Planetary Boundary Layer Influence Research Articles

Contribution of new particle formation to the total aerosol concentration at the high‐altitude site Jungfraujoch (3580 m asl, Switzerland)

AbstractPrevious modeling studies hypothesized that a large fraction of cloud condensation nuclei (CCN) is attributed to new particle formation (NPF) in the free troposphere. Despite the potential importance of this process, only few long‐term observations have been performed to date. Here we present the results of a 12 month campaign of NPF observations at the high‐altitude site Jungfraujoch (JFJ, 3580 m above sea level (asl)). Our results show that NPF significantly adds to the total aerosol concentration at the JFJ and only occurs via previous precursor entrainment from the planetary boundary layer (PBL). Freshly nucleated particles do not directly grow to CCN size (90 nm) within observable time scales (maximum 48 h). The contribution of NPF to the CCN concentration is low within this time frame compared to other sources, such as PBL entrainment of larger particles. A multistep growth mechanism is proposed which allows previously formed Aitken mode particles to add to the CCN concentration. A parametrization is derived to explain formation rates at the JFJ, showing that precursor concentration, PBL influence, and global radiation are the key factors controlling new particle formation at the site.

Analysis of long‐term aerosol size distribution data from Jungfraujoch with emphasis on free tropospheric conditions, cloud influence, and air mass transport

AbstractSix years of aerosol size distribution measurements between 20 and 600 nm diameters and total aerosol concentration above 10 nm from March 2008 to February 2014 at the high‐alpine site Jungfraujoch are presented. The size distribution was found to be typically bimodal with mode diameters and widths relatively stable throughout the year and the observation period. New particle formation was observed on 14.5% of all days without a seasonal preference. Particles typically grew only into the Aitken mode and did not reach cloud condensation nucleus (CCN) sizes on the time scale of several days. Growth of preexisting particles in the Aitken mode, on average, contributed very few CCN. We concluded that the dominant fraction of CCN at Jungfraujoch originated in the boundary layer. A number of approaches were used to distinguish free tropospheric (FT) conditions and episodes with planetary boundary layer (PBL) influence. In the absence of PBL injections, the concentration of particles larger than 90 nm (N90, roughly corresponding to the CCN concentration) reached a value ~40 cm−3 while PBL influence caused N90 concentrations of several hundred or even 1000 cm−3. Comparing three criteria for free tropospheric conditions, we found FT prevalence for 39% of the time with over 60% during winter and below 20% during summer. It is noteworthy that a simple criterion based on standard trace gas measurements appeared to outperform alternative approaches.

Application of Lidar Data to Assist Airmass Discrimination at the Whistler Mountaintop Observatory

AbstractA ground-based lidar system that has been deployed in Whistler, British Columbia, Canada, since the spring of 2010 provides a means of evaluating vertical aerosol structure in a mountainous environment. This information is used to help to determine when an air chemistry observatory atop Whistler Mountain (2182 m MSL) is within the free troposphere or is influenced by the valley-based planetary boundary layer (PBL). Three case studies are presented in which 1-day time series images of backscatter data from the lidar are analyzed along with concurrent meteorological and air-chemistry datasets from the mountaintop site. The cases were selected to illustrate different scenarios of diurnal PBL evolution that are expected to be common during their respective seasons. The lidar images corroborate assumptions about PBL influence as derived from analysis of diurnal trends in water vapor, condensation nuclei, and ozone. Use of all of these datasets together bolsters efforts to determine which atmospheric layer the site best represents, which is important when evaluating the provenance of air samples.

Seasonal and Diurnal Variations in Aerosol Concentration on Whistler Mountain: Boundary Layer Influence and Synoptic-Scale Controls

AbstractA mountain air chemistry observatory has been operational on the summit of Whistler Mountain in British Columbia, Canada, since 2002. A 1-yr dataset of condensation nuclei (CN) concentration from this site has been analyzed along with corresponding meteorological data to assess the frequency and patterns of influence from the planetary boundary layer (PBL). Characterization of air masses sampled from the site as either PBL influenced or representative of the free troposphere (FT) is important to subsequent analysis of the chemistry data. Median CN concentrations and seasonal trends were found to be comparable to other midlatitude mountain sites. Monthly median number concentrations ranged from 120 cm−3in January to 1601 cm−3in July. Using well-defined diurnal cycles in CN concentration as an indicator of air arriving from nearby valleys, PBL influence was found to occur on a majority of days during spring and summer and less frequently in late autumn and winter. Days with PBL influence were usually associated with synoptic-scale weather patterns that were conducive to convective mixing processes. Although more common in the warm season, vertical mixing capable of transporting valley air to the mountaintop also occurred in February during a period of high pressure aloft. In contrast, an August case study indicated that the more stable character of marine air masses can at times keep the PBL below the summit on summer days. Considerable variability in the synoptic-scale weather conditions at Whistler means that careful analysis of available datasets must be made to discriminate FT from PBL periods at the observatory.

Aerosol climatology and planetary boundary influence at the Jungfraujoch analyzed by synoptic weather types

Abstract. Fourteen years of meteorological parameters, aerosol variables (absorption and scattering coefficients, aerosol number concentration) and trace gases (CO, NOx, SO2) measured at the Jungfraujoch (JFJ, 3580 m a.s.l.) have been analyzed as a function of different synoptic weather types. The Schüepp synoptic weather type of the Alps (SYNALP) classification from the Alpine Weather Statistics (AWS) was used to define the synoptic meteorology over the whole Swiss region. The seasonal contribution of each synoptic weather type to the aerosol concentration was deduced from the aerosol annual cycles while the planetary boundary layer (PBL) influence was estimated by means of the diurnal cycles. Since aerosols are scavenged by precipitation, the diurnal cycle of the CO concentration was also used to identify polluted air masses. SO2 and NOx concentrations were used as precursor tracers for new particle formation and growth, respectively. The aerosol optical parameters and number concentration show elevated loadings during advective weather types during the December–March period and for the convective anticyclonic and convective indifferent weather types during the April–September period. This study confirms the consensus view that the JFJ is mainly influenced by the free troposphere during winter and by injection of air parcels from the PBL during summer. A more detailed picture is, however, drawn where the JFJ is completely influenced by free tropospheric air masses in winter during advective weather types and largely influenced by the PBL also during the night in summer during the subsidence weather type. Between these two extreme situations, the PBL influence at the JFJ depends on both the time of year and the synoptic weather type. The fraction of PBL air transported to the JFJ was estimated by the relative increase of the specific humidity and CO.

13-month climatology of the aerosol hygroscopicity at the free tropospheric site Jungfraujoch (3580 m a.s.l.)

Abstract. A hygroscopicity tandem differential mobility analyzer (HTDMA) was operated at the high-alpine site Jungfraujoch in order to characterize the hygroscopic diameter growth factors of the free tropospheric Aitken and accumulation mode aerosol. More than ~5000 h of valid data were collected for the dry diameters D0 = 35, 50, 75, 110, 165, and 265 nm during the 13-month measurement period from 1 May 2008 through 31 May 2009. No distinct seasonal variability of the hygroscopic properties was observed. Annual mean hygroscopic diameter growth factors (D/D0) at 90% relative humidity were found to be 1.34, 1.43, and 1.46 for D0 = 50, 110, and 265 nm, respectively. This size dependence can largely be attributed to the Kelvin effect because corresponding values of the hygroscopicity parameter κ are nearly independent of size. The mean hygroscopicity of the Aitken and accumulation mode aerosol at the free tropospheric site Jungfraujoch was found to be κ≈0.24 with little variability throughout the year. The impact of Saharan dust events, a frequent phenomenon at the Jungfraujoch, on aerosol hygroscopicity was shown to be negligible for D0<265 nm. Thermally driven injections of planetary boundary layer (PBL) air, particularly observed in the early afternoon of summer days with convective anticyclonic weather conditions, lead to a decrease of aerosol hygroscopicity. However, the effect of PBL influence is not seen in the annual mean hygroscopicity data because the effect is small and those conditions (weather class, season and time of day) with PBL influence are relatively rare. Aerosol hygroscopicity was found to be virtually independent of synoptic wind direction during advective weather situations, i.e. when horizontal motion of the atmosphere dominates over thermally driven convection. This indicates that the hygroscopic behavior of the aerosol observed at the Jungfraujoch can be considered representative of the lower free troposphere on at least a regional if not continental scale.

Incorporation of planetary boundary layer dynamics in a numerical model of long-range air-pollutant transport

A numerical model of long-range air-pollutant transport is developed, in which a simple planetary boundary layer (PBL) is incorporated. The pollution field results from the superposition of discrete ‘puffs’ of pollutants which are emitted periodically in different regions. The instantaneous sources in the different cells are approximated by rotational ellipsoids with Gaussian concentration distributions. The puff movement due to the external flow is followed by the displacement of the centroid. The expansion of the puff is modelled by nonisotropic Fickian diffusion. A simple barotropic PBL model is used to study the PBL influence. This model gives the flow velocity and the vertical turbulent exchange coefficient, which depend on the external parameters Ro and S — Rossby number and stratification parameter. The model performance is investigated by special test runs. The dependence of the pollution field on source height, stability conditions and vertical motions is shown.