Extreme scenario of lightning strikes would generate ultra-fast rotation of state-of-polarization (RSOP) up to 5.1 Mrad/s and large polarization mode dispersion (PMD) in optical ground wire (OPGW). Unfortunately, the conventional multiple modulus algorithm (MMA) cannot equalize these polarization impairments in polarization division multiplexing (PDM) probabilistic constellation shaping (PCS)-64QAM system. Moreover, due to unavoidable linearization errors and higher modulation order, the extended Kalman filter based on measurement equations of concatenated multiplication (EKF-CM) is highly unstable and fails under such scenarios. To address the above issues, we have proposed a joint equalization scheme of PMD and RSOP, which fuses probability-aware with square-root cubature Kalman filter (PA-SCKF). Firstly, according to the characteristic that the amplitude of PCS signals obeys mixed Rician distribution, the scheme combines maximum a posteriori criterion to obtain the optimal radius of constellation ring which the received symbol belongs to, for the sake of calculating the innovations of SCKF. Secondly, it performs joint equalization of PMD and RSOP impairments based on SCKF and time-frequency conversion architecture. 28GBaud PDM PCS-64QAM simulation results demonstrate that our scheme can jointly equalize maximum impairments of 8.34 Mrad/s RSOP and 90ps DGD under entropy of 4.5bits/symbol. Additionally, only 0.9 dB OSNR penalty is obtained after joint equalization of 6 Mrad/s RSOP with 70ps DGD impairments. Even under entropy of 5.5bit/symbol, it can still jointly equalize impairments of 6.05 Mrad/s RSOP with 60ps DGD. Furthermore, 16GBaud PCS-64QAM experimental results indicate that the maximum joint equalization performances of PA-SCKF scheme under entropy of 4.5bit/symbol and 5bit/symbol are 17 Mrad/s RSOP with 52ps DGD, and 9 Mrad/s RSOP with 52ps DGD, respectively. These results manifest that our PA-SCKF scheme outperforms both MMA and EKF-CM schemes. Importantly, its complexity is on an order of O(Llog2 L), which is comparable to that of EKF-CM scheme.