Polished Samples Research Articles

Low‐temperature bubble formation in silica glass

AbstractPhase separation was observed in silica glass following low‐temperature heat treatment in high water vapor pressure through the formation of bubbles. Although the 6 day diffusion treatment in saturated water vapor pressure at 250°C does not normally cause phase separation, the reactive fracture surface and subsurface damage caused by polishing with cerium oxide (CeO2) allowed for an increase in water absorption during treatment and heterogeneous nucleation of the bubbles at damaged sites. The sub‐surface damage, characteristic of blunt contact damage, was only revealed when the polished sample was etched. The formation of bubbles and polishing damage were observed in two silica glasses—one containing chlorine impurities and the other containing OH impurities. Raman spectra collected after fracture or polishing and water diffusion treatment demonstrated an increase in the abundance of –OH species including silanol (SiOH) groups and an evolution in the glass structure in the bubble regions compared with the bubble‐free regions. These results indicate an increase in the reactivity between water and glass fracture surfaces relative to the bulk.

Experimental study of the surface finishing of CNC magnetic abrasive finishing based on ANN

ABSTRACT CNC Magnetic Abrasive Finishing (CNC MAF) is famous for aluminium sheet processing. This study used an artificial neural network (ANN) analytical model with a Bayesian regularisation algorithm (BR) to examine how machine parameters (rotation speed, feed rate, depth of cut, and several passes) affect surface roughness during CNC MAF of aluminium sheet. Experimental and quantitative data proved its prediction ability. ANN model to select the best machine parameters for low surface roughness. The perfect numerical solution was experimentally tested, and surface morphology and roughness were used to evaluate processing quality under optimal machine parameters. The ANN model is also compared to Taguchi L16 for prediction and optimisation. Compared to ANN, prediction and optimal surface finishing mean absolute error are 96% lower. The results show that the ANN model is better at studying machine configuration during CNC MAF of Al sheet. SEM and 3D Optical profilometer were also used to analyze the Al sheet. The UV-VIS Spectrophotometer measures Al polished sample reflectance at 200–700 nm.

The Spiritual Well-Being Scale in the Polish Catholic Setting: Construct, Structure, and Relationships with Psychological Well-Being.

The population of Poland could be of particular interest to researchers studying religion and spirituality. Catholicism has played a significant role in shaping the country's culture, history, and tradition and is considered a national religion. More recently, however, the processes of moving away from regular participation in religious services and loosening ties with the institution of the Catholic Church are marked (Polish Public Opinion Research Center, CBOS). The Polish Catholic setting may modify the associations between psychological variables that have been studied in their relationships with spirituality, which have been investigated in religious contexts differing from a PolishCatholic one. Given this context, we examined the internal structure of spiritual well-being in the sample of present-dayPolishCatholics (Study 1) and how spiritual well-being is related to mental health (Study 2). The internal structure of the Spiritual Well-Being Scale was replicated in the Polish sample, but only positively worded items loaded on the Religious and Existential Well-Being subscales. Spiritual well-being was positively related to positive mood, satisfaction with life, and psychological well-being; it wasnegatively associated with negative mood, depression, and anxiety, thus remaining significantly related to psychological well-being among Polish Catholics.

Evaluating metal levels and potential health risks of nail polish brands on the Ghanaian market

ABSTRACT Research has shown possible existence of heavy metals in cosmetic products, as they are known to impact colour. Assessments have been carried out on selected brands of nail polishes on Ghanaian markets in the Ashanti Region, for levels of six metals, i.e., lead (Pb), cadmium (Cd), aluminium (Al), chromium (Cr), manganese (Mn), and copper (Cu). A total of twenty (20) nail polish samples were analysed using the Atomic Absorption Spectrophotometer model nova 400P. The highest concentrations determined were Al (77.50 mg/L), Cu (2.126 mg/L), and Cr (25.66 mg/L). The levels of Pb, Cd, and Mn were all below detection limit. All samples analysed were below the WHO permissible limits, making them safe for use. Health risks associated with intake of these metals via dermal route, inhalation, and ingestion are evaluated, Hazard Quotient (HQ) and Hazard Index (HI) are below unity, suggesting no potential health risks associated with their use.

Characterization of identical lithium-ion battery electrodes before and after charge/discharge cycles via in-plane large-area polishing

As an effective method to fabricate a large-area cross-sectional sample for lithium-ion battery electrodes, we perform in-plane polishing of LiNi0.8Co0.15Al0.05O2(NCA) cathode samples and obtain a large cross-sectional area with a diameter of 1.5 mm. The polished cross-sections of NCA cathode particles are sufficiently flat to perform the atomic force microscopy (AFM) measurements on each cathode particle. Following AFM-based Kelvin probe force microscopy and scanning spreading resistance microscopy measurements, an identical in-plane polished NCA sample is assembled into a coin cell for the charge and discharge processes. After 90 charge/discharge cycles, the in-plane-polished sample is successfully disassembled from the coin cell without causing critical damage. In addition, a microcrack structure, which is a typical degradation feature of the cycles of NCA particles, is observed for the identical in-plane polished NCA sample. This indicates that the in-plane polishing method is effective for investigating identical NCA electrode samples before and after the charge/discharge process. Furthermore, the in-plane polishing method can be successfully applied to the large-area polishing of a Si-based anode which is a mixture of Si carbon complexes and graphite particles. This study presents a novel methodology for analyzing the degradation of lithium-ion battery electrode materials.

Psychometric properties of the generalized anxiety disorder questionnaire (GAD-7) in a polish postpartum women sample

ObjectiveGeneralized Anxiety Disorder is an international mental health problem. Prevalence for anxiety disorders reported in perinatal period is high and related with adverse parental and child outcomes. Thus, the objective of this study was to investigate the psychometric properties and factorial validity of General Anxiety Disorder-7 questionnaire (GAD-7) in the context of postpartum mothers.MethodsIn this cross-sectional study, 278 mothers (mean age 31.09; SD = 4.42) were recruited at the Neonatology, Gynecology, and Obstetrics Ward. Generalized Anxiety Disorder was assessed with GAD-7, stress with Parental Stress Scale (PSS), while risk of depression with Edinburgh Postpartum Depression Scale (EPDS). Confirmatory factor analysis (CFA) was used to verify factor structure of GAD-7 and the internal consistency was evaluated using reliability coefficients: Cronbach’s Alpha and McDonald’s Omega.ResultsThe internal consistency of the GAD-7 was high (Cronbach’s Alpha = 0.90 and MacDonald’s Omega = 0.91). GAD-7 had significant correlations with the variables examined for construct validity, stress (PSS; r = 0.35, p < 0.01) and risk of depression (EPDS; r = 0.76, p < 0.01). The Confirmatory Factor Analysis results supported a good fit of the data to the model: χ²(df) = 14.19 (14), p = 0.44; Comparative Fit Index (CFI) = 0.99; Tucker-Lewis Index (TLI) = 0.99; Root Mean Square Error of Approximation (RMSEA) = 0.007 (90% C.I. 0.000; 0.059).ConclusionGAD-7 has satisfactory psychometric properties. GAD-7 had significant correlations with the variables examined for construct validity with PSS and EPDS. GAD-7 is a reliable instrument for screening anxiety symptoms in perinatal period in research and clinical setting.

Features of cavitation wear of chrome electrolytic coatings

Cavitation wear is a pervasive phenomenon on water transport. The parts of ship propulsion system as well as the water-cooled surface of cylinder liners of high-speed ship diesels are subjected to cavitation attack. Bright chromium deposits are used to protect the water-cooled surface of liners. Nevertheless, the effect of cracks appearing in the electrolytic chrome coating upon depositing on the cavitation resistance of coating is still an open relevant problem. The goal of the study is to analyze the kinetics and mechanism of the destruction of the bright chrome electrolytic deposit under cavitation attack. The cavitation resistance of chrome electrolytic coatings after grinding and after polishing was studied. The chrome electrolytic coatings were obtained on the plates (90 × 30 × 7 mm in size) made of cast iron SCh21. The chrome was deposited on one side (90 × 30 mm) of the plate placed vertically by flow anodic jet chrome plating in standard electrolyte (kg/m3): chrome anhydride — 250; sulfuric acid — 2.5; trivalent chrome — no more than 5; trivalent iron ions — no more than 10. The electrolyte was prepared using distilled water of a single distillation. The parameters of depositing: electrolyte temperature is 50°C; the current density amounts to 60 A/dm2. Four samples cut from the same plate were used. The coatings on the first two samples were ground using the abrasive paper number 320. The coatings on the second pair of samples were first ground successively on the abrasive paper of different grit: 320, 500, 800, 1000, and 1200, and then polished on the cloth with GOI paste. The cavitation wear tests were carried out on a magnetostrictive vibratory rig in fresh water, the frequency and amplitude of the rig horn vibration was equal to 22 kHz and 28 μm, respectively. The spacing between the chrome-plated sample surface and the horn butt was 0.5 mm. The wear of the samples was evaluated by periodical weighing during testing. The wear of the ground samples turned to be significantly higher, than that of polished samples. The photographs of the surface after different duration of the cavitation attack show that the initial cracks formed on the coating during chrome plating are the centers of cavitation destruction. To reduce the negative impact of initial cracks on the cavitation resistance of the bright chrome electrolytic coatings deposited on the water-cooled surface of the cylinder liners of diesels it is shown expedient to include polishing in the technological process of depositing chrome coatings.

The image of sexual expression of female patients suffering from mood disorders: the questionnaire study on Polish clinical sample.

Aim of the studyMood disorders are significantly connected with sexual functioning impairment among women. The aim of this study was to assess and describe specifics of sexual expression and its dysfunc-tion in groups of women diagnosed with bipolar disorders (F31), major depressive disorder (F32 and F33) and persistent mood disorders (F34).Subject or material and methodsThe sample comprised 129 female patients aged 19-65. Subjects were recruited in the Polish psy-chiatry hospital wards. Patients were interviewed using the sexological questionnaire Mell-Krat (Kromierzyńska’s version) for women (SFK/K) for clinical assessment of patients' mood Mont-gomery–Åsberg Depression Rating Scale (MADRS), and Young Mania Rating Scale (YMRS) were used. Alcohol Use Disorder Identification Test (AUDIT) was also used to control alcohol addiction's influence on sexual functions.ResultsThe mean final score in SFK/K for the whole sample was 35.3 points (SD=15.65), clearly below the cut-off point for the average level of sexual reaction for the Polish population. More than 88.4% of patients achieved scores lower than optimal.DiscussionThe prevalence of sexual dysfunctions among women suffering from mood disorders is in-creased. However, the image of the sexual expression of those patients is not homogenous.ConclusionsThe paper put light on the sexual functioning of women with mood disorders. However, further research using more specific methods and bigger samples is needed.

Applying UHPLC-HRAM MS/MS Method to Assess Host Cell Protein Clearance during the Purification Process Development of Therapeutic mAbs.

Host cell proteins (HCPs) are one of the process-related impurities that need to be well characterized and controlled throughout biomanufacturing processes to assure the quality, safety, and efficacy of monoclonal antibodies (mAbs) and other protein-based biopharmaceuticals. Although ELISA remains the gold standard method for quantification of total HCPs, it lacks the specificity and coverage to identify and quantify individual HCPs. As a complementary method to ELISA, the LC-MS/MS method has emerged as a powerful tool to identify and profile individual HCPs during the downstream purification process. In this study, we developed a sensitive, robust, and reproducible analytical flow ultra-high-pressure LC (UHPLC)-high-resolution accurate mass (HRAM) data-dependent MS/MS method for HCP identification and monitoring using an Orbitrap Ascend BioPharma Tribrid mass spectrometer. As a case study, the developed method was applied to an in-house trastuzumab product to assess HCP clearance efficiency of the newly introduced POROS™ Caprylate Mixed-Mode Cation Exchange Chromatography resin (POROS Caprylate mixed-mode resin) by monitoring individual HCP changes between the trastuzumab sample collected from the Protein A pool (purified by Protein A chromatography) and polish pool (purified by Protein A first and then further purified by POROS Caprylate mixed-mode resin). The new method successfully identified the total number of individual HCPs in both samples and quantified the abundance changes in the remaining HCPs in the polish purification sample.

Investigating the Ochratoxin Production Potential of Aspergillus spp in Indian Rice: A Comprehensive Study

Rice (Oryza sativa), world’s second most important cereal crop and most commonly consumed grains in the world. Though more than 100,000 species of fungi are known to exist, majority of mycotoxigenic fungi belong to the species of Aspergillus, Penicillium, and Fusarium. Among Aspergillus spp, Aspergillus niger and Aspergillus ochraceus are known to produce Ochratoxin A (OTA), a notable mycotoxin having adverse effects due to ubiquitous presence, renal toxicity and lengthy persistence. Totally eighty-one samples including unpolished (n = 36) and polished rice samples (n = 45) were collected in various districts of Tamil Nadu to identify ochratoxigenic fungi particularly Aspergillus spp. Out of 81 samples, 62 % (50/81) of samples including unpolished (n = 24) and polished rice (n = 26) documented the occurrence of ochratoxigenic fungi. Extraction of OTA was carried out by agar plug method and the ability of fungus to produce OTA was quantified by RP HPLC-FLD analysis. Among the fungal genera, Aspergillus spp (80 %) recorded the predominant fungus in rice. Molecular confirmation of ochratoxigenic fungi A. niger and A. ochraceus isolates was performed by 18s rDNA analysis. OTA producing ability by RP HPLC-FLD analysis revealed A. ochraceus of section Circumdati recorded the highest OTA production than A. niger isolates of section Nigri. The concentration range of OTA by A. ochraceus vary between 12.33 - 196.84 ng/g and 0.18 - 2.82 ng/g respectively in A. niger isolates. Among the A. ochraceus isolates, potent isolate AO 9 documented the highest OTA production (196.84 ng/g) followed by AO 6 (104.74 ng/g). Similarly, in A. niger AN 1 showed highest production of 2.82 ng/g followed by AN 5 isolate (1.25 ng/g) respectively. The objective of the study is to determine and quantify the ochratoxin production potential of Aspergillus spp in Indian rice by RP HPLC-FLD analysis. The occurrence of Aspergillus spp in rice and the subsequent ochratoxin production raise concern about possible health risk to animal and human environment upon consumption. Hence there is need for improved storage practices and regular monitoring to prevent the prevalence of Aspergillus fungus and OTA contamination in rice supply chain.

Laser-zoned treatment of magnesium surfaces with predictable degradation applications

Magnesium metal is a promising material for medical applications due to its biocompatibility and similar modulus of elasticity to human bone. However, its complex corrosion process must be addressed before it can be used clinically to match post-implantation tissue repair. This study aims to regulate material degradation by utilizing laser surface treatment. The surface of pure magnesium was modified using nanosecond and femtosecond laser methods to create various micro-nanostructures, such as chain, streak, column, and groove structures. Surface roughness and wettability tests revealed that the groove structures had higher roughness values. All structures exhibited hydrophilicity, but the femtosecond laser-generated structures were more hydrophilic. Electrochemical tests and immersion experiments demonstrated that femtosecond laser modification significantly improved the corrosion resistance of magnesium metal compared to polished samples. Cytotoxicity experiments showed that the laser-treated magnesium was not cytotoxic. Based on the results, we constructed various structures on the magnesium rods in different regions. As a result, the rods exhibited multi-stage biodegradation behavior in simulated body fluids (SBF). This study presents a novel approach to controlling the degradation sequence of medical metals.

Nickel release from 316L stainless steel following a Ni-free electroplating cycle

Electroplating can induce nickel release even from 316L stainless steel, typically considered safe. In this work, the influence of different electroplating processes and surface treatments on nickel release was evaluated. The nickel release was tested according to the EN 1811 standard. The impact of surface roughness on nickel release was assessed by comparing polished and unpolished samples. Results indicate that internal stresses can worsen nickel release, while increasing the thickness of the precious metal layer is beneficial. To corroborate our hypothesis, it was verified that coatings obtained through physical vapor deposition (PVD), without removing the passivation layer of the steel, did not release nickel. For these reasons, we identified the main cause of nickel release as the combined effect of the removal of the passivation layer of stainless steel and the microporosity of the electroplating process.

Determination of Total Aflatoxins in Polished Rice by Liquid Chromatography-Fluorescence Detection with Multifunctional Column Cleanup and Precolumn Derivatization: Single-Laboratory and Inter-Laboratory Validation Studies.

Aflatoxins are toxic metabolites produced by Aspergillus spp. Because aflatoxins are potent carcinogens in humans and animals, many countries have set regulatory limits for aflatoxins in foods to prevent dietary exposure. From a global food safety perspective, in 2023, the Codex Alimentarius Commission established the maximum level (ML) of total aflatoxins in certain cereals and cereal-based products, including polished rice. Therefore, validated analytical methods for aflatoxin detection are necessary. In this study, a high performance liquid chromatography (HPLC)-fluorescence method coupled with multifunctional column clean-up and trifluoroacetic acid derivatization was developed for the determination of aflatoxin levels in polished rice. Our method was validated in a single laboratory study using aflatoxin-spiked materials, followed by an inter-laboratory validation study. Twelve laboratories participated in the inter-laboratory validation study, and five polished rice test samples artificially contaminated with aflatoxins were analyzed. In a single laboratory study, the ranges of mean recoveries of aflatoxin B1, B2, G1, G2, and total aflatoxins were 101%, 100-103%, 93-96%, 95-98%, and 97-99%, respectively. The relative standard deviations for within-day and between-day variations were all ≤ 4.4%. In the inter-laboratory validation study, the relative standard deviations for repeatability and reproducibility were from 0.7 to 2.7% and 3.3 to 8.9% for all analytes, respectively. In response to the Codex ML and method performance criteria for aflatoxins in polished rice, an analytical method based on HPLC-fluorescence detection was developed. All method performance parameters estimated from the testing results of the single-laboratory and inter-laboratory validation studies met the criteria required by the Codex. Single- and inter-laboratory studies for the validation of an analytical method for aflatoxin level determination in polished rice were successfully performed. This analytical method will be suitable to determine aflatoxin levels around the Codex ML set for polished rice.

Behavior of Retained Austenite and Carbide Phases in AISI 440C Martensitic Stainless Steel under Cavitation

In this work emphasis was given to determine the evolution of the retained austenite phase fraction via X-ray diffractometry technique in the as-hardened AISI 440C martensitic stainless steel surface subjected to cavitation for increasing test times. Scanning electron microscopy results confirmed the preferential carbide phase removal along the prior/parent austenite grain boundaries for the first cavitation test times on the polished sample surface during the incubation period. Results suggest that the strain-induced martensitic transformation of the retained austenite would be assisted by the elastic deformation and intermittent relaxation action of the harder martensitic matrix on the austenite crystals through the interfaces between both phases. In addition, an estimation of the stacking fault energy value on the order of 15 mJ m−2 for the retained austenite phase made it possible to infer that mechanical twinning and strain-induced martensite formation mechanisms could be effectively presented in the studied case. Finally, incubation period, maximum erosion rate, and erosion resistance on the order of 7.0 h, 0.30 mg h−1, and 4.8 h μm−1, respectively, were determined for the as-hardened AISI 440C MSS samples investigated here.

Evaluating the bio-functionalities of Ti-6Al-7Nb alloy after surface modification using electrical discharge machining

The present work evaluates the influence of surface modification on the bio-functionalities of Ti-6Al-7Nb alloy in terms of apatite formation, metal ion release rate and anti-bacterial activities. The surface modification in the form of change in surface integrity, and increases in the exposed surface area, has been achieved using wire-electrical discharge machining (WEDM) and electrical discharge μ-drilling(EDD). Due to high discharge energies, molten material will deposit on the parent material (recast layer), which increases the surface roughness (parent surface 0.5 μm to 2.34 μm) and hardness (patent material 304VH to 385VH) after subsequent re-solidification and quenching. Surface roughness and hardness near the micro-drilled hole are observed to increase. After surface modification, the apatite formation is increased on Ti-6Al-7Nb alloy with increasing immersion time and the ion released rate was found lowest on the WEDMed surface as compared to micro drilled and polished surface. Field-emission electron scanning microscopy (FESEM) and energy dispersive x-ray spectroscopy (EDAX) observations confirmed the presence of phosphate and calcium ions on the WEDMed surface and nearby the micro-drilled surface. The variation in colour of the simulated body fluid (SBF) after the immersion of WEDMed, EDD, and polished samples indicates the variable effecton pH levels of the SBF solution for three types of samples.The anti-bacterial bioactivity of Ti-6Al-7Nb was found to be better on the WEDMed surface as compared to polished surfaces, which is due to the formation of a rutile-TiO2 layer on WEDMed surface.

Tribological behaviour of laser textured Ti3AlV 2.5V alloy under simulated body fluid

The use of lasers to fabricate micro-textures on the surface of medical implants is an effective method to improve their bio-tribological properties. In the present study, three distinct configurations of micro-textures, namely, co-axial circles, hexagon, and line with varying spacing of 300 µm, 400 µm, and 500 µm, were fabricated on Ti3Al2.5V alloy using Nd:YAG fibre lasers. The influence of micro-textured geometries on microhardness, coefficient of friction (COF), and wear rate was estimated. The tribological properties of the polished and textured samples were investigated using a linear reciprocating tribometer against silicon nitride (Si3N4) balls under simulated body fluid (SBF) lubricant. Orthogonal results indicate that the co-axial circles with a spacing of 305 µm prove to be the most efficient in enhancing the tribological performance of textured surfaces. This configuration demonstrates a significant improvement, with a 33.62 % reduction in friction coefficient and a 61.81 % reduction in wear rate compared to polished samples. The decrease in spacing appears to enhance the anti-friction and anti-wear properties of the textured surfaces. The working mechanism behind the reduction in the friction coefficient and wear rate lies in the capacity of the textures to trap particles.

Improvement of Laser Damage Resistance of Fused Silica Using Oxygen-Aided Reactive Ion Etching

Reactive ion etching (RIE) with fluorocarbon plasma is a facile method to tracelessly remove the subsurface damage layer of fused silica but has the drawback of unsatisfactory improvement in laser damage resistance due to the induction of secondary defects. This work proposes to incorporate O2 into the CHF3/Ar feedstock of RIE to suppress the formation of secondary defects during the etching process. Experimental results confirm that both the chemical structural defects, such as oxygen-deficient center (ODC) and non-bridging oxygen hole center (NBOHC) defects, and the impurity element defects, such as fluorine, are significantly reduced with this method. Laser-induced damage resistance is consequently greatly improved, with the 0% probability damage threshold increasing by 121% compared to the originally polished sample and by 41% compared to the sample treated with conventional RIE.

Cultural and gender differences in predicting flourishing through gratitude and life purpose: A moderated mediation analyses

Background: This study investigated the relationship between gratitude, purpose in life and flourishing, as well as the mediating role of purpose in life in the relationship between gratitude and flourishing in two different cultures, Indian and Polish. We also examined the moderating role of gender in the relationship between gratitude and purpose in life. Methods: A sample of 328 Indian and 303 Polish participants aged 18–56 years completed the Gratitude, Resentment, and Appreciation Scale, the Purpose in Life Questionnaire, and the Flourishing Scale. Pearson’s correlations were used to assess the associations between the main study variables, and PROCESS software was used to calculate moderated mediation. Results: Findings showed that gratitude and purpose in life were positively related to flourishing. Life purpose mediated the relationship between gratitude and flourishing. In the Indian sample, gender was a statistically significant moderator between gratitude (and its three facets) and purpose in life. In the Polish sample, gender moderated the relationship between overall gratitude and only one dimension (a sense of abundance) and purpose in life. Conclusions: The results suggest that enhancing gratitude and a sense of purpose in life can significantly improve individuals’ flourishing, considering gender and cultural differences.

Influence of titanium surface roughness on a nanoscale on the zeta potential and platelet adhesion.

Thromboembolic complications still arise on blood contacting surfaces. Surface charge and topography influence the subsequent deposition of proteins and platelets, potentially leading to thrombi. Research showed a correlation of surface charge and nanoscale roughness, and a negative surface charge as well as a smooth surface finish are associated with lower thrombogenicity. The aim of this study was to compare the platelet adhesion on titanium with different nanoscale roughnesses and to examine if those roughness variations caused a change in surface charge. Titanium samples were polished and roughened to four different nanoscale roughness levels. Platelet adhesion (covered surface area (CSA), N = 8) was tested in flow chambers with human whole blood using fluorescence imaging. ζ-potential was measured over a broad range of pH-values and interpolated to obtain the ζ-potential for pHBlood (7.4). Platelet adhesion tests were evaluated in terms of p-values and the Wilcoxon test effect size and the trend of the ζ-potential at pHBlood and the CSA was compared. Ra-values ranged between 35 (polished) and 156 nm. Regarding platelet adhesion, the polished sample showed the lowest mean CSA with a medium or strong effect size compared to the roughened samples. The interpolated ζ-potentials for pHBlood follow a similar trend as the CSA, with the lowest ζ-potential measured for the polished surface. These findings suggest that the decreasing ζ-potential due to lower nanoscale roughness might be an additional explanation for the improved hemocompatibility besides the smoother topography.

Investigation on the Dry-Type Electrochemical Polishing of 304 Stainless Steel with Ion-Exchange Resin Particles

Dry-type electrochemical polishing (DECP) technology integrates the mechanical action of resin particles with the electrochemical action of working solutions to enhance the results of existing treatments. Homogeneous polishing across the entire surface of the piece is the main advantage compared with mechanical polishing. This article utilizes this method to polish the surface of 304 stainless steel, leading to an improved surface roughness from the original 1.23 μm to the final 98 nm. This innovation expands the potential applications of 304 stainless steel in the medical and food industries. Energy dispersive X-ray spectroscopy (EDS) analysis subtle detect residual electrolyte components. It implies that resin particles containing liquid electrolytes can effectively prevent the remained harmful substance from the metal surface. Electrochemical analysis of polished sample shows that the E corr was −0.109 V for DECP specific sample compared with −0.0385 V for initial sample. The polishing process can be seen as the generation and removal of corrosion products.