Plagioclase Symplectites Research Articles

Petrology, phase equilibria modelling, and fluid inclusion study of mafic granulites from Bhavani Suture Zone, Southern India

We report new petrology, mineral chemistry, P–T conditions, and fluid inclusion data on mafic granulites from the Mettupalayam region along the Bhavani Suture Zone, Southern Granulite Terrane, India. Phase equilibria modelling of mafic granulites yielded peak P–T conditions of 780–860 °C and 7.6–10.1 kbar followed by a near isothermal decompression along a clockwise P–T path. The trapped fluid inclusions in the peak metamorphic minerals display a melting temperature range from −57.4 °C to −56.6 °C, close to the triple-point temperature of pure CO2. The primary inclusions homogenized at −18.9 °C to +0.2 °C, corresponding to density values of 0.93–1.03 g/cm3. Homogenization of the secondary inclusions occurred within the range from −6.3 to +18.1 °C, corresponding to low CO2 densities of 0.79–0.96 g/cm3. From the textural characteristics of the high-density primary carbonic fluid inclusions, we interpret these inclusions as the CO2-rich syn-metamorphic fluid present during the high-grade metamorphism. The secondary fluids characterised by lower densities have undergone re-equilibration during the exhumation stage (decompression) from the peak granulite-facies metamorphism along a clockwise P–T trajectory. This interpretation is consistent with the occurrence of hornblende + plagioclase symplectite around the porphyroblastic garnet, suggesting decompression. We infer that the high-density CO2 was the dominant syn-metamorphic fluid components present during the granulite-facies metamorphism in the Mettupalayam region. Such carbonic fluids, possibly derived by degassing from carbonates or mantle sources, probably played a significant role in stabilizing high-grade mineral assemblages along this collisional suture zone.

Two Types of Symplectites in a Lower Crust Granulite Xenolith from the Zarnitsa Kimberlite (Yakutia): A Record of Si-Metasomatism and Decompression

Abstract ––The paper presents data on a granulite xenolith from the Zarnitsa kimberlite pipe (Yakutia, Russia), which stores a record of two metasomatic events in addition to the main stage of metamorphism. The granulitic mineral assemblage consists of garnet, clinopyroxene, and plagioclase as main phases. The granulite xenolith contains kyanite–clinopyroxene and later orthopyroxene–plagioclase symplectites. Kyanite–clinopyroxene symplectites appear as short veins inside or between grains of rock-forming minerals. Orthopyroxene–plagioclase symplectites form kelyphite rims in all garnets or occur as veins in garnet grains. The P–T conditions for granulite in the lower crust reconstructed by Perple_X phase equilibrium modeling are 700–750 ℃ and 1.2–1.3 GPa. According to TWQ thermodynamic calculations, the kyanite–clinopyroxene symplectites were produced by Si-metasomatism at invariable Р–Т parameters. The growth of orthopyroxene–plagioclase symplectites after garnet was maintained by Ca inputs upon heating and decompression (200 ℃ temperature increase and 0.6 GPa pressure decrease) while the xenolith was transported by ascending kimberlite melt.

Omphacite breakdown, symplectite formation and carbonate metasomatism in a retrograded continental eclogite: Implications for the exhumation of the Tso Morari Crystalline Complex (Trans-Himalaya, NW India)

The India-Eurasia collision zone in eastern Ladakh, India, is marked by the Tso Morari Crystalline Complex (TMCC), which underwent continental subduction, eclogite grade metamorphism, and rapid exhumation during the Himalayan orogeny. The TMCC is characterized by eclogitic enclaves, metamorphic evolution of which has been extensively studied in the past. Detailed petrography, mineral chemistry, Raman spectroscopy, and P-T-X pseudosection modelling of two such eclogite samples from the core and western margin of TMCC were carried out to address the differences and discrepancies from previous studies. Our study suggests peak metamorphism at ∼2.75 ± 0.1 GPa and ∼550 ± 50 °C, followed by a decompression stage at ∼1.50 ± 0.1 GPa and ∼580 ± 50 °C and subsequent high-temperature overprint at ∼0.85 ± 0.1 GPa and ∼680 ± 50 °C. Fine-grained grain boundary omphacite + garnet + amphibole symplectite colonies indicate exhumation along with fluid infiltration. The transition of omphacite into a more calcic variety and its subsequent replacement with amphibole are also observed. Presence of diopside + plagioclase symplectite indicates post-peak decompression and fluid infiltration. Carbonates in the matrix as veins and within fractures indicate late-stage fluid infiltration and metasomatism. Our study shows that lawsonite and/or Na-amphibole have not played any significant role in the metamorphic evolution of TMCC. In contrast to most of the previous studies carried out in TMCC, we opine that omphacite breakdown and metasomatism through externally derived carbonaceous fluids played a vital role in the exhumation and retrogression. We further opine that our mineral chemistry data and metamorphic modelling resemble a continental eclogite and mark differences from oceanic eclogites.

Isothermal compression of an eclogite from the Western Gneiss Region (Norway)

AbstractIn the Western Gneiss Region in Norway, mafic eclogites form lenses within granitoid orthogneiss and contain the best record of the pressure and temperature evolution of this ultrahigh‐pressure (UHP) terrane. Their exhumation from the UHP conditions has been extensively studied, but their prograde evolution has been rarely quantified although it represents a key constraint for the tectonic history of this area. This study focused on a well‐preserved phengite‐bearing eclogite sample from the Nordfjord region. The sample was investigated using phase‐equilibrium modelling, trace‐element analyses of garnet, trace‐ and major‐element thermobarometry and quartz‐in‐garnet barometry by Raman spectroscopy. Inclusions in garnet core point to crystallization conditions in the amphibolite facies at 510–600°C and 11–16 kbar, whereas chemical zoning in garnet suggests growth during isothermal compression up to the peak pressure of 28 kbar at 600°C, followed by near‐isobaric heating to 660–680°C. Near‐isothermal decompression to 10–14 kbar is recorded in fine‐grained clinopyroxene–amphibole–plagioclase symplectites. The absence of a temperature increase during compression seems incompatible with the classic view of crystallization along a geothermal gradient in a subduction zone and may question the tectonic significance of eclogite facies metamorphism. Two end‐member tectonic scenarios are proposed to explain such an isothermal compression: Either (1) the mafic rocks were originally at depth within the lower crust and were consecutively buried along the isothermal portion of the subducting slab or (2) the mafic rocks recorded up to 14 kbar of tectonic overpressure at constant depth and temperature during the collisional stage of the orogeny.

Multi‐stage metamorphism of ultrahigh‐temperature Mg‐Al granulites during Gondwana assembly: Evidence from southern India

The Southern Granulite Terrane (SGT) in India hosts granulite facies rocks metamorphosed at ultra‐high temperature (UHT) conditions in the various crustal blocks, as well as within the Palghat‐Cauvery Suture Zone (PCSZ), that is considered as a trace of the Late Neoproterozoic—Cambrian Gondwana suture. Here we investigate UHT granulites from the northern margin of the Madurai Block adjacent to the PCSZ where Mg‐Al‐rich granulites are exposed. We identify sodic gedrite + kyanite in these rocks as the high‐pressure prograde stage assemblage, followed by sillimanite‐garnet‐orthopyroxene that formed during pressure decrease and temperature increase. The rare remnant gedrite is also stable at the near‐peak UHT metamorphism until it was replaced by sapphirine. The rocks subsequently underwent decompression that formed sapphirine + cordierite and sapphirine + plagioclase symplectite around sillimanite. Dehydration during decompression generated orthopyroxene‐sillimanite‐quartz assemblage with the appearance of sapphirine, defining the diagnostic mineral assemblage indicative of peak UHT metamorphism (T > 900°C) at relatively high‐pressure (P > 9 kbar). The UHT peak metamorphism in this region is consistent with the results of P–T calculations using conventional geothermometers and phase equilibrium modelling (T up to 1,050°C, P over12 kbar). Zircon and monazite geochronology on the UHT metapelites indicate distinct stages. Detrital zircon grains in the metasediments indicate protolith from ca. 2.5 Ga igneous source and the metamorphic overgrowths yield 206Pb/238U mean ages concentrated at ca. 550–520 Ma. Monazite ages define another younger group 206Pb/238U mean ages at ca. 450 Ma. The prograde high‐pressure granulite‐facies metamorphism and following UHT event correlate with the subduction‐collision tectonics at 550–500 Ma associated with the final stage of amalgamation of the Gondwana supercontinent, while the 420–460 Ma monazite age records a later hydration at the post‐orogenic stage, possibly associated with deep shearing and fluid influx.

Mechanism of crustal thickening and exhumation of southern Lhasa terrane during the Late Cretaceous: Evidence from high-pressure metamorphic rocks of the Eastern Himalayan Syntaxis

AbstractThe mechanism of Late Cretaceous crustal thickening and exhumation of the southern Lhasa terrane is critical for understanding the tectonic evolution of the Tibetan Plateau. High-pressure metamorphic rocks from the lower crust are good candidates for addressing this issue. In this study, we focus on Late Cretaceous, high-pressure, garnet-bearing amphibolites from the Nyingchi Complex of the Eastern Himalayan Syntaxis and present an integrated study of geochronology, petrography, mineral chemistry, and thermodynamic modeling. Petrographic data determine three metamorphic stages (M1–M3). The M1 stage is characterized by a peak mineral assemblage of garnet + hornblende + albite + rutile + muscovite + quartz, which is followed by a post-peak (M2) assemblage of garnet + hornblende + plagioclase + epidote + biotite + rutile + quartz. The late retrograde stage (M3) is defined by hornblende + plagioclase symplectites surrounding garnet porphyroblasts. Mineral chemistry, with thermodynamic modeling, constrains the P-T conditions of the M1–M3 stages to 14–19 kbar/660–720 °C, 8–10 kbar/650–660 °C, and <7 kbar/<600 °C, respectively. Metamorphic zircons yield a concordant age at 90 Ma, which indicates the formation of garnet-bearing amphibolites. These results indicate a P-T-t path involving near-isothermal decompression for garnetbearing amphibolites, which suggests that the Nyingchi Complex underwent peak-pressure metamorphism (M1) at 90 Ma, followed by rapid exhumation to the depth of 32–26 km along the subduction channel. Moreover, the garnet-bearing amphibolites are considered to be the product of high-pressure metamorphism of mafic crust at the base of the Gangdese belt. Hence, the crust of the Gangdese belt experienced significant crustal thickening of up to 60 km at 90 Ma.

Tectonothermal transition from continental collision to post‐collision: Insights from eclogites overprinted in the ultrahigh‐temperature granulite facies (Yadong region, central Himalaya)

AbstractEclogites and granulites are fossil records of orogenies and provide crucial evidence of geodynamic processes. Incomplete knowledge on both hampers the establishment of detailed tectonothermal models for the central Himalaya. Utilizing detailed petrography, pseudosection modelling, mineral thermometers, and zircon petrochronology, the granulitized eclogites discovered firstly at Yadong region at the southern tip of the Yadong–Gulu Rift record five metamorphic stages. The epidote–amphibole eclogite facies metamorphism (M1) is preserved in the garnet core including the relics of omphacite. The peak eclogite facies metamorphism (M2) is represented by the garnet rim and melt‐related polymineralic inclusions. From M1 to M2, the eclogites experienced a prograde path from 1.7 GPa/620°C to 2.1 GPa/750–770°C. The clockwise pressure–temperature path, the occurrence as coherent layers in gneiss, and zircon U–Pb dating imply that the Indian crust subducted to a maximum depth of ~60 km in the central Himalaya, close to the Moho of southern Lhasa block at c. 17 Ma. Afterwards, the exhumation started with decompressional heating. In the high‐pressure granulite facies metamorphism (M3), almost all the omphacite broke down to the symplectites of diopside and plagioclase. The subsequent two‐pyroxene granulite facies metamorphism (M4) is characterized by the intergrowth of clinopyroxenes and orthopyroxenes, high‐Ti amphibole, and antiperthite. The exhumed eclogites eventually reached ultrahigh‐temperature conditions of ~0.8 GPa/950–1,000°C in M4 and were near completely transformed into mafic granulites. At the final stage, these granulitized eclogites cooled in the middle crust to amphibolite facies (M5) of 0.6 GPa/700–750°C. Given the spatio‐temporal consistencies between the granulitized eclogites, post‐collisional magmatism, and north‐trending rifts, the heat source of the ultrahigh‐temperature metamorphism was attributed to the upwelling of asthenospheric mantle due to slab tear of subducted Indian lithosphere. The granulitized eclogites from Yadong evolved from the high‐pressure eclogite to the ultrahigh‐temperature granulite facies, which recorded the transitions from collisional convergence to post‐collisional extension during their exhumation.

Melt-rock interaction in the lower crust based on silicate melt inclusions in mafic garnet granulite xenoliths, Bakony–Balaton Highland

Major and trace element composition of silicate melt inclusions (SMI) and their rock-forming minerals were studied in mafic garnet granulite xenoliths from the Bakony–Balaton Highland Volcanic Field (Western-Hungary). Primary SMIs occur in clinopyroxene and plagioclase in the plagioclase-rich domains of mafic garnet granulites and in ilmenite in the vicinity of these domains in the wall rock. Based on major and trace elements, we demonstrated that the SMIs have no connection with the xenolith-hosting alkaline basalt as they have rhyodacitic composition with a distinct REE pattern, negative Sr anomaly, and HFSE depletion. The trace element characteristics suggest that the clinopyroxene hosted SMIs are the closest representation of the original melt percolated in the lower crust. In contrast, the plagioclase and ilmenite hosted SMIs are products of interaction between the silicic melt and the wall rock garnet granulite. A further product of this interaction is the clinopyroxene–ilmenite±plagioclase symplectite. Textural observations and mass ­balance calculations reveal that the reaction between titanite and the silicate melt led to the formation of these assemblages. We propose that a tectonic mélange of metapelites and (MOR-related) metabasalts partially melted at 0.3–0.5 GPa to form a dacitic–rhyodacitic melt leaving behind a garnet-free, plagioclase+clinopyroxene+orthopyroxene+ilmenite residuum. The composition of the SMIs (both major and trace elements) is similar to those from the middle Miocene calc-alkaline magmas, widely known from the northern Pannonian Basin (Börzsöny and Visegrád Mts., Cserhát and Mátra volcanic areas and Central Slovakian VF), but the SMIs are probably the result of a later, local process. The study of these SMIs also highlights how crustal contamination changes magma compositions during asthenospheric Miocene ascent.

Petrology and zircon U-Pb dating of the Neoarchean scapolite-garnet calc-silicate from the Namakkal Block of the Southern Granulite Terrain, India, and their geological implications

本文对印度南部麻粒岩地体Namakkal陆块Tammampatti地区方柱石石榴子石钙硅酸盐岩进行了详细的岩石学、锆石U-Pb年代学和变质相平衡模拟研究，以研究其岩石成因和地质意义。岩相学观察识别出两阶段变质矿物组合：第一阶段为石榴子石+方柱石+斜长石+榍石+钛铁矿；第二阶段为石榴子石边部的绿帘石和方柱石边缘的方解石、斜长石和石英冠状体。CL图像分析显示锆石可分为两种，分别为高亮度和低亮度的变质锆石。LA-ICP-MS锆石U-Pb定年得到高亮度变质锆石²⁰⁷Pb/²⁰⁶Pb加权平均年龄为2562±17Ma，而低亮度变质锆石的²⁰⁷Pb/²⁰⁶Pb加权平均年龄稍年轻，为2495±15Ma。基于相平衡模拟计算了2个样品18ID-24和18ID-25的P-T视剖面图，确定它们峰期变质PT条件分别为4.3~7.1kbar、800~960℃和4.0~7.8kbar、750~854℃。高亮度变质锆石年龄2562±17Ma与Namakkal陆块紫苏花岗岩的原岩结晶年龄相当，其代表了紫苏花岗岩的原岩侵入导致的接触交代变质作用形成方柱石石榴子石钙硅酸盐岩的时代；低亮度变质锆石年龄2495±15Ma与该地区大约2530~2440Ma的高温-超高温变质作用时代相吻合，因此认为其代表区域性变质作用叠加的时代。根据全岩成分以及矿物组合，我们推测该岩石为中酸性岩浆岩（紫苏花岗岩原岩）与碳酸盐岩发生交代变质作用的产物。;Granulite terranes are considered as windows open to the lower crustal processes of the Earth. In this paper, we present detailed petrology, zircon U-Pb dating and phase equilibrium modeling of scapolite-garnet calc-silicate samples from the Tammampatti area of the Namakkal Block, Southern Granulite Terrain, India. On the basis of petrographic observation, two stages of metamorphic mineral assemblages were determined, which are garnet+scapolite+plagioclase+sphene+ilmenite (M1) and epidote corona+the symplectite of calcite, plagioclase and quartz. Cathodoluminescence (CL) imaging reveals that there are two types of metamorphic zircons: zircons with high luminescence and another is characterized by low luminescence. Zircon U-Pb dating using LA-ICP-MS yielded a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2562±17Ma for the zircons with high luminescence, whereas those with low luminescence have a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2495±15Ma. The peak metamorphic conditions of two samples 18ID-24 and 18ID-25 are constrained to be 800~960℃/4.3~7.1kbar and 750~854℃/4.0~7.8kbar, respectively. The metamorphic age of 2562±17Ma is the similar as the crystallization age of the charnockite pluton within the Namakkal Block, which is interpreted to represent the timing of contact metasomatism caused by magma emplacement of the charnockite. The metamorphic age of 2495±15Ma is considered to be the overprinted time by the previously reported ca. 2530~2440Ma regional HT-UHT metamorphism. The calc-silicate should be resulted from metasomatism of intermediate-acid pluton (protolith of charnockite) and carbonatite.

Partial melting due to breakdown of phengite and amphibole in retrogressed eclogite of deep Precambrian crust: An example from the Algonquin terrane, western Grenville Province, Canada

Characterizing partial melting of eclogite in Precambrian orogens is critical to understanding the petrological processes that operate in the deep orogenic crust. Retrogressed eclogite from the Algonquin terrane in the western Grenville Province, Canada, was taken as an example to study such processes. The studied samples contained the assemblage of garnet, omphacite, amphibole, phengite, biotite, and rutile at peak pressure. Various exhumation- and melt-related textures formed show evidence for a complex post-peak pressure history. Rutile is only found in the core of garnet, whereas ilmenite-bearing assemblages predominate in the garnet rim and the matrix. Symplectite of diopside + plagioclase + amphibole replaced former omphacite. Symplectite of amphibole and plagioclase formed as a corona around garnet. Polymineralic inclusions of plagioclase + K-feldspar ± ilmenite ± biotite ± amphibole ± apatite ± sulfides in garnet crystallized from melt, which was captured during garnet growth and reacted with the host. Cusps of plagioclase into the boundaries of other phases (e.g. garnet and clinopyroxene) mimic the original melt-solid interface. Neoblasts of garnet with euhedral crystal faces were formed as a peritectic phase during eclogite melting. Leucocratic veins without external connection, present in the sampled mafic pod at outcrop scale, are interpreted as crystallized pockets of melt which derived internally. Pseudosection modeling of the studied samples along with compositional isopleths of chemically zoned garnet yielded an exhumation path from 1.7 ± 0.1 GPa, 680 ± 50 °C to 1.3 ± 0.1 GPa, 920 ± 50 °C. Along this path, the modal content of melt increased in response to the breakdown of phengite and amphibole along with involvement of omphacite and rutile. The melt crystallized during cooling and equilibrated at 0.6–0.8 GPa, 710–750 °C, estimated using empirical thermobarometry. This study shows that metabasite from Proterozoic collisional orogens can be partially melted on the exhumation and heating path through phengite- and amphibole-dehydration melting.

Cenozoic retrogression and exhumation of the amphibolites in the eastern Gangdese Belt, SW China

Abstract The collision between India and Asia is marked by the Yarlung Zangbo suture zone, which can be traced from Tibet into northwest Yunnan. The suture zone provides a record of the subduction of Neotethyan oceanic lithosphere beneath the Lhasa Block, creating the Gangdese magmatic belt, prior to the India–Asia collision. This paper reports petrological, zircon U–Pb, and whole-rock elemental and isotope data for amphibolite from the extension of the Gangdese belt in northwestern Yunnan. Two metamorphic stages are identified in relict amphibolite-facies rocks preserved in granitic gneisses from the belt. They are early amphibolite-facies metamorphism (M1) and late amphibolite-facies retrograde metamorphism (M2). The assemblage of M1 comprises garnet, amphibole, and plagioclase that formed at 0.89–0.97 GPa and 658–700 °C. Dating of syn-metamorphic zircons assigns this event to the middle Eocene (44–38 Ma). Symplectites (corona) of amphibole, plagioclase, and quartz surrounding garnet formed during retrograde stage M2, at 30–29 Ma, under P–T conditions of 0.41–0.68 GPa and 549–716 °C. The amphibolites display geochemical characteristics similar to those of mid-ocean ridge basalt, with eNd(t) values of +1.8 to +8.9, and are inferred to have formed in a back-arc-basin setting, suggesting that they constitute part of the lithospheric mantle of the Tengchong terrane that lies to the east. The amphibolite-facies metamorphism was related to underplating of the Indian plate during the India–Asia collision, which led to clockwise rotation of eastern Tibet during the middle Eocene, generating amphibolite recrystallization and, subsequently, with ongoing convergence of the two plates, exhumation of the region during the middle Oligocene.

Orthovanadate wakefieldite-(Ce) in symplectites replacing vanadium-bearing omphacite in the ultra-oxidized manganese deposit of Praborna (Aosta Valley, Western Italian Alps)

Abstract Because of their unique structure and properties, rare-earth (REE) orthovanadates have been extensively employed for decades in advanced ceramics, in particular in the laser industry in replacement of Nd:YAG. A Ca-bearing REE orthovanadate with the empirical formula (Ce0.279Ca0.271Y0.267Gd0.057Nd0.055Dy0.032Sm0.027La0.020Th0.027Sr0.002)(V0.9085+Cr0.0673+Fe0.0173+As0.0055+)O4⋅nH2O has been found in metacherts from Praborna (Italian Alps) as micrometer-sized euhedral crystals in clinopyroxene + plagioclase symplectites replacing eclogite-facies vanadium-bearing omphacite (Aegirine55–48Jadeite42–33Diopside10–8 with V2O3 ≤ 1.39 wt%). We applied the synchrotron radiation, single crystal, micro-diffraction technique, recently optimized at ID09A beamline (ESRF, France), to determine the crystal structure of this mineral. It is tetragonal and isostructural with zircon, with a = 7.2233(12) Å, c = 6.3949(18) Å, V = 333.66(13) Å3, Z = 4, space group I41/amd, and it has been therefore identified as Ca- and Y-bearing wakefieldite-(Ce) (ideally CeV5+O4). Cell parameters are in agreement with those of synthetic Ce0.7Ca0.3VO4. Raman spectra of the studied wakefieldite-(Ce) are comparable with natural and synthetic wakefieldite-(Ce) spectra and revealed the presence of OH groups and/or water of hydration, which is also suggested by the low totals in microprobe analyses. Mass balance indicates that wakefieldite-(Ce) is a by-product of the omphacite breakdown; omphacite and Mn-rich epidote, a minor reactant, provided vanadium and REE, respectively. Petrological observations and thermodynamic modeling suggest that the mineral, coexisting with hematite, Mn-rich epidote, and braunite, formed during retrogression to greenschistfacies conditions at ultra-oxidized conditions (DFMQ ≥ +16 log units), which are often observed in Mn-oxide ores. Wakefieldite is an effective scavenger of REE in oxidized geological environments at P-T conditions that range from sedimentary to medium-grade metamorphic settings, even where the REE bulk concentration is negligible. Its rarity reflects both the overall low abundance of vanadium and the need for ultra-oxidized conditions that are rarely achieved in metamorphic rocks, where REE phosphates (i.e., monazite, xenotime) are commonly found instead.

U–Pb geochronology and REE geochemistry of zircons in mafic granulites from the Lützow-Holm complex, East Antarctica: Implications for the timing and P–T path of post-peak exhumation and Antarctica–Sri Lanka correlation

We report new petrological and geochronological data, together with zircon REE patterns, of mafic granulites from the Lützow-Holm Complex (LHC), East Antarctica, and investigate the pressure-temperature-time (P-T-t) evolution of granulite-facies metamorphism in order to unravel the timing and tectonics of Neoproterozoic collisional processes related to the amalgamation of Gondwana. The LHC is composed of three tectonic units: a ca. 2.5 Ga continental fragment (Shirase Microcontinent), a ca. 1.0 Ga magmatic arc (Prince Olav–Vijayan Block; PVB), and a latest Neoproterozoic suture zone (Lützow-Holm Bay Suture Zone; LHSZ) separating the two. Mafic granulites from Tenmondai Rock and Sudare Rock, which belong to the PVB and the LHSZ, respectively, contain orthopyroxene + plagioclase symplectites around garnets, probably formed during post-peak decompression. The application of phase equilibrium modeling and geothermobarometry indicates similar peak P-T ranges of 850–860 °C/7.8–8.4 kbar (Tenmondai Rock) and 800–810 °C/8.5–9.0 kbar (Sudare Rock), together with clockwise P-T paths for both localities. LA-ICP-MS zircon U-Pb dating of the studied granulites yielded Mid-Neoproterozoic magmatic ages of >808 Ma (Tenmondai Rock) and >783 Ma (Sudare Rock) from igneous cores, and Late Neoproterozoic to Cambrian metamorphic ages of ca. 630–481 Ma from overgrown rims and/or structureless grains. Zircon REE analyses indicate that younger 560–510 Ma metamorphic zircons from the localities exhibit heavy-REE-enriched patterns and negative Eu anomalies, suggesting that the consumption of garnet and growth of plagioclase took place during zircon growth. This process was probably related to the formation of post-peak decompressional textures (orthopyroxene + plagioclase symplectite around garnet) observed in the mafic granulites. The results of this study therefore indicate that post-peak exhumation of the LHC started at ca. 560 Ma. Available U-Pb and REE data from 560 to 510 Ma metamorphic zircons of the Highland Complex, Sri Lanka, show similar heavy-REE-enriched patterns and Eu negative anomalies, suggesting that post-peak exhumation of both the LHC and the Highland Complex took place almost simultaneously at ca. 560 Ma. The results of this study further support the proposed tectonic model in which the Highland Complex and the LHSZ are parallel collisional sutures formed during the Late Neoproterozoic-Cambrian Gondwana amalgamation.

Subduction and exhumation of Luliangshan eclogite in the North Qaidam, northern Tibet: Constraints from petrology, geochemistry and phase equilibrium modelling

Eclogites in the high‐pressure (HP) and ultrahigh‐pressure (UHP) belt record important information about the subduction process and evolution history of the orogenic belt. The Luliangshan eclogites surrounded by granitic gneiss or paragneiss as lenses are exposed in the western segment of the North Qaidam UHP metamorphic belt, northwestern China. Petrology, mineral chemistry, and P–T pseudosection modelling show that the eclogites have experienced a multi‐stage metamorphic process. The peak eclogite‐facies metamorphic stage, is characterized by omphacite in matrix and as inclusion in garnet, with the peak mineral assemblages of garnet + omphacite + rutile + quartz atT > 790°C andP > 25.5 kbar. The initial HP granulite‐facies retrogression is characterized by the symplectite of diopside + plagioclase around omphacite, with P–T conditions of 911°C and 16.9 kbar. The subsequent amphibolite‐facies stage is characterized by amphibole + plagioclase symplectite around the clinopyroxene, with the metamorphic conditions of 674–686°C and 6.4–6.9 kbar. Zircon U–Pb analyses yielded two metamorphic age clusters: (a) HP granulite‐facies metamorphic age of 422–425 Ma, and (b) amphibolites‐facies retrograde age of 397–420 Ma. The protolith of eclogite have geochemical characteristics similar to those of normal mid‐ocean ridge basalt (N‐MORB); and the varyingεNd(t) values (−6.3 to 2.1) indicate that the Luliangshan eclogites were derived from a mantle source with rare crustal contamination. Combining these data with previous studies, a multi‐stage tectonic model can be proposed: In the Early Neoproterozoic, the protolith of the Luliangshan eclogites were emplaced into ancient continental crust; during 460–430 Ma, following the oceanic subduction, the subduction of continental crust was dragged by the oceanic slab and continue to subduct towards the Qilian Block, and metamorphosed at the depth of at least 75 km. After a long and slow exhumation process, it returned to the shallow crust.

Paleoproterozoic UHT metamorphism with isobaric cooling (IBC) followed by decompression–heating in the Khondalite Belt (North China Craton): New evidence from two sapphirine formation processes

AbstractInterpretation of reaction microstructures may provide constraints on the P–T path followed by rocks, with implications for the geodynamic evolution. Sapphirine generally occurs in diverse microstructures in ultrahigh‐temperature (UHT) Mg–Al‐rich granulites. Understanding multi‐stage sapphirine formation processes and the resultant P–T path may provide insights into the cause of UHT metamorphism, which is otherwise under broad debate. Here, we investigate samples of UHT granulite containing two distinct types of sapphirine from the Dongpo locality in the Khondalite Belt, North China Craton, with the aim of understanding the processes of sapphirine formation and the metamorphic evolution of the host rocks. Petrographic observations show that early sapphirine, which occurs as coronas on spinel and as single porphyroblasts, formed together with biotite, sillimanite, and inclusion‐rich garnet. Late symplectitic sapphirine along with fine‐grained plagioclase and spinel plus plagioclase symplectites, formed by consumption of sillimanite, biotite, and garnet. Three pseudosections based on the bulk compositions of microdomains inferred to reflect spatially restricted equilibrium suggest that the rocks record near isobaric cooling (IBC) from ~980 to 830ºC at ~0.9 GPa for early sapphirine formation, and decompression and heating to ≤0.7 GPa and ~900ºC for late sapphirine formation. Our study in combination with other metamorphic P–T and age information reveals the common occurrence of IBC paths and long duration (c. 1.93 to 1.86 Ga) regional UHT metamorphism in the Khondalite Belt, North China Craton. Locally, this is followed by decompression–heating paths at c. 1.86 Ga. The Palaeoproterozoic UHT metamorphism with long‐lived IBC path in the Khondalite Belt, North China Craton supports large hot orogen model in the amalgamation of this part in the supercontinent Nuna.

Metamorphic Petrology of Clinopyroxene Amphibolite from the Xigaze Ophiolite, Southern Tibet: P-T Constraints and Phase Equilibrium Modeling

The clinopyroxene amphibolite from the Bailang terrane is located in the central section of the Yarlung Zangbo suture zone (YZSZ), southern Tibet. The study of it is expected to provide important clues for the subduction of the Neo-Tethyan Ocean below the Asian Plate and thus for better understanding of the development of the India-Asia collision zone. Based on integrated textural, mineral compositional, metamorphic reaction history and geothermobarometric studies of the clinopyroxene amphibolite within a serpentinite melange, four overprinted metamorphic stages are established. They are the first metamorphic record of M1 stage indicated by a relict assemblage of plagioclase+clinopyroxene+amphibole, an early M2 stage characterized by an assemblage of medium-grained clinopyroxene+amphibole+plagioclase+quartz as well as rutile inclusion in titanite, which is formed during burial process, an isobaric cooling M3 stage which is characterized by an assemblage of clinopyroxene+amphibole+plagioclase+titanite, and a decomposing retrograde stage M4, which is represented by the amphibolite+plagioclase symplectite+titanite+ rutile+quartz. By applying the THERMOCALC (versions 6.2 and 6.3) technique in the NCFMASHTO system, the P-T conditions estimated from M1 to M4 stages are ca. 8.6 kbar/880 °C, 10.8-13.4 kbar/800-840 °C, 12.7-13.2 kbar/650-660 °C and <11.2 kbar/640 °C, respectively. The mineral assemblages and their P-T conditions define a counterclockwise P-T path for the clinopyroxene amphibolite of the Xigaze ophiolite, suggesting that the rocks underwent a cooling process during burial from magmatic protolith, and a decompressing stage after the pressure peak metamorphic conditions, which implies that the Bailang terrane of the Xigaze ophiolite may have experienced subduction/collision-related tectonic processes. The peak metamorphism reaches to the transitional P-T conditions among amphibolite facies, granulite facies and eclogite facies with a burial depth of 30–40 km. After exhumation of the ophiolitic unit to the shallow crustal levels, the clinopyroxene amphibolite exposes to a high fO2 condition on the basis of the stable epidotebearing assemblage in the T-MO2 diagrams. A late subgreenschist facies overprinting subsequently occurs, the relevant mineral assemblage is prehnite+albite+chlorite+epidote+quartz.

Myrmekite and strain weakening in granitoid mylonites

Abstract. At mid-crustal conditions, deformation of feldspar is mainly accommodated by a combination of fracturing, dissolution–precipitation, and reaction-weakening mechanisms. In particular, K-feldspar is reaction-weakened by the formation of strain-induced myrmekite – a fine-grained symplectite of plagioclase and quartz. Here we use electron backscattered diffraction to (i) investigate the microstructure of a granodiorite mylonite, developed at ∼ 450 °C during cooling of the Rieserferner pluton (Eastern Alps); and (ii) assess the microstructural processes and the weakening associated with myrmekite development. Our analysis shows that the crystallographic orientation of plagioclase in pristine myrmekite was controlled by that of the replaced K-feldspar. Myrmekite nucleation resulted in both grain-size reduction and anti-clustered phase mixing by heterogeneous nucleation of quartz and plagioclase. The fine grain size of sheared myrmekite promoted grain-size-sensitive creep mechanisms including fluid-assisted grain boundary sliding in plagioclase, coupled with heterogeneous nucleation of quartz within creep cavitation pores. Flow laws, calculated for monomineralic quartz, feldspar, and quartz + plagioclase aggregates (sheared myrmekite) during deformation at 450 °C, show that grain-size-sensitive creep in sheared myrmekite accommodated strain rates several orders of magnitude higher than monomineralic quartz layers deforming by dislocation creep. Therefore, diffusion creep and grain-size-sensitive processes contributed significantly to bulk rock weakening during mylonitization. Our results have implications for modelling the rheology of the felsic middle crust.

Integrating X‐ray mapping and microtomography of garnet with thermobarometry to define theP–Tevolution of the (near)UHPMiędzygórze eclogite, Sudetes,SWPoland

AbstractDetailed X‐ray compositional mapping and microtomography have revealed the complex zoning and growth history of garnet in a kyanite‐bearing eclogite. The garnet occurs as clusters of coalesced grains with cores revealing slightly higher Ca and lower Mg than the rims forming the coalescence zones between the grains. Core regions of the garnet host inclusions of omphacite with the highest jadeite, and phengite with the highest Si, similar to values in the cores of omphacite and phengite located in the matrix. Therefore, the core compositions of garnet, omphacite, and phengite have been chosen for the peak pressure estimate. Coupled conventional thermobarometry, averageP–T, and phase equilibrium modelling in theNCKFMMnASHTsystem yieldsP–Tconditions of 26–30 kbar at 800–930°C. Although coesite is not preserved, theseP–Tconditions partially overlap the coesite stability field, suggesting near ultra‐high–pressure (UHP) conditions during the formation of this eclogite. Therefore, the peak pressure assemblage is suggested to have been garnet–omphacite–kyanite–phengite–coesite/quartz–rutile. Additional lines of evidence for the possibleUHPorigin of the Międzygórze eclogite are the presence of rod‐shaped inclusions of quartz parallel to the c‐axis in omphacite as well as relatively high values of Ca‐Tschermak and Ca‐Eskola components. Late zoisite, rare diopside–plagioclase symplectites rimming omphacite, and minor phlogopite–plagioclase symplectites replacing phengite formed during retrogression together with later amphibole. These retrograde assemblages lack minerals typical of granulite facies, which suggests simultaneous decompression and cooling during exhumation before the crustal‐scale folding that was responsible for final exhumation of the eclogite.

Partial melting due to breakdown of an epidote‐group mineral during exhumation of ultrahigh‐pressure eclogite: An example from the North‐East Greenland Caledonides

AbstractIn the North‐East Greenland Caledonides, P–T conditions and textures are consistent with partial melting of ultrahigh‐pressure (UHP) eclogite during exhumation. The eclogite contains a peak assemblage of garnet, omphacite, kyanite, coesite, rutile, and clinozoisite; in addition, phengite is inferred to have been present at peak conditions. An isochemical phase equilibrium diagram, along with garnet isopleths, constrains peak P–T conditions to be subsolidus at 3.4 GPa and 940°C. Zr‐in‐rutile thermometry on inclusions in garnet yields values of ~820°C at 3.4 GPa. In the eclogite, plagioclase may exhibit cuspate textures against surrounding omphacite and has low dihedral angles in plagioclase–clinopyroxene–garnet aggregates, features that are consistent with former melt–solid–solid boundaries and crystallized melt pockets. Graphic intergrowths of plagioclase and amphibole are present in the matrix. Small euhedral neoblasts of garnet against plagioclase are interpreted as formed from a peritectic reaction during partial melting. Polymineralic inclusions of albite+K‐feldspar and clinopyroxene+quartz±kyanite±plagioclase in large anhedral garnet display plagioclase cusps pointing into the host, which are interpreted as crystallized melt pockets. These textures, along with the mineral composition, suggest partial melting of the eclogite by reactions involving phengite and, to a large extent, an epidote‐group mineral. Calculated and experimentally determined phase relations from the literature reveal that partial melting occurred on the exhumation path, at pressures below the coesite to quartz transition. A calculated P–T phase diagram for a former melt‐bearing domain shows that the formation of the peritectic garnet rim occurred at 1.4 GPa and 900°C, with an assemblage of clinopyroxene, amphibole, and plagioclase equilibrated at 1.3 GPa and 720°C. Isochemical phase equilibrium modelling of a symplectite of clinopyroxene, plagioclase, and amphibole after omphacite, combined with the mineral composition, yields a P–T range at 1.0–1. 6 GPa, 680–1,000°C. The assemblage of amphibole and plagioclase is estimated to reach equilibrium at 717–732°C, calculated by amphibole–plagioclase thermometry for the former melt‐bearing domain and symplectite respectively. The results of this study demonstrate that partial melt formed in the UHP eclogite through breakdown of an epidote‐group mineral with minor involvement of phengite during exhumation from peak pressure; melt was subsequently crystallized on the cooling path.

P–T–t evolution of the high-pressure mafic granulites from northern Hengshan, North China Craton: Insights from phase equilibria and geochronology

The Hengshan complex has drawn attention for the occurrence of typical high-pressure mafic granulites, representing the Paleoproterozoic collisional orogeny in the North China Craton. Mafic granulites occur as boudins of various scales in tonalite–trondhjemite–granodiorite (TTG) gneisses. They are composed of garnet, clinopyroxene, plagioclase, orthopyroxene, hornblende, biotite, quartz, rutile and ilmenite. Garnet porphyroblasts are usually surrounded by plagioclase coronas, and early jadeite-rich clinopyroxene is totally decomposed to the symplectite of clinopyroxene and plagioclase. Two high-pressure granulites and one two-pyroxene granulite were studied by the pseudosection approach, and clockwise P–T paths with four metamorphic stages were recognized. The pre-peak prograde stage was identified from garnet core to mantle compositions, with increasing P–T from 630 to 710 °C at 11–13 kbar. The peak pressure stage hasn’t been well preserved but its mineral assemblages inferred from petrography to be garnet + jadeite-rich clinopyroxene + quartz + rutile ± plagioclase, with P–T condition of 760–820 °C at ∼15 kbar. The post-peak decompression with slight heating is characterized by symplectite, plagioclase coronas, and the formation of orthopyroxene. Locally, two-pyroxene granulite assemblages develop, defining P–T condition of 6–8 kbar and 840–860 °C for the temperature peak (Tmax). The post-Tmax cooling is represented by the occurrence of amphibolite facies assemblages especially in boudin margins with P–T condition of 6–8 kbar and 720–760 °C, suggesting an isobaric cooling process with fluid infiltration. U–Pb dating of metamorphic zircons record ages mainly ranging from 1897 to 1830 Ma with weighted mean ages of 1862 ± 11 Ma for the high-pressure granulite and 1837 ± 7 Ma for the two-pyroxene granulite. These metamorphic ages were interpreted to record the post-peak cooling stage especially the time close to solidus, which is also supported by the result of Ti-in-zircon thermometer. A summary of P–T–t evolution for metamorphic terrains corresponding to different crust levels in Hengshan–Wutai area indicates that the main episode of crust thickening-dominated collisional orogeny is ∼1.95 Ga or earlier and finished at ∼1.92 Ga. This was followed by post-orogenic cooling-uplifting or the overprinting of another thermal-tectonic event during the period of 1.92–1.80 Ga.