs was low. Risk quotient (RQ) calculation of water samples suggested high ecological risk level for Benzo[a]anthracene (BaA), and low to moderate for other individual PAHs and ΣPAHs. The result of PAHs partitioning between sediment and water phases revealed that most PAHs prefer to accumulate in sediment. Sediments probably act as a secondary source for some PAHs in the oil collection and pumping station.

Polycyclic aromatic hydrocarbons in the Yellow River estuary: Levels, sources and toxic potency assessment

This paper presents a systematic but preliminary study on the levels, sources and risk of exposure to polycyclic aromatic hydrocarbons (PAHs) in the Yellow River estuary by examining 16 priority PAHs listed by the U.S. EPA in four main environmental media (soil, surface water, groundwater and sediment). The concentration of individual PAHs in each medium in the study area was compared with the reported PAH values in China and abroad and to related environmental quality standards. The pollution levels of PAHs were found to be moderate in the soil and sediment, and low in the surface water and groundwater. Wood, coal combustion and petroleum inputs are the main PAH sources in soil and sediment, while petroleum inputs and petroleum combustion are the main PAH sources in surface water and groundwater. This indicates that PAH input caused by the high-speed inflow of external water over a long time has made a definite contribution to the occurrence of PAHs in surface water and groundwater in the study area. Furthermore, the mean value of the sum of the Excess Lifetime Cancer Risk (∑ELCR) exposure to PAHs in all media exceeded the generally acceptable risk level of 1.0E−06 recommended by the USEPA for carcinogenic chemicals, and the relative proportion contributed by DBA to the ∑ELCR was the greatest.

Polycyclic aromatic hydrocarbons and black carbon in intertidal sediments of China coastal zones: Concentration, ecological risk, source and their relationship

Polycyclic aromatic hydrocarbons (PAHs) and black carbon (BC) have attracted many attentions, especially in the coastal environments. In this study, spatiotemporal distributions of PAHs and BC, and the correlations between BC and PAHs were investigated in the intertidal sediments of China coastal zones. BC in sediments was measured through dichromate oxidation (BCCr) and thermal oxidation (BCCTO). The concentrations of BCCr in the intertidal sediments ranged between 0.61 and 6.32mgg−1, while BCCTO ranged between 0.57 and 4.76mgg−1. Spatial variations of δ13C signatures in TOC and BC were observed, varying from −21.13‰ to −24.87‰ and from −23.53‰ to −16.78‰, respectively. PAH contents of sediments ranged from 195.9 to 4610.2ngg−1 in winter and 98.2 to 2796.5ngg−1 in summer, and significantly seasonal variations were observed at most sampling sites. However, the results of potential toxicity assessment indicated low ecological risk in the intertidal sediments of China coastal zones. Greater concentrations of PAHs measured in the sediments of estuarine environments indicated that rivers runoff may have been responsible for the higher PAH pollution levels in the intertidal sediments of China coastal zones. Pearson's correlation analysis suggested that pyrogenic compounds of PAH were significantly related to BC, due to that both BC and these compounds derived mainly from the combustion process of fossil fuels and biomass. Overall, increasing energy consumptions caused by anthropogenic activities can contribute more emissions of BC as well as PAHs and thus improve the importance of BC in indicating pyrogenic compounds of PAHs in the intertidal sediments of China coastal zones.