The shock response of anti-hydrogen steel (HR-2) and iron was studied in a series of laser-driven shock wave experiments. A line-imaging optical recording velocity interferometer system for any reflector was used to record the free surface velocity histories of shock loaded samples, 100–300 \(\upmu \hbox {m}\) thick and with an initial temperature ranging from 296 to 1073 K. Based on the recorded free surface velocity profiles, the elastic precursors, dynamic yield and tensile (spall) strengths of HR-2 and iron were calculated. The dependence of the measured HEL stresses on the propagation distance for HR-2 and polycrystalline iron is approximated by a power law relationship.But, that for the single crystal iron with orientation of (110) seems to be constant. Spall strengths \((\upsigma _{\mathrm{sp}})\) of HR-2 estimated from the magnitude of the pull-back signal show that the spall strength dependence on the strain rate \((\dot{\upvarepsilon })\) is approximated by a power law relationship \(\upsigma _{\mathrm{sp}} =0.24\left( \dot{\upvarepsilon } \right) ^{0.24}\,\left( {\hbox {GPa}} \right) \). The spall strength of HR-2 and single crystal iron at the initial temperatures of 296–1073 K decreases slightly with increasing temperature and that of poly crystal iron abnormally increases at a temperature of 873 K. The X-ray diffraction results on the recovered poly crystal samples indicate significant changes in the relative peak intensity and the change in the crystal orientation may be the reason for the abnormal increasing at 873 K. The spall fracture surfaces of HR-2 were observed using a 3D laser scanning confocal microscope. The spall surface contains many dimples, suggesting that the fracture mode is that of ductile fracture. At ambient temperatures, the dimples and crowns were evenly distributed at the fracture surface. At high temperatures, many large crowns appeared and were unevenly distributed at the fracture surface.