Pilbara Craton Research Articles

Is the Mesoarchean Mulgandinnah shear zone, Pilbara Craton, the world's oldest arc-slicing transform fault?

Abstract Arc-slicing transform faults represent an integral component of convergent margin tectonics. They are developed above oblique subduction systems, cutting through and displacing the entire magmatic section of arcs, leading to tectonic repetition of segments of the overriding plate in the ensuing orogenic collage. Extant examples clearly show this process in Sumatra, New Zealand, and the Philippines, while ancient examples are reported from the Paleozoic Altaids and Neoarchean Superior and Yilgarn cratons. Here, we report data that document that the Paleo-Mesoarchean Eastern Pilbara craton, recently interpreted to be a preserved mid-upper crustal level of a magmatic arc, is cut and repeated by a major 3.0–2.93 Ga arc-slicing fault, the Mulgandinnah, which sliced a previously 600 × 100 km segment of a Mesoarchean arc system, laterally moving different segments to their presently juxtaposed 200 × 200 km preserved fragment. This evidence demonstrates lateral plate motions by 3.0 Ga and shows oblique subduction, arc plutonism, arc-slicing, and repetition, reflecting that crustal growth in modern-style convergent margins was in full operation by the Mesoarchean.

Growth faults and avalanches: Reconstructing Paleoarchean basins in the Pilbara and Kaapvaal cratons

Four new volcano-sedimentary complexes (VSC's), respectively c. 3510, 3460, 3430, and 3320 Ma old, are identified in the East Strelley, Coongan, and Kelly belts of the East Pilbara craton and compared with the extraordinarily complete c. 3450 Ma Buck Reef-VSC in the southern African Kaapvaal craton. The VSC’s reveal an intricate relationship between volcanic deposition, sedimentation, development of syndepositional fault arrays, both extensional and contractional, and magmatism. The geometry and kinematics of these fault systems were analyzed after restoring the tilt of the stratigraphic sequences back to the depositional horizontal. The growth fault arrays are interpreted to have been generated by lack of lateral support of depositional basin margin prisms as known from present-day deltas and passive margins. This ‘basin margin collapse’ scenario for deformation and kinematics of the topmost section of the crust relies on topographic relief combined with vertical crustal oscillation. The relationship between supracrustal collapse and coeval deformation on deeper-seated detachments within the basement of the Pilbara remains as yet unsolved.The restoration corroborates the (semi-)circular basin architecture we proposed in 2017, which preceded, and is unrelated to, the present-day configuration of granitoid complexes and greenstone belts. The new findings also assess an early, syndepositional presence of the east–west Warrawoona Lineament as a major dividing line of as yet unknown structural character between two areas of basin superposition.For the Coonterunah Subgroup a multistorey architecture is established: the Table Top/Coucal-VSC with its near-water level chert top is overlain by regularly bedded Double Bar Basalt. The ensemble is truncated by the newly introduced tectono-stratigraphic Bergamina Unit, interpreted as a mega-avalanche emplaced somewhere between 3496 and 3466 Ma, possibly time-equivalent to the Duffer Fm.The crustal depths of the detachments below the (water-level) tops of all VSC’s identified, in other words the thicknesses of the VSC’s, are used as proxy for determining minimum basin centre depths ranging from 1000 to 3800 m. The greatest depth was reached in the North and South Coongan Basins, where voluminous bimodal volcanism of the Duffer Fm, maximum subsidence and deposition rates resulted in maximum basin margin instability.

Archean (3.3 Ga) paleosols and paleoenvironments of Western Australia.

The Pilbara craton of northwestern Australia is known for what were, when reported, the oldest known microfossils and paleosols on Earth. Both interpretations are mired in controversy, and neither remain the oldest known. Both the microfossils and the paleosols have been considered hydrothermal artefacts: carbon films of vents and a large hydrothermal cupola, respectively. This study resampled and analyzed putative paleosols within and below the Strelley Pool Formation (3.3 Ga), at four classic locations: Strelley Pool, Steer Ridge, Trendall Ridge, and Streckfuss, and also at newly discovered outcrops near Marble Bar. The same sequence of sedimentary facies and paleosols was newly recognized unconformably above the locality for microfossils in chert of the Apex Basalt (3.5 Ga) near Marble Bar. The fossiliferous Apex chert was not a hydrothermal vein but a thick (15 m) sedimentary interbed within a sequence of pillow basalts, which form an angular unconformity capped by the same pre-Strelley paleosol and Strelley Pool Formation facies found elsewhere in the Pilbara region. Baritic alluvial paleosols within the Strelley Pool Formation include common microfossil spindles (cf. Eopoikilofusa) distinct from marine microfossil communities with septate filaments (Primaevifilum) of cherts in the Apex and Mt Ada Basalts. Phosphorus and iron depletion in paleosols within and below the Strelley Pool Formation are evidence of soil communities of stable landscapes living under an atmosphere of high CO2 (2473 ± 134 ppmv or 8.8 ± 0.5 times preindustrial atmospheric level of 280 ppm) and low O2 (2181 ± 3018 ppmv or 0.01 ± 0.014 times modern).

The stability of cratons is controlled by lithospheric thickness, as evidenced by Rb-Sr overprint ages in granitoids

The ancient cores of modern continents, cratons, are the oldest blocks of “stable” lithosphere on Earth. Their long-term survival relies on the resistance of their underlying thick, strong, and buoyant mantle keels to subsequent recycling. However, the effect of substantial geographical variations in keel thickness on the post-assembly behaviour and mass movement within these continental cores remains unknown. Here, we demonstrate that the spatial distribution of fluid-reset in-situ Rb-Sr ages for Paleo-Mesoarchean (3.6–2.8 billion years ago; Ga) granitoids of the Pilbara Craton, Australia shows remarkable correlation with independently-constrained lithospheric thickness models. Without craton-wide heating/magmatic events, these anomalously young Rb-Sr ages document episodes of fluid infiltration into granitoid complexes as a response to lithospheric reactivation by far-field stresses. This correlation implies that craton-wide fluid mobilization triggered by extra-cratonic Neoarchean to Mesoproterozoic (2.8–1.0 Ga) tectonic events is facilitated by variations in lithospheric strength and thickness. Compared to areas of older overprints, the two-thirds of the craton comprised of younger reset ages is underlain by comparatively thin lithosphere with higher susceptibility to reactivation-assisted fluid flow. We propose that even the strongest, most pristine cratons are less stable and impermeable than previously thought, as demonstrated by the role of granitoid complexes and cratons as selective lithospheric “sponges” in response to minor tectonic forces. Therefore, variations in lithospheric thickness, likely attained before cratonization, exert a crucial control on billions of years of fluid movement, elemental redistribution and mineralization within ancient continental nuclei.

Paleogeography and high-precision geochronology of the Neoarchean Fortescue Group, Pilbara, Western Australia

While rates of Phanerozoic plate movements and magnetic field reversals have been well studied, little is known about such phenomena on early Earth. The ca. 2.8–2.7 Ga Fortescue Group on the Pilbara craton in Western Australia has been recognized as a well-preserved sequence of Archean rift volcanics thought to derive from a flood basalt province, and may have been moving rapidly across the globe at two different intervals in its depositional history. We present the results of a magnetostratigraphic study integrated with high-precision U-Pb ID-TIMS geochronology aiming to quantify rates of cratonic motion and provide a continuous time series for changes in Pilbara paleogeography during these two rapid intervals, at ∼2.77 and 2.72 Ga. We provide six new or updated high-quality paleomagnetic poles for inclusion in databases tracking Precambrian cratonic motion. During the craton’s largest geographic displacement at ∼2.77 Ga, we resolve a minimum drift rate of 23 ± 20 cm/a if there was substantial rotation of the Pilbara craton along with translational motion, and a more rapid minimum estimate of 64 ± 23 cm/a if the motion was dominated by translation; these estimates exceed both Mesoarchean and most modern rates of plate motion. We provide a new high-precision U-Pb zircon age of 2721.23 ± 0.88/0.88/6.9 Ma for the Tumbiana Formation stromatolite colony, which developed as the Pilbara craton drifted from 51.5 ± 7.0° to 32.1 ± 5.7° paleolatitude. Although the Fortescue Group has been considered an early prototype of large igneous provinces, it was emplaced over a longer duration than its Phanerozoic counterparts and does not fit at least one definition of a large igneous province (LIP). But as a potential prototype of LIP magmatism, the Fortescue succession chronicles eruptive dynamics, rapid paleogeographic changes, and a series of robustly determined magnetic field reversals during the Neoarchean.

Geochronology of the Daitari Greenstone Belt, Singhbhum Craton, India

The Singhbhum Craton in India contains well-preserved Palaeoarchaean greenstone belts that rival their Australian and South African counterparts, but their stratigraphic make-up remains to be resolved. Here we provide new SHRIMP- and LA-ICP-MS-based U–Pb and Lu-Hf data on magmatic and detrital zircons from stratigraphically resolved samples of the Daitari Greenstone Belt (DGB) in the south of the Singhbhum Craton. A minimum age for the Kalisagar Formation, the lowermost mafic–ultramafic volcanic suite of the DGB, is provided by a felsic sill dated at 3505 ± 6 Ma. Felsic volcaniclastic rocks from the overlying Talpada Formation provided a weighted mean age of 3507 ± 5 Ma. Zircon εHf(t) indicate a juvenile source for 3.5 Ga felsic volcanic rocks. Erosion of the volcanic edifice of the Talpada Formation acted as a predominant source for the overlying turbidite sequence of the Sindurimundi Formation, having identical U-Pb detrital zircon ages of ∼ 3505 Ma. A maximum age of deposition of 3502 ± 2 Ma is proposed for the Sindurimundi Formation. Magmatic zircon ages obtained from different intrusive felsic rocks in the Daitari belt ranges from c. 3.37 to 3.35 Ga and support the notion of widespread felsic magmatism of the Singhbhum Suite in the southern part of the craton. Xenocrystic zircon crystals dated at c. 3.55 to 3.52 Ga may correspond to an earlier phase of magmatism. 3.5 Ga marks an important period in the Earth’s history, when extensive felsic magmatism facilitated continental crustal growth as recorded in the Singhbhum, Kaapvaal and Pilbara cratons.

Tectonic fluid expulsion: U-Pb evidence for punctuated hydrothermal fluid flow and hydraulic fracturing during orogenesis

Tectonic fluid expulsion has been linked to fluid flow in permeable foreland basin sequences, but it is unclear how fluids migrate through underlying low-permeability successions. Here we report U-Pb data which indicate that fluids expelled during tectonic compression migrated through older compacted shales inboard of the deforming craton margin by fracture permeability and enhanced diffusion. From a ∼350 m drill-core interval of Neoarchean shale (drill-hole ABDP9), Hamersley region, Australia, we document abundant bedding-parallel veins indicating pervasive hydraulic fracturing. Thermometry of vein-filling chlorite indicates temperatures between 329-374°C, which is higher than estimates (175-280°C) from metamorphic assemblages in underlying basalts, implying the passage of hydrothermal fluids. New in situ secondary ion mass spectrometry (SIMS) U-Pb geochronology of monazite and xenotime in bedding-parallel veins verifies and expands earlier results, showing that microfracturing and hydrothermal fluid flow spanned ∼650 million years and was restricted to five short intervals: 2.30 Ga, 2.20 Ga, 2.10 Ga, 2.05 Ga and 1.65 Ga. Three of the five age populations coincide with known fabric-forming orogenic events (i.e. 2.30 Ga Sylvania orogeny; 2.22-2.15 Ga Ophthalmia orogeny; 1.68-1.65 Ga Mangaroon orogeny), which are focused along the southern Pilbara Craton margin. Our results show that the timing of veining was not random, but coeval with major orogenic events, linking fluid overpressure and hydraulic fracturing to the expulsion of heated orogenic fluids 100s of km inboard of the craton margin. The crack-seal veins indicate repeated cycles of fluid overpressure resulting in hydrofracturing and fluid drainage, followed by cavity collapse. The tectonic expulsion of pressurized hydrothermal fluids produced fracture and matrix permeability in Earth's upper crust, leading to episodic open-system behaviour with enhanced fluid-rock reactions and the large-scale transfer of heat and mass.

Hematite geochronology reveals a tectonic trigger for iron ore mineralization during Nuna breakup

Abstract Hematite and goethite deposits hosted in banded iron formations (BIFs) in the Pilbara craton (Western Australia) represent one of Earth's most significant Fe reserves; however, the timing and tectonic triggers underpinning deposit genesis remain contentious. Uncertainty in ore genesis stems from a lack of direct age measurements, which could aid in correlating periods of BIF mineralization with tectono-thermal events observed elsewhere. Archean–Paleoproterozoic BIFs in the Hamersley Province host extensive martite–microplaty hematite orebodies that formed at 2.2–2.0 Ga, based on indirect constraints. In contrast, combined hematite in situ U-Pb geochronology and (U-Th)/He thermochronology demonstrate that martite–microplaty hematite ores in the Chichester Range crystallized ca. 1.26–1.22 Ga and underwent cratonic denudation between ca. 0.57 and 0.38 Ga. Nanoscale imaging of dated hematite indicates that U-Th-Pb is lattice bound and not hosted in inclusions. New U-Pb hematite ages overlap with other mineral ages reported at the margins of the Pilbara and Yilgarn cratons (1.3–1.1 Ga), where mineral formation was driven by plate reorganization following breakup of the Nuna supercontinent. This age correlation suggests that a combination of increased orogenic (+diagenetic) and heat (+fluid) generative processes resulting from supercontinent reconfiguration was a key trigger for iron ore formation in the Pilbara craton.

Did transit through the galactic spiral arms seed crust production on the early Earth?

Abstract Although there is evidence for periodic geological perturbations driven by regular or semi-regular extra-terrestrial bombardment, the production of Earth's continental crust is generally regarded as a function of planetary differentiation driven by internal processes. We report time series analysis of the Hf isotopic composition of zircon grains from the North Atlantic and Pilbara cratons, the archetypes of Archean plate tectonic and non-plate tectonic settings, respectively. An ~170–200 m.y. frequency is recognized in both cratons that matches the transit of the solar system through the galactic spiral arms, where the density of stars is high. An increase in stellar density is consistent with an enhanced rate of Earth bombardment by comets, the larger of which would have initiated crustal nuclei production via impact-driven decompression melting of the mantle. Hence, the production and preservation of continental crust on the early Earth may have been fundamentally influenced by exogenous processes. A test of this model using oxygen isotopes in zircon from the Pilbara craton reveals correlations between crust with anomalously light isotopic signatures and exit from the Perseus spiral arm and entry into the Norma spiral arm, the latter of which matches the known age of terrestrial spherule beds. Our data support bolide impact, which promoted the growth of crustal nuclei, on solar system transit into and out of the galactic spiral arms.

A positive syn-fold test from the Neoarchaean Klipriviersberg Group of South Africa: Quo vadis Vaalbara?

Abstract The existence of Vaalbara, the combined Neoarchaean to Palaeoproterozoic Kaapvaal-Pilbara supercraton, is questionable during the early Neoarchaean when scrutinised through the lens of recent Australian and South African palaeomagnetic data. Remarkably similar ~2.7 to 2.5 Ga geological successions (with near bed-for-bed correlatability) support a coherent Vaalbara at the end of the Neoarchaean. Here we report palaeomagnetic and rock magnetic results from the Klipriviersberg Group of South Africa, which is the oldest rock sequences used to define Vaalbara originally. A positive syn-fold test illustrated a high-temperature remanence component acquired during the formation of the Witwatersrand syncline. This fold structure predates the Vredefort Impact Structure and its formation is synchronous with the deposition of the Mesoarchaean Central Rand Group and extrusion of the Klipriviersberg Group. The studied rocks of the Klipriviersberg Group are not directly dated, but most are likley younger than 2 780 to 2 789 Ma, based on detrital zircon ages from the lowermost Ventersdorp Supergroup and U-Pb baddeleyite ages for mafic sills that intrude the Witwatersrand Supergroup that are regarded as feeders of the Kliprivierberg Group lavas, but older than the overlying 2 720 to 2 750 Ma Platberg Group. The Klipriviersberg Group pole is at 27.7°S, 32.7°E with an A95 of 11°. A comparison of Meso- to Neoarchaean palaeopoles from the Kaapvaal and Pilbara cratons suggests their shared drift path traversing the polar circle and thus supports the existence of Vaalbara across the 2.78 to 2.70 Ga interval.

U-Pb dating reveals multiple Paleoproterozoic orogenic events (Hamersley orogenic cycle) along the southern Pilbara margin (Australia) spanning the onset of atmospheric oxygenation

Abstract The early Paleoproterozoic was a time of unprecedented change in Earth's climate and surface environment. The key to resolving some of the controversies surrounding the timing and causes of these changes lies with supracrustal sequences, such as the 2.45–2.22 Ga Turee Creek Group in the southern Pilbara craton, northwestern Australia. The group preserves a predominantly siliciclastic sequence; however, its precise age, tectonic setting, and postdepositional history are disputed. Although it is interpreted to have been deposited in a foreland basin setting shortly after 2.45 Ga, the oldest well-recognized deformational event, marked by northward folding and thrusting, is the 2.20–2.15 Ga Ophthalmia orogeny. Evidence for a pre-Ophthalmia fabric-forming tectonic event north of the Archean Sylvania Inlier, southeast Pilbara craton, which is marked by tight to isoclinal folding, has been largely overlooked. In this area, we report in situ U-Pb geochronology of authigenic monazite and xenotime in shale with a well-developed tectonic cleavage from the ca. 2.63 Ga Jeerinah Formation. Monazite porphyroblasts, which are locally wrapped by strain fringes aligned in a tectonic cleavage, yielded weighted mean 207Pb/206Pb ages at 2370 ± 11 Ma and 2312 ± 8 Ma, whereas xenotime, which overprints a crenulation cleavage, gave a weighted mean 207Pb/206Pb age of 2291 ± 11 Ma, constraining fabric development to between 2.31 Ga and 2.29 Ga. Our results confirm the existence of a pre-Ophthalmia deformational event in the southeastern Pilbara craton, herein referred to as the Sylvania orogeny, which is part of an ~300 m.y. interval (2.45–2.15 Ga) of northward-directed compression (“Hamersley orogenic cycle”). This orogenic cycle is marked by east-west and northwest-southeast folding, cleavage development, veining, hydrothermal gold mineralization, and isotopic resetting across the southern Pilbara craton. Our results indicate that the syn–Great Oxidation Event Turee Creek Group was deposited in one or more foreland basins after 2.45 Ga. Our results provide a new tectonostratigraphic and geodynamic framework for understanding the timing and origin of geochemical records in a key succession deposited during an interval of global environmental change.

Recent pegmatite-hosted spodumene discoveries in Western Australia: insights for lithium exploration in Australia and globally

ABSTRACT The discovery and development of world-class Lithium–Caesium–Tantalum (LCT) spodumene-bearing pegmatites in Western Australia underpins growth of a significant new sector of its mining industry. Recently, several new spodumene discoveries have been delineated in the Yilgarn and Pilbara Cratons. Contrary to exploration narratives that new economic mineral discoveries will generally be made at increasingly greater depths, beneath barren cover rocks, or in remote geological environments, all new lithium discoveries have clear surface expressions in relatively ‘mature’ greenstone belts. The exploration implication is that the search space for pegmatite-hosted spodumene deposits in Western Australia remains immature. These recently discovered LCT pegmatites have geological features relevant to exploration including their age, amphibolite-facies metamorphic setting and syn-metamorphic timing, and 3D geometry, particularly their typically gentle dips, that match other such world-class pegmatites globally. Further spodumene discoveries within pegmatites at or near surface are likely in the Archean terranes of Western Australia based on these consistent exploration criteria and supportive capital market conditions.

AGE OF THE HANNIVKA GRANITE (MIDDLE-DNIEPER MEGABLOCK OF THE UKRAINIAN SHIELD)

The Middle-Dnieper megablock, which is a fragment of the craton, differs from other cratons found on Earth. This is because of the large variety of granitoids (Tokiv, Mokro-Moskowka, and Demuryne complexes) in the former that were formed after the Mesoarchean TTG. Thus, the Middle-Dnieper megablock is important for studying the genesis and geodynamic formation conditions of Late Archaean granitoids. The granitoids in the Middle-Dnieper megablock are not well understood. They include the Hannivka granites of the East Hannivka monocline of the Kryvyi Rih-Kremenchuk structure, whose age and stratigraphic position has been a matter of a long-standing debate. The purpose of the work is to study the geochemistry, genesis and U-Pb age of the Hannivka granites. Based on our results, the Hannivka granites possibly formed in the crust resulting from the melting of older rocks. They differ from other Late Archean granitoids of the Middle-Dnieper megablock by their high U (56.4 ppm) content and the presence of Mo (4.3 ppm). The Hannivka granites underwent tectonic reworking during a collisional event about 2.0 billion years ago, which is probably associated with the kalishpatization of these rocks. The U-Pb age of the cores of zircons sampled from the Hannivka granites, determined by LA-ICP-MS method, are about 2827±16 million years in age. Younger rims probably formed during kalishpatization. The Hannivka granites are the same age as the granitoids of the Mokro-Moskowka and Tokiv complexes. Late Archean granitoids were formed between 2.99-2.7 Ga in the Middle-Dnieper granite-greenstone block and in the geologically similar granite-greenstone block KMA are 2.6 Ga in age. In the Pilbara craton, which is a Paleoarchean granite-greenstone complex, the age of biotite and feldspar granites is similar to the age of the rocks on the Middle-Dnieper megablock (2.94-2.93 Ga). The difference in magmatism ages may be due to the drift of the different cratons above mantle plumes of different ages.

Kinematics and structural evolution of the Anziling dome-and-keel architecture in east China: Evidence of Neoarchean vertical tectonism in the North China Craton

The debate on the role of vertical versus horizontal tectonism in Archean cratons is intimately linked to the initiation of plate tectonics. The dome-and-keel architecture has been considered as a consequence of vertical tectonism. Although such a structural pattern is documented in some Mesoarchean and older cratons, such as the Kaapvaal and Pilbara cratons, whether it also occurs in Neoarchean cratons is poorly constrained. Determining the kinematics, structural evolution, and the timing of these structures is crucial in understanding how the tectonic behavior operated during the evolution of the early Earth. The North China Craton, especially its eastern part, is a Neoarchean continental block and preserves typical greenstone-granite rock assemblages. Detailed structural mapping reveals that the Anziling area (east China) is characterized by a typical dome structure without significant reworking by later deformation. The dome is in tectonic contact with a supracrustal rock assemblage that is now the dip-slip Shuangshanzi ductile shear zone. In the supracrustal rocks, compositional layers are folded into upright isoclinal folds. Meanwhile, along the shear zone, foliation varies from NNW to SW with sub-vertical dip. Mineral stretching lineations indicate a sinistral shear sense with a slightly oblique-slip component in the north, but show NWW-directed and SW-directed steep dip-slip shear in the west and south, respectively. Kinematic indicators imply that the granitic dome formed through a vertically upward movement accompanied by an uneven clockwise rotation. The supracrustal rocks sank downwards to form the regional keel structure. Structural data suggests that the Anziling area is a typical dome-and-keel structure. U-Pb zircon dating on pre-, syn-, and post-tectonic dykes indicate that the dome-and-keel structure formed at 2530−2500 Ma, and was intimately related to the emplacement of tonalite-trondhjemite-granodiorite granitoids. New data from this study suggest that until the late Neoarchean, the vertical tectonism was still a dominant tectonic regime that was operating in the eastern North China Craton.

Zircon U–Pb Geochronology and Hf–O Isotope Characteristics of Granitoids from the Capricorn Orogen, Western Australia

AbstractThe Capricorn Orogen, Western Australia, is a complex orogenic zone that records the convergence and collision of the Archaean Yilgarn and Pilbara cratons in forming the West Australian Craton (WAC), then over one billion years of subsequent intracontinental reworking. Granites associated with these tectonothermal events (the Dalgaringa, Bertibubba, Moorarie, Durlacher and Thirty Three supersuites) are exposed in the western part of the Capricorn Orogen. This study integrates radiogenic (U–Pb and Hf) and stable isotope (O) analysis of zircon grains from granitic rocks in the Capricorn Orogen to determine their ages and magmatic sources, including the relative contributions of mantle versus crustal material. Granites from the margin of the Yilgarn Craton record periods of crustal growth and reworking during the Archaean that influenced later Proterozoic magmatic events. Components of the Capricorn Orogen, collectively termed the Glenburgh Terrane, have previously been considered to be exotic to the adjacent Pilbara and Yilgarn cratons. However, new U–Pb zircon geochronology and Lu–Hf isotope compositions of basement rocks in the Glenburgh Terrane (the Halfway Gneiss) have similarities to some terranes of the Yilgarn Craton, and are interpreted to represent a reworked portion of the craton that was re-accreted during the Glenburgh Orogeny. Arc magmatism during the Ma Glenburgh Orogeny resulted in a period of crustal growth, with magmas representing a mixture of 50–90 % mantle-derived magmas and 50–10 % magmas derived from an evolved crustal component with an isotopic composition equivalent to that of the Halfway Gneiss. Following assembly of the WAC, granite magmatism in the Capricorn Orogen records a significant change from one dominated by mantle-derived magmatism to one dominated by crustal melting and an increased contribution from metasedimentary material. This transition reflects a geodynamic evolution from subduction–accretion to collision and intracratonic reworking. The isotopic characteristics of granites from the Moorarie Supersuite indicate three distinct sources: (1) a metasedimentary component; (2) an evolved crustal component, comparable with the Glenburgh Terrane; (3) a mafic juvenile component. Following this, the Hf–O compositions of the Durlacher Supersuite indicate that they were derived from reworking of the Moorarie Supersuite granites, and require no juvenile contribution or any additional sedimentary source. The isotopic compositions of the Thirty Three Supersuite pegmatites indicate that they were largely derived from reworking of the Moorarie and Durlacher supersuites.

Assessment of natural hydrogen systems in Western Australia

The discovery of a large accumulation of natural hydrogen in Mali has triggered the opportunity to search for hydrogen accumulations in other countries. The generation of hydrogen in Mali is linked to the presence of very old iron-rich basement rocks. Solid-liquid redox reactions between iron-rich minerals and groundwater are a possible source of H2 in deep basement rocks. The hypothesis is that hydrogen degassing may result in the surface circular shallow depressions. The Archean iron-rich Yilgarn and Pilbara cratons that cover a vast area of Western Australia contain abundant iron-rich mafic-ultramafic rocks. The craton reveals many surficial circular depressions visible through satellite images. The area has abundant fault systems and is blanketed with Eocene sedimentary rocks containing high-quality reservoir rocks. All these characteristics appear to provide most of the required elements, such as a hydrogen source, migration pathway, and reservoir rock for a complete “Hydrogen System” to be developed in the area.

Neoarchean atmospheric chemistry and the preservation of S-MIF in sediments from the São Francisco Craton

Sulfur mass-independent fractionation (S-MIF) preserved in Archean sedimentary pyrite is interpreted to reflect atmospheric chemistry. Small ranges in Δ33S that expanded into larger fractionations leading up to the Great Oxygenation Event (GOE; 2.45–2.2 Ga) are disproportionately represented by sequences from the Kaapvaal and Pilbara Cratons. These patterns of S-MIF attenuation and enhancement may differ from the timing and magnitude of minor sulfur isotope fractionations reported from other cratons, thus obscuring local for global sulfur cycling dynamics. By expanding the Δ33S record to include the relatively underrepresented São Francisco Craton in Brazil, we suggest that marine biogeochemistry affected S-MIF preservation prior to the GOE. In an early Neoarchean sequence (2763–2730 Ma) from the Rio das Velhas Greenstone Belt, we propose that low δ13Corg (<−30‰) and dampened Δ33S (0.4‰ to −0.7‰) in banded iron formation reflect the marine diagenetic process of anaerobic methane oxidation. The overlying black shale (TOC up to 7.8%) with higher δ13Corg (−33.4‰ to −19.2‰) and expanded Δ33S (2.3‰ ± 0.8‰), recorded oxidative sulfur cycling that resulted in enhance preservation of S-MIF input from atmospheric sources of elemental sulfur. The sequence culminates in a metasandstone, where concomitant changes to more uniform δ13Corg (−30‰ to −25‰), potentially associated with the RuBisCO I enzyme, and near-zero Δ33S (−0.04‰ to 0.38‰) is mainly interpreted as evidence for local oxygen production. When placed in the context of other sequences worldwide, the Rio das Velhas helps differentiate the influences of global atmospheric chemistry and local marine diagenesis in Archean biogeochemical processes. Our data suggest that prokaryotic sulfur, iron, and methane cycles might have an underestimated role in pre-GOE sulfur minor isotope records.

Trace Element Contents of Mantle-Derived Magmas Through Time

Abstract A large compilation of quality-curated major and trace element data has been assembled to investigate how trace element patterns of mafic and ultramafic magmas have varied with time through particular settings from the Archean to the Phanerozoic, the primary objective being to recognise at what times particular patterns of variation emerge, and how similar these are to baseline data sets representing tectonic settings in the modern Earth. The most informative element combinations involve Nb, Th and the REE, where REE are represented by ‘lambda’ parameters describing slope and shape of patterns. Combinations of the ratios of Th, Nb, La and lambda values from Archean and early Proterozoic basalts and komatiites reveal a distinctive pattern that is common in most well-sampled terranes, defining a roughly linear trend in multi-dimensional space from compositions intermediate between modern n-MORB and primitive mantle at one end, towards compositions approximating middle-to-upper continental crust at the other. We ascribe this ‘Variable Th/Nb’ trend in most instances to varying degrees of crustal contamination of magmas with similar compositions to modern oceanic plateau basalts. Komatiites had slightly more depleted sources than basalts, consistent with the hypothesis of derivation from plume tails and heads, respectively. The most significant difference between Precambrian and Phanerozoic plume-derived basalts is that the distinctive OIB-like enriched source component appears to be largely missing from the Archean and Proterozoic geologic record, although isolated examples of OIB-like trace element characteristics are evident in datasets from even the oldest preserved greenstones. Phanerozoic intra-cratonic LIPs, such as the 260 Ma Emeishan LIP in China, have fundamentally different geochemical characteristics to Archean and Paleoproterozoic assemblages; the oldest Proterozoic LIP we have identified that has this type of ‘modern’ signal is the Midcontinent Rift at 1100 Ma. The data are consistent with plume tail sources having changed from being dominantly depleted in the Archean Earth to dominantly enriched in the Phanerozoic Earth, while plume head sources have hardly changed at all. Trace element patterns considered to be diagnostic of subduction are locally present but rare in Archean terranes and become more prevalent through the Proterozoic, although this conclusion is tempered by the large degree of overlap in compositional space between continental arc magmas and continental flood basalts. This overlap reflects the difficulty of distinguishing the effects of supra-subduction metasomatizm and flux melting from those of crustal contamination. Additional factors must also be borne in mind, particularly that trace element partitioning systematics may have been different in all environments in a hotter planet, and large-scale asthenospheric overturns might have been predominant over modern-style plumes in the Archean Earth. Some basaltic suites in particular Archean terranes, notably the western parts of both the Yilgarn and Pilbara cratons in Western Australia and parts of the Superior Craton, have restricted, but locally predominant, suites of basalts with characteristics akin to modern oceanic arcs, suggesting that some process similar to modern subduction was preserved in these particular belts. Ferropicrite magmas with distinctive characteristics typical of modern OIBs and some continental LIPs (notably Emeishan) are rare but locally predominant in some Archean and early Proterozoic terranes, implying that plume sources were beginning to be fertilised by enriched, probably subducted, components as far back as the Mesoarchean. We see no evidence for discontinuous secular changes in mantle-derived magmatism with time that could be ascribed to major mantle reorganisation events. The Archean–Proterozoic transition appears to be entirely gradational from this standpoint. The transition from Archean-style to Phanerozoic-style plume magmatism took place somewhere between 1900 Ma (age of the Circum-Superior komatiitic basalt suites) and 1100 Ma (the age of the Midcontinent Rift LIP).

A southern African perspective on the co-evolution of early life and environments

AbstractThe Kaapvaal and Zimbabwe cratons host some of the earliest evidence for life. When compared to the contemporaneous East Pilbara craton, cherts and other metasedimentary horizons in southern Africa preserve traces of life with far greater morphological and geochemical fidelity. In spite of this, most fossiliferous horizons of southern Africa have received relatively limited attention. This review summarises current knowledge regarding the nature of early life and its distribution with respect to environments and ecosystems in the Archaean (&amp;gt;2.5 Ga) of the region, correlating stratigraphic, sedimentological, geochemical and palaeontological understanding. There is abundant and compelling evidence for both anoxygenic photosynthetic and chemosynthetic biomes dominating Palaeoarchaean-Mesoarchaean strata dating back to around 3.5 Ga, and the prevalence of each is tied to palaeoenvironmental parameters deducible from the rock record. Well-developed, large stromatolites characteristic of younger Mesoarchaean-Neoarchaean sequences were probably constructed by oxygenic photosynthesisers. Isotopic evidence from the Belingwe greenstone belt and the Transvaal Supergroup indicates that both a full sulphur cycle and complex nitrogen cycling were in operation by the Mesoarchaean-Neoarchaean. The Archaean geological record of southern Africa is thus a rich repository of information regarding the co-evolving geosphere and biosphere in deep time.

Apatite nanoparticles in 3.46–2.46 Ga iron formations: Evidence for phosphorus-rich hydrothermal plumes on early Earth

AbstractPhosphorus is an essential nutrient that is thought to have regulated primary productivity in global oceans after the advent of oxygenic photosynthesis. The prime source of seawater phosphorus is regarded to be continental weathering of phosphate minerals. Ancient seawater phosphorus concentrations have been constrained using the phosphorus content of iron-rich chemical sediments—banded iron formations (BIFs); however, the removal processes and depositional phases remain unclear. Here we report that nanometer-sized apatite crystals (&amp;lt;500 nm) are ubiquitous in 3.46–2.46 Ga BIFs and cherts from the Kaapvaal (South Africa) and Yilgarn, and Pilbara (Western Australia) cratons. The apatite is uniformly dispersed in a chemical sediment comprising greenalite nanoparticles, which were encased in very early diagenetic silica cement that limited compaction and chemical reactions. The lack of organic carbon (below detection; &amp;lt;0.3 wt%) and absence of primary iron oxides implies that the phosphorus was not derived from the degradation of organic matter or seawater scavenging by oxide particles. Instead, the occurrence of apatite in sediments derived from hydrothermally sourced Fe2+ and SiO2(aq) suggests that phosphorus too was derived from vent plumes. Today, seawater P is rapidly removed from vent fluids due to scavenging by oxidized Fe2+. However, prior to the Great Oxidation Event (2.45–2.32 Ga), dissolved phosphorus released during anoxic alteration of seafloor basalts escaped the iron-oxidation trap. Our results point to the existence of a submarine hydrothermal flux of dissolved phosphorus that supplied nutrients to the early anoxic oceans. High amounts of seawater P may help to explain why phosphorus is ubiquitous in cell biology—it was not limiting during the origin and early evolution of life.