Addition Of Plasticizer Research Articles

The Influence of the Solid Phase on the Properties of Foam Concrete

An overview of literary sources related to the formation and development of the technology of aerated concrete is given. It is shown and systematized in which directions scientific research aimed at improving their functional properties was conducted. It is noted that almost all researchers associate the dependence of the properties of porous concrete with the character of their porosity. The conducted analysis allowed the authors to hypothesize that the properties of aerated concrete are exclusively determined by the nature of the distribution of the solid phase, that is, by the nature of its structure. Determination of the influence of the solid phase and its nature on the properties of aerated concrete is devoted to experimental studies. They were conducted in two stages. At the first, when applying physical modeling, the effect of the total porosity and water consumption of the dry mixture on the change in the nature of the solid phase of the model was studied. Internal interfaces between structural elements are taken as characteristics of the solid phase - their total length and width. It is shown that the water consumption of the mixture has different effects on materials with a dense and porous structure. At the next stage of experimental research, the influence of the water consumption of the mortar mixture on its strength (strength of the matrix material) and the strength of foam concrete was studied. The initial rheological conditions of the formation of the structure were changed by changing the size and amount of filler, changing the amount of liquid and plasticizing additives. The results of the experiments confirmed that the initial rheological conditions have different effects on the materials of dense and porous structure. Under certain conditions, in materials with a porous structure (in foam concrete), an increase in the water-solid ratio leads to an increase in the strength of concrete. Which indicates that with such water consumption, more favorable conditions are created for the formation of a porous structure, which is reproduced on the character of the solid phase. The given results confirm the given hypothesis and can be used in the synthesis of new building materials, including with the use of artificial intelligence.

Progress in the Study of Occurrence, Distribution, Material Flows, and Environmental Release of Substances of Very High Concern （SVHCs） in Plastics

Plastic additives provide plastics with excellent functions such as plasticizing, flame retardant, and antioxidant properties and are widely used in various plastics. Of these, 189 plastic additives have been included in the European Union's Candidate List of substances of very high concern （SVHCs） due to their potential environmental and health risks. These SVHCs are mainly used in PVC, PUR, and PE plastics and in the packaging, automotive, construction, electronic and electrical equipment, and textile sectors. Plasticizers and flame retardants are the most widely used and therefore the focus of SVHC risk assessment and risk management. Existing studies have carried out material flow analysis （MFA） for SVHCs in plastics, revealing the environmental and health risks of typical flame retardants and plasticizers throughout the product life cycle, such as polybrominated diphenyl ethers （PBDEs）, hexabromocyclododecane （HBCD）, and phthalic acid esters （PAEs）. A large amount of SVHCs enter waste streams at the end of the product life cycle, highlighting the importance of strengthening waste management for SVHCs risk management. In addition to the release of SVHCs from plastic products into the environment, plastic leakage is another important source of environmental release of SVHCs. Plastic debris that have been in the environment for a long time continue to release SVHCs and pose a long-term threat to the ecosystem and human health. In the future potentially hazardous chemicals must be crucially identified in different types of plastics and to assess their environmental release during their life cycle, in particular by establishing a database on hazardous chemicals in plastics and measuring emission factors, optimizing dynamic material flow analysis （d-MFA）, as well as studying the release mechanisms of hazardous chemicals from plastic leakage.

Phthalates Induced Neurotoxicity: A Mechanistic Approach.

Phthalates play a significant role as plastic modifying additives in everyday items like plastics, pesticides, paints, and cosmetics. This review explores the relationship between phthalates and neurotoxicity and sheds light on the potential risks these ubiquitous chemicals pose to neurological health. The review elucidates the diverse neurotoxic effects of phthalates exposure, spanning developmental neurotoxicity, neuropathy, neurodegenerative diseases, and neurobehavioral toxicity. Mechanistic insights reveal the pathways through which phthalates induce cellular damage, including oxidative stress, disruption of calcium signalling, alteration in lipid metabolism, and interference with thyroid hormone homeostasis. Moreover, the review discusses regulatory measures aimed at restricting phthalate usage and highlights the imperative for further research and awareness to safeguard public health against the neurotoxic effects of phthalates.

Mechanical Properties and Fire Resistance of 3D-Printed Cementitious Composites with Plastic Waste

The study focuses on the development of cementitious composites using 3D printing and plastic waste as a sustainable aggregate substitute. This study involves experimenting with various percentages of plastic waste as a partial substitute for ground granulated blast furnace slag (GGBFS) in a control mix. The study examines the anisotropy of the 3D printing process, comparing it with properties of mold-cast samples. In addition, it assesses the fire resistance and mechanical properties of samples at elevated temperatures (100 °C, 300 °C, and 600 °C). Key mechanical properties, including 28-day compressive stress and flexural strength, are determined through experimental testing using a standard compression test and three-point bending test. The study also considers the modulus of elasticity (MOE) in compressive tests to evaluate a sample’s ability to deform elastically and the flexural toughness index to assess energy absorption and crack resistance of flexural samples. Following the experimental testing, the study’s key findings suggest that significant mass loss occurred at 300 °C and above, with plastic samples demonstrating increased mass loss at 600 °C. At 600 °C, plastic degradation led to the formation of voids and cracks within samples due to heightened internal pressure. Anisotropy was evident in 3D-printed samples, with loads parallel to the layer direction resulting in greater compressive strength and MOE. Furthermore, layer direction parallel to the longitudinal axis of flexural samples yielded higher flexural strength and flexural toughness. Mold-cast samples displayed superior compressive strength and stiffer behavior, with higher MOE compared to 3D-printed samples. However, 3D-printed plastic samples exhibited superior flexural strength compared to mold-cast samples, attributed to the alignment of plastic within the samples. The study also observed a reduction in compressive strength with the addition of plastic, explained by the poor bonding of plastic with cement due to its hydrophobic nature. Despite this, flexural strength generally improved with plastic addition, except at 600 °C, where plastic samples showed significant degradation in both compressive and flexural strength due to plastic degradation within the samples.

Gas check prevention during calendering of poly(vinyl chloride) films using poly(caprolactone)‐based additives

AbstractGas checks on poly(vinyl chloride) (PVC) calendered films are a common but not well understood surface quality defect that causes delays and resource wastage during the manufacturing of plastic sheets and films. Three modified poly(caprolactone) (PCL)‐based additives of differing molecular weights were used as a secondary plasticizer in PVC with the goal of preventing the formation of gas checks without modifying the calendering process conditions. To better understand gas check prevention processes, the effects of the PCL‐based additives on the thermal, mechanical, rheological, and chemical properties of PVC blends were assessed. A high molecular weight (2000 g/mol) PCL‐based additive was unable to prevent gas checks in PVC blends, unlike the lower molecular weight (540 g/mol and 900 g/mol) additives. Chemical and physicochemical properties affect the prevention or reduction of gas checks showing that the acid values and molecular weights of the PCL‐based additives are related to the number of gas checks. In contrast, physical properties, including rheological ones like complex viscosity or the storage and loss moduli that were previously hypothesized to be important factors in preventing gas check formation, were not significantly impacted by the addition of the secondary plasticizer. Furthermore, the acid value was observed to be related to the reduction in gas checks, likely due to the interaction of the dispersed functional acid groups with the entrapped air. Consequently, the effectiveness of the additive in eliminating gas checks declines as the acid value decreases.Highlights Low concentrations of PCL‐based additives prevent gas checks on PVC films. They do not significantly affect the physical/mechanical properties of films. Higher molecular weight additives are beneficial, but only below 2000 g/mol. The effectiveness of PCL‐based additives increases with acid value.

Selective solvothermal extraction of tetrabromobisphenol A to promote plastic recycling

Removal of brominated flame retardants (BFRs) is imperative for increasing the recycling rate of hazardous plastic waste. In mechanical recycling, BFRs should be removed without damaging the surrounding polymer matrix, but economically viable processes under mild conditions are still rare. In this study, tetrabromobisphenol A (TBBPA) was solvothermally extracted from a compounded high-impact polystyrene (HIPS, 2500 ppm Br) model sample in an autoclave using mixtures of water, isopropanol (IPA) and NaOH as solvents. Removal of total elemental bromine was analyzed with X-ray fluorescence (XRF), whereas the removal of TBBPA and other plastic additives was evaluated with direct insertion probe mass spectrometry (DIP-MS). IPA/NaOH extraction provided efficient bromine removal, but it also extracted plenty of other plastic additives, including phenolic stabilizers Irganox 1076 and Cyasorb UV-2908. The inclusion of water in the IPA/NaOH mixture shifted the extraction selectivity towards TBBPA, leaving most of the other additives unaffected. Furthermore, H2O/IPA/NaOH was found to be equally effective in removing TBBPA from the samples with bromine concentrations an order of magnitude higher (25,000 ppm). Yet, larger plastic particle size hindered the extraction efficiency. 1H NMR and size exclusion chromatography confirmed that the HIPS matrix was left unaffected after all the studied extractions. Additionally, DIP-MS was found to be a valuable characterization method for assessing the removal and decomposition of various additives from solid plastic samples with minimal sample preparation. Overall, the results presented herein offer a target-selective extraction processes under relatively mild conditions for further advancing the mechanical recycling of plastics.

Putative signaling pathways for contraction and its recovery from DEHP arrest in Hymeniacidon heliophila

With sessile habits, sponges (phylum Porifera) are susceptible to marine pollution impacts and recently microplastics were identified as one source of contamination. Microplastics have a physical impact on filtration rates and plastics additives such as di(2-ethylhexyl)phthalate (DEHP), a ubiquitous marine contaminant, were already identified in their tissues indicating bioaccumulation. However, few studies assessed the impacts of such compounds in its physiology. One verified effect of phthalate exposure is the arrest of the contraction cycles observed in the sponge Hymeniacidon heliophila. In this work, proteomics of DEHP exposed organisms of this species was performed to identify modifications in signaling pathways that could lead to this arrest and recovery. The results indicate that exposed organisms had different expressed 5HT receptors, associated to intracellular calcium signaling, the principal pathway to contraction animals. The Myosin Light-Chain Kinase (MLCK) pathway is detected only in exposed organisms as well as components linked to binding of organic cyclic compounds. Results show that for healing from DEHP exposure, H. heliophila may activate an alternative contraction signaling pathway, the MLCK pathway. These coordinate mechanisms could restore contractions in H. heliophila after acute exposure to DEHP. SynopsisResearch into the impact of microplastics on organisms uses animal models known to science such as mussels. In our work, we tested the effects of a plastic additive, DEHP, on the physiology of a much less studied marine organism: sponges.

Recycling of Post-Consumer Waste Polystyrene Using Commercial Plastic Additives

Recycling of Post-Consumer Waste Polystyrene Using Commercial Plastic Additives

Stress indicators in conservative tissues of Humboldt penguin under captivity

Humboldt penguins (Spheniscus humboldti) from the Barcelona zoo (n=9) were followed to assess their physiological stress status using conservative protocols. Corticosterone levels were measured in feathers and plasma as indicative of chronic and acute physiological stress, respectively. Other markers: B-esterases, potentially indicative of xenobiotic exposure were measured in plasma of these same individuals and reported for the first time in this species. The sensitivity to chemicals of environmental concern, employed as plastic additives, was assessed in vitro with plasma of this species using the inhibition of carboxylesterase (CE) and acetylcholinesterase enzymatic measurements. Among the tested additives, the organophosphorus flame retardants displayed the highest in vitro inhibitory potential on basal CE activity, suggesting their potential utility as biomarkers of this particular chemical class. Additionally, enzymatic measurements in plasma are determined for the first time in Humboldt penguin and can be regarded as baseline values for a potential field monitoring application.

Disentangling mechanisms by which microplastic films affect plant-soil systems: physical effects of particles can override toxic effects of additives

BackgroundMicroplastics, polymer-based particles < 5 mm, affect plant–soil systems positively or negatively, suggesting there are different modes of action. Microplastics, as particles, have physical effects but the leaching of additives likely contributes chemical mechanisms, both of which may be dependent on microplastic size. To disentangle such mechanisms, we established a controlled experiment involving polypropylene and polyethylene films of small, medium and large size, and we evaluated the individual and combined effect of plastic particles and additives (leachates from plastic particles) on soil properties and plant performance of the phytometer Daucus carota and on bare soils.ResultsWe find that additives better explained variation in soil properties (e.g., 44.6% vs 1.3%). Soil respiration and aggregation were negatively affected for additives, likely due to the presence of toxic substances. Overall, such effects increased as plastic size decreased. By contrast, plastic particles better explained plant biomass responses. The positive effect of particles on aeration which may promote root penetration and nutrient uptake, and microplastics itself as a source of carbon potentially promoting soil microbial activity, help explain the positive effect of particles on plant biomass. Plants mitigated the negative effects of additives on bare soils while enhancing the positive effects of particles. This improvement was likely linked to an increase in root activity and rhizodeposition, as plastic particles improved soil aeration. The combined effect of additives and particles, which mimics the microplastic found in the soil, mitigated their individual negative effects on plant–soil systems. As the negative effect of additives could have been masked by the positive effects of particles, simply reporting net positive effects would capture only part of the response.ConclusionsAdditives and plastic particles differently affect soil properties and plant biomass. Additives primarily negatively affect soil properties due to toxic substances, while plastic particles enhance plant biomass likely by improving soil aeration. When examining microplastics effects on terrestrial systems (i.e., the combined effect of additives and particles), the negative effect of additives may be masked by the positive effects of plastic particles. Reporting only net positive effects risks overlooking these underlying negative effects. Plants can mitigate the negative impacts of additives and amplify the positive effects of plastic particles. Our study emphasizes the importance of investigating both the individual and combined effects of additives and particles to fully understand and address the impacts of microplastics on terrestrial ecosystems.

Metal heteroatoms significantly enhance efficacy of TiO2 nanomaterials in promoting hydrolysis of organophosphates: Implications for mitigating pollution of plastic additives

Organophosphate esters (OPEs) are prevalent pollutants in the aquatic environment. OPEs are released from many sources, particularly, from the breakdown and weathering of plastic wastes, as OPEs are commonly used plastic additives. Metal oxide mineral nanoparticles play critical roles in the hydrolytic transformation of OPEs. While natural minerals often contain metal impurities, it is unclear how metal heteroatoms affect the efficiency of mineral nanoparticles in mediating hydrolysis reactions. Herein, we show that transition metal-doped anatase titanium dioxide (TiO2) nanomaterials are more effective in catalyzing the hydrolysis of 4-nitrophenyl phosphate (pNPP), a model OPE compound, with the relative effects of the heteroatoms following the order of Fe > Cr > Mn ≈ Ni > Co > Cu. With multiple lines of evidence based on spectroscopic analysis, kinetics modeling, and theoretical calculations, we show that metal doping increases the Lewis acidity of the TiO2 nanomaterials by increasing the oxidation state of surface Ti atoms, inducing oxygen vacancies, and creating additional Lewis acid sites with stronger acidities. Moreover, the increased amounts of surface hydroxyl groups due to metal doping enhance inner-sphere complexation of pNPP through ligand exchange. The interesting observation that Fe-doped TiO2 exhibited the highest catalytic efficiency may have important implications for reducing the risks of organophosphate plastic additives, as iron is the most common heteroatom of naturally occurring TiO2 (nano)materials.

Characterization of Chemical Exposome in A Paired Human Preconception Pilot Study.

Parental preconception exposure to synthetic chemicals may have critical influences on fertility and reproduction. Here, we present a robust LC-MS/MS method covering up to 95 diverse xenobiotics in human urine, serum, seminal and follicular fluids to support exposome-wide assessment in reproductive health outcomes. Extraction recoveries of validated analytes ranged from 62% to 137% and limits of quantification from 0.01 to 6.0 ng/mL in all biofluids. We applied the validated method to a preconception cohort of Australian couples (n = 30) receiving fertility treatment. In total, 36 and 38 xenobiotics were detected across the paired biofluids of males and females, respectively, including PFAS, parabens, organic UV-filters, plastic additives, antimicrobials, and other industrial chemicals. Results showed 39% of analytes in males and 37% in females were equally detected in paired serum, urine, and reproductive fluids. The first detection of the sunscreen ingredient avobenzone and the industrial chemical 4-nitrophenol in follicular and seminal fluids suggests it can cross both blood-follicle/testis barriers, indicating potential risks for fertility. Further, the blood-follicle transfer of perfluorobutanoic acid, PFOA, PFHxS, PFOS, and oxybenzone corroborate that serum concentrations can be reliable proxies for assessing exposure within the ovarian microenvironment. In conclusion, we observed significant preconception exposure to multiple endocrine disruptors in couples and identified potential xenobiotics relevant to male and female fertility impairments.

Evaluating microplastic particles as vectors of exposure for plastic additive chemicals using a food web model

Microplastic particles (MPs) represent potential hazards for humans and wildlife, including as vectors for chemical exposure (e.g. plastic additives and pollutants sorbed from the surrounding environment). The leaching of chemicals from MPs has been identified as a potential exposure pathway but the relative magnitude of this pathway under environmentally relevant conditions remains unclear. Here, we describe a modification of the ACC-HUMANSTEADY bioaccumulation model to include dietary exposure to MPs containing either accumulated chemicals from the surrounding environment or embedded plastic additive chemicals (PACs). Chemical transfer to humans and wildlife is described using two-film resistance concepts assuming spheroidal particles of different sizes. The relative contribution of MPs and environmental media to the estimated daily chemical intake in humans was assessed in various exposure scenarios, for a range of hypothetical chemicals with varying octanol-water and air-water partition coefficients (KOW and KAW, respectively; i.e. 0 < log KOW <8 and − 5 < log KAW < 3). Results imply that MPs could act as sources of exposure to chemical additives when the ingestion rate of 1 μm MPs is ≥ 10 mg d− 1, and the concentration of hydrophobic plastic additive is ≥ 5% wt wt− 1. The contribution made by MPs as vectors of exposure decreased with increasing particle size and decreasing ingestion rates of MPs. Human health risks were evaluated for four specific PACs to illustrate the application of the model for risk assessment. Risks were negligible when the ingestion rate of MPs was < 100 μg d− 1. Uncertainties are high regarding the characterization and quantification of ingestion of MPs by humans and wildlife, including particle sizes and polymer composition, as well as on the presence of PACs in MPs. These data gaps need to be addressed if the issue of MPs as vectors of chemical exposure is to be fully understood. The work illustrates that mechanistic models, which account for all major exposure pathways, can be used to identify the importance of different exposure pathways, help prioritize research needs and support decision making.

Empirical and statistical investigation of injection molded Enset–PLA biocomposites’ characteristics in response to impact loading

This paper incorporates characteristics of Enset reinforced Poly lactic Acid biocomposite in response to impact loading. In this study fiber ratio, fiber size, plasticizer amount and fiber age are considered as a factor affecting its impact strength. Analytical and statistical approaches are employed to analyze the abovementioned characteristics; JMP 13 pro software and Python programing are used during the statistical analysis. The result showed that addition of plasticizer up to 6 % to pure PLA continuously increases impact strength and decline happens afterward. The statistical analysis result also revealed that fiber ratio is correlated best with the impact strength with feature importance value of 0.5168 followed by plasticizer amount with feature importance value of 0.0484. It was also witnessed that, by adding fibers to a PLA containing 6 % plasticizer, the impact strength of pure PLA can be enhanced up to 19 % and the maximum impact strength achieved for 25 % fiber containing Enset-PLA composite. The findings show the promising potential of Enset-PLA biodegradable composite with good impact properties, making it suitable for applications in automotive interiors, such as dashboards. Also, the study finds the optimal plasticizer ratio, easing compounding and injection molding without a major degradation of material properties.

Influence of bisphenol A concentration on organic matter removal and nitrification in biological wastewater treatment

Microplastics and plastic additives have become ubiquitous in our environment, posing a major challenge to wastewater treatment processes. This study investigated the impact of Bisphenol A (BPA), a common plastic additive, on the efficiency of organic matter removal and nitrification in biological wastewater treatment. The obtained results indicated that a BPA concentration of 10 mg·L−1 in the influent affected the Chemical Oxygen Demand (COD) in the effluent. In comparison, concentrations of 1 or 5 mg·L−1 did not show such noticeable differences. Additionally, an increase in BPA load inhibited the nitrification process, resulting in a high concentration of nitrogen in its ammoniacal form in the effluent when the BPA concentration was increased to 10 mg·L−1. In fact, the microbial community analysis revealed a considerable reduction of Nitrosomonas in the reactor fed with wastewater containing 10 mg·L−1 of BPA. Despite compromising the nitrification process, this situation did not deprive the biomass of its ability to remove BPA from the system, as this component was not detected in the effluent once the microorganisms completed their adaptation process. 16 S rRNA gene sequencing showed that the predominant phyla across all samples were associated with Proteobacteria, Bacteroidota, Patescibacteria and Actinobacteriota, similar to previous studies.

Evaluation of char properties from co-pyrolysis of biomass/plastics: effect of different types of plastics

Co-pyrolysis of biomass/plastics is a viable method to obtain high-quality carbon materials. The synergistic effect in the char production process of co-pyrolysis of biomass/plastics affects the properties of the obtained char. However, the synergistic effect research on the char production process of co-pyrolysis of biomass/plastics is facing challenges owing to highly varying composition of different plastics. In this study, the synergistic effect during co-pyrolysis of bamboo (BM) and plastics (polypropylene (PP), polystyrene (PS), polyethylene terephthalate (PET), polycarbonate (PC), and polybutylene terephthalate (PBT)) was investigated. TG results showed that PP, PS, PET, and PBT promoted the release of biomass volatiles and increased co-pyrolysis char yield. Notably, the O-aromatic structure in PC underwent cleavage and deoxygenation reactions, inhibiting the production of co-pyrolysis char during co-pyrolysis process. Char yield from co-pyrolysis process decreased from 24.80% for bamboo pyrolysis to 15.74% for co-pyrolysis of bamboo/PC. The results of physicochemical tests on char samples indicated that the addition of polyhydrocarbon plastics (PP and PS) increased H/C ratio, O/C ratio, heating value and oxidative reactivity of the char compared to bamboo char due to the vapor deposition of hydrocarbons derived from thermal decomposition of plastics on the biomass char. While, co-pyrolysis of biomass and polyester plastics (PET, PC, PBT) improved the pore structure of char and increased oxygen content.

Inverse vulcanized sulfur-styrene polymers as effective plasticizers for polystyrene

Inverse vulcanized polymers have demonstrated significant potential as alternatives to conventional petrochemical polymers in various applications, including environmental remediation, where they are used to absorb heavy metals and pollutants from water and soil, and energy devices, such as in the development of high-capacity lithium-sulfur batteries. Despite their promise in these areas, the full application scope of these sulfur-based polymers remains unexplored. There is substantial potential for their use in other fields, such as advanced material coatings, medical devices, and as additives to improve the properties of existing polymers, yet these possibilities have not been thoroughly investigated. This study presents a sulfur-based polymer, synthesized via the inverse vulcanization of sulfur and styrene and partially crosslinked with divinylbenzene, as a novel plasticizer for polystyrene (PS). This polymer blend was prepared using an internal mixer to replace conventional organic-based plasticizers. The selected system was designed to maximize miscibility. Both virgin and plasticized PS were injection molded for comprehensive characterization. Differential Scanning Calorimetry (DSC) confirmed the complete consumption of sulfur, revealing a significant reduction in the glass transition temperature of PS upon the addition of the sulfur-based plasticizer. Morphological analysis showed a homogeneous surface with uniform single-phase morphology, indicating full miscibility of the blend. Tensile tests demonstrated enhanced ductility and reduced stiffness in plasticized PS, with strain at maximum tensile strength and elongation at break increasing by 22.0 % and 28.1 %, respectively. The plasticizer also improved the toughness of PS by 25.2 %. Rheological assessments corroborated the plasticization effect and confirmed the blend's full miscibility. Contact angle measurements indicated increased hydrophilicity of the plasticized PS samples. This newly developed sulfur-based plasticizer proved to be highly effective for PS, showcasing competitive efficiency comparable to commercial plasticizers. This advancement paves the way for new applications in the expanding field of sulfur-based polymers.

A multidisciplinary perspective on the role of plastic pollution in the triple planetary crisis

In this perspective paper, we discuss the negative impacts of plastics and associated chemicals on the triple planetary crisis of environmental pollution, climate change and biodiversity loss from a multidisciplinary perspective. Plastics are part of the pollution crisis, threatening ecosystems and human health. They also impact climate change and accelerate biodiversity loss; in this, they aggravate the triple planetary crisis. We analyze the scientific state-of-the-art to identify critical knowledge gaps regarding the life cycle, release, fate, exposure, hazard and governance of plastics and associated chemicals, as well as links to climate change and biodiversity loss. Based on the outcome, we derive key research needs for a comprehensive hazard assessment of plastics and associated chemicals, amongst others, to address the largely missing regulation of plastic additives and in-use plastics. We offer a holistic perspective bridging disciplinary expertise from natural and social sciences to achieve effective plastic governance and risk management of plastics and associated chemicals that protect the Earth, its ecosystems and human health from the plastics crisis.

The Influence of the Type and Concentration of Plasticizer on the Properties of Biopolymer Films based on Wild Flax (Camelina Sativa)

The development of biodegradable packaging materials using naturally occurring, renewable biopolymers has gained attraction due to consumer demand for high-quality products and concerns about environmental waste problems. However, the inferior mechanical properties and low water resistance of packaging materials based on natural polymers pose a significant obstacle to their wider use. One of the ways to improve the properties of biopolymer-based packaging materials is the addition of plasticizers during their synthesis. In this work, the influence of the type and concentration of plasticizer on the properties of new biopolymer films based on wild flax (Camelina sativa) was investigated. Camelina sativa oil cake (CSoC) remains after edible oil cold pressing as a by-product. One of the possibilities for its valorization is the synthesis of biopolymer materials. During the synthesis, different plasticizers - glycerol and polyethylene glycol 400 - were added in different concentrations - 20%-60%. The obtained CSoC-based biopolymer films were analyzed for the following properties: Moisture content, solubility, thickness, tensile strength, elongation at break, and water vapor permeability. The results obtained showed significant differences when different plasticizers were applied at different concentrations. The biopolymer film with optimal properties was obtained by adding glycerol at a concentration of 40%.

Rapid Generation of Microplastics and Plastic-Derived Dissolved Organic Matter from Food Packaging Films under Simulated Aging Conditions.

In this study, we show that low-density polyethylene films, a prevalent choice for food packaging in everyday life, generated high numbers of microplastics (MPs) and hundreds to thousands of plastic-derived dissolved organic matter (DOM) substances under simulated food preparation and storage conditions. Specifically, the plastic film generated 66-2034 MPs/cm2 (size range 10-5000 μm) under simulated aging conditions involving microwave irradiation, heating, steaming, UV irradiation, refrigeration, freezing, and freeze-thaw cycling alongside contact with water, which were 15-453 times that of the control (plastic film immersed in water without aging). We also noticed a substantial release of plastic-derived DOM. Using ultrahigh-resolution mass spectrometry, we identified 321-1414 analytes with molecular weights ranging from 200 to 800 Da, representing plastic-derived DOM containing C, H, and O. The DOM substances included both degradation products of polyethylene (including oxidized forms of oligomers) and toxic plastic additives. Interestingly, although no apparent oxidation was observed for the plastic film under aging conditions, plastic-derived DOM was more oxidized (average O/C increased by 27-46%) following aging with a higher state of carbon saturation and higher polarity. These findings highlight the future need to assess risks associated with MP and DOM release from plastic wraps.