Planar Laser-induced Fluorescence Research Articles

Mixing Of A Starting Turbulent Jet In Homogeneous And Isotropic Turbulence

The mixing of a starting turbulent jet, injected with an injection velocity of U = 18.8 m/s from a tube with a diameter of D = 4mm (Reynolds number Re = 4800, characteristic time scale t* = D/U = 0.21 ms at the nozzle exit), is experimentally investigated in the presence of homogenous and isotropic turbulence (HIT) using Planar Laser-induced Fluorescence (PLIF). The root-mean-square (RMS) velocity of the ambient HIT is 0.38 and 0.63 m/s, corresponding to turbulent Reynolds numbers of Reλ = 190 and 250, respectively. Spatial distributions of mixture fraction and scalar dissipate rate (SDR) were measured within an axial range of y = 0 – 10 D and at different times after the start of injection (ASIs) up to 21.4 t*. Ambient HIT did not alter the location or size of the leading vortex ring in the initial formation stage. However, it was able to enhance the entrainment of ambient fluids in this stage and deform/transport both the leading and the trailing vortex rings at later stages, despite that the ASIs examined were only comparable to its Kolmogorov timescale. Ambient HIT also introduced a significant increase to the fluctuations of the jet penetrations length but only a marginal reduction (less than 10%) to the averaged jet penetration speed. PDFs of the ensemble averaged mixture fraction within the whole jet region showed increased probability of low mixture fraction values – and therefore indicating enhanced entrainment and mixing – in the presence of ambient HIT. Ensemble averaged distributions of the SDR showed no significant alterations by the ambient HIT in the initial formation stage of the leading vortex ring. At later stages, while the high SDRs in the leading vortex ring remained concentrated in a layer along the edge of the vortex ring for Reλ = 0, it became increasingly uniformly distributed with a lower maximum value as the ambient HIT increased. Similar, but less significant, impact of the ambient HIT on the SDR fields was observed in the trailing vortex rings, while no noticeable impact was found in the shear layer close to the nozzle exit.

On The Determination Of Conditional Statistics Along Gradient Trajectories At The Turbulent/Non-Turbulent Interface Of Jet Flows.

Conditional sampling and averaging are valuable techniques for discerning and quantifying notable regions within turbulent flows. These methods have been particularly prevalent in experimental and numerical investigations of turbulent shear flows. Conditional statistics effectively analyze the dynamics and characteristics of turbulent flows, offering insights into transitional behaviors and distinct features within these regimes. This approach is instrumental in studying turbulent shear flows, such as jets or mixing layers, where a well-defined zone separates the turbulent core from the non-turbulent surrounding fluid. This zone, known as the Turbulent/Non-Turbulent Interface (TNTI), plays a crucial role in various phenomenological changes, including the transfer of mass, momentum, and scalar fluxes. While statistics in jet flows are often reported along the radial direction for a given downstream position, this method can obscure the underlying physical processes. Scalar dissipation rate, transport, or turbulent kinetic energy involve velocity or concentration gradients at the flow interface. To date, the impact of sampling direction on conditional statistics within jet flows has not yet been thoroughly discussed. This study focuses on determining gradient trajectories at the interface of turbulent flows. Gradient trajectories have been used to explore structures in turbulent flows, proving effective in analyzing homogeneous shear turbulence. This study introduces a methodology for sampling conditional data by computing gradient trajectories intersecting the TNTI. The primary objective is to verify whether sampling statistics along the gradient of scalar concentration provide a more detailed understanding of the processes occurring near the TNTI. The methodology involves computing a field of gradient trajectories from concentration fields obtained through Planar Laser-Induced Fluorescence (PLIF) in a N2/N2 jet with Re = 2900. Conditional statistics at the TNTI of a jet flow along the gradient trajectory for a given downstream position are calculated and reported. The paper aims to compare conditional statistics along gradient trajectories with those obtained along radial and normal directions at the TNTI. It is expected that gradient trajectory statistics align more closely with normal direction statistics near the interface and diverge as it gets into the jet or coflow fluid.

Mixing Of A Starting Turbulent Jet In Homogeneous And Isotropic Turbulence

The mixing of a starting turbulent jet, injected with an injection velocity of U = 18.8 m/s from a tube with a diameter of D = 4mm (Reynolds number Re = 4800, characteristic time scale t* = D/U = 0.21 ms at the nozzle exit), is experimentally investigated in the presence of homogenous and isotropic turbulence (HIT) using Planar Laser-induced Fluorescence (PLIF). The root-mean-square (RMS) velocity of the ambient HIT is 0.38 and 0.63 m/s, corresponding to turbulent Reynolds numbers of Reλ = 190 and 250, respectively. Spatial distributions of mixture fraction and scalar dissipate rate (SDR) were measured within an axial range of y = 0 – 10 D and at different times after the start of injection (ASIs) up to 21.4 t*. Ambient HIT did not alter the location or size of the leading vortex ring in the initial formation stage. However, it was able to enhance the entrainment of ambient fluids in this stage and deform/transport both the leading and the trailing vortex rings at later stages, despite that the ASIs examined were only comparable to its Kolmogorov timescale. Ambient HIT also introduced a significant increase to the fluctuations of the jet penetrations length but only a marginal reduction (less than 10%) to the averaged jet penetration speed. PDFs of the ensemble averaged mixture fraction within the whole jet region showed increased probability of low mixture fraction values – and therefore indicating enhanced entrainment and mixing – in the presence of ambient HIT. Ensemble averaged distributions of the SDR showed no significant alterations by the ambient HIT in the initial formation stage of the leading vortex ring. At later stages, while the high SDRs in the leading vortex ring remained concentrated in a layer along the edge of the vortex ring for Reλ = 0, it became increasingly uniformly distributed with a lower maximum value as the ambient HIT increased. Similar, but less significant, impact of the ambient HIT on the SDR fields was observed in the trailing vortex rings, while no noticeable impact was found in the shear layer close to the nozzle exit.

Characterization Of The Electrothermal Conversion Mechanisms Of A Plasma Actuator For Icing Control

The characterization of a new icing protection system, specifically a dielectric barrier discharge (DBD) plasma actuator, is conducted in this study. The system operates by establishing an AC high voltage between two electrodes arranged on opposite sides of a dielectric material. This setup generates a plasma on the dielectric surface, which in turn induces a significant temperature rise (about 30°C) in both the dielectric surface and the surrounding air. To gain a comprehensive understanding of the electrothermal conversion mechanisms involved in the discharge, a Planar Laser Induced Fluorescence technique is employed. Using a two-colour one-dye ratiometric method (PLIF2c1d), the technique provides measurements of the temperature evolution of an ice droplet deposited on the actuator during its melting process by the discharge. An annular actuator configuration is chosen to minimise the effect of the generated ionic wind and maintain the droplet in the discharge. A pyranine and sucrose solution is identified and temperature calibrated. The calibration process involves depositing a droplet of the solution in a temperature-controlled enclosure capable of reaching temperatures as low as -22°C. Through detailed spectral analysis, two specific detection spectral bands are selected for the imaging applications. These bands enable measurements of the ice temperature with a sensitivity of 7.61%/°C. The effects of laser light scattering by ice and fluorescence reabsorption are also investigated by varying the ice thickness. They are found to have limited influence on the fluorescence emission when the solution in ice form. Finally, the capacity of the technique is evaluated by measuring the ice temperature evolution during the melting induced by a plasma discharge. Droplets are deposited on two dielectric materials, namely PTFE and Sapphire, which possess distinct thermal and dielectric properties. Comparisons under varying plasma discharge power levels provide valuable insights into the optimization of DBD plasma actuators for effective icing protection.

Comparative Analysis Of Brightness-Based Laser-Induced Fluorescence (BBLIF) And Structured Planar Laser-Induced Fluorescence (S-PLIF) For Film Thickness Measurement In Two-Phase Flow

Improved understanding of the interactions between gas and liquid phases in gas sheared film flow is crucial for n improved capability to employ computational modelling in the future to optimize systems, thereby reducing environmental impact, increasing efficiency, and enhancing productivity. This abstract compares two techniques for measuring the thickness of the film in different regimes visible in a rectangular cross-section gas-sheared liquid film rig, namely previously published Brightness Based Laser Induced Fluorescence (BBLIF) data and Structured Planar Laser Induced Fluorescence (S-PLIF) from the current investigation. The study presents and compares examples at a specific liquid flow rate (8 litres per minute) for superficial gas velocities in the range 1 m/s to 10 m/s, noted as being in different flow regimes. The investigation reveals that the S-PLIF technique produces results that are within the uncertainty bands of the BBLIF data for most scenarios. However, in the transition regime, statistical variations emerge. The frequency content of the two film heights is analyzed using a Hilbert-Huang Technique. This shows clearer results for the S-PLIF than for BBLIF which is attributed to the erratic values that can occur in BBLIF when total internal reflection occurs. It is concluded that the S-PLIF technique demonstrates promise as a reliable method for determining film thickness which is highly advantageous as it can be applied to images obtained with seeded flow intended for PIV analysis. The S-PLIF film thickness data can be used for generating automated masks for PIV analysis concurrently conducted in both the gas and liquid phases. This advancement facilitates the enhanced capability to advance understanding of complex fluid dynamics and optimize system performance.

Photofragmentation laser-induced fluorescence imaging of CH3 by structured illumination in a plasma discharge

Methyl is crucial in plasma-assisted hydrocarbon chemistry, making precise in situ imaging essential for understanding various plasma applications. Its importance in methane chemistry arises from its role as a primary byproduct during the initial phase of methane dehydrogenation. Detecting the CH3 radical is challenging due to its high reactivity and the prevalence of strongly pre-dissociative electronically excited states. To address this, photofragmentation planar laser-induced fluorescence (PF-LIF) techniques have been developed. These involve laser-induced photodissociation of the CH3 radical into CH fragments, which are then probed using another laser. This method allows for both temporally and spatially resolved measurements. However, quantifying the signal from photofragmented species is complicated by the overlap with naturally occurring CH fragments. We employ PF-LIF with structured illumination to distinguish photofragmented species from naturally occurring ones using a frequency-sensitive lock-in technique. This methodology is demonstrated in an atmospheric pressure dielectric barrier discharge (DBD) containing argon and methane, enabling spatially and temporally resolved data acquisition of the CH3 radical. This approach facilitates interference-free PF-LIF measurements of methyl in various applications.

Two-Photon Planar Laser-Induced Fluorescence Of Near-Wall CO During The Interaction Between A Flame And A Cooling Air Film

Reducing the anthropogenic pollutant emissions is a major concern in the aeronautical community. Implementing high-power density core engines made of lighter materials would undoubtedly increase the thermal efficiency and reduce CO 2 emissions. Nevertheless, near-wall combustion processes will become significant, raising concerns regarding thermal management. As a result, walls in aero-engine combustors are commonly cooled, but it also introduces more complex physical phenomena associated to pollutant formation during flame-cooling air interaction (FCAI). This experimental study aims at elucidating the role of the cooling air film on CO emissions during FCAI. The experiments are conducted in an atmospheric pressure and optically-accessible lab-scale combustion test rig dedicated to near-wall combustion. It generates a lean premixed turbulent methane/air V-shaped flame, with one branch of the flame that interacts with an oil-cooled stainless-steel wall. A splash-cooling plate system enables to generate a momentum-controlled parietal cooling air film. The novelty of this study is to develop and implement planar laser-induced fluorescence of the CO molecule (CO-PLIF), complemented by planar laser-induced fluorescence of the OH radical (OH-PLIF) as well as global CO emissions in the exhaust gases. Results show that the excitation of the Hopfield-Birge system enables to detect the AN ngström bands and the third positive system. However, significant interferences with C 2 and CN emissions are highlighted, being more pronounced in rich combustion conditions, and originating from the incomplete fuel oxidation as well as the high energy density of the two-photon excitation process. A broadband collection strategy of the AN ngström bands is selected, since these interferences are limited in lean combustion regimes. The analysis of the flame dynamics indicates that the increase of the cooling air film momentum shifts the reactive flow away from the wall, but also controls the flame wrinkling through modified aerodynamics. As a result, the flame is not influenced anymore by thermal quenching processes, and can effectively burn further away from the wall. Global emission measurements indicate an increase in CO when the cooling air film momentum increases. While thermal quenching favors a faster oxidation downstream of the flame, the establishment of the cooling air film leads to a longer flame with more production areas. CO-PLIF imaging concurs this phenomenon, with a CO distribution all along the wall when the cooling air film is well established.

Characterizing lean blowout dynamics of DME/air premixed swirl flames in a gas turbine model combustor with and without confinement

This work investigates lean blowout (LBO) dynamics of dimethyl ether (DME)/air premixed swirl flames in a gas turbine model combustor with and without confinement. CH* chemiluminescence imaging and 2 kHz high-speed OH* chemiluminescence imaging are performed to capture the swirl flame macrostructures. Particle image velocimetry (PIV) and planar laser-induced fluorescence (PLIF) are used to visualize the flow fields and reaction zones, respectively. Compared to the unconfined flame, the addition of confinement results in the appearance of an outer recirculation zone (ORZ), variation in flame topology, enhanced overall heat release (HR) rate, increased turbulent kinetic energy (TKE), and extended LBO limits. Far from LBO, all flames are stabilized in the shear layer. Approaching LBO, the confinement enhances the flow vortex structures along the shear layers, which is associated with extinction at the flame base and shear layer. However, the unconfined flame is still stabilized in the shear layer due to the weaker flow vortex structures. Different extinction mechanisms during the LBO process are also discussed between the unconfined and confined flames. The unconfined flame suddenly leaves the inner shear layer (ISL) and recedes to the inner recirculation zone (IRZ) within about 100 ms before LBO. Abundant CH2O is transported into IRZ mainly by recirculation, which reduces the HR region area and give rise to LBO. For the confined flame, more and more cold reactants gather near the base plate and then are gradually brought into IRZ by ISL vortices, which makes the flame lift from the base plate and decrease the HR region area until LBO happens.

Reynolds number effect of a vortex ring impinging on a concave hemi-cylindrical shell

Experimental investigations were conducted on a single vortex ring impinging on a concave hemi-cylindrical shell with Dm/De = 2 at different Reynolds numbers. Vortex rings with five different Reynolds numbers were generated for experimental studies, i.e., Re = 750, 1500, 3000, 5000, and 7000. The planar laser-induced fluorescence visualizations and two-dimensional particle image velocimetry measurements were used in the experiment. The vorticity field based on the Eulerian framework and the finite-time Lyapunov exponent (FTLE) field based on the Lagrangian framework were used to identify the dynamic processes of vortex rings, respectively. The results show that as the vortex rings impinge on concave surfaces from Re = 750 to Re = 7000, the extension of the main vortex ring in the straight-edged direction is larger than that in the concave direction, and the instability of the vortex ring is promoted. While the Reynolds number is increasing, the vortex ring deformation becomes larger, and the overall vortex ring cross section becomes smaller, leading to a larger attenuation of the vortex ring rotation. Calculations performed by the FTLE field were used to derive the Lagrangian coherent structure to analyze the boundaries of the vortex ring motion process, clearly observe the shape of the secondary vortex connecting segments, and verify the speculation by the vortex ring trajectory identification results. Finally, a dynamic model of vortex rings impinging a concave surface was proposed, and the inference of the experimental process was explained by the model.

Deep learning-based image segmentation for instantaneous flame front extraction

This paper delves into the methodology employed in examining lean premixed turbulent flame fronts extracted from Planar Laser Induced Fluorescence (PLIF) images at elevated pressures. In such flow regimes, the PLIF signal suffers from significant collisional quenching, typically resulting in image data with low signal-to-noise ratio (SNR). This poses severe difficulties for conventional flame front extraction algorithms based on intensity gradients and requires intense user intervention to yield acceptable results. In this work, we propose Convolutional Neural Network (CNN)-based Deep Learning (DL) models as an alternative to problem specific conventional methods. The pretrained DL models were fine-tuned, employing data augmentation, on a small annotated dataset including a variety of conditions between SNR ≈\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\approx$$\\end{document} 1.6 to 2.6 and subsequently evaluated. All DL models significantly outperformed the best-scoring conventional implementation both quantitatively and visually, while having similar inference times. IoU-scores and Recall values were found to be up to a factor ≈\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\approx$$\\end{document} 1.2 and ≈\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\approx$$\\end{document} 2.5 higher, respectively, with ≈\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\approx$$\\end{document} 1.15 times improved Precision. Small-scale structures were captured much better with fewer erroneous predictions, becoming particularly pronounced for the lower SNR data investigated. Moreover, by applying artificially modeled noise, it was shown that the range of image conditions in terms of SNR that can be reliably processed extends well beyond the images included in the training data, and satisfactory segmentation performances were found for SNR as low as ≈\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\approx$$\\end{document} 1.1. The presented DL-based flame front detection algorithm marks a methodology with significantly increased detection performance, while a similar computational effort for inference is achieved and the need for user-based parameter tuning is eliminated. It enables a very accurate extraction of instantaneous flame fronts in large image datasets where supervised processing is infeasible, unlocking unprecedented possibilities for the study of flame dynamics and instability mechanisms at industry-relevant conditions.

Dynamics of regime transition of autoignitive jet flames from conventional to MILD combustion

Turbulent combustion of jet flames in a hot diluted coflow of combustion products has been studied across a range of jet Reynolds numbers for propane, ethylene, and an ethylene-propane blend as fuels. The study revealed a transition from conventional autoignitive combustion to a regime of Moderate or Intense Low-oxygen Dilution (MILD) combustion, which is characterized by a nearly invisible flame. The flames studied are luminous at low jet velocities and become MILD at higher jet velocities. Planar Laser-Induced Fluorescence (PLIF) of formaldehyde (CH2O), a key intermediate species in hydrocarbon combustion, is combined with CH*-chemiluminescence imaging and Rayleigh scattering to investigate the phenomena. The transition to MILD combustion is found to accompany a broadening of the formaldehyde region, indicating a broader low-temperature reaction zone. As the transition is approached, the appearance of holes in the chemiluminescent front is also observed. Correspondence between the location and structure of these holes with regions of formaldehyde in the flame are illustrated. These regions are proposed to be signatures that precede the transition to a fully MILD flame. In other words, the transition to MILD combustion begins at a local level and the MILD region spreads to engulf the entire combusting mixture. Scalar gradients were imaged to further unravel the local turbulence/chemistry interactions that yield the MILD inception. The measured scalar gradients were found to be commensurate with scalar gradients obtained from chemical kinetic simulations at the stoichiometric mixture fractions, while being an order of magnitude larger at other locations; this suggests that the inception of MILD combustion occurs near the stoichiometric region.

Effects of inorganic sodium on the soot generation of coal particle: Insights with PLIF and DFT calculation

Inorganic sodium in low rank coal exerts significant influence on the soot generation in the early stage of combustion. The effect of inorganic sodium on the PAHs, soot formation and OH generation of coal particle was investigated on a concentrating light heating platform using Planar Laser Induced Fluorescence (PLIF) of OH radicals and PAHs. The generation characteristics of PAHs during coal particles pyrolysis with the temperature of 500 °C and 800 °C were also investigated. Raw coal, acid-washed (AW) coal and AW impregnated with different mass ratio of NaCl (1 %, 3 % and 5 % NaCl-loaded) were studied. Theoretical calculations using density functional theory was performed to explore the effect of sodium on the conversion of small molecule to macromolecular substances during early coal combustion. The results showed that the NaCl addition inhibited the OH radical and soot generation in the early stage of coal combustion, as demonstrated by the reduced OH intensity, and decreased soot intensity by observing the flame luminosity for the NaCl-loaded coals, compared with AW coal. Simultaneously, the PAHs generation was significantly reduced for NaCl-loaded coals, both at the early stage of coal combustion and under pyrolysis conditions, compared with AW coal. The quantum chemistry calculation revealed that the formed C-Na structure enhanced coal structural stability, making the chemical bonds less prone to cleavage, thereby inhibiting the volatile and PAHs release during the early stage of coal combustion. On the other hand, the released Na+ can catalyze the addition reactions of small ring PAHs (naphthalene, naphthalene derivatives) to larger ring PAHs (phenanthrene, pyrene), which would promote the PAHs and soot generation in homogeneous reactions, explaining the highest PAHs with 3-to-5 rings for 5 % NaCl-loaded coal among NaCl-loaded coals. The above two kings of reaction pathways were related to soot formation, but considering the results of reduced soot yield after NaCl addition, the former dominated. Furthermore, the results from the two pathways also illustrated that the Na inhibit the OH formation, which was corresponding to the decreased OH intensity for NaCl-loaded coals, as detected by OH-PLIF, and thus was detrimental to soot consumption. Therefore, the presence of Na in the early stage of combustion inhibited the release of volatiles and PAHs, which was the main reason for the decreased soot generation amount of NaCl-loaded coal.

On the effects of walking speed, crowd density and human-to-source distance on pollutant dispersion in indoor spaces

The effects of walking speed, crowd density and human-to-source distance on pollutant dispersion in two scaled room models are investigated using simultaneous planar laser-induced fluorescence and particle-image velocimetry techniques. For a small 3 m high room, where the length-scales of the people and room are comparable, the walking motions significantly influenced the macro room mean flow patterns. This has a strong effect on the scalar dispersion properties as the magnitudes of the advective scalar fluxes are often comparable or larger than the turbulent scalar fluxes. As such, the scalar dispersion properties are case specific. For a large 9 m high room, the walking motion influenced only the local mean flow field. The increase in walking speed and crowd density improves the efficiency in which the scalar is transported and mixed with fresh ambient fluid out of the measurement plane (i.e. along the direction of the motion), leading to scalar-free zones observed on the opposite side of the room from the ventilation outlet. The area of the scalar-free zone increases with an increase in the walking speed and crowd density. The advective scalar fluxes are more sensitive to the human motion than the turbulent components, and as the mixing efficiency improves, the advective fluxes show a greater weakening with increased distance from source. The concentration PDFs in the near-source region can be described by the exponential function where the expected value at the 99% percentile can be derived as C99/crms′=4.61, which agreed well with the experimental measurements of 4.1 to 5.9.

LES and RANS Spray Combustion Analysis of OME3-5 and n-Dodecane

Clean-burning oxygenated and synthetic fuels derived from renewable power, so-called e-fuels, are a promising pathway to decarbonize compression–ignition engines. Polyoxymethylene dimethyl ethers (PODEs or OMEs) are one candidate of such fuels with good prospects. Their lack of carbon-to-carbon bonds and high concentration of chemically bound oxygen effectively negate the emergence of polycyclic aromatic hydrocarbons (PAHs) and even their precursors like acetylene (C2H2), enabling soot-free combustion without the soot-NOx trade-off common for diesel engines. The differences in the spray combustion process for OMEs and diesel-like reference fuels like n-dodecane and their potential implications on engine applications include discrepancies in the observed ignition delay, the stabilized flame lift-off location, and significant deviations in high-temperature flame morphology. For CFD simulations, the accurate modeling and prediction of these differences between OMEs and n-dodecane proved challenging. This study investigates the spray combustion process of an OME3 − 5 mixture and n-dodecane with advanced optical diagnostics, Reynolds-Averaged Navier–Stokes (RANS), and Large-Eddy Simulations (LESs) within a constant-volume vessel. Cool-flame and high-temperature combustion were measured simultaneously via high-speed (50 kHz) imaging with formaldehyde (CH2O) planar laser-induced fluorescence (PLIF) representing the former and line-of-sight OH* chemiluminescence the latter. Both RANS and LES simulations accurately describe the cool-flame development process with the formation of CH2O. However, CH2O consumption and the onset of high-temperature reactions, signaled by the rise of OH* levels, show significant deviations between RANS, LES, and experiments as well as between n-dodecane and OME. A focus is set on the quality of the simulated results compared to the experimentally observed spatial distribution of OH*, especially in OME fuel-rich regions. The influence of the turbulence modeling is investigated for the two distinct ambient temperatures of 900 K and 1200 K within the Engine Combustion Network Spray A setup. The capabilities and limitations of the RANS simulations are demonstrated with the initial cool-flame propagation and periodic oscillations of CH2O formation/consumption during the quasi-steady combustion period captured by the LES.

Quantitative acetone/toluene planar laser‐induced fluorescence measurements of equivalent ratio

AbstractIn this work, we establish a quantitative relationship between the fluorescence signal intensity of acetone and toluene and their concentration, and acetone/toluene planar laser‐induced fluorescence (PLIF) is developed to measure the concentrations of two components simultaneously, providing an equivalent ratio distribution of the flow field. Due to a thorough consideration of the tracer effect on each other's fluorescence signals, the uncertainty in the PLIF concentration measurement is reduced to 10.4%. Experimental results of OH‐PLIF and acetone/toluene PLIF indicate that the equivalence ratio distribution obtained by acetone/toluene PLIF in cold‐state flow fields can be employed to predict and analyze the trend of equivalence ratio distribution in the combustion field.

Advancements in laser-based spatiotemporal measurements of flow boiling

Recent advancements in laser and imaging systems, as well as in computational processing capabilities, have made quantitative optical imaging, which is often combined with laser illumination, highly adaptable, robust and reliable. Laser-based diagnostic techniques, such as planar laser-induced fluorescence (PLIF), offer the possibility of simultaneous spatiotemporally resolved measurements of temperature fields in the liquid phase at boiling conditions. In this paper, we examine the applicability of two-colour PLIF (2cPLIF), where the ratio between individual fluorescent emissions from uniformly dispersed dyes is used to take temperature measurements in the liquid phase in the presence of moving vapour-liquid interfaces typical of boiling flow. The implementation of 2cPLIF necessitates uniformity in the concentration of different dyes across the flow field. However, in the case of a multiphase flow such as boiling, thermophoresis can lead to inhomogeneous dye distributions. To overcome this challenge, a single-dye multispectral planar laser-induced fluorescence (SDMS-PLIF) method has been developed, which employs fluorescent emissions in different spectral bands of the same dye (Nile Red). The spectral characteristics of Nile Red were measured using a spectrometer to identify its temperature-sensitive bands over a wide range of dye concentrations, from 0.3 to 30 mg/L. Following this, we demonstrate the measurement capabilities of SDMS-PLIF thermography as applied to a boiling flow in a miniaturised vertical square channel, gaining insight into the thermohydrodynamic interactions between vapour bubbles and a heated wall.

Comprehending flame development and misfire at advanced engine conditions: Detailed experimental characterizations and machine learning-assisted kinetic analyses

Through comprehensive experimental and modeling efforts, this work unravels the underlying mechanisms governing flame development and misfire at advanced engine conditions that are representative of low-load and lean blow-out operations. Toward this, preliminary heat release, autoignition, and flame developing patterns are characterized, via a case study of n-heptane, at ultra-lean conditions in a well-controlled optical engine under various combustion modes including homogeneous charge compression ignition (HCCI), partially premixed combustion (PPC), and reactivity-controlled compression ignition (RCCI). Changes in preliminary heat release and flame developing patterns at three overall equivalence ratios (0.12, 0.18, and 0.24) are first characterized under the PPC mode. Flame development characteristics including flame areas and number of initial flame kernels at close-to-misfire conditions are further extracted and compared across the HCCI, RCCI, and three PPC modes, with two distinctive and one transition regimes identified. Further analyses indicate that sustainable flame development and misfire are largely controlled by the spatial distribution of local equivalence ratio (phi) and local temperature in the mixture, which dictate the initial flame kernel generation and the subsequent flame propagation through localized preliminary heat release and autoignition. Chemical kinetic modeling is also undertaken, using a recently updated gasoline chemistry model, in conjunction with a backpropagation neural network, where the predicted ignition delay map well captures the different regions of flame development. Further kinetic analysis and heat rate of production per reaction analysis corroborate the CH2O planar laser-induced fluorescence experiments and highlight the important chemical kinetics that govern the initial flame development patterns.

Effect of water content in ethanol on flame front wrinkling and curvature in a spark-ignition engine using OH PLIF imaging

The production of ethanol fuel involves separating water and ethanol by distillation and dehydration in an energy intensive process. To reduce the carbon footprint, hydrous ethanol is seen as a promising alternative. This study focused on the effect of water content in ethanol on flame development in a single-cylinder optical spark-ignition engine. Ethanol with 0%, 4% and 10% water content per volume was used with Port Fuel Injection (PFI) and Direct Injection (DI) for homogeneous and heterogeneous mixture preparation. Tests were also conducted with iso-octane for comparison. Flames captured by Planar Laser Induced Fluorescence (PLIF) of OH were spatially filtered to remove scales larger than the flame size, then the flame brush was quantified in terms of thickness, crossing frequency between instantaneous and filtered contours, and curvature. Increasing water content resulted in slower flame growth, with 10% hydrous exhibiting marginally higher flame speed than iso-octane. PFI led to faster flame growth and thicker flame brushes than DI at the same timing after ignition. When the brush thickness was normalised by flame radius, all hydrous fuels and iso-octane exhibited similar values with PFI, whilst anhydrous ethanol exhibited the thickest normalised brush. The alcohols maintained similar normalised thicknesses with DI and iso-octane exhibited the thickest normalised brush. When flames of the same radii were considered with PFI at the same timing, the fuels with sequentially lower laminar burning velocity were associated with larger crossing frequency. For PFI, increasing water content resulted in decreased flame roundness irrespective of size, with the 4% hydrous and iso-octane exhibiting similar values. With DI, anhydrous ethanol flames were rounder than the 4% hydrous when averaged over all cycles, but marginally rounder than the 10% hydrous and iso-octane. Increasing water content widened the curvature distribution and increased the mean with PFI. Flame roundness decreased with increase in mean curvature and Lewis number for both PFI and DI.

Investigation of the three-dimensional structure of low-swirl methane-hydrogen flames with multiple UV cameras-based OH* chemiluminescence tomography

Blending hydrogen with natural gas is useful for reducing CO2 emissions, but this alters the flame structure, creating challenges for flame stability. Numerous researches on methane-hydrogen flame structure have been carried out based on two-dimensional combustion diagnostic techniques such as flame chemiluminescence and planar laser-induced fluorescence. In this paper, a low-cost OH* chemiluminescence imaging system consisting of 8 ultraviolet (UV) cameras is proposed to reconstruct the three-dimensional (3D) structure of methane-hydrogen flames, and validated through use of the correlation coefficient. Further experimental investigations of the low-swirl methane-hydrogen flames are performed by this computed tomography of chemiluminescence (CTC) system. The flame properties are determined to evaluate the effects of various fractions of blended hydrogen on the flame structure, including the flame center of mass, flame surface density and fractal dimension. Results showed that the flame initially has bowl-shape structure. The flame height gradually decreases and the flame cross-sectional area increases as the blended hydrogen fraction increases. Meanwhile, the bottom of the flame moves toward the nozzle outlet. Nevertheless, when the blended hydrogen fraction reaches 50%, the flame transforms into a cup-shaped flame and shows a double-layer flame structure. When the flame is bowl-shaped, the flame center of mass moves away from the nozzle center axis with increasing blended hydrogen fraction, but the fractal dimension and flame surface density are not sensitive to the blended hydrogen fraction. In contrast, when the flame is cup-shaped, the flame center of mass moves towards the nozzle center axis, and the flame surface density and fractal dimension increase significantly, indicating the increase of flame wrinkling. These results reveal that blending hydrogen leads to two distinct flame structures and characteristics in low-swirl flame, also demonstrate that the proposed 3D low-cost CTC system based on multiple UV cameras is well-suited for combustion diagnostics.

On the errors and their mitigation in planar laser induced fluorescence

In planar laser induced fluorescence (PLIF), scalar concentration fields are obtained from fluorescence images of the flow where the scalar is ‘tagged’ with a suitable fluorescent dye and illuminated with a laser sheet. While the fluorescence occurs, the intensity of the laser sheet is attenuated along its passage through the dye field. This paper discusses the effect of correcting for the attenuation of the laser by the dye while obtaining the scalar concentration field from the fluorescent images of the flow. If the attenuation correction cannot be done, the paper discusses three possible calibration scenarios to minimise the error. It is shown that the error in ignoring the attenuation due to turbulent concentration fluctuations cannot be corrected by any means. However, the remaining error can be exactly corrected if it were possible to calibrate with the mean concentration field. It is shown that a uniform concentration field, centred around the mean field, greatly reduces the error when compared to having no attenuation correction but still is significantly more when compared to the use of the average field. Relying on these results, we propose an iterative technique which ideally achieves the accuracy obtainable when calibrating with the mean concentration field, but which requires no reference cell. In addition, the paper explores the removal striations, of a common artefact during PLIF image acquisition with origins in the image optics. A technique to remove the same is proposed and its advantages discussed when compared to available techniques.