ABSTRACT Monitoring marine oil pollution holds both practical and scientific significance. Synthetic Aperture Radar (SAR) is an active microwave remote sensing technique capable of all-weather and all-day with fine spatial resolution. However, under low wind conditions, rain cells and young ice are examples of look-alikes affect the accuracy of oil spill detection. Polarimetric SAR assumes a crucial role in this context, as it can extract abundant polarimetric features by polarimetric target decomposition. Drawing inspiration from this advancement, an improved polarimetric feature named relative feature based on Cloude-Pottier target decomposition was proposed. The Jeffries-Matusita distance indicates the substantial potential of the relative feature in detecting oil spills. The improved polarimetric feature within U-Net, FCN-8s, and DeepLabv3+ResNet-18 for oil spill detection using polarization SAR images. Experiment results demonstrated that the relative feature has superior performance compared to other polarimetric features and obtained the highest accuracy and dice within U-Net compared to the other two models. These findings introduce promising concepts for achieving rapid and precise detection of oil spills in future applications.