Plasma Pretreatment Research Articles

Development of cold plasma pretreatment ultrasound-assisted extraction for enhancing phenolic acids extractability from Salvia sclarea

This research aimed to investigate the effect of cold plasma pretreatment on the ultrasound-assisted extraction of phenolic acids from the Salvia genus. In this study, Salvia sclarea L., a member of the genus, was selected as a source of phenolic acids. First, the powdered aerial parts of the plant were treated with cold plasma generated at atmospheric pressure, followed by ultrasound-assisted extraction of phenolic acids. These acids were then identified and quantified using HPLC analysis, and the results were compared with those from non-treated extracts. The findings revealed a significant increase in the total phenolic acid content in the treated extract, with values of 55.92 mg/g compared to 28.70 mg/g in the non-treated extract. Notably, salvianolic acid B and salicylic acid showed substantial increases, approximately 4 and 2 times higher, respectively, in the treated extract. Based on these results, cold plasma pretreatment effectively enhanced the yield of phenolic acids, which holds promise for industrial and large-scale applications. SEM images further illustrated the impact of cold plasma on plant materials, supporting the observed increase in phenolic acid content. These findings suggest that cold plasma pretreatment is an efficient, eco-friendly, and cost-effective method for improving phenolic acid extraction from plant materials

Pulsed N2 plasma surface treatment for AlGaN/GaN HEMTs prior to PECVD SiNx passivation to reduce plasma damage

In this work, a pulse-mode N2 plasma surface treatment process was proposed as a means of reducing plasma damage and improving the GaN/GaOx ratio on the surface before SiNx deposition, which further contributes to an enhanced density of 2DEG and a reduced sheet resistance. With the pulsed N2 plasma surface treatment combined with subsequent SiNx passivation, the fabricated GaN HEMTs exhibit negligible current collapse and suppressed leakage current. The improved behavior is attributed to the fact that the pulsed N2 plasma is capable of nitriding the surface and removing carbon contaminants as identified through x-ray photoelectron spectroscopy and energy dispersive x-ray spectroscopy. Compared to the traditional continuous-wave-mode N2 plasma, the pulsed N2 plasma pre-treatment effectively prevents continuous collisions of the plasma during acceleration, thereby significantly reducing plasma damage. This work offers valuable insights for surface treatment processes in micro- and nanofabrication.

Glycerol Vapor Assisted Cu Direct Bonding: Implications for 3D Semiconductor Packaging

AbstractAs the scaling down of semiconductor devices reaches its physical limits, 3D stacking packaging technology is emerging as a new miniaturization solution. Among the various 3D packaging technologies, Cu direct bonding is widely adopted due to copper's excellent electrical conductivity and the absence of intermetallic compounds for solder bumps. Since copper readily undergoes oxidation, technologies that prevent Cu surface oxidation during Cu direct bonding are essential. However, current research suggests that the methods require additional pretreatment processes, which demand high costs. In this study, a Cu direct bonding method utilizing glycerol vapor is developed to effectively streamline the pretreatment steps. The potential of glycerol as a reducing agent and antioxidant for Cu is demonstrated using a silicon die sample with a size of 10 × 10 mm2, verified through the X‐ray photoelectron spectroscopy. The Cu direct bonding for 3D semiconductor packaging is successfully performed under glycerol vapor atmosphere, without any plasma pretreatment. The cross‐section of the bonded specimens is examined by scanning electron microscopy, and mechanical reliability is assessed by die shear testing.

The effect of cold plasma pretreatment on drying efficiency of beetroot by intermittent microwave-hot air (IMHA) hybrid dryer method: Assessing drying kinetic, physical properties, and microstructure of the product

This study examined the effects of cold plasma (CP) pretreatment with durations of 1, 3, and 5 minutes on drying kinetics, microstructure, and physical properties, including shrinkage, rehydration ratio (RR), and bulk density of beetroot dried samples using intermittent microwave-hot air (IMHA) drying at 40 °C and pulse ratios (PR) of 1 and 2. While increasing PR decreased drying rate (DR) and effective moisture diffusivity (Deff), increasing microwave power from 180 to 600 W increased both, reducing drying time and specific energy consumption (SEC). Extended CP-pretreatment doubled DR, 66% increased Deff, and 24% reduced SEC. Both increasing CP-pretreatment time and microwave power had similar effects on shrinkage, RR, and bulk density, but CP-pretreatment was more prominent; reducing shrinkage by 18%, bulk density by 23%, and increasing RR by approximately 36% in 5-minutes. X-ray imaging showed that 600 W of microwave power increased porosity by 87%, while 5-minute CP-pretreatment increased it by 27%. As the optimum condition, CP-pretreatment for 5 minutes, continuous microwave application, and 600 W of MW power produced the best kinetics and physical properties. Overall, the results demonstrated that the appropriate CP-pretreatment duration could produce high-quality dried samples.

Investigation of the impact of cold plasma pretreatments, long term storage and drying on physicochemical properties, bioactive contents and microbial quality of 'Keitt' mango

There is heightened demand for dried mango fruits with desired nutritional and physicochemical qualities, microbiologically stable and chemical residue free. This has led to the exploration of innovative preservation technologies for the extension of storability prior to processing. This study investigated the impact of cold plasma (CP) treatment on physicochemical properties and microbial stability in fresh and dried 'Keitt' mango during long term storage. Freshly harvested 'Keitt' mangoes were subjected to: CP treatment (for 5 min (CP5) and 10 min, CP10), dipping in “Chronos Prochloraz” for 30 s (industry practice), and untreated group (control). All samples were stored at 11 °C for 30 days, prior to minimal processing and hot air drying at 60 °C. Results after 30 days of storage demonstrated that untreated samples (control) had the highest TSS (15.06 ± 0.32 °Brix), while CP10 pretreated samples had the lowest TSS (13.80 ± 0.06 °Brix) value (p ≤ 0.05). In comparison to the fresh samples post storage, all pretreated dried mango slices retained lower total flavanols with CP5 (13.49 ± 1.64 mg GAE 100/g), CP10 (20.12 ± 1.42 mg GAE 100/g) and SMB (23.89 ± 3.35 mg GAE 100/g), but higher than the dried untreated samples (6.68 ± 0.53 mg GAE 100/g). Yellowness (b∗) of the fresh pulp (38.53 ± 1.73) increased significantly (p ≤ 0.05) with the long-term storage (39.88–46.74) and drying (55.01–64.90). CP pre-treatment combined with drying resulted in ≥2 Log reduction in microbial count. This study shows the potential of cold plasma as a pretreatment for extending storability and maintaining the quality of 'Keitt' mangoes.

Green Advances in Wet Finishing Methods and Nanoparticles for Daily Textiles.

This work presented an overview of greener technologies for realizing everyday fabrics with enhanced antibacterial activity, flame retardancy, water repellency, and UV protection. Traditional methods for improving these qualities in textiles involved dangerous chemicals, energy and water-intensive procedures, harmful emissions. New strategies are presented in response to the current emphasis on process and product sustainability. Nanoparticles (NPs) are suggested as a potential alternative for hazardous components in textile finishing. NPs are found to efficiently decrease virus transmission, limit combustion events, protect against UV radiation, and prevent water from entering, through a variety of mechanisms. Some attempts are made to increase NPs efficiency and promote long-term adherence to textile surfaces. Traditional wet finishing methods are implemented through a combination of advanced green technologies (plasma pre-treatment, ultrasound irradiations, sol-gel, and layer-by-layer self-assembly methods). The fibrous surface is activated by adding functional groups that facilitate NPs grafting on the textile substrate by basic interactions (chemical, physical, or electrostatic), also indirectly via crosslinkers, ligands, or coupling agents. Finally, other green options explore the use of NPs synthesized from bio-based materials or hybrid combinations, as well as inorganic NPs from green synthesis to realize ecofriendly finishing able to provide durable and protective fabrics.

A Novel Method for Rapid and High-Performance SERS Substrate Fabrication by Combination of Cold Plasma and Laser Treatment.

In this paper, we report a simple yet efficient method for rapid and high-performance SERS substrate fabrication by a combination of cold plasma and laser treatment. Our analysis reveals that cold plasma pre-treatment significantly reduced surface roughness, transforming 200 nm spikes into an almost perfectly uniform surface, while enhancing the substrate's surface energy by lowering the water contact angle from 59° to 0°, all achieved within just 30 s of 0.9-mW plasma treatment, while 15-min green-laser treatment facilitated more uniform deposition of AuNPs across the entire treated area, effectively creating the SERS substrates. The combined treatments result in enhancement of the Raman intensity (11 times) and consistency over the whole area of the SERS substrates, and their reusability (up to 10 times). The fabricated SERS substrates exhibit a significant enhancement factor of approximately 3 × 10⁸ with R6G, allowing detection down to a concentration of 10-12 M. We demonstrate the application of these SERS substrates by detecting amoxicillin-an antibiotic used worldwide to treat a diversity of bacterial infections-in a dynamic expanded linear range of seven orders (from 10-3 to 10-9 M) with high reliability (R2 = 0.98), and a detection limit of 9 × 10-10 M. Our approach to high-performance SERS substrate fabrication holds potential for further expansion to other metallic NPs like Ag, or magnetic NPs (Fe3O4).

Atmospheric cold plasma pretreatment for effective enhancement of covalent crosslinking between coconut globulin and tannic acid: Improving interfacial activity and emulsifying properties

Atmospheric cold plasma (ACP) represents a promising approach for enhancing covalent interactions between proteins and polyphenols, circumventing the drawbacks associated with traditional methods. This study aims to investigate the enhancement of covalent interactions between coconut globulin (CG) and tannic acid (TA) facilitated by ACP at varying pH levels. At acidic pH, ACP treatment was found to promote free radical-induced covalent cross-linking between CG and TA, whereas at pH 7.0 and 9.0, ACP treatment enhanced quinone-induced covalent cross-linking. In contrast, the covalent crosslinking induced by quinone significantly disrupted the protein structure, leading to greater exposure of hydrophobic groups. At pH 9.0, the CG-TA complex treated with ACP exhibited the highest interfacial activity, with an interfacial adsorption mass of 5292 ng/cm2. This was accompanied by improvements in droplet size, viscosity, and stability of the CG-TA-stabilized emulsion. These findings offer novel insights into the covalent modification of proteins and polyphenols, thereby broadening the potential applications of food protein.

The effect of low-temperature plasma pretreatment on the biodegradability of polyethylene films

ABSTRACT With the increasing focus on environmental friendliness and sustainable development, extensive research has been conducted on the biodegradation of plastics. The non-hydrolyzable, highly hydrophobic, and high-molecular-weight properties of polyethylene (PE) pose challenges for cell interaction and biodegradation of PE substrates. To overcome these obstacles, PE films were treated with low-temperature plasma before biodegradation. The morphology, surface chemistry, molecular weight, and weight loss of PE films after plasma treatment and biodegradation were studied. The plasma treatment decreased the surface water contact angle, formed C–O and C = O groups, and decreased the molecular weight of PE films. With the increased pretreatment time, the biodegradation efficiency rose to 2.6% from 0.63% after 20 days of incubation. The mechanism was proposed that the surface oxygen-containing groups formed by plasma treatment can facilitate the bio-accessibility and be further decomposed and utilised by the microbes. This study provided an effective and rapid pretreatment strategy for improving biodegradation of PE.

Enhancing moisture transfer and quality attributes of tomato slices through synergistic cold plasma and Osmodehydration pretreatments during infrared-assisted pulsed vacuum drying

The present study examines the impacts of combined cold plasma treated water (PW) and osmodehydration (OD) pretreatment (PO), and operation parameters like PW duration and voltage of treatment on the dehydration, functional and sensory characteristics of sliced tomato fruits subjected to simultaneous infrared-assisted pulsed vacuum drying (IR-PVD). From the results, PO pretreatment modified the surface structures by the formation of microchannels and cavities through impingements from the reactive species (RS), and was improved due to increased treatment duration and voltage, and resulted in accelerating the transfer of moisture from the slices to the surroundings during the dehydration process. Consequently, PO pretreatment achieved an enhancement in the moisture diffusivity by up to 64.83%, shortened the total drying time by up to 40%, and presented substantial improvements in the physicochemical properties including vitamin C, lycopene, colour, total soluble solids, phenolic and flavonoid contents, and overall human acceptability. However, significant decreases in rehydration and hardness properties were shown compared with control, and higher rehydration by up to 21.66% at higher treatment duration and voltage when compared with OD pretreatment. Overall, PO pretreatment incited an effective moisture removal and retention of vital physicochemical and bioactive constituents in the slices due to the activities of plasma injected RS. This study provides an empirical basis for the application of PO during IR-PVD of fruits and vegetables and demonstrated as a suitable energy-saving alternative for improving the conventional OD of foods in the industry.

Optimization of PET depolymerization for enhanced terephthalic acid recovery from commercial PET and post consumer PET-bottles via low-temperature alkaline hydrolysis

The increasing demand for plastic has resulted in a surge in plastic waste production. Polyethylene terephthalate (PET), commonly used in beverage bottle manufacturing, is only partially recycled, with an estimated recycling rate of just 28.4% in 2019. This accumulation of plastic waste is harmful to the environment and living organisms, necessitating effective recycling methods for PET waste. One promising method is alkaline hydrolysis using NaOH, which can break down PET into its monomer components, terephthalic acid (TPA) and ethylene glycol (EG). This process not only recycles PET efficiently but also manages contaminants effectively, producing high-quality TPA, supporting the development of a circular economy. This study looks into PET depolymerization via alkaline hydrolysis at low temperature by investigating effects of various factors: pH levels, water to ethanol ratio, NaOH concentration, NaOH to PET ratio, reaction time, PET size, reusability of unreacted PET, air plasma pretreatment of PET, and different kinds of PET. Promisingly, PET conversion rates of over 90% and a TPA purity of 99.6% were achieved in this study highlighting the efficacy of alkaline hydrolysis in depolymerizing post-consumer PET waste. Ultimately, this research advances sustainable plastic waste management and supports the integration of PET into a circular economy framework.

Study of the Effects of Plasma Pretreatment on the Microstructure of Peanuts

In this study, cold plasma treatments are employed to modify peanuts. This study systematically investigates the effects of various plasma treatment conditions, including power, duration, and gas type, on the microstructure of peanut seed coats and embryos. Observations under a scanning electron microscope (SEM) reveal that as plasma treatment power increases from 100 W to 500 W, the etching level of peanut seed coats significantly intensifies, surface roughness deepens, and concavities become more pronounced. Additionally, micro-pores on the seed coat gradually enlarge and form cracks. Specifically, when the plasma treatment is set at 200 W for 60 s, the oxygen (O2) treatment group shows interconnected cracks on the peanut seed coat surface, with lipid particles exuding and protein particles and polymers decomposing. In contrast, the helium (He) treatment group displays clear cell structures and deep grooves, with no noticeable lipid particles exuding around surface cracks. The argon (Ar) treatment group exhibits a distinct rectangular cell structure with clear boundaries, and although surface cracks form, only a few protein particles escape from the cracks. The embryo surface structure becomes looser after plasma treatment, leading to the disintegration of lipid particles, protein particles, and polymers, affecting the fusion and migration of large and small lipid bodies within the peanut’s internal structure. Increasing treatment duration intensifies the etching phenomenon, resulting in more lipid particles exuding, which indicates a positive correlation between lipid particles exuding and treatment duration. This study sheds light on the mechanisms underlying changes in peanut microstructure due to cold plasma treatment, providing scientific evidence for improving peanut quality, enhancing oil extraction efficiency, and optimizing food processing techniques.

Rapid oxygen plasma treatment of tin oxide layers for improving the light stability of perovskite solar cells

Surface treatment of SnO2 as an electron transport layer is essential for improving charge transport and device performance in the fabrication of perovskite solar cells. In this study, oxygen plasma with a controlled ion–radical composition ratio was used for rapid surface treatment to clean the surface of SnO2, and its performance was compared with that of the conventional UV–ozone treatment. Consequently, the plasma treatment succeeded in increasing the processing speed up to 40 times faster than that required for the conventional UV–ozone pretreatment. Furthermore, plasma pretreatment improved the photostability of solar cells.

Improved coloration of hemp fabrics via low-pressure argon plasma assisted surface modification

Interest in hemp as a viable cellulosic fibre for clothing has increased, driven partly by its economic benefits and the importance of natural renewable materials in emerging circular economies. However, the coloration and chemical finishing of lignocellulosic fibres such as hemp typically require large quantities of water and chemicals. Argon plasma pretreatment provides a way of modulating the physical properties of hemp fibres to improve the coloration process without compromising other bulk properties such as tensile strength. Such plasma treatments may contribute to alleviating the negative environmental impacts associated with liquid pretreatments, heating, or the use of auxiliary chemicals. Dyeing of hemp fibres is particularly challenging due to its crystalline chemical structure. In this study, low-pressure argon plasma-assisted surface modification of woven hemp fabrics up to 600 s at 40 and 80 Hz was explored for enhanced dyeability, resulting in enhanced dye-fibre bonding. Fourier-transform infrared spectroscopy and Raman spectroscopy of argon plasma pretreated hemp fabrics produced no noticeable changes in the functional groups of the fibres, but a physiochemical modification was observed in terms of the density of polar groups. Scanning electron microscopy (SEM) images revealed marked morphological changes including nano-etching of the fibre surface at certain argon plasma process conditions. The pretreatment process increased fibre hydrophilicity, and enhanced reactivity of the surficial –OH groups towards fibre-reactive and vat dyes, resulting in higher colour strength in dyed woven hemp fabrics. Overall, we envisage such plasma pretreatments may impact positively on the material and energy efficiency of the hemp fabric dyeing process.

Mitigation of polycyclic aromatic hydrocarbons (PAHs) in roasted beef patties by cold plasma treatment and products quality evaluation

The cold plasma (CP) technique was applied to alleviate the contamination of polycyclic aromatic hydrocarbon (PAH) in this investigation. Two different CP treatments methods were implemented in the production of beef patties, to investigate their inhibition and degradation capacity on PAHs. With 5 different cooking oils and fats addition, the inhibition mechanism of in-package cold plasma (ICP) pretreatment was explored from the aspect of raw patties fatty acids composition variation. The results of principal component analysis showed that the first two principal components accounted for more than 80 % of the total variation in the original data, indicating that the content of saturated fatty acids was significantly positively correlated with the formation of PAHs. ICP pretreatment inhibited the formation of PAHs by changing the composition of fatty acids, which showed that the total amount of polyunsaturated fatty acids decreased and the total amount of monounsaturated fatty acids increased. Sensory discrimination tests demonstrated there were discernable differences between 2 CP treated samples and the controls, utilization of the ICP pretreatment in meat products processing was expected to achieve satisfying eating quality. In conclusion, CP treatment degraded PAHs through stepwise ring-opening oxidation in 2 reported pathways, the toxicity of PAHs contaminated products was alleviated after CP treatment.

Effect of Cold Plasma and Microwave Pretreatments Combined with Hot-Air Drying on Physical Properties, Chemical Composition, and Volatile Profile of Pomegranate Peels

Effect of Cold Plasma and Microwave Pretreatments Combined with Hot-Air Drying on Physical Properties, Chemical Composition, and Volatile Profile of Pomegranate Peels

Ohmic Contact Formation to β-Ga2O3 Nanosheet Transistors with Ar-Containing Plasma Treatment

Effective Ohmic contact between metals and their conductive channels is a crucial step in developing high-performance Ga2O3-based transistors. Distinct from bulk materials, excess thermal energy of the annealing process can destroy the low-dimensional material itself. Given the thermal budget concern, a feasible and moderate solution (i.e., Ar-containing plasma treatment) is proposed to achieve effective Ohmic junctions with (100) β-Ga2O3 nanosheets. The impact of four kinds of plasma treatments (i.e., gas mixtures SF6/Ar, SF6/O2/Ar, SF6/O2, and Ar) on (100) β-Ga2O3 crystals is comparatively studied by X-ray photoemission spectroscopy for the first time. With the optimal plasma pre-treatment (i.e., Ar plasma, 100 W, 60 s), the resulting β-Ga2O3 nanosheet field-effect transistors (FETs) show effective Ohmic contact (i.e., contact resistance RC of 104 Ω·mm) without any post-annealing, which leads to competitive device performance such as a high current on/off ratio (>107), a low subthreshold swing (SS, 249 mV/dec), and acceptable field-effect mobility (μeff, ~21.73 cm2 V−1 s−1). By using heavily doped β-Ga2O3 crystals (Ne, ~1020 cm−3) for Ar plasma treatments, the contact resistance RC can be further decreased to 5.2 Ω·mm. This work opens up new opportunities to enhance the Ohmic contact performance of low-dimensional Ga2O3-based transistors and can further benefit other oxide-based nanodevices.

Passivated indium oxide thin-film transistors with high field-effect mobility (128.3 cm2 V−1 s−1) and low thermal budget (200 °C)

Here, we demonstrate a high-mobility indium oxide (In2O3) thin-film transistor (TFT) with a sputtered alumina (Al2O3) passivation layer (PVL) with a low thermal budget (200 °C). The sputtering process of the Al2O3 PVL plays a positive role in improving the field-effect mobility (µ FE) and current on/off ratio (I ON/I OFF) performance of the In2O3 TFTs. However, these enhancements are limited due to the high density of intrinsic trap defects in the In2O3 channels, as reflected in their large hysteresis and poor bias stability. Treating the In2O3 channel with oxygen (O2) plasma prior to sputtering the Al2O3 PVL results in notable improvements. Specifically, a high µ FE of 128.3 cm2V−1 s−1, a high I ON/I OFF over 106 at V DS of 0.1 V, a small hysteresis of 0.03 V, and a negligible threshold voltage shift under negative bias stress are achieved in the passivated In2O3 TFT (with O2 plasma pretreatment), representing a significant improvement compared to the passivated In2O3 TFT (without O2 plasma pretreatment) and the unpassivated In2O3 TFT. The remarkable reduction of intrinsic trap defects in the passivated In2O3 TFT compensated by O2 plasma is the primary mechanism underlying the improvement in µ FE and bias stability, as validated by x-ray photoelectron spectra, hysteresis analysis, and temperature-stress electrical characterizations. Plasma treatment effectively compensates for intrinsic trap defects in oxide semiconductor (OS) channels, when combined with sputter passivation, resulting in a significant enhancement of the overall performance of OS TFTs under low thermal budgets. This approach offers valuable insights into advancing OS TFTs with satisfactory driving capability and wide applicability.

Influence of pre-treatment with non-thermal atmospheric pressure plasma on bond strength of TP340 titanium-PEEK direct bonding

Direct bonding of a TP340 titanium to PEEK by hot pressing via pre-treatment of non-thermal atmospheric pressure plasma jet has been demonstrated. The plasma irradiation effect on the bonding surface on the bond strength after hot pressing was investigated. The tensile shear strength of TP340-PEEK joined by hot pressing after plasma pre-treatment was measured by comparing specimens bonded using conventional hot pressing and those bonded using adhesives. The plasma treatment to the TP340 side resulted in the formation of TiO2, which is chemically fed to oxide formation due to the irradiation of oxygen radicals generated by the plasma, resulting in a bond strength of less than 1 MPa, similar to the bond strength of the untreated specimens. The plasma irradiation effect on the PEEK side on the bond strength of TP340-PEEK bonded samples was also investigated. The bonding strength was increased by plasma irradiation to PEEK. As the plasma irradiation time was increased, the bonding strength gradually increased to 9.2 MPa, which is about 19 times higher than the bonding strength without plasma irradiation. These results suggest that oxygen radicals in the atmospheric pressure RF plasma jet produced oxygen-containing surface functional groups on the PEEK surface, which increased the strength of the TP340-PEEK direct joining.

Impact of Cold Atmospheric Plasma Pretreatment on the Recovery of Phenolic Antioxidants from Spent Coffee Grounds

In the present study, cold atmospheric plasma (CAP) was employed as a pretreatment method for the extraction of phenolic compounds from spent coffee grounds (SCGs). The impact of CAP treatment conditions, i.e., thickness of the SCGs layer (mm), distance between the plasma source and the SCGs layer (mm) and duration of CAP treatment (min), on the total phenol content, in vitro antioxidant activity, as well as caffeine and chlorogenic acid content of SCGs, was investigated. The process parameters were optimized with the aid of response surface methodology (RSM). After optimizing the CAP pretreatment conditions, the CAP-treated SCGs were subjected to ultrasound-assisted extraction using ethanol as the extraction solvent. The optimum conditions for CAP treatment identified, i.e., thickness, 1 mm; distance, 16 mm; and duration, 15 min, led to a significant enhancement in the recovery of bioactive compounds from SCGs compared to those obtained from untreated SCGs. Total phenolic content and antioxidant activity significantly increased (i.e., TPC from 19.0 ± 0.7 to 24.9 ± 1.4 mg GAE/100 g dry SCGs, ADPPH from 106.7 ± 5.01 to 112.3 ± 4.3 μmol Trolox/100 g dry SCGs, AABTS from 106.7 ± 5.01 to 197.6 ± 5.8 μmol Trolox/100 g dry SCGs, ACUPRAC from 17938 ± 157 to 18299 ± 615 μmol Trolox/100 g dry SCGs). A significant increase in caffeine content from 799.1 ± 65.1 mg to 1064 ± 25 mg/100 g dry SCGs and chlorogenic acid content from 79.7 ± 15.3 mg to 111.3 ± 3.3 mg/100 g dry SCGs, was also observed. Overall, CAP pre-treatment can be used to enhance the recovery of bioactive compounds from SCGs.