Sky View Factor (SVF) is commonly used to describe the impact of urban geometry on the urban thermal environment. Shading effects from plants and buildings also exert a considerable influence. To investigate the influence of view factors on outdoor thermal comfort in residential areas, we employed the Physiological Equivalent Temperature (PET) and view factors (SVF, TVF, BVF) as indicators to determine outdoor thermal comfort and the quantity of shaded spaces. Thermal measurements collected from 13 points in Guangzhou, China, Our findings revealed that high TVF points exhibited more stable air temperature throughout the daytime, with average temperature differentials ranging 0.4-1.9°C lower than other points. Air temperature demonstrated a positive correlation with SVF (R2 = 0.53), while exhibiting a negative correlation with TVF (R2 = 0.45). Additionally, shading provided by plants and buildings manifests heterogeneity. At similar SVF levels, points predominantly shaded by plants (TVF > BVF) showcased lower Mean Radiant Temperature (MRT) and PET compared to points shaded mainly by buildings (BVF > TVF). The maximum reduction in air temperature and PET reached 1.1°C and 1.2°C, respectively. BVF exerted greater influence earlier in the morning, as solar altitude angle rises, the average thermal parameters of sites with BVF > TVF escalated rapidly until eventually surpassing sites with TVF > BVF. Last, superior thermal conditions were only ensured under high shading conditions. When the effective shading ratio of plants and buildings diminished (SVF > 0.3), the microclimate of measurement points might be impacted by the long-wave radiation from the underlying surface.