The lightest atmospheric gas constituents, like H- and He- atoms, are known to escape from planetary gravitational fields to open space. Hereby it counts that not only the uppermost atmospheric layer, the so-called exobase, contributes to this planetary gas escape, but the layers below do contribute as well, especially since from below a nonthermal character of the final particle outflow is induced.We consider the outflow of H - atoms from lower levels of a planetary oxygen-dominated upper atmosphere, stratified by the planet‘s gravitational field - as given in case of the Earth. The terrestrial H-atom outflow is locally modified by elastic collisions of upwards flying H-atoms with the heavy major atmospheric background constituent. This causes a collision–induced velocity-modulation of the upwards directed H-atom flow and induces nonthermal kinetic signatures of the local H ˗ atom distribution function. An important, hitherto unrespected point hereby is that angle-integrated elastic O ˗ H- collision cross sections are velocity-dependent, falling off with increasing velocity v like (1/v). Consequently this modulation influences low velocity H-atoms stronger than high-velocity ones, which changes the kinetic profile of the escaping H-atoms and causes deviations from the classic Jeans escape. Deeply down in the lower thermosphere the local H-atoms, like as well the O-atoms, indeed are in a thermodynamical equilibrium characterized by Maxwell distributions with a common temperature TH = TO. Nevertheless, at the upper exobase border of the atmosphere the resulting H-atom escape flow turns out to be a, non-equilibrium flow with non-thermal escape-relevant properties. Here we describe this collisional modification of the H-escape flow and quantify the upcome of kinetic non-equilibrium features like power laws in the wings of the H-distribution function. This collisional modulation via velocity-dependent collision cross-sections acts as a typical process to convert equilibrium distributions into non-equilibrium kappa-like distribution functions. On the basis of this theoretical approach and stabilizing the upper atmosphere by the type of so-called "iso-baric Kappa functions" which all represent the same H ˗ atom- pressure we can calculate the effective escape flux of H- atoms to open space and can quantify its difference with respect to the classical Jeans escape value. While finding again that the classical Jeans formula slightly overestimates the actual escape flux, we now for the first time taking into account the nonthermal influence of collisional modulations can show that the actual escape with respect to the actual Jeans value is even enhanced by factors 2 to 3.
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