AbstractA LiNbO3 waveguide quasi‐phase‐matched sum‐frequency generation (SFG) device is studied. From the design of the device and a study of the sampling characteristic, it is determined that picosecond optical sampling can be realized at high conversion efficiency. A device 5 mm long with a fan‐shaped polarization inversion grating is fabricated for optical sampling experiments. By using the sampling pulse light with a width of 25 ps obtained by gain‐switching operation of a laser diode, the waveform of the signal light at a wavelength of 1.5 μm is observed. Optical sampling at a normalized SFG conversion efficiency of 43%/W is realized. © 2001 Scripta Technica, Electron Comm Jpn Pt 2, 84(5): 29–36, 2001