Pin Electrode Research Articles

The interaction between filaments in dielectric barrier discharge excited by bipolar/unipolar nanosecond pulse powers

This study investigates the behavior of discharge filaments in dielectric barrier discharges with a focus on the effects of nanosecond pulse voltage polarity. We observed significant repulsion between discharge filaments when the pin electrode was grounded in bipolar nanosecond pulse discharge. The tilt angle of the filaments was directly proportional to the peak current, which is indicative of charge density. When the bare pin electrode acted as an H.V. electrode, the repulsion phenomenon was diminished. Surface charges released through the bare pin electrode instead of accumulated on the dielectric surface accounts for this phenomenon. The study also highlights the impact of bipolar versus unipolar nanosecond pulse powers. The addition of a water resistor (WR) results in a slower falling edge of the pulse voltage and the absence of subsequent reverse discharges. The repulsion between filaments disappears both in pin-to-ground discharge and pin-to-H.V. discharge. The introduction of WR leads to a reduction of the current pulse’s duration and a premature termination of the discharge process, resulting the influence of surface charges on filament positioning negligible. It is hypothesized that the spatial distribution of ions does not exhibit significant repulsion, attributed to their substantial mass and sparse distribution in space.

Breakdown and interface dynamics of pulsed discharge plasma across air-water interface: From single to repetitive stimulation

Pulsed discharge in the vicinity of a multi-phase interface, where a discontinuity of physical properties exists, can be a joint problem of both electro- and thermo-physics. This study shows a comprehensive analysis of electric breakdown across an air-water interface and its successive multi-physical effects. The scenario is constructed via a pair of pin electrodes positioned on both sides of the interface, and the transient discharge is analyzed using high-speed backlight photography synchronized with electrical and optical diagnostics. It is observed that the corona/streamer develops from either side of the pin electrode. Electrostatic instability causes the interface to fluctuate and a water column to form above the interface. By increasing the applied voltage, discharge evolves from “dielectric barrier” mode (pin to interface) to “through breakdown” mode (pin to pin). Once the conductive channel bridges two electrodes, electric power of ∼40 kW peak and deposited energy of 100 mJ will be injected into the channel and promote the “streamer-spark” transition, resulting in a crown-like splash (100 m s-1) near the interface and cavity formation. As the quenching of diffused plasmas, the over-expanded splash (5 mm in diameter) would be re-compressed by the ambient air. Particularly, the shrinkage of the thin water film of the splash can reach a 20 mm jet near the axis and develop Rayleigh-Taylor instability, along with the formation of micro-jets eruption during the convergent collision. More sophisticated interactions will appear at higher repetitive frequency (>100 Hz), where the perturbation caused by one pulse will influence the next, namely the “memory” effect. Furthermore, periodic loading on the interface effectively changes the cavity characteristics, showing an attractive prospect in fluid control applications.

Formation of diffuse and spark discharges between two needle electrodes with the scattering of particles

The development of a nanosecond discharge in a pin-to-pin gap filled with air at atmospheric pressure has been studied with high temporal and spatial resolutions from a breakdown start to the spark decay. Positive and negative nanosecond voltage pulses with an amplitude of tens of kilovolts were applied. Time-resolved images of the discharge development were taken with a four-channel Intensified Charge Coupled Device (ICCD) camera. The minimum delay between the camera channels could be as short as ≈ 0.1 ns. This made it possible to study the gap breakdown process with subnanosecond resolution. It was observed that a wide-diameter streamer develops from the high-voltage pointed electrode. The ionization processes near the grounded pin electrode started when the streamer crossed half of the gap. After bridging the gap by the streamer, a diffuse discharge was formed. The development of spark leaders from bright spots on the surface of the pointed electrodes was observed at the next stage. It was found that the rate of development of the spark leader is an order of magnitude lower than that of the wide-diameter streamer. Long thin luminous tracks were observed against the background of a discharge plasma glow. It has been established that the tracks are adjacent to brightly glowing spots on the electrodes and are associated with the flight of small particles.

Electron density in a non-thermal atmospheric discharge in contact with water and the effect of water temperature on plasma-water interactions

In this study the electron density of an atmospheric plasma generated between a pin electrode and a water surface is measured by determining the Stark broadening of H α and H β emission lines. Comparable values for the electron density are achieved using the H α and H β broadening obtained in separate measurements. During the temporally evolving system, increasing electron densities are measured of 0.5−3⋅1015 cm−3 during the plasma treatment of 5–10 min. The effect of the water temperature on plasma-water interaction is investigated by heating the water to ≈70∘ C prior to the measurements. This resulted in higher gas temperatures during the discharge up to 2500 K and 4000 K for positively and negatively pulsed discharge, respectively. Furthermore, an earlier increase of electron density and conductivity of the water is measured for the preheated experiments. The humidity of the gas is likely to be an important parameter causing the observed results.

The effect of cold plasma seed treatments on nodulation and plant growth in pea (Pisum sativum) and lentil (Lens culinaris)

AbstractCold plasma enhances various biological processes in plants. This study assessed the impact of cold plasma seed treatments on nodulation, root, and shoot growth in pea and lentil under controlled environmental conditions. Seeds were treated with cold plasma generated by a dielectric barrier discharge (DBD) and a pin electrode reactor (PER), with three different exposure durations (3, 6, and 12 min). At 4 weeks, notable enhancements were observed in nodule number and dry weight, root dry weight, length, volume, surface area, and shoot dry weight. The 3‐ and 6‐min exposure using the DBD and the 3‐min exposure using the PER system demonstrated the most significant increases or upward trends in these traits, highlighting the intricate nature of seed–plasma interactions.

Fast breakdown process and characteristics diagnosis of nanosecond pin–pin discharge

In this paper, the characteristics of a nanosecond spark discharge with a pin–pin electrode configuration have been systematically studied. Both a streak camera with high temporal resolution and an intensified charge-coupled device (ICCD) camera are employed together to investigate the breakdown and evolution process of the discharge. The formation of initial breakdown and mode transition from streamer to spark in the electrode gap are clearly observed on the time scale of several nanoseconds with a temporal resolution of 100 ps. In addition, the time-resolved spectra technology is also used to analyze the generation and quenching mechanisms of reactive species, the electron density, and the electron temperature. The results show that there is a 1.25 ns initial discharge breakdown and that a bright cathode spot exists before the transformation from streamer to spark channel. After a faster cathode filament and a slower anode filament propagate and merge at the electrode gap, the spark discharge phase begins. The generation processes of different reactive species depend on the discharge phase to a great extent. The N2* is first generated during the streamer phase while the O*, N*, and N+ are mainly generated under the spark phase, in which the electron temperature calculated by Boltzmann plots is 2.74 eV, and the electron density determined from the Stark broadening of O lines is on the order of 1016 cm−3.

Heterogeneous liquid discharge cracking of n-hexadecane as a heavy oil model compound: A way to generate plasma in liquid hydrocarbons at low voltage

Plasma is an excellent way of coupling renewable power resources and poor-quality heavy oil resources into high value petrochemicals. In order to achieve discharge in liquid hydrocarbons under low-voltage operating conditions, it was proposed a new liquid-phase discharge mode - heterogeneous liquid discharge. The aqueous-phase feedstock was injected into n-hexadecane as a heavy oil model compound through a pin electrode, and plasma was generated directly in the liquid feedstocks at room temperature, atmospheric pressure, and low voltage to achieve the in-situ reforming of n-hexadecane and the generation of syngas, C2 hydrocarbons, and other high value-added chemicals. The effects of injection of water and ethanol solution on the gaseous and liquid products, and feedstocks conversion were discussed, and the distribution of various products was explored in detail. Gas production increased with the concentration of injected ethanol up to a maximum of 110.8 mL/min. A n-hexadecane conversion of 2.0% was obtained on injection of 50% ethanol, 4.56 kV, and discharge for 2 min. Varying the ethanol concentration can regulate the composition of the product. The auxiliary effects of water and ethanol on n-hexadecane cracking and the origin of the main gaseous products were examined in the mechanistic analysis section.

Effects of Dielectric Barrier on Water Activation and Phosphorus Compound Digestion in Gas-Liquid Discharges.

To generate a stable and effective air-liquid discharge in an open atmosphere, we investigated the effect of the dielectric barrier on the discharge between the pin electrode and liquid surface in an atmospheric-pressure plasma reactor. The atmospheric-pressure plasma reactor used in this study was based on a pin-plate discharge structure, and a metal wire was used as a pin-type power electrode. A plate-type ground electrode was placed above and below the vessel to compare the pin-liquid discharge and pin-liquid barrier discharge (PLBD). The results indicated that the PLBD configuration utilizing the bottom of the vessel as a dielectric barrier outperformed the pin-liquid setup in terms of the discharge stability and that the concentration of reactive species was different in the two plasma modes. PLBD can be used as a digestion technique for determining the phosphorus concentration in natural water sources. The method for decomposing phosphorus compounds by employing PLBD exhibited excellent decomposition performance, similar to the performance of thermochemical digestion-an established conventional method for phosphorus detection in water. The PLBD structure can replace the conventional chemical-agent-based digestion method for determining the total dissolved phosphorus concentration using the ascorbic acid reduction method.

Predictive modeling and optimization of pin electrode based cold plasma using machine learning approach

Predictive modeling and optimization of pin electrode based cold plasma using machine learning approach

DBD-like and electrolytic regimes in pulsed and AC driven discharges in contact with water

The interaction of an ambient air plasma with a water surface in a pin–water electrode configuration is presented in a polydiagnostic study. A discharge was generated by applying different high-voltage (HV) waveforms to a metallic pin electrode, positioned 2 mm above the water surface of a Petri dish filled with demineralized water. For pulsed discharge operation, a clear distinction is observed between a dielectric barrier discharge regime featuring a transient discharge at the rising as well as at the falling slope of the HV pulse, while a steady discharge is present in the gap during the complete HV pulse for the electrolysis regime. The occurrence of those two regimes is coupled to the increasing conductivity of the water over time, which additionally results in a quick rise of the dissipated discharge power and an increase of the gas temperature. The AC driven discharges exhibit only the electrolysis regime and do not significantly evolve over the treatment time. The resulting water conductivity was found to be a function of the total dissipated energy, irrespective of the discharge driving mode. Additionally, the resulting water conductivity shows a strong correlation with the total transferred charge in the gas phase. The total dissipated energy can potentially be used as a global measure to compare different experiments involving plasma–water interaction across different setups in different research groups.

Commissioning the digital mass-filter/ion-trap module for the MS SPIDOC prototype

The combination of a linear quadrupole ion-filter and linear Paul trap operated with a rectangular guiding field for the filtering and accumulation of ions within the Mass Spectrometry for Single Particle Imaging of Dipole Oriented protein Complexes (MS SPIDOC) prototype [T. Kierspel et al., Anal. Bioanal. Chem., published online] is characterized. Using cationic caesium-iodide clusters, the ion-separation performance, ion accumulation, cooling, and ejection via in-trap pin electrodes is evaluated. Furthermore, proof-of-principle measurements are performed with 64 kDa multiply-charged non-covalent protein complexes of human hemoglobin and 804 kDa non-covalent complex of GroEL, to demonstrate that the module meets the criteria to handle high-mass ions which are the main objective of the MS SPIDOC project. The setup's performance is found to be in line with previous results from ion-trajectory simulations [F. Simke et al., Int. J. Mass Spectrom. 473 (2022) 116779].

The stability of perception threshold tracking for long session evaluation of Aβ- and Aδ-fiber function.

Research has proven that epidermal and transcutaneous stimulation can identify the function of Aβ and Aδ fibers (i.e., in diabetes) individually using different electrodes. In this study we aimed to determine the stability of perception thresholds when using such electrodes. Twenty healthy volunteers participated in this study. The perception threshold of Aβ fibers (patch electrode) and Aδ fibers (pin electrode) was estimated 30 times during a period of 60 minutes. A threshold was established every other minute, alternating between the two electrodes. The stimulus duration was 1 millisecond and the interstimulus interval was 1.5 to 2.5 seconds. Linear regressions of the perception threshold as a function of time were performed. The slopes were used as an estimate of habituation and were compared between the electrodes. The slope was significantly larger when assessed by the pin electrode (median: 0.020 [0.009 to 0.030] mA/trial) than when assessed by the patch electrode (median: 0.005 [0.001 to 0.018] mA/trial) (P = .017, paired t test). During the session, total increases in perception threshold of approximately 55% and 1% were seen for the pin and patch electrodes, respectively. The two fiber types assessed showed significant perception threshold increases. The higher slope of the pin electrode indicated that the Aδ fibers were more prone to habituation than the Aβ fibers, and that habituation should be considered during prolonged experiments. This assessment is valuable for future research on nerve fiber function using the technique for long session experiments.

Key Modes of Ignition and Maintenance of Corona Discharge in Air

Theoretical and experimental studies of various modes of corona discharge operation in atmospheric pressure air are presented in this short review. The original results of modeling negative corona discharges are presented, taking into account the non-stationary plasma-chemical kinetics of charged particles in air plasma. The space–time evolution of the discharge in needle-to-plane geometry is investigated and analyzed. Several stages of discharge development are revealed from the moment of initiation of a low-negative current corona to the quasi-stationary mode of a glow discharge. Experimental data of the authors are presented. Modern technology and diagnostic equipment with a wide variation of the main parameters (the shape and polarity of the applied voltage, the type of gap, etc.) was used. The measurement of the optical characteristics of the plasma glow was carried out with high spatial resolution. Corona discharge current pulse profiles in the air at atmospheric pressure have been recorded with subnanosecond time resolution. With a positive polarity of the pin electrode and high voltage, a transition from a spherical streamer initiating a corona discharge to a cylindrical streamer is shown. The author’s results are rigorously evaluated through a critical comparison with findings from other research groups.

Spectroscopic investigation of atmospheric pressure cold plasma jet produced in dielectric barrier discharge

Non-thermal cold atmospheric pressure plasma jet (APPJ) produced in multi-pulse dielectric barrier discharge (DBD) preferentially heats the electrons that subsequently transfer their energy to the other plasma species converting them into reactive species. Therefore the characterization of different energy groups of electrons is essential for efficient production and control of reactive plasma species contributing to surface modifications. Here we present the spectroscopic investigations of the APPJ produced in multi-pulse DBD using pin electrode configuration. Boltzmann plot relates the emission intensities of the several Ar–I spectral lines to their corresponding threshold excitation energies to give the electron temperature more precisely. The Stark broadening of the Ar–I (696.54 nm) line profile gives the electron number density after de-convoluting the contributions of the Doppler and instrumental broadenings. Plasma measurements correlate the gas flow rate, applied jet power across the electrodes, and a group of electrons contributing to optical emission. Sequential imaging correlates the size of the plasma bullets momentarily with the discharge pulse for different argon flow rates and applied jet powers. With an increasing flow rate of up to 1.4 L/min, the plasma plume of the jet becomes more elongated, intense, and spatially uniform. However, the glow intensity and size of the plume start reducing with a further increase in gas flow rate. Experimental findings propose plasma processing for small-scale localized plasma surface treatments.

Water activated by the atmospheric air streamer‐to‐spark transition discharge over its surface

AbstractHere, we report on the optimized design for the needle‐to‐plane electrode geometry to generate the atmospheric air streamer‐to‐spark transition discharge over the surface of the water at the pulsed voltage of ±30 kV. This design contributes to an increase in the electric field at the head of air surface streamers during their propagation, which eventually evolves into a spark over water. The length of streamer‐to‐spark transition discharge is up to 150 mm, which is affected by the conductivity of water, the electrode polarity, and the horizontal distance between the high‐voltage pin electrode and the grounded plane electrode. Water is quickly activated by the streamer‐to‐spark transition discharge, which can be attributed to the dissolution of plasma‐generated species including long‐lived and short‐lived reactive species in the gas phase. Compared to the negative streamer‐to‐spark transition discharge, the positive one is more effective in increasing the biological reactivity of water. Analysis indicates that the positive ions in the positive surface streamers can dissolve in water, which contributes to the formation of reactive species in water, thus an increase in the biological reactivity of water.

Removal of powders from cavities in contaminated surfaces by shock and plasma generated by an adjacent electro-static discharge

An electrostatic discharge (ESD) produced between pin electrodes above a cavity filled with powder is explored as means of contactless removal of particles from contaminated surfaces. The ESD is produced by discharging a capacitor through an air gap. Glass beads of different sizes serve as model powders filling cavities of different depths. Masses of both loaded and ejected powders are measured. The motion of the ejected particles is studied using high-speed video. Most of the ejected particles move vertically up with the initial velocities varied from ca. 4 to 11 m/s. Changing the mechanical properties of the substrate holding the powder does not significantly affect the velocities of the ejected particles. For powders removed from cavities as a result of interaction with the shock and plasma produced by ESD, the number of particle layers ejected is determined by the particle size and the ESD energy, but is not significantly affected by the cavity depth. A single ESD pulse can be effective in the complete removal of powder particles from relatively shallow, 0.2-mm deep cavity. Estimates suggest that the particles are primarily ejected due to the lift forces produced by local velocity gradients of the gas above the loaded powder layer.

Electric charge build-up and dissipation at pulsed streamer corona by EFISH and probe measurements

This work examines the dynamics of volumetric electric charge deposited by a single pin electrode streamer corona in atmospheric air at ambient conditions. Recent studies show that, at pulse-periodic operation, electric charge remains in surrounding air after the first discharge. This residual charge significantly affects the electric field distribution and morphology of discharges at subsequent pulses. In this study, the residual electrical potential/field was measured during and after dissipation of a pulsed 80 kV streamer corona of alternating polarity. This was accomplished using electrostatic probes and the electric field induced second harmonic method (EFISH generation). The residual volumetric charge of a positive pulse polarity streamer corona occupies a zone of up to 80 mm from the electrode. The subsequent application of a negative polarity pulse leads to partial neutralization of the previous charge and the generation of a region with a high-amplitude electric field. The propagation of following positive polarity pulses is limited by the residual positive volumetric charge. The EFISH method reveals the magnitude of the electric field at discharge propagation and electrostatic probes inform the polarity. Intensified imaging acquisition was used to evaluate the spatial distribution and dynamics of corona discharge during the alternating polarity waveform.

Development of large-scale electret fabrication system for triboelectric nanogenerator electrical output amplification

The triboelectric nanogenerator (TENG), which converts mechanical energy to electrical output, is garnering attention owing to their application in low-energy electronic devices as a power source. To utilize the TENG as a power source, amplifying the electrical output and enhancing energy conversion efficiency are necessary. As the TENG generates electrical output through contact electrification and electrostatic charge induction, the electrical output can be amplified by enhancing the two mechanisms through the enlargement of the TENG area and the adoption of the pre-charge injected film (electret). In this regard, the fabrication of the large-scale electret is significant for amplifying the electrical output of the TENG. In this study, a corona charging system is proposed for the fabrication of the large-scale electret with a uniform charge-distributed area. Corona charging injects O2 ions into a dielectric film with an electric field generated between the pin electrode and ground electrode (GE). Through the utilization of a multi-PE (MPE) and conveyor belt-shaped GE (CBsGE) in the corona charging system, the O2 molecules near the pins can be ionized simultaneously while the CBsGE is rotating. Thus, the O2 ions can be injected uniformly into a wide area. About a voltage of 400 V and current of 45 μA can be generated by applying the fabricated electret to the TENG. As several electrets with various sizes can be fabricated simultaneously, the TENG with high electrical output can be batch fabricated to enhance its practicality significantly.

Initial stages of pulsed discharge in saline solutions in a vicinity of threshold voltages

Data are presented on an investigation of pulsed discharges in a solution of 30 g of NaCl per liter of distilled water. The interelectrode gap consists of the active pin electrode and the return plane electrode. The voltage pulse of positive polarity forms by means of an electric circuit where a capacitor bank of 40 μF with an initial voltage V 0 of up to 1500 V is discharged via the gap. In a range of initial voltages V 0 = (550 – 1100) V vapor cavities in a form of the microbubbles are generated near the active electrode and at the electrode surface. The microbubbles are able to merge with each other thus forming macrobubbles and vapor layers, which shield the active electrode from current passage. The process of vapor cavity generation and the effect of shielding are discussed in detail. The discharge at the vapor layer appears at the critical voltage V 0 = 1100 V. The principal prerequisite for discharge arising is that the electrode has to be completely shielded by the vapor layer and the voltage at the layer at the instant of discharge initiation has to be at least at a level of 500 V. However, when the voltage at the gap exceeds the critical value, the condition of complete shielding is not obligatory.

Plasma breakdown in bubbles passing between two pin electrodes

The ignition of plasmas in liquids has applications from medical instrumentation to manipulation of liquid chemistry. Formation of plasmas directly in a liquid often requires prohibitively large voltages to initiate breakdown. Producing plasma streamers in bubbles submerged in a liquid with higher permittivity can significantly lower the voltage needed to initiate a discharge by reducing the electric field required to produce breakdown. The proximity of the bubble to the electrodes and the shape of the bubbles play critical roles in the manner in which the plasma is produced in, and propagates through, the bubble. In this paper, we discuss results from a three-dimensional direct numerical simulation (DNS) used to investigate the shapes of bubbles formed by injection of air into water. Comparisons are made to results from a companion experiment. A two-dimensional plasma hydrodynamics model was then used to capture the plasma streamer propagation in the bubble using a static bubble geometry generated by the DNS The simulations showed two different modes for streamer formation depending on the bubble shape. In an elliptical bubble, a short electron avalanche triggered a surface ionization wave (SIWs) resulting in plasma propagating along the surface of the bubble. In a circular bubble, an electron avalanche first traveled through the middle of the bubble before two SIWs began to propagate from the point closest to the grounded electrode where a volumetric streamer intersected the surface. In an elliptical bubble approaching a powered electrode in a pin-to-pin configuration, we experimentally observed streamer behavior that qualitatively corresponds with computational results. Optical emission captured over the lifetime of the streamer curve along the path of deformed bubbles, suggesting propagation of the streamer along the liquid/gas boundary interface. Plasma generation supported by the local field enhancement of the deformed bubble surface boundaries is a mechanism that is likely responsible for initiating streamer formation.