Achieving a sustainable dielectric medium for Electrical Discharge Machining (EDM) has now drawn the attention of researchers and industries alike. Increased awareness among the Government and NGOs paved the way for the manufacturing industries to move towards a green environment and sustainability in the production process. To search for sustainable dielectric, 5 different types of oils viz., Jatropha, coconut, groundnut, sunflower, and EDM 4 oil (conventional oil) are experimented in this paper and revealed its suitability of potential replacement for the conventional dielectric. The properties such as viscosity, density, flash point, electrical conductivity, and BDV (Break down Voltage) are tested as per the standards. Since the number of output response is more than, Multi Attribute Decision Making (MADM) algorithms namely PIV, TOPSIS, and MOORA are used for the ranking and optimization. Entropy weight method is adopted to endow criteria weight to each of the MADM techniques. Jatropha oil has been ascertained to be rank 1 followed by groundnut, coconut, sunflower, and EDM 4 oil. Subsequently, the Gas Chromatography & Mass Spectrometry (GC–MS) analysis has revealed the quantitative constituents present in Jatropha as well as remaining oils. Furthermore GC–MS analysis reports that the retention time of Jatropha (43.042 min) is relatively longer than other oils except coconut oil, to release Ricinoleic acids. Groundnut and EDM 4 oils took relatively less retention time to release the alkanes. Machining performance was also conducted with the obtained dielectric and compared with conventional type oil (EDM 4 oil).
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