Surface interactions occur near the land–atmosphere interface, thus affecting the temperature, convection, boundary layer, and stability of the atmosphere. A proper representation of surface interactions is a crucial component for numerical atmospheric and air quality modeling. We assessed four land surface schemes—1. 5–layer thermal diffusion scheme (1 5-Layer); 2. unified Noah land surface model (2 Noah); 3. rapid update cycle (3 RUC) land surface model; and 4. Pleim–Xiu land surface model (4 Pleim–Xiu)—from the Weather Research and Forecasting with Chemistry (WRF-Chem V3.2) model for the purposes of atmospheric modeling in Cuenca, which is a region with a complex topography and land use configuration and which is located in the Southern Andean region, in Ecuador. For this purpose, we modeled the meteorological and air quality variables during September 2014. It was found that the meteorological and short-term air quality variables were better modeled through the 2 Noah scheme. Long-term (mean monthly) air quality variables were better modeled by the 1 5–Layer and 3 RUC options. On average, the 2 Noah scheme was better at modeling meteorology and air quality. In addition, we assessed the 2 Noah scheme combined with the urban canopy model (UCM) (5 Noah UCM), which was developed as an option to represent the urban effects at a subgrid-scale. Results indicated that the performance of the 5 Noah UCM scheme was not better at modeling than the 2 Noah scheme alone. Moreover, the 5 Noah UCM scheme notably decreased the modeling performance for carbon monoxide and fine particulate matter. These results complement previous assessments of other schemes, allowing us to recommend a basic configuration of parameters for atmospheric modeling in the Andean region of Ecuador.
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