In-plane Orientation Research Articles

Orientation-dependent structural properties during growth and growth mechanism of CoO films

The orientation-dependent local structural properties of CoO films on sapphire substrates during growth were investigated through linearly-polarized extended X-ray absorption fine structure (EXAFS) measurements. Specifically, CoO(111) and (100) crystals with a rock-salt structure (Fm3m) were epitaxially grown on α-Al2O3(0001) and (101¯2) substrates, respectively, at 700℃ using a radio-frequency sputtering system. The local structural properties of CoO films in the in-plane and out-of-plane orientations were quantitatively determined using linearly-polarized EXAFS at the Co K-edge during growth. The EXAFS analysis revealed that during the initial stages of growth, the local structural properties exhibit significant differences compared to thick films, with short atomic distances and large (small) Debye-Waller factors observed in the out-of-plane (in-plane) orientations. The local structural strain mostly diminished when approximately 20 CoO layers accumulated on the substrate. Density functional theory (DFT) calculations further supported these findings by confirming that cobalt atoms initially form stable bonds with the sapphire surface, leading to the simultaneous growth of oxygen and cobalt layers in a coordinated manner through layer-by-layer growth.

Superior bendability enabled by inherent in-plane elasticity in Bi2Te3 thermoelectrics

With the rapid development of modern wearable electronics, powerful and deformable thermoelectric generators have become an urgent need as the power units that convert environmental or body heat into electricity. Existing efforts mostly focused on the assistance for deformability by substrates/additives, the resultant devices usually output much less power and showed very poor power retainment. Elasticity is inherent to all solids, which therefore offers an intrinsic solution for making thermoelectrics deformable without compromise in power output because of its full recoverability. This work demonstrates this in best-performing (Bi, Sb)2(Te, Se)3 thermoelectrics near room temperature, ending up in the film devices with both extraordinary power density and robust recoverable bendability. This originates from the inherent large elasticity for the in-plane orientation, which is enabled by an easy tape stripping approach for the Van der Waals layered structure, allowing the realization of both powerfulness and bendability that are equally important for wearable thermoelectrics.

Advanced hybrid nanomaterials based on carboxymethyl-modified biopolymer: Green synthesis and application in sustainable antimicrobial products

The utilization of agricultural by-products for the synthesis of hybrid nanomaterials represents an environmentally sustainable approach. This research aims to comprehensively investigate high-performance silver and copper nanoparticles hybrid materials based on carboxymethyl-modified cellulose / lignin derived from rice husks (CMC / CML-AgNPs and CMC / CML-CuONPs) and apply them for antimicrobial activities. CMC / CML was used to reduce Ag / Cu cations to the atomic level and then efficiently stabilize Ag / CuO nanoparticles, an eco-friendly method and sustainable development. The hybrid nanomaterials were successfully synthesized with spherical shapes and particle sizes ranging from 4 to 16 nm. The diffraction peaks at 38.46°, 46.57°, 64.93°, and 77.55° were ascribed to the face-centered cubic crystal lattice (111), (200), (220), and (311) of silver nanoparticles in the CMC / CML-AgNPs. The peaks were 32.26°, 46.06°, 52.16°, 61.71°, 63.80°, and 71.23° associating with the (110,20−2), (112), (11−3), (310), and (221) plane orientations of CuO nanoparticles. The proposed materials demonstrated highly efficient antimicrobial performances. Particularly, CMC-AgNPs and CML-CuONPs exhibited an inhibitory capability of up to 100 % against E. coli and S. aureus within 72 h. Simultaneously, the antifungal results showed that hybrid nanomaterials have a better ability to inhibit the A. niger than A. flavus fungus. When experimenting on peanut seeds, hybrid nanomaterials showed an inhibitory capability of up to 99.0 % against A. niger. IC50 values of the hybrid nanomaterials range from 0.872 mg/mL to 1.188 mg/mL, confirming that these materials are non-cytotoxic. These materials exhibit significant stability and enduring antimicrobial efficacy, making them ideal for sustainable development of various antibacterial and antifungal blocks for the near future.

Research on the Identification of Rock Mass Structural Planes and Extraction of Dominant Orientations Based on 3D Point Cloud

The different spatial distribution forms of rock mass structural planes create weak zones in the rock mass, which is also a key factor in controlling rock mass stability. Accurately and efficiently identifying rock mass structural planes and obtaining their dominant orientations is critical for rock mass engineering design and construction. Traditional surveying methods for high and steep rock mass structural planes pose high safety risks, offer limited data, and make comprehensive statistical analysis difficult. This paper utilizes complex rock mass surface 3D point cloud data obtained through 3D laser scanning technology and uses the Hough space transform method to calculate the normal vectors of the 3D point cloud. Based on the difference in normal vectors and surface variation, region growing segmentation is applied to identify and extract rock mass structural planes. Additionally, the fast search and density peak clustering method (CFSFDP) is used for clustering analysis of the rock mass structural planes to obtain dominant orientations. This method was applied to a highway’s high and steep rock slope, successfully identifying 281 structural planes and two sets of dominant structural planes. The orientation of the dominant structural planes identified through RocScience Dips 7.0 analysis showed a deviation of no more than ±3°, complying with engineering standards. The research results offer a feasible solution for the identification of high and steep rock mass structural planes and the extraction of the orientation of dominant structural planes.

The Orientation in Space of the Maxillary Arch: New and Old Devices in the Prosthetic Digital Workflow.

In extensive prosthetic rehabilitations and in those involving the anterior area, a correct 3D spatial position is of fundamental importance for effective communication between the clinician and the dental technician. The aim of this article is to analyze the different methods used to position in space and/or in an articulator the maxillary arch in analog workflows highlighting shortcomings and difficulties in order to understand how to overcome them when employing digital workflows. Traditional mechanical devices, such as anatomical, kinematic, esthetic and postural facebows, have clear indications, but also limitations, especially in cases of skeletal asymmetries. Modern digital tools, including photography, CBCT, facial scanners and jaw recording devices, are here critically analyzed to illustrate the advantages of working in a virtual space. The adoption of digital tools in the prosthetic workflow represents a significant improvement compared to traditional techniques, as it reduces errors and artifacts of registration and transfer of the position of the maxillary arch in the articulator space. This contributes to more predictable esthetic and functional results, with a positive impact for clinicians and technicians, improving clinical-laboratory communication, operational efficiency and overall quality of work. The integration of digital tools into prosthetic workflows represents an important advancement in clinical practice since they reduce human error and facilitate communication between the clinician and the laboratory. When carrying out rehabilitations involving changes in esthetics or occlusal plane orientation, the proper and accurate positioning of the upper arch in space is particularly relevant.

Néel Vector Auto-Oscillations and Reorientations Induced by Spin-Polarized Electric Currents in Antiferromagnetic Mn2Au Nanolayer

The electrical excitation of spin dynamics in antiferromagnets is important for the development of high-speed spintronic devices with a low power consumption. Here, we present a theoretical study of the spin dynamics generated in the Ni/Cu/Mn2Au/Cu/Ni nanostructure by a perpendicular-to-plane electric current. Our investigation includes atomistic simulations of spin reorientations in a few monolayer antiferromagnetic Mn2Au film and numerical calculations of nonequilibrium spin accumulation in the nanostructure comprising ferromagnetic Ni polarizers with antiparallel magnetizations. This combined approach enables us to quantify the dynamics of Mn magnetic moments induced by the spin-transfer torque created by the spin-polarized charge flow. The calculations show that the direct electric current with the density exceeding some temperature-dependent threshold value gives rise to steady-state auto-oscillations of the Néel vector in the [Formula: see text]-oriented Mn2Au nanolayer. As the precession of Mn magnetic moments occurs around an out-of-plane direction strongly deflected from their initial in-plane orientations, the emergence of auto-oscillations should be regarded as the realization of a dynamic spin reorientation transition in the antiferromagnetic crystal. Remarkably, the precession frequency rises with increasing current density J and exceeds 1[Formula: see text]THz at [Formula: see text][Formula: see text]A[Formula: see text]m[Formula: see text], which makes the described antiferromagnetic spin transfer nano-oscillator attractive for device applications. Furthermore, our simulations demonstrate that a picosecond current pulse injected into the Ni/Cu/Mn2Au/Cu/Ni nanostructure can induce a precessional switching of the Néel vector. Depending on the current density and pulse duration, the Néel vector rotates by either 90° or 180° and attains stable orientation along the corresponding [Formula: see text] easy axis in the plane of the Mn2Au nanolayer. This feature shows that the Ni/Cu/Mn2Au/Cu/Ni nanostructure could be used as a nonvolatile memory cell with the electrical writing and readout.

Effect of Printing Orientation on the Mechanical Properties of Low-Force Stereolithography-Manufactured Durable Resin

This study presents the results of fracture toughness tests conducted on specimens obtained by additive manufacturing techniques, specifically using low-force stereolithography. The samples were manufactured from a transparent 3D printing material for biocompatible applications, the so-called BioMed Durable Resin, which is a Formlabs-patented polymer material that simulates the strength and rigidity of polyethylene. The selected toughness tests in this context were performed following the ASTM D5045-99 guidelines. All tests were conducted under controlled laboratory conditions at 23 °C and 50% relative humidity, ensuring adherence to the standard and the replicability of the experimental results. To investigate the influence of printing plane orientation, specimens were produced at three printing orientation angles (0, 45, and 90 degrees). These angles were selected to provide a comprehensive evaluation of the anisotropy effects in the material. They cover both extreme orientations (0° and 90°) and include an intermediate value (45°), allowing us to assess variations in mechanical behavior across a representative range of printing orientations, consistent with prior research in the field. The experimental tests yielded data on the crack resistance and energy release rate for each angle of orientation. There are various implications of the findings, beyond materials engineering, for applications in biomedicine. Indeed, this same approach opens the door to new research methods for manufacturing certified biocompatible materials from such durable resins. Finally, complementary issues such as related medical applications have been slightly addressed for future work, since biomedicine innovation clusters can contribute to accelerating growth in this crucial field for productive sector activity and the local business environment.

STRUCTURAL AND MAGNETIC PROPERTIES OF Gd1-xBixFeO3

This work presents the synthesis of the Gd1-xBixFeO3 system by the combustion method at a temperature of 650°C using citric acid, the doping with Bi3+ took values from x=0.0 to x=0.14 with an increase of 0.02 per sample. The structural characterization of the system was carried out with the application of X-Ray Diffraction (XRD), which by Rietveld refinement showed a perovskite-type compound with orthorhombic structure, Pbnm space group, preferential orientation in the (112) plane and no secondary phases. The micrographs SEM show the presence of particles with irregular shape and average particle size between 0.092 to 0.24 µm. Finally, the magnetic analysis showed that the materials obtained exhibit anti-ferromagnetic properties with ferromagnetic components.

Improvement of the microstructure and corrosion behavior of Ni-TiO2 composite coatings electrodeposited at various amounts of TiO2 powder

The purpose of this study was to produce efficient Ni-TiO2 composite coatings at different concentrations of TiO2 particles to enhance BS2 microstructure and corrosion resistance in 3.5 wt. % NaCl. % NaCl solution. EDS analysis shows that the Ti and O content increases by increasing the amount of TiO2. XRD results reveal that the preferential growth plane of pure Ni is (100), which corresponds to the (111) and (100) planes for Ni-TiO2 composite coatings. SEM shows that the substrates are coated homogeneously. In addition to the microstructural improvements, the corrosion resistance efficiency was enhanced significantly with the inclusion of TiO2 particles. Specifically, the study showed that 10 g/L of TiO2 provided the optimal balance, achieving a corrosion resistance efficiency of 74.6%, along with a marked reduction in porosity. Furthermore, the surface morphology confirmed a uniform and defect-free distribution of the TiO2 particles, contributing to the overall anti-corrosion properties. These findings suggest that Ni-TiO2 composite coatings are a promising candidate for industrial applications, particularly in environments where materials are exposed to harsh conditions, such as marine environments. The outcomes of this research have the potential to inform the development of advanced anti-corrosion strategies for various industries.

Segmentation-Free Estimation of Left Ventricular Ejection Fraction Using 3D CNN Is Reliable and Improves as Multiple Cardiac MRI Cine Orientations Are Combined.

We aimed to study classical, publicly available convolutional neural networks (3D-CNNs) using a combination of several cine-MR orientation planes for the estimation of left ventricular ejection fraction (LVEF) without contour tracing. Cine-MR examinations carried out on 1082 patients from our institution were analysed by comparing the LVEF provided by the CVI42 software (V5.9.3) with the estimation resulting from different 3D-CNN models and various combinations of long- and short-axis orientation planes. The 3D-Resnet18 architecture appeared to be the most favourable, and the results gradually and significantly improved as several long-axis and short-axis planes were combined. Simply pasting multiple orientation views into composite frames increased performance. Optimal results were obtained by pasting two long-axis views and six short-axis views. The best configuration provided an R2 = 0.83, a mean absolute error (MAE) = 4.97, and a root mean square error (RMSE) = 6.29; the area under the ROC curve (AUC) for the classification of LVEF < 40% was 0.99, and for the classification of LVEF > 60%, the AUC was 0.97. Internal validation performed on 149 additional patients after model training provided very similar results (MAE 4.98). External validation carried out on 62 patients from another institution showed an MAE of 6.59. Our results in this area are among the most promising obtained to date using CNNs with cardiac magnetic resonance. (1) The use of traditional 3D-CNNs and a combination of multiple orientation planes is capable of estimating LVEF from cine-MRI data without segmenting ventricular contours, with a reliability similar to that of traditional methods. (2) Performance significantly improves as the number of orientation planes increases, providing a more complete view of the left ventricle.

Selective area epitaxy of in-plane HgTe nanostructures on CdTe(001) substrate

Semiconductor nanowires (NWs) are believed to play a crucial role for future applications in electronics, spintronics and quantum technologies. A potential candidate is HgTe but its sensitivity to nanofabrication processes restrain its development. A way to circumvent this obstacle is the selective area growth technique. Here, in-plane HgTe nanostructures are grown thanks to selective area molecular beam epitaxy on a semi-insulating CdTe substrate covered with a patterned SiO2mask. The shape of these nanostructures is defined by the in-plane orientation of the mask aperture along the <110>, <11¯0>, or <100> direction, the deposited thickness, and the growth temperature (GT). Several micron long in-plane NWs can be achieved as well as more complex nanostructures such as networks, diamond structures or rings. A good selectivity is achieved with very little parasitic growth on the mask even for a GT as low as 140 °C and growth rate up to 0.5 monolayer per second. For <110> oriented NWs, the center of the nanostructure exhibits a trapezoidal shape with {111}B facets and two grains on the sides, while <11¯0> oriented NWs show {111}A facets with adatoms accumulation on the sides of the top surface. Transmission electron microscopy observations reveal a continuous epitaxial relation between the CdTe substrate and the HgTe NW. Measurements of the resistance with four-point scanning tunneling microscopy indicates a good electrical homogeneity along the main NW axis and a thermally activated transport. This growth method paves the way toward the fabrication of complex HgTe-based nanostructures for electronic transport measurements.

Effect of sawdust fillers loaded on Cucumis sativus fiber‐reinforced polymer composite: a novel composite for lightweight static application

AbstractThis research investigates the impact of sawdust fillers on Cucumis sativus fiber‐reinforced polymer composites through a conventional hand layup process. The objective is to develop a novel material suitable for static applications that is both lightweight and environmentally sustainable. A range of analytical techniques including X‐ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, mechanical testing, thermogravimetric analysis (TGA), scanning electron microscopy (SEM) and energy‐dispersive X‐ray (EDX) analysis were employed to thoroughly characterize the resulting composite material. By integrating Cucumis sativus fibers and sawdust fillers into a polymer matrix, the study demonstrates the potential to create materials with improved mechanical properties due to addition of sawdust filler, including tensile strength (27.61 MPa), flexural strength (32.84 MPa), impact resistance (14.7 J cm−2) and hardness (42). These enhancements, averaging at 16.2%, are attributed to the addition of sawdust filler, which opens new avenues for environmentally conscious engineering solutions. XRD analysis reveals the composite's crystalline structure, indicating a crystallinity index of 64.5% and the orientation of crystalline planes. FTIR spectroscopy identifies chemical bonding and CO and CO functional groups present in the material with major peaks at 2123 and 2438 cm−1. TGA assesses the composite's thermal stability and decomposition behavior up to 380 °C. Additionally, SEM imaging elucidates the microstructural features and distribution of Cucumis sativus fibers and sawdust fillers within the epoxy matrix, while EDX analysis provides quantitative data on elemental composition. © 2024 Society of Chemical Industry.

Self-Sacrificed Additive in Preparing PbI2 Film Enables the Oriented Growth of Perovskite Crystals for Improved Solar Cell Performance.

Due to the limitation of the diffusion kinetics of organic amine salts on the PbI2 layer in the two-step method, prepared perovskite particles are small in size, have many defects, and are randomly oriented, and the cell efficiency and stability are difficult to guarantee due to PbI2 residues. Here, we added a volatile additive, N,N,N',N'-tetramethylethylenediamine (TMEDA), to the PbI2 precursor solution and formed preaggregated atomic clusters with PbI2 through TMEDA, which reduced the Gibbs free energy of nucleation to obtain a porous PbI2 layer, and finally obtained a perovskite film with large particles, few defects, ideal crystal plane orientation, and no additive residues. The results show that the photoelectric conversion efficiency of the optimized device is increased by 1.68% (from 21.68% to 23.36%), and the unpackaged optimized device still maintains the maximum efficiency of 77% after being placed in the air for 1200 h. This study provides an effective way to fabricate efficient and stable perovskite solar cells by promoting the nucleation-induced crystallization orientation by volatile additives.

Unveiling Nanoscale Ordering in Amorphous Semiconducting Polymers Using Four-Dimensional Scanning Transmission Electron Microscopy.

We present four-dimensional (4D) scanning transmission electron microscopy (STEM) analysis to obtain a high level of detail regarding the nanoscale ordering within largely disordered organic semiconducting polymers. Understanding nanoscale molecular ordering in semiconducting polymers is crucial due to its connection to the materials' important properties. However, acquiring such information in a spatially localized manner has been limited by the lack of a nanoscale experimental probe, weak signal from ordering, and radiation damage to the sample. By collecting nanodiffraction patterns with a high dynamic range pixelated detector, we acquired statistically robust, high signal-to-noise ratio diffraction patterns from semiconducting organic materials, including poly(3-hexylthiophene-2,5-diyl) (P3HT), P3HT/[6,6]-phenyl C61 butyric acid methyl ester, and indacenodithiophene-co-benzothiadiazole (IDTBT), which largely have disordered structures. Real-space images of the ordered domains were reconstructed from the 4D-STEM data set for a variety of scattering vectors and in-plane angles to capture the different molecular stacking distances and their in-plane orientation. These were then analyzed to obtain the average size of the ordered domains within the sample. Such measurements were arranged in a two-dimensional (2D) histogram, which showed a direct relationship between the type and size of molecular ordering. Complementary analyses, such as intensity variance and angular correlation, were applied to obtain ordering and symmetry information. These analyses enabled us to directly characterize the alkyl and π-π stacking of P3HT, as well as the fullerene domains caused by donor segregation in the P3HT sample. Furthermore, the analysis also captured changes in the P3HT domains when the fullerenes are incorporated. Lastly, IDTBT showed a much lesser degree of ordering without much disinclination between the domains within the 2D histogram. The 4D-STEM analysis that we report here unveils new details of molecular ordering that can be used to optimize the properties of this important class of materials.

Impact of Deposition Temperature on Structural and Electrical Properties of Sputtered AlN/ Si (111) for CMOS compatible MEMS

Aluminium nitride (AlN) thin films are grown by reactive sputtering on Silicon (Si) with (111) orientation at low temperature (< 450 °C) for piezoelectric-based micro-electromechanical systems (MEMS). The grown AlN thin films were polycrystalline wurtzite hexagonal structure with a high texture coefficient for the (002) plane of orientation. The leakage current density by the current-voltage (I-V) measurement was found to be as low as 1.6 ×10-6Acm−2 in the grown films. The trapped charges are crucial in controlling these electrical characteristics, and low interface trap density (6.72 ×1010cm−2 eV) was observed for the sputtered AlN grown at a substrate temperature of 300 °C. This study on the structural and electrical properties of AlN/Si (111) at low substrate temperature is compatible with the complementary metal oxide semiconductor (CMOS) process for constructing piezoelectric-based MEMS devices for various applications.

In-plane and out-of-plane domain orientation dispersions in 1 to 3 monolayers epitaxial WS2 and MoS2 films on GaN(0001) film/sapphire(0001)

Transition-metal dichalcogenides and their heterostructures have attractive potential applications in electronics and optoelectronics. Wafer scale 1 to 3 monolayers WS2 and MoS2 ultrathin films on GaN/sapphire substrates were grown by metal organic chemical vapor deposition. Azimuthal reflection high-energy electron diffraction (ARHEED) was used to characterize the long-range order of these TMDC ultrathin films. The RHEED patterns of WS2 and MoS2 show stripes and arcs but the MoS2 on GaN shows sharp spots in addition to stripes and arcs. The 2D map constructed from ARHEED patterns shows that WS2 is epitaxial and has an in-plane domain orientation dispersion. For the MoS2 on GaN/sapphire substrate, the 2D map shows concentric continuous rings for each diffraction order of MoS2 and GaN indicating that the in-plane MoS2 domain orientation and GaN nanocrystals are random. The out-of-plane orientation dispersion of MoS2 on the GaN substrate is larger than that of WS2 on the GaN substrate. The observations of stripes, arcs, and spots from RHEED patterns and the 2D maps reveal the deviation of ultrathin epitaxial films from its perfect epitaxy, especially the TMDC domain orientation dispersion over a large area. These rich findings from 2D maps broaden the application of ARHEED in more than one monolayer thick 2D materials.

Sky localization of space-based detectors with time-delay interferometry

The accurate sky localization of gravitational wave (GW) sources is an important scientific goal for space-based GW detectors. The main differences between future space-based GW detectors, such as Laser Interferometer Space Antenna (LISA), Taiji, and TianQin, include the time-changing orientation of the detector plane, the arm length, the orbital period of the spacecraft and the noise curve. Because of the effects of gravity on three spacecraft, it is impossible to maintain the equality of the arm length, so the time-delay interferometry (TDI) method is needed to cancel out the laser frequency noise for space-based GW detectors. Extending previous work based on equal-arm Michelson interferometer, we explore the impacts of different first-generation TDI combinations and detector's constellations on the sky localization for monochromatic sources. We find that the sky localization power is almost unaffected by the inclusion of the TDI Michelson (X, Y, Z) combination in the analysis. We also find that the variation in the sky localization power for different TDI combinations is entirely driven by the variation in the sensitivities of these combinations. For the six particular TDI combinations studied, the Michelson (X, Y, Z) combination is the best for source localization.

Optimization of Bioactive Compounds Extraction from Platanus Orientalis Leaves using Microwave-Assisted Technique

Optimization of Bioactive Compounds Extraction from Platanus Orientalis Leaves using Microwave-Assisted Technique

Deep‐Focus Earthquake Mechanisms at the Subducting Nazca Plate (Peru‐Brazil Border): Cold Slab Behavior in a Warm Plate

AbstractWe calculate focal mechanisms and centroid depths for deep‐focus earthquakes (DFEs) along the Peru‐Brazil border. We obtained a total of 28 focal solutions for events with magnitudes between 4.2 and 7.5 Mw and occurring between 2014 and 2022. Focal mechanisms indicate predominance of normal faulting, demonstrating a rather uniform down‐dip compression (DDC) regime within the plate. The orientations of the nodal planes suggest that earthquakes tend to occur along faults parallel to the local slab strike, although other fault types are documented. Stress orientations derived from the focal mechanisms agree with patterns expected if faulting were initiated by transformational faulting on a metastable olivine wedge (MOW) under DDC. Centroid depths range between 557 and 659 km, defining a narrow seismic zone within the lower portion of the subducting plate and an aseismic upper portion. We suggest that DFEs nucleate through transformational faulting within a narrow MOW preserved at a colder slab segment right above the lower mantle and juxtaposed to a shallower, warmer segment at around 500 km depth. This thermal complexity was possibly produced through flat subduction initiated by the subduction of the Nazca Ridge. We speculate that subduction of other aseismic ridges is possibly controlling the thermal state of the Nazca slab as a whole and, consequently, the depth distribution of DFEs along the South America subduction front.

Utilization of organic waste from Chinar leaves as sustainable and eco-friendly adsorbent for fluoride removal.

Due to concerns about high water fluoride concentrations and their detrimental consequences on health, particularly dental and skeletal fluorosis, dependable and cost-effective defluoridation techniques are needed. Chinar leaves (Platanus orientalis), a common waste, might be utilized for the production of activated carbon. For Chinar leaf activated carbon (CLAC) manufacturing, two pre-pyrolysis chemical modification procedures were used: acidic HCl (H-activation) and alkaline NaOH (OH-activation). The success of fluoride removal suggests further research and implementation in locations with fluoride-related water quality issues. This study examines how CLAC dosage, fluoride concentration, temperature, pH, and contact exposure effect defluoridation efficiency. The pseudo-second-order non-linear kinetic model and Freundlich non-linear isotherm model with R2 = 0.99 fit the data, resulting in a peak adsorption capacity of 30.3mg/g for 0.3g CLAC. In the present work, the adsorption mechanism was regulated by more than intraparticle diffusion. Adsorption occurred spontaneously as exothermic monolayer chemisorption, according to thermodynamic studies. Adsorbent activated with HCl (H-activated) showed promising results, with 73% F- removal efficiency for OH-activated and 91% for H-activated CLAC.