History Of Heavy Metal Pollution Research Articles

Spatiotemporal variations of heavy metal historical accumulation records and their influencing mechanisms in the Yangtze River Estuary

Complex transformations of heavy metals in the mega-river-estuary continuum limit our understanding of their pollution history. This study investigated sedimentary compositions of heavy metals, major elements, total organic carbon, grain size, and radionuclides to study spatiotemporal variations in heavy metal accumulation patterns and their controlling mechanisms in four sediment cores (E1-E4) from the Yangtze River Estuary (YRE). Results show that only E3 in the distal YRE front mirrors well the heavy metal pollution history due to its continuous deposition in a stable sedimentary environment, while E1 and E2 record the influence of riverine and estuarine projects and processes apparently. E1 in the proximal YRE front registers intense human disturbance through sediment dredging and dumping activities to produce a thick layer of abnormal low 210Pbex and minor heavy metal concentrations. E2 in the intermediate YRE front demonstrates the recently increasing influence of reduced sediment discharge by its upcore coarsening trend with decreased heavy metal concentrations. Flood and storm events left different imprints in core sediments of E2 and E3 by their coarse stratal units with fewer heavy metal concentrations. The source analysis indicates that heavy metals in estuarine sediments mainly come from natural processes but are significantly affected by human activities. A direct linkage of the heavy metal accumulation history with the socioeconomic development in recent decades is found by a comparison study of core data from the tidal river to the estuary, albeit with a remarkable spatiotemporal difference, which is jointly determined by grain size, offshore distance, hydrodynamic condition, depositional status, and sedimentation rate besides estuarine processes. This warns us to carefully interpret the heavy metal history from single or sparse core data in a mega estuary system with intense natural forces and human disturbances analogous to the YRE.

A 600 years sediment record of heavy metal pollution history in the Danube Delta

Heavy metal pollution in the Danube Delta (in sediments, water and living organisms) has recently received increasing attention due to its impact on ecosystems health and water quality. However, long term records of heavy metal contamination are not available to date. In this study radiometric dating and geochemical analyses for major elements (Al, Fe, Ca and S) and metals (Cu, Zn, Pb, Ni, Cr and Cd) were performed on the top 4 m of a 9-m sediment core retrieved from the alluvial plain of Sulina distributary channel aiming to reconstruct the heavy metal geological background and contamination history and discuss the possible origins (natural vs. anthropogenic) of metals and the main factors driving their temporal variation. Chronological analysis revealed that the top 4 m of the core span the last ~600 years. Three distinct sediment units (U1: 400–200, U2: 200–140, U3: 140–15) were identified based on the downcore element concentration variation. The lower unit (400–200 cm, ~1450–1700 CE) shows an upward increase of Cu, Zn, Pb, Ni, Cr and Cd metal contents, which are strongly correlated with Al. Enrichment factor (EF) analysis indicates that metals detected in this unit are derived primarily from natural sources. In contrast, metals show elevated EF values within the middle (200–140 cm, ~1700–1770 CE) and upper unit (140–15 cm, ~1770 CE to present). The highest degrees of enrichment of Cu, Zn and Cd occur in the peat layer of the middle unit (U2) which displays higher organic carbon and sulfur contents, indicating that diagenetic enrichment of detected metals occurs under reducing condition. Overall, sediment contamination is moderate while the level increases with time. This study provides new insights into the metal contamination history of deltaic environments and yields baseline values for heavy metal contents in pristine sediments deposited prior to the onset of anthropogenic impact.

Attention deficit among preschool and school-aged children living near former metal-processing plants in Romania

Industrial areas affected by high and long-term heavy metal pollution have a great impact on health of the resident population. Children represent a group at high-risk with an increased susceptibility to chronic heavy metal intoxication.Our work included the assessment of attention particularities through a case-control study in pre-school and school-aged children (4–6 years and 8–11 years) from two study areas, Copşa Mică and Zlatna, compared to a non-polluted locality with no history of heavy metal pollution. Copşa Mică and Zlatna are two of the most polluted heavy metals regions in Romania due to non-ferrous metallurgy for a long period of time. Recruitment of participants was made by a random selection of an entire class for each age within the schools and kindergartens from the study areas (Copşa Mică and Zlatna) and from the non-polluted region. Interpretation of data was performed using statistical analysis (ANOVA and Student's t-test). Preschool children (4–6 years) were tested using Wechsler Preschool and Primary Scale of Intelligence (WPPSI) tests, Animal House and labyrinth samples. The results of the attention tests applied to pre-school children were lower in the study areas compared to the control group, but no statistical differences were found. The results of the attention tests applied to children aged between 8 and 11 years (Toulouse-Pieron test and Traffic light test) indicate lower average scores within the study groups from polluted areas, compared to the control group. Differences with statistically significance were registered for the 8 years age group (p = 0.037).In these areas efficient strategies and precise intervention measures are needed in order to limit or remove the heavy metal exposure and protect the human health, especially the groups exposed to a high level of risk.

Ecological Risk Assessment and Contamination History of Heavy Metals in the Sediments of Chagan Lake, Northeast China

The study deals with the spatio-temporal distribution of heavy metals in the sediments of Chagan lake, Northeast China. The pollution history of heavy metals is studied simultaneously through the 210Pb dating method by analyzing the characteristic of As, Hg, Cd, Cr, Ni, Cu, Pb, and Zn concentration-depth profiles. The potential ecological risk index (RI) and geo-accumulation index (Igeo) were used to evaluate the contamination degree. Principal component analysis (PCA), based on the logarithmic transformation and isometric log-ratio (ilr) transformed data, was applied with the aim of identifying the sources of heavy metals. The element concentrations show that the heavy metals are enriched in the surface sediment and sediment core with a varying degree, which is higher in the surficial residue. The results of Igeo indicate that the Cd and Hg in the surface sediment have reached a slightly contaminated level while other elements, uncontaminated. The results of RI show that the study area can be classified as an area with moderate ecological risk in which Cd and Hg mostly contribute to the overall risk. For the sediment core, the 210Pb dating results accurately reflect the sedimentary history over 153 years. From two evaluation indices (RI and Igeo) calculated by element concentration, there is no contamination, and the potential ecological risk is low during this period. The comparative study between raw and ilr transformed data shows that the closure effect of the raw data can be eliminated by ilr transformation. After that, the components obtained by robust principal component analysis (RPCA) are more representative than those obtained by PCA, both based on ilr transformed dataset, after eliminating the influence of outliers. Based on ilr transformed data with RPCA, three primary sources could be inferred: Cr, Ni, As, Zn, and Cu are mainly derived from natural sources; the main source of Cd and Hg are associated with agricultural activities and energy development; as for Pb, it originated from traffic and coal-burning activities, which is consistent with the fact that the development of tourism, fishery, and agriculture industries has led to the continuous increasing levels of anthropogenic Pb in Chagan Lake. The summarized results and conclusions will undoubtedly enhance the governmental awareness of heavy metal pollution and facilitate appropriate pollution control measures in Chagan Lake.

Baseline radionuclide and heavy metal concentrations in sediments of Sabaki River estuary (Kenya, Indian Ocean)

Baseline study of natural (7Be, 210Pb, 226Ra, 234Th, 228Ra, 40K) and anthropogenic (137Cs) radionuclides was carried out in two cores collected from Sabaki River estuary (Kenya, Indian Ocean). There was no exponential decrease of excess 210Pb down the cores, which did not allow dating and determination of heavy metal pollution history. The use of 137Cs as a time marker was not possible due to its low fallout rates in East Africa. The short-lived radioisotope 7Be, a tracer of river floods, confirmed 2018 flood in Sabaki River estuary. Heavy metal concentration in the two cores showed nonsystematic trends with depth. Only Pb concentration in Sabaki River estuary was higher than the background levels. Application of the “Environmental Risk from Ionising Contaminants Assessment and management” (ERICA) tool confirmed that the potential dose rates to biota from the sediment radioactivity concentrations are unlikely to pose appreciable ecological risks.

Recent history of metal contamination in the Fangcheng Bay (Beibu Gulf, South China) utilizing spatially-distributed sediment cores: Responding to local urbanization and industrialization

In this study, the recent history of heavy metal pollution in the Fangcheng Bay (South China) was reconstructed utilizing three 210Pb-dated sediment cores. The metal concentration profiles display three trends since the 1970s and clearly reflect local urbanization and industrialization. The metals in the Fangcheng Bay started to accumulate in the 1970s but remained relatively low until the 1990s which corresponds to the slow urbanization and industrialization. The metal accumulation in the eastern Fangcheng Bay peaked in the early 2000s following the steep increases in accordance with the rapid industrialization of the eastern Fangcheng Bay where the core HSL was collected. Conversely, the heavy metal profiles in the western Fangcheng Bay present slight step increases in the early 2000s followed by a dramatic metal enrichment in the late 2000s; the expansion of these two cores, which begins in the early 2000s, concurs well with the rapid local urbanization and industrialization.

Modern modes of sediment distribution and the anthropogenic heavy metal pollution record in northeastern Beibu Gulf, south China sea.

During the expedition 908 survey in 2007, 539 seafloor surface sediment samples and two cores were collected over a narrow sector of the northeastern Beibu Gulf, South China Sea. Currently, three dynamic sedimentological processes prevail in the study area: circulation-controlled sand deposition, mud deposition under weak sediment dynamics, and fluvial input. Core A233 from the circulation-controlled sand area, with a 60 cm mixed layer, provides evidence of dynamics disturbance since the mid-Holocene. To reconstruct the anthropogenic heavy metal pollution history, we selected core A146 from the stable mud sector influenced by fluvial input. The dating of core A146 was based on 210Pb activity analysis, showing an ~90-year historical record in the upper 40 cm. The heavy metal contamination results showed a generally low pollution level. Nonetheless, increased pollution has happened since the 1950s, especially after 1978 A.D., corresponding to the beginning of China's reform and opening up.

Geochronology and sources of heavy metal pollution in sediments of Istanbul Strait (Bosporus) outlet area, SW Black Sea, Turkey

Geochemical and sedimentological analyses and radionuclide (210Pb and 137Cs) dating of three cores from the Bosporus outlet area of the Black Sea, north of Istanbul, were conducted to assess the sources and history of heavy metal pollution. The sedimentary succession in the shelf core KD12-01 consists mainly of clay (49–80%) and silt (15–41%). Radionuclide dating of the core indicates that it consists of old sediments that are uncontaminated with heavy metals. In contrast, cores KD12-04 and KD12-07 recovered from −350 m and −304 mm in the upper slope area represent sediments consisting of silt and clay that were deposited since at least the last 120 years and 60 years, respectively. The latter core contains two mass-flow units represented by relatively old sedimentary material according to the low 210Pb activity and relatively low heavy metal contents. The upper 40 and 48 cm of cores KD 12-04 and KD 12-07 represent sediments deposited since 1970s and 1980s that are significantly polluted with Cu, Ni, Zn, Mo, Pb and Cr, Cu, Co, Ni, Mo, Pb, Zn, respectively. However, high Pb and Cr concentrations with high TOC contents date back to early part of the 20th century in core KD 12-04. The geochemical data, together with the high 137Cs concentrations of the contaminated sediments, strongly suggest that the pollution is mainly delivered to the western and north western Black Sea by the large European rivers, from there transported to the study area by the rim current, and deposited in the sediments under anoxic conditions.

Heavy metal distribution in Tiaoxi River's sediment.

According to current study, seven surface sediments and three sediment cores were collected from three typical areas of Tiaoxi River, which were living area, agricultural area, and industrial area. The water quantity into the Lake Taihu from the Tiaoxi River accounted for almost one third of the total water quantity by all rivers into the Lake Taihu. To study geochemical features and pollution history of heavy metals in three typical areas of Tiaoxi River, total content and chemical fractionations of Cu, Pb, Cd, Cr, Mn, Zn, Fe, As, and Hg were analyzed for surface and core sediments using the speciation extraction procedure, proposed by the Commission of the European Communities Bureau of Reference (BCR), together with grain size and organic carbon measurements. The results showed that the concentration of nine heavy metals and the variation characteristics of Zn, Cu, Fe, Mn, and Cr are different among five cores, which has shown that the river responses to natural and anthropogenic activities were dissimilar in various areas. BCR sequential extraction showed contents of Cr, Fe, and Cu were dominated in the remaining parts. Non-residual fractions for Zn and Mn contained major portions. Based on RAC (risk assessment core), the risk of Mn was high to very high in the three typical areas, and the risk of Zn was medium in the three typical areas.

Long-Term and Ontogenetic Patterns of Heavy Metal Contamination in Lake Baikal Seals (Pusa sibirica).

Little is known about the history of heavy metal pollution of Russia's Lake Baikal, one of the world's largest lakes and a home to numerous endemic species, including the Baikal Seal, Pusa sibirica. We investigated the history of heavy metal (V, Cu, Zn, Cd, Hg, Tl, Pb, U) pollution in Lake Baikal seals over the past 8 decades. C and N stable isotope analysis (SIA) and laser-ablation ICP-MS of seal teeth were used to examine changes in feeding ecology, heavy metal levels associated with life history events and long-term variation in metal exposure. SIA did not suggest large changes in the feeding ecology of Baikal seals over the past 80 years. LA-ICP-MS analyses revealed element-specific ontogenetic variability in metal concentrations, likely related to maternal transfer, changes in food sources and starvation. Hg and Cd levels in seals varied significantly across the time series, with concentrations peaking in the 1960s - 1970s but then declining to contemporary levels similar to those observed in the 1930s and 1940s. Trends in atmospheric emissions of Hg suggest that local sources as well as emissions from eastern Russia and Europe may be important contributors of Hg to Lake Baikal and that, despite the size of Lake Baikal, its food web appears to respond rapidly to changing inputs of contaminants.

Long-term variations in sediment heavy metals of a reservoir with changing trophic states: Implications for the impact of climate change

Two dated sediment cores from the Miyun Reservoir of Beijing in China were analyzed to reconstruct the pollution history of heavy metals including cadmium (Cd), chromium (Cr), iron (Fe), nickel (Ni), and zinc (Zn) as well as phosphorus (P). Enrichment factor (EF) and geoaccumulation index (Igeo) were applied to assess the enrichment status of heavy metals. Average EF and Igeo values indicated that the studied heavy metals in the sediments mainly originated from non-point source pollution and soil-water erosion, showing low ecological risks. In addition, correlation analysis and principal component analysis (PCA) identified that Cd, Zn, and P were mainly from agricultural diffusion pollution caused by utilization of the phosphate fertilizer; Zn, Ni, and Cr originated from soil erosion. PCA analysis was further conducted to investigate the relationships among meteorological factors, algae-dominant total organic carbon (TOC), and heavy metals. Results showed that algae-dominant TOC had strong positive correlation with temperature, which can be explained by that increased temperature accelerated the growth of algae. Meanwhile the opposite loadings between algae-dominant TOC and heavy metal suggested that primary production played an important role in migration and transformation of metals. Moreover, stepwise multiple regression models showed that Fe was sensitive to temperature, which accounted for approximately 39.0% and 40.1% of the variations in Fe of two sediment cores, respectively. Fe showed significant decreasing trends during the past 50years. Reductive environment of water-sediment interface caused by increasing temperature probably contributed to the restoration of ferric iron, resulting in the release of soluble Fe to overlying waters. Future climate change with elevated temperature and extreme weather events will aggravate the ecological risk of heavy metals in water environment due to the enhanced leaching effect and non-point source pollution as well as the release of heavy metals from sediments to water environment.

Ecological risk and contamination history of heavy metals in the Andong tidal flat, Hangzhou Bay, China

ABSTRACTIn this study, we collected two sediment cores (C1 and C2) from the Andong tidal flat, Hangzhou Bay, and studied the temporal variations of heavy metals in the cores. Vertical distributions of heavy metals were almost unchanged in both the cores before 2000. After 2000, however, the heavy metal concentrations increased dramatically, suggesting that the sediments have been affected by enhanced human pollution in the recent decade. In the core C1, the sediments were severely polluted by Pb, moderately to considerably polluted by Cr and Zn, and low to moderately polluted by other heavy metals. The core C2 was relatively unpolluted before 2000 and low to moderately polluted after 2000. Multi-statistical analyses indicated that the core C1 was additionally contaminated by local human activities such as wastewater discharge and the Hangzhou Bay Bridge. The heavy metals in the core C2, however, were largely contributed by the Yangtze River and controlled by sedimentation process. The calculated sedimentary flux (4–8 g m−2 a−1) of heavy metals generally increased with time. It was closely related to the wastewater discharge in adjacent areas. This study reconstructed the local heavy metal pollution history and provides important information for environmental protection and policy making.

Copper pollution decreases the resistance of soil microbial community to subsequent dry–rewetting disturbance

Dry–rewetting (DW) disturbance frequently occurs in soils due to rainfall and irrigation, and the frequency of DW cycles might exert significant influences on soil microbial communities and their mediated functions. However, how microorganisms respond to DW alternations in soils with a history of heavy metal pollution remains largely unknown. Here, soil laboratory microcosms were constructed to explore the impacts of ten DW cycles on the soil microbial communities in two contrasting soils (fluvo-aquic soil and red soil) under three copper concentrations (zero, medium and high). Results showed that the fluctuations of substrate induced respiration (SIR) decreased with repeated cycles of DW alternation. Furthermore, the resistance values of substrate induced respiration (RS-SIR) were highest in non-copper-stressed (zero) soils. Structural equation model (SEM) analysis ascertained that the shifts of bacterial communities determined the changes of RS-SIR in both soils. The rate of bacterial community variance was significantly lower in non-copper-stressed soil compared to the other two copper-stressed (medium and high) soils, which might lead to the higher RS-SIR in the fluvo-aquic soil. As for the red soil, the substantial increase of the dominant group WPS-2 after DW disturbance might result in the low RS-SIR in the high copper-stressed soil. Moreover, in both soils, the bacterial diversity was highest in non-copper-stressed soils. Our results revealed that initial copper stress could decrease the resistance of soil microbial community structure and function to subsequent DW disturbance.

Distribution and Risk Assessment of Heavy Metals in Surface Water from Pristine Environments and Major Mining Areas in Ghana.

Ghana, like many countries in Africa, has a history of heavy metal pollution largely emanating from industrial effluent discharges and anthropogenic deposits on prevailing winds of pollutants from industrial activities. One of the biggest contributors to pollution in the Ghanaian environment is mineral mining. The aim of this study was to determine the distribution and health risks of heavy metals in surface water from both pristine environments and major mining areas in Ghana. A total of 32 composite samples were collected between September and October, 2014 to assess concentrations of heavy metals and pollution levels, as well as cancer and non-cancer risks to human health from exposure to heavy metals from four major mining regions and four rain forest reserves in the Western, Ashanti, Brong Ahafo and Eastern regions of Ghana. Samples were analyzed using atomic absorption spectrometry. The mean concentrations (mg/L) of heavy metals at the pristine sites ranged from 1.747 for iron (Fe) to 0.001 for mercury (Hg) and 0.453 for Fe to 0.002 for Hg at the mining sites. All the metals were found to be below World Health Organization (WHO) and United States Environmental Protection Agency (USEPA) recommended limits except for Hg, which was at the USEPA guideline limit. However, the concentrations of the metals from the mining sites were found to be slightly higher than those from the pristine sites. The concentrations of heavy metals in the Nyam, Subri, Bonsa and Birim Rivers from the mining sites and the Atiwa Range, Oda, Ankasa and Bosomkese Rivers from the pristine sites were found to be either below or within the USEPA and WHO's recommended limits for surface water. The health risk assessment values for the hazard quotient for ingestion of water (HQing), dermal contact (HQderm) and chronic daily intake (CDI) indicated no adverse effects as a result of ingestion or dermal contact from the rivers. However, arsenic (As) in both the pristine and mining sites and chromium (Cr) in the pristine sites pose a carcinogenic threat to the local residents.

Three centuries of heavy metal pollution in Paris (France) recorded by urban speleothems

The first record of urban speleothems used to reconstruct the history of heavy metal pollution of shallow groundwaters is presented. Two speleothems grew during the last 300years in an underground aqueduct in the north-eastern part of Paris. They display high Pb, Mn V, Cu, Cd and Al concentrations since 1900 due to the urbanization of the site which triggered anthropogenic contamination of the water feeding the speleothems. Surprisingly, these heavy metal concentrations are also high in the oldest part. This early pollution could come from the use of Parisian waste as fertilizers in the orchards and vineyards cultivated above the aqueduct before urbanization. Lead isotopes were measured in these carbonates as well as in lead artifacts from the 17th–18th centuries (206Pb/207Pb=1.180+/−0.003). The mean 206Pb/207Pb ratio, for one of the speleothems is 1.181+/−0.003 unvarying with time. These lead signatures are close to those of coal and old lead from northern European mines, lower than the natural background signature. It confirms that the high metal concentrations found come from anthropogenic pollution. Conversely, the lead isotopic composition of the second speleothem presents two temporal trends: for the oldest levels, the mean value (1.183+/−0.003) is similar to the first speleothem. For the youngest part, a lower value (1.172+/−0.005) is recorded, evidencing the contribution of a new lead source at the beginning of the industrial revolution. Pb isotopes were also measured in recent samples from a nearby superficial site. The first sample is a recent (AD 1975+/−15years) deposit (206Pb/207Pb=1.148+/−0.003), and the second, a thin subactual layer (206Pb/207Pb=1.181+/−0.002). These data are compatible with the adding of anthropogenic sources (leaded gasoline and industrial lead from Rio Tinto ore).

Ecological risk and pollution history of heavy metals in Nansha mangrove, South China

Owing to the Industrial Revolution in the late 1970s, heavy metal pollution has been regarded as a serious threat to mangrove ecosystems in the region of the Pearl River Estuary, potentially affecting human health. The present study attempted to characterize the ecological risk of heavy metals (Cd, Cr, Cu, Mn, Ni, Pb and Zn) in Nansha mangrove, South China, by estimating their concentrations in the surface sediment. In addition, the pollution history of heavy metals was examined by determining the concentrations of heavy metals along the depth gradient. The phytoremediation potential of heavy metals by the dominant plants in Nansha mangrove, namely Sonneratia apetala and Cyperus malaccensis, was also studied. Results found that the surface sediment was severely contaminated with heavy metals, probably due to the discharge of industrial sewage into the Pearl River Estuary. Spatial variation of heavy metals was generally unobvious. The ecological risk of heavy metals was very high, largely due to Cd contamination. All heavy metals, except Mn, decreased with depth, indicating that heavy metal pollution has been deteriorating since 1979. Worse still, the dominant plants in Nansha mangrove had limited capability to remove the heavy metals from sediment. Therefore, we propose that immediate actions, such as regulation of discharge standards of industrial sewage, should be taken by the authorities concerned to mitigate the ecological risk posed by heavy metals.

Assessment of potential risks associated with heavy metal contamination in sediment in Aobaopao Lake, China, determined from sediment cores

Lianhuan Lake is found in the lowest point of the Songnen Plain in Eastern China and is a typical hardwater lake. Lianhuan Lake is constituted by eighteen lakes and Aobaopao Lake is located in the eastern portion. Geochemical features and pollution history of heavy metals in Aobaopao Lake were investigated. Total metal contents and chemical fractionations of Cu, Fe, Mn, Ni, Pb, Cd, Cr and Zn were analyzed for core sediment samples taken from north sampling site for Core AB1 and south sampling site for Core AB2 of the lake using the speciation extraction procedure proposed by the Commission of the European Communities Bureau of Reference (BCR) together with grain size and TOC measurements. Heavy metal analyses showed that sediments have similar geochemical features. In order to quantify the anthropogenic contamination of the metals according to their speciation composition, the RSP approach was applied. In Core AB1, Cd is moderate and significant contaminate while Mn is minor, moderate and significant contamination. In Core AB2, Cd is more significant contaminate from 3.75 cm to the surface. The risk assessment code (RAC) established by Perin et al. (Heavy Metals in the Environment, CEP Consultants, Edinburgh, 1985) was used to evaluate the risk of heavy metals in sediments of Aobaopao Lake. The results for both cores suggest that Mn and Cd posed a high risk to local environment.

A magnetic record of heavy metal pollution in the Yangtze River subaqueous delta

The rapid industrial development in the Yangtze River watershed over the last several decades has drawn great attention with respect to heavy metal pollution to the Yangtze River estuary and nearby coastal areas. In this study, a 236cm long sediment core was retrieved from the Yangtze River subaqueous delta (122°36′ E, 31°00′ N) in 2008 and analyzed for magnetic properties and geochemical compositions to investigate heavy metal pollution history. The activity of 137Cs peaked at depth 140cm, with a broad plateau between 120cm and 140cm, suggesting an average sedimentation rate of 3.11cmyr−1 for the upper 140cm layer. Magnetic susceptibility (χ), saturation isothermal remanent magnetization (SIRM), anhysteretic remanent magnetization (χARM) and heavy metal enrichment factors (EF) all showed an upward increase trend above depth 140cm, suggesting that increased ferrimagnetic mineral concentration was accompanied by heavy metal enrichment in the sediment. Geochemical and granolumetric analyses showed that sediment sources and particle sizes played minor roles in the variations of magnetic properties. The effect of diagenesis, which can lead to the selective removal of magnetic minerals, was noticeable in the lower part of the core (140–236cm). Co-variation between magnetic properties (χ, SIRM and χARM) and EF of Cu and Pb suggests that the elevated ferrimagnetic mineral concentration can be used as an indicator of heavy metal pollution in the reconstruction of environmental changes in estuarine and coastal settings.

Reconstructing the History of Heavy Metal Pollution by Tree-Ring

This article is based on gold-mine. Analyzing the correlation of heavy metal content between tree rings and soil. Through the distribution of heavy metal content in the trees inverse the process of heavy metal pollution in soil. Discussing the time distribution of heavy metal pollution.

Population specific fitness response of Drosophila subobscura to lead pollution

Differences in heavy metal tolerance among separate populations of the same species have often been interpreted as local adaptation. Persistence of differences after removing the stressor indicates that mechanisms responsible for the increased tolerance were genetically determined. Drosophila subobscura Collin (Diptera: Drosophilidae) populations were sampled from two localities with different history of heavy metal pollution, and reared for eight generations in the laboratory on a standard medium and on media with different concentrations of lead (Pb). To determine whether flies from different natural populations exposed to the Pb-contaminated media in the laboratory show population specific variability in fitness components over generations, experimental groups with different concentrations of lead were assayed in three generations (F2 , F5 , and F8 ) for fecundity, developmental time, and egg-to-adult viability. On the contaminated medium, fecundity was reduced in later generations and viability was increased, irrespective of the environmental origin of populations. For both populations, developmental time showed a tendency of slowing down on media with lead. Faster development was observed in later generations. Preadaptation to contamination, meaning higher fecundity, higher viability, and faster egg to adult development in all studied generations, was found in D. subobscura originating from the locality with a higher level of heavy metal pollution.