Polar Shell Research Articles

Domain swapping: a mathematical model for quantitative assessment of structural effects.

The domain-swapping mechanism involves the exchange of structural elements within a secondary or supersecondary structure between two (ormore) proteins. The present paper proposes to interpret the domain-swapping mechanism using a model that assesses the structure of proteins (and complexes) based on building the structure of a common hydrophobic core in a micelle-like arrangement (a central hydrophobic core with a polar shell in contact with polar water), which has a considerable impact on the stabilisation of the domain structure built by domain swapping. Domains with a hydrophobicity system that is incompatible with the micelle-like structure have also been identified. This incompatibility is the form of structural codes related to biological function.

Self-assembling properties of mono and di-rhamnolipids characterized using small-angle X-ray scattering

Rhamnolipids are glycolipid surfactants composed by a hydrophilic head of either one (mono-RL) or two (di-RL) rhamnose moieties coupled to hydroxyaliphatic chains that can be of different lengths. In spite of their importance in different fields of applications, as bioremediation processes for instance, self-aggregation physico-chemical properties of RLs are not unique. This because a variety of aggregates morphologies (shape and size) can either exist or coexist in aqueous dispersion due to mono-RL:di-RL molar ratio, hydrophobic tails length, pH and the presence of co-surfactants and additives. Recently, a theorethical approach reported the self-assembling morphologies of either pure mono or di-RL in aqueous environment, predicting the formation of spherical to ellipsoidal micelles to worm-like and disk-like aggregates depending on RL concentration and fatty acid chain length. In order to add new information to those previously available, the present work investigated the self-assembling properties of mono-RL-C10-C10 and di-RL-C10-C10 separately in aqueous dispersion by small angle X-Ray scattering (SAXS). A novel approach was applied to the data analysis coupling the scattering length density profiles of the RLs chemical groups and Monte Carlo simulations. Such an approach allowed us to infer about the preferred mono-RL and di-RL conformations that fit better in the self-assembling morphologies. In this way, we show that mono-RL-C10-C10 self-assembles into lamella-like aggregates coexisting with 30 % of multi-lamella aggregates (circa of 5 closed stacked lamella) from a concentration ranging from 10 to 50 mM, with hydrophobic thickness of about 12 Å, a hydrated polar head thickness of 10 Å, and an area per glycolipid of 76 Å2. On the other hand, di-RL prefers to self-associate into flexible cylinder-like aggregates, from 70 mM to 110 mM concentration, with hydrophobic radius on the order of 7.5 Å, a hydrated polar shell of 21.5 Å, with hydropobic/polar interface of 110 Å2 per glycolipid. Interestingly, the parameters obtained from the best fitting to the experimental data associated to the volume fraction distribution of the chemical groups within the aggregates revealed that the hydrophobic chains are more disordered in mono-RL planar aggregates than in di-RL worm-like aggregates, as well as the hydration properties. Further, the addition of 100 mM NaCl in di-RL aqueous dispersion leads to the formation of longer worm-like aggregates. Taking together, this work opens a new avenue regarding characterization of biosurfactants self-assembling properties by using SAXS, also contributing to prepare more efficient biosurfactant dispersions depending on the desired applications in industrial sectors and bioremediation.

Fruit characteristics and phenology Tahiti lime in two Colombian environments

The surge in Tahiti lime exports over the past year, combined with heightened quality standards of the international market, have made it necessary to improve production processes to obtain fruit with increasingly better organoleptic characteristics. Thus, the foundation lies in selecting a property with suitable edaphoclimatic conditions and possessing precise knowledge of the ecophysiological behavior of the tree in these specific conditions. This study aimed to document the flowering phenology and study the physicochemical characteristics of Tahiti lime fruits in two environments in the Andean region of Colombia. Evaluations were conducted on eight Tahiti lime trees (ten-year-old) per orchard grafted on Sunki x English. Observations were made for 12 months of the buds, flowers and fruits of the marked trees in each evaluated area (Manizales – 2280 m asl and Santagueda 1010 m asl). The flowering phenology according to the stages of the BBCH phenological scale, the physical-chemical characteristics of the fruit, and the climatic conditions of the two areas were evaluated. A completely randomized experimental design and Duncan's comparison of means were used. Significant differences were found in polar diameter, ascorbic acid, soluble solids, juice yield, shell mass, and titratable acidity according to locality. The Phenology of flowering took less time, and the accumulation of heat units was higher in the lower altitude zone. The physical and chemical characteristics of Tahiti lime fruits are influenced by the environment in which the trees develop.

Equivalent permittivity and design of nanoparticle lasers for nonlocal polar dielectrics

Polar dielectrics are being actively investigated as a promising platform for mid-infrared nanophotonics, and it indicates dramatic nonlocal phenomena at the nanoscale. Based on full-wave nonlocal extended Mie theory, we analytically derive the equivalent permittivity of nonlocal polar dielectric nanospheres. Then, we establish the conditions for surface phonon amplification by stimulated emission of radiation of the nonlocal polar dielectric core-gain shell nanoparticle laser based on phonon polaritons. The results show that the nonlocality dramatically affects the selection of the gain medium for lasing condition, which also indicates a new degree of freedom in the modulation of the gain medium. The validity of the derived equivalent permittivity is demonstrated by comparing the obtained extinction spectra and the choice of the threshold gain with those under nonlocal extended Mie theory. Our research may provide a practical tool for designing phonon polariton nanoparticle lasers.

Structural Specificity of Polymorphic Forms of α-Synuclein Amyloid.

The structural transformation producing amyloids is a phenomenon that sheds new light on the protein folding problem. The analysis of the polymorphic structures of the α-synuclein amyloid available in the PDB database allows analysis of the amyloid-oriented structural transformation itself, but also the protein folding process as such. The polymorphic amyloid structures of α-synuclein analyzed employing the hydrophobicity distribution (fuzzy oil drop model) reveal a differentiation with a dominant distribution consistent with the micelle-like system (hydrophobic core with polar shell). This type of ordering of the hydrophobicity distribution covers the entire spectrum from the example with all three structural units (single chain, proto-fibril, super-fibril) exhibiting micelle-like form, through gradually emerging examples of local disorder, to structures with an extremely different structuring pattern. The water environment directing protein structures towards the generation of ribbon micelle-like structures (concentration of hydrophobic residues in the center of the molecule forming a hydrophobic core with the exposure of polar residues on the surface) also plays a role in the amyloid forms of α-synuclein. The polymorphic forms of α-synuclein reveal local structural differentiation with a common tendency to accept the micelle-like structuralization in certain common fragments of the polypeptide chain of this protein.

(1-x)[0.90NN-0.10Bi(Mg2/3Nb1/3)O3]-x(Bi0.5Na0.5)0.7Sr0.3TiO3 ceramics with core–shell structures: A pathway for simultaneously achieving high polarization and breakdown strength

Modern electronics and electrical power systems demand a large energy storage density (Wrec), high efficiency (η), and board operating temperature to deliver high performance. Nevertheless, the inverse correlation between polarization and dielectric breakdown strength hinders Pb-free dielectric ceramics from providing sufficient energy density and consequently limits their practical applications. This study demonstrates the effectiveness of (1-x)[0.90NN-0.10Bi(Mg2/3Nb1/3)O3]-x(Bi0.5Na0.5)0.7Sr0.3TiO3 (abbreviated as xBNST) ceramics with a core−shell structure in overcoming these challenges. Phase-field simulations reveal that the existence of a polar core in the grain effectively reduces the local electric field distribution of the weak polar shell, thereby significantly improving the breakdown strength. Further analyses of intrinsic electronic structure reveal the intrinsic mechanism for enhancing the breakdown strength via first-principles calculations based on density functional theory. Accompanied by the unique structure, grain inhomogeneity featuring the coexistence of strong polar and weak polar clusters contributes to the enhancement of the polarization difference. Consequently, the ceramics exhibit comprehensive energy storage performances [high Wrec = 7.72 J/cm3, large η = 83.78%, and broad usage temperature range (between −40 and 200 °C)]. These findings are expected to provide a feasible way to develop high-performance capacitors for advanced energy storage materials and applications.

Geometrical Theory of the Periodical Spheroid Transformation in Modelling of the Ecology Hybrid Electric and Modular Aircraft/ Airship and Flight Simulation

This article is devoted to the search for the Geometry Periodic Table Regularities architect structures in the space-group set and 2D/3D integrating variation of the any Geometric Transformations of the polar Spheroid shells models and Adaptive Simulation of the Synthesis of integral-differential layouts of the Aircraft and Airship and their Full Flight or Processing Training Simulations with spherical visual panoramic screen matrix. Using idea as the periodic table of the variety of elements proposed by Mendeleev DI., which allows us to naturally discover new yet unknown elements, it is possible to create a similar geometric table-matrix of element-by-element transformation of the layout forms of the aircraft for the development of a digital computer modeling complex in an Artificial intelligence environment, as a digital double of a qualified human designer. Perhaps the industry of electric vehicles and electric water transport and space projects can follow this path, as it is flexibly and variously

Embedding Photoacids into Polymer Opal Structures: Synergistic Effects on Optical and Stimuli-Responsive Features.

Opal films with their vivid structural colors represent a field of tremendous interest and obtained materials offer the possibility for many applications, such as optical sensors or anti-counterfeiting materials. A convenient method for the generation of opal structures relies on the tailored design of core-interlayer-shell (CIS) particles. Within the present study, elastomeric opal films were combined with stimuli-responsive photoacids to further influence the optical properties of structurally colored materials. Starting from cross-linked polystyrene (PS) core particles featuring a hydroxy-rich and polar soft shell, opal films were prepared by application of the melt-shear organization technique. The photoacid tris(2,2,2-trifluoroethyl) 8-hydroxypyrene-1,3,6-trisulfonate (TFEHTS) could be conveniently incorporated during freeze-drying the particle dispersion and prior to the melt-shear organization. Furthermore, the polar opal matrix featuring hydroxylic moieties enabled excited-state proton transfer (ESPT), which is proved by spectroscopic evaluation. Finally, the influence of the photoacid on the optical properties of the 3-dimensional colloidal crystals were investigated within different experimental conditions. The angle dependence of the emission spectra unambiguously shows the selective suppression of the photoacid’s fluorescence in its deprotonated state.

Tunable White Light-Emitting Devices Based on Unilaminar High-Efficiency Zn2+-Doped Blue CsPbBr3 Quantum Dots.

Perovskite-based white-light-emitting devices (WLEDs) are expected to be the potential candidate for the next-generation lighting field due to their scalability and low-cost process. However, simple and adjustable WLED fabrication technology is in urgent need. Here, WLEDs with a single layer of perovskite quantum dots (PQDs) were constructed by combining Zn2+-doped CsPbBr3 PQDs with exciplex emission between poly(9-vinylcarbazole) (PVK) and ((1-phenyl-1H-benzimidazol-2-yl)benzene)) (TPBi). Zn2+-doped CsPbBr3 PQDs with polar ion shells were prepared by means of low temperature and post-treatment. The photoluminescence quantum yield (PLQY) can reach as high as 95.9% at the emission wavelength of 456 nm. The blue shift of its PL (∼60 nm) is much greater than that of other reported Zn2+-doped CsPbBr3 PQDs (5-10 nm), thus realizing the true blue-emission Zn2+-doped CsPbBr3 PQDs. As a result, just by controlling the thickness of TPBi, the adjustment of cold (CIE (0.2531, 0.2502)) and warm WLEDs (CIE (0.3561, 0.3562)) is realized for the first time.

High‐Capacity and Stable Sodium‐Sulfur Battery Enabled by Confined Electrocatalytic Polysulfides Full Conversion

AbstractThe efficient polysulfide capture and reversible sulfur recovery during reverse charging process are critical to exploiting the full potential of room temperature NaS batteries. Here, based on a core‐shell design strategy, the structural and chemical synergistic manipulation of sodium polysulfides quasi‐solid‐state reversible conversion is proposed. The sulfur is encapsulated in the multi‐pores of 3D interconnected carbon fiber as the core structure. The Fe(CN)64−‐doped polypyrrole film serves as a redox‐active polar shell to lock up polysulfides and promote complete polysulfide conversion. Importantly, the short‐chain Na2S4 polysulfides are reduced to Na2S directly leaving with a small fraction of soluble intermediates as the cation‐transfer medium at the core/shell interface, and freeing up formation of solid Na2S2 incomplete product. Further, the redox mediator with open Fe species electrocatalytically lowers the Na2S oxidation energy barrier and renders the high reversibility of electrodeposited Na2S. The tunable quasi‐solid‐state reversible sulfur conversion under versatile polymer sheath greatly enhances sulfur utilization, affording a remarkable capacity of 1071 mAh g−1 and a stable high capacity of 700 mAh g−1 at 200 mA g−1 after 200 cycles. The confined electrocatalytic effect provides a strategy for tuning electrochemical pathway of sulfur species and guarantees high‐efficiency sulfur electrochemistry.

Two Grapes Short of a Fruit Salad: Raspberry-, Strawberry-, and Seedpod-Like Organic Microspheres via Colloidal Nanotemplating.

The morphology of surfaces critically influences their interaction with the surrounding phase. Herein, we report a modular approach for the synthesis of organic-inorganic raspberry-, strawberry-, and seedpod-like particles to template the porosity of superficially porous particles. Divinylbenzene (DVB) microspheres were employed as core particles, which were modified with polar and nonpolar polymer shells. Subsequently, silica nanoparticle templates were covalently tethered to said particles. Further grafting of polymer shells and subsequent template removal yielded superficially porous core-shell particles. In addition, we introduce a facile procedure for the synthesis of superficially porous particles without distinguishable core-shell morphology. Organic seedpod-like particles were prepared from DVB and silica templates, yielding superficially porous particles after template removal. The surface morphology of the templated particles was investigated via scanning electron microscopy (SEM), transmission electron microscopy (TEM), and atomic force microscopy (AFM). X-ray photoelectron spectroscopy (XPS) was performed to prove the chemical modification of the particle surfaces.

Synergistic effect between a novel silane-containing hyperbranched polyphosphamide and ammonium polyphosphate on the flame retardancy and smoke suppression of polypropylene composites

A novel hyperbranched polyphosphamide with abundant terminal groups of silane (HBPPA-Si) was synthesized from phosphorus oxychloride (POCl3), 4, 4′-diaminodiphenylmethane (DDM) and (3-aminopropyl) triethoxysilane (APTES), which had high thermal stability with a residual weight of 44.0 wt% at 800°C in nitrogen atmosphere. By incorporating 25 wt% of APP and HBPPA-Si with an optimum mass ratio of 1:1 into polypropylene (PP) composites, the PP/APP/HBPPA-Si composite reached V-0 rating at the UL-94 test and also obtained a maximum LOI value of 27.5%. Meanwhile, their peak heat release rates (PHRR), total heat release (THR), and total smoke production (TSP) reduced dramatically by 72.5%, 35.8%, and 62.7% respectively, when compared with virgin PP. The improved flame retardancy and smoke suppression of PP/APP/HBPPA-Si composite were ascribed to their excellent synergistic effect working efficiently in both condensed-phase and gas-phase actions. It is noticeable that the high-quality and high-quantity char residue possessing thermal-stable P- and Si-containing cross-linked structures can shield the underlying polymeric materials from further hydrolysis and simultaneously insulate the volatile fuel and heat transfer. Moreover, the weak polar silane shell of HBPPA-Si improved the interfacial compatibility of APP within the PP matrix, leading to enhanced mechanical properties with increasing HBPPA-Si concentration.

Apparent molal volumes and hydration numbers from viscosity studies for microemulsions with a nonionic surfactant derived from castor oil and a series of polar oils

The cloud point of a nonionic surfactant is related to the hydration of its polar shell. Viscosity data can be used to determine the total amount of water associated with micelles. The aim of this study was to apply this model to a more complex system comprising a series of oil-in-water microemulsions. These consisted of the nonionic surfactant, Kolliphor® RH 40, with and without polar oils. The oils used were isopropyl myristate (IPM), neopentyl glycol diethylhexanoate (NGDO), diisopropyl sebacate (DIS) and diisopropyl adipate (DIA) while the alcoholic solvents ethanol, 2-propanol and diethylene glycol monoethyl ether (DEG) were the co-surfactants. The apparent molal volumes were determined from the densities using a pycnometric method while the viscosities were measured using capillary viscometry. The partial excess volumes with IPM ranked as DEG>2-propanol>ethanol while the excess volumes varied as IPM>NGDO>DIS>DIA. These results were most likely related to the effect of the co-surfactant on the size and curvature of the micellar pseudophase and to the site of oil solubilization, respectively. The presence of oil induced increases in the intrinsic viscosities, the Huggins constants and the hydration numbers. The magnitudes of the latter two parameters were in excellent agreement with the values reported for micelles of nonionic surfactants. With DIS, the changes in the hydration numbers showed a good relationship with the excess volumes. Therefore, meaningful hydration values for microemulsions may be obtained with polar oils which are solubilized in the palisade layer rather than in the core as occurs with hydrophobic oils.

Polarized Gaussian basis sets from one-electron ions.

We demonstrate that basis sets suitable for electronic structure calculations can be obtained from simple accuracy considerations for the hydrogenic one-electron ions Y(Y-1)+ for Y ∈ [1, Z], necessitating no self-consistent field calculations at all. It is shown that even-tempered basis sets with parameters from the commonly used universal Gaussian basis set (UGBS) [E. V. R. de Castro and F. E. Jorge, J. Chem. Phys. 108, 5225 (1998)] reproduce non-relativistic spin-restricted spherical Hartree-Fock total energies from fully numerical calculations to better accuracy than UGBS, which is shown to exhibit huge errors for some elements, e.g., 0.19 Eh for Th+ and 0.13 Eh for Lu, as it has been parameterized for a single atomic configuration. Having shown the feasibility of the one-electron approach, partially energy-optimized basis sets are formed for all atoms in the Periodic Table, 1 ≤ Z ≤ 118, by optimizing the even-tempered parameters for Z(Z-1)+. As the hydrogenic Gaussian basis sets suggested in this work are built strictly from first principles, polarization shells can also be obtained in the same fashion in contrast to previous approaches. The accuracy of the polarized basis sets is demonstrated by calculations on a small set of molecules by comparison to fully numerical reference values, which show that chemical accuracy can be reached even for challenging cases such as SF6. This approach is straightforward to extend to relativistic calculations and could facilitate studies beyond the established Periodic Table.

Towards stable lithium-sulfur battery cathodes by combining physical and chemical confinement of polysulfides in core-shell structured nitrogen-doped carbons

Despite intensive research on porous carbon materials as hosts for sulfur in lithium-sulfur battery cathodes, it remains a problem to restrain the soluble lithium polysulfide intermediates for a long-term cycling stability without the use of metallic or metal-containing species. Here, we report the synthesis of nitrogen-doped carbon materials with hierarchical pore architecture and a core-shell-type particle design including an ordered mesoporous carbon core and a polar microporous carbon shell. The initial discharge capacity with a sulfur loading up to 72 wt% reaches over 900 mA h gsulfur−1 at a rate of C/2. Cycling performance measured at C/2 indicates ∼90% capacity retention over 250 cycles. In comparison to other carbon hosts, this architecture not only provides sufficient space for a high sulfur loading induced by the high-pore-volume particle core, but also enables a dual effect of physical and chemical confinement of the polysulfides to stabilize the cycle life by adsorbing the soluble intermediates in the polar microporous shell. This work elucidates a design principle for carbonaceous hosts that is capable to provide simultaneous physical-chemical confinement. This is necessary to overcome the shuttle effect towards stable lithium-sulfur battery cathodes, in the absence of additional membranes or inactive metal-based anchoring materials.

Synthesis of amphiphilic copolymers based on dendritic polyethylene grafted by polyhydroxyethylmethacrylate and polyhydroxypropylmethacrylate and their use for construction of nanoparticles

By grafting from approach amphiphilic grafted copolymers with a hydrophobic core based on dendritic polyethylene and hydrophilic grafts of polyhydroxyethylmethacrylate (PHEMA) and polyhydroxypropylmethacrylate (PHPMA) were synthesized by tandem chain walking copolymerization and ATRP. Copolymers with molar mass 160–1400 kg/mol and ∼50–90% of hydrophilic grafts were obtained. Core-shell nanoparticles with very narrow size distribution were prepared from the copolymers by solvent displacement method. Particles diameter was efficiently regulated by molar mass of the copolymers in the range of 60–180 nm. We demonstrated that these nanoparticles can act as nanocontainers for hydrophobic Nile red dye, achieving up to 25% encapsulation efficiency. Dendritic polyethylene (dPE) nanoparticles with biocompatible polar PHEMA and PHPMA shell can find application in nanocatalysis and cargo delivery.

Preparation of polymer electrolyte membranes with continuous PEG channel via the fusion of self-assembled polycyclooctene-graft-polyethylene glycol copolymer micelles

Small molecular weight polyethylene glycol (PEG 350 g/mol) based polymer electrolyte membranes (PEMs) with continuous lithium ion transport channels are prepared via the fusion of the self-assembled micelles of amphiphilic copolymer. The self-assembled micelles consisted of nonpolar polycyclooctene (PCOE) core and polar PEG shell are formed via dialyzing the dichloromethane solution of amphiphilic polycyclooctene-graft-polyethylene glycol (PCOE-g-PEG) copolymer with ethanol, which is a good solvent for PEG and nonsolvent for PCOE. The resulted electrolyte membrane with bicontinuous morphology is obtained by casting the self-assembled micelle solution in a stainless steel plate and heating at 80 °C for 24 h after mixing with a certain amount of lithium perchlorate (LiClO4). When the content of PEG is 20 wt%, the ion conductivity of the self-assembled PEM can exceed 10−4S/cm at 25 °C, which is 3 orders of magnitude higher than the counter PEM groups prepared via directly casting of the copolymer dichloromethane solution without self-assembled process. While the mechanical strength of the self-assembled PEMs is almost the same as those directly casting ones, in which only PCOE phase is continuous.

A reconstructed local [formula omitted] formulation for isogeometric Kirchhoff–Love shells

An efficient assumed strain formulation for avoiding the membrane locking of non polar shells is developed in the context of B-spline interpolation. Assumed membrane strains are introduced locally in each element with a local L2-projection, and then a spline reconstruction algorithm, developed by Thomas et al. (2015), is employed for reconstructing the membrane strain at the global patch level. In this way, a banded stiffness matrix is obtained that strongly reduces the computational cost with respect to the standard B̄ formulation for isogeometric analysis. The main advantages of the proposed method are: the reproduction of regular membrane strain fields, an accurate membrane locking-free solution and an high computational efficiency with respect to standard B̄ formulation. The method can be applied for any polynomial degree of the B-spline interpolation. The effectiveness of the proposed method is demonstrated analyzing some bending and membrane dominated problem, commonly employed as benchmark in the shell literature.

Biomimetic Bipolar Microcapsules Derived from Staphylococcus aureus for Enhanced Properties of Lithium–Sulfur Battery Cathodes

AbstractLithium–sulfur (Li–S) batteries suffer from some serious issues, such as volume expansion, polysulfide migration, and so on, which lead to inferior rate properties, low Coulombic efficiency, and poor cycling stability. To a great extent, the significantly changing polarities, conductivities, and solubilities of sulfur species complicate these issues and make them hard to deal with. In this study, a biomimetic bipolar microcapsule is developed via bacteria fermentation and chemical modification. The biomimetic hierarchical microcapsule has a nonpolar core to load active materials and a polar shell to “selectively” control mass transport in and out. Each capsule acts as a microreactor, which adsorbs sulfur with the porous carbon core, retards polysulfide migration with the polar TiO2 shell, and only facilitates lithium ion diffusion through the shell. The advantages of bipolar microcapsules are able to concurrently address S hosting, electron conducting, and polysulfide migration issues in particle scales instead of electrode scales. Because the resulting sulfur cathodes effectively interact with all sulfur species and confine them inside microcapsules, those intractable issues that lead to poor cycling properties are significantly managed. Thus, a high specific capacity and excellent cycling stability are achieved by using this novel structure design.

Introducing the Bipolar Solvent Media Using the Aqueous Mixtures of Amino Acid Anion-Based Ionic Liquids.

To carry out a chemical reaction between the reactants with largely different polarities, it becomes important to have a reaction medium that possesses both the polar and nonpolar solvation environments. In an attempt to explore the reaction media with such unique polarity properties, the present study provides a thorough understanding of the bipolar solvent media using the aqueous mixtures of amino acid anion-based ionic liquids. The highly polar behavior of the binary mixtures used in the study has been ascribed to the pure ionic liquid state. However, the less polar solvation shells have been attributed to the presence of a neutral form of the anions. Addition of water in the amino acid anion-based ionic liquids causes the protonation of a certain fraction of the anions of the ionic liquids, resulting into the formation of a less polar nonionic protonated form along with the highly polar natural anionic form. This results into the formation of two solvation spheres with different polarities, which can be seen very clearly from the presence of two absorption bands (lower wavelength absorption band and higher wavelength absorption band) in the UV-vis absorption spectrum of Reichardt's ET(30) dye and two emission bands (lower wavelength emission band and higher wavelength emission band) in the fluorescence emission spectrum of C481 dye. The values of the ETN polarity parameter corresponding to the two solvation shells having different polarities have been calculated from the deconvoluted absorption spectra of the Reichardt's ET(30) and were analyzed in three amino acid anion-based ionic liquids. Generation of the neutral form of anions in the aqueous mixtures formed via a protonation transfer reaction has been confirmed by the 1H NMR spectroscopy and UV-vis absorption spectrum of 18DHAQ dye. The study also establishes that the Reichardt's ET(30) dye can be used as a valid polarity probe to study the solvatochromic behavior of the binary mixtures of amino acid-based ionic liquids.