Phyllosilicate Minerals Research Articles

Coal structure evaluation and morphological properties that affect the coal usage in industries

The contemporary research article is central to understanding coal structure evaluation and the morphological development impacting its utilization in different applications. Through Mineral Liberation Analysis (MLA) designs high content phyllosilicates minerals and swelling clay minerals were rationalized to provides a novel insight into enhanced coal beneficiation and the benefits of coal by-product re-utilization progressions that encourage safer environments and economic sustainability. This work commences with collection of five (5) different coal samples from the central district region in Botswana, sample characterization deploying Thermogravimetric coal analysis (TGA), x-ray fluorescence spectroscopy (XRF), x-ray diffraction (XRD), scanning electron microscopy (SEM) and the Hardgrove Grindability Index (HGI) test that was directed to quantification of the coal hardness and fracture toughness during milling. The cumulative objective was to understand the correlation that exists between the natural composition of the coal sample and their adaptation and application in various carbonaceous products. A solid connection was thus identified in the sulfur and phosphorus weight percentage inclusions in all the coal materials hence higher significance in sphalerite mineral phases (Zn, Fe) S critically increased the fracture toughness and hardness properties. Moreover, mineral amalgams intrinsic to the coal maceral such as aluminum oxides (Al2O3), silicate (SiO2), calcites (CaO), Iron oxide (Fe2O3), potassium feldspars (K − AlSi3O8), albite (Na − AlSi3O8), and anorthite (Ca − Al2Si2O8) compounds in alkali feldspars were detected in larger quantities. The coal industry has attracted much industrial attention to manufacturing foundations producing cement, ceramic tiles, paving bricks, and material synthesis and will continue to supply other economic sectors in the conceivable future.Graphical

Fundamentals of copper(II) adsorption on phyllosilicate minerals relevant to crud formation in solvent extraction from heap leach liquors

Because of the common presence of different silicate minerals, like kaolinite, montmorillonite and muscovite as gangue minerals in the beneficiation of copper oxide ores, the interaction between copper(II) ions in solution and each of these minerals is a field of strong interest, considering their implications on the aggregation of these minerals in the extreme pH conditions typical of hydrometallurgical unit operations for copper production. After copper adsorption isotherms determination at pH 2 and 4, specific adsorption data were fitted to both Langmuir and Freundlich models. It was found that adsorption is systematically larger at pH 4, and that montmorillonite is the mineral that displays a larger adsorption capacity, as in principle expected by its larger cation exchange capacity, CEC. A good fitting to the Langmuir model was obtained for the three samples, and montmorillonite also appears to conform to Freundlich isotherm predictions, as the tested concentrations of copper(II) do not allow to reach saturation. Furthermore, some desorption is measured for kaolinite and muscovite at the highest copper concentrations, probably because of significant interactions between the adsorbed ions. No such desorption was detected in montmorillonite samples. An XPS analysis of the surfaces of the three minerals suggests that copper adsorption in kaolinite is not associated to a cation exchange process but rather to electrostatic interactions between silica-like faces of the clay. In contrast, ionic exchange of structural calcium (for montmorillonite) or potassium (in the case of muscovite) seems to be the predominant mechanism of Cu(II) adsorption in the other two samples. Electrophoretic mobility determinations agree with this hypothesis: the mobility (always negative, with no traces of charge inversion) decreases in absolute value when kaolinite particles are in contact with solutions of increasing copper concentration at pH 2 or pH 4. On the other hand, the electrophoretic mobility values of muscovite and montmorillonite showed a weak pH and copper concentration dependence, a result that matches well with the ion exchange processes detected in the XPS measurements.

Dependence of Simulated Fault Gouge Frictional Behavior on Mineral Surface Chemistry Quantified by Cation Exchange Capacity

AbstractThe slip behavior of crustal faults is known to be controlled by the composition of the fault gouge, but the exact mechanisms, especially considering the role of water‐rock interactions, are still under investigation. Here, we use a geochemical approach measuring the cation exchange capacity (CEC) of several phyllosilicate minerals and non‐clays, using CEC as a proxy for the ability to bind water to the mineral surfaces and/or develop electrostatic forces between particles. Laboratory shearing experiments show that low CEC materials (<3 mEq/100 g) tend to exhibit high friction, low cohesion, and velocity‐weakening frictional behavior. Phyllosilicate minerals exhibit CEC values up to 78 mEq/100 g and correspondingly lower friction coefficients, higher cohesion, and a tendency for velocity‐strengthening friction. Zeolite behavior is atypical, exhibiting a high CEC value typical of phyllosilicates but the strength and frictional characteristics of a non‐clay with low CEC. This suggests that the structure of the mineral is important for non‐phyllosilicates. For phyllosilicates, our results can be explained by water bound to mineral surfaces, creating bridges of hydrogen or van der Waals bonds between particles. The enhanced particle bonding for high CEC materials is consistent with high cohesion under zero effective stress conditions, and lowered friction by trapping bound water between the mineral surfaces under normal load. Bound water may explain the tendency for velocity‐strengthening friction in high CEC materials by hindering a Dieterich‐type time‐dependent frictional strengthening mechanism.

Variations of organic functional chemistry in carbonaceous matter from the asteroid 162173 Ryugu

Primordial carbon delivered to the early earth by asteroids and meteorites provided a diverse source of extraterrestrial organics from pre-existing simple organic compounds, complex solar-irradiated macromolecules, and macromolecules from extended hydrothermal processing. Surface regolith collected by the Hayabusa2 spacecraft from the carbon-rich asteroid 162173 Ryugu present a unique opportunity to untangle the sources and processing history of carbonaceous matter. Here we show carbonaceous grains in Ryugu can be classified into three main populations defined by spectral shape: Highly aromatic (HA), Alkyl-Aromatic (AA), and IOM-like (IL). These carbon populations may be related to primordial chemistry, since C and N isotopic compositions vary between the three groups. Diffuse carbon is occasionally dominated by molecular carbonate preferentially associated with coarse-grained phyllosilicate minerals. Compared to related carbonaceous meteorites, the greater diversity of organic functional chemistry in Ryugu indicate the pristine condition of these asteroid samples.

Bespoke strategies of Paxillus involutus to extract potassium from diverse phyllosilicates

Phyllosilicates provide a primary source of minerals used by microorganisms and plants, particularly clay minerals, i.e., phyllosilicates of very small particle size. Fungi can actively break down (or “weather”) minerals to extract nutrients, but whether they use identical mechanisms when accessing different clay minerals is unclear. In addition, it is yet to be understood whether starvation stresses due to the limited availability of a mineral-nutrient would result in different weathering behaviours of microbes.Here, we performed a microcosm experiment to address these questions. We used the ectomycorrhizal basidiomycete Paxillus involutus and the phyllosilicates K-vermiculite, muscovite and phlogopite. These silicates have different degrees of recalcitrance to the removal of K cations from the mineral, and each was provided in the microscosm experiment as the sole potassium (K) source. The type of potassium "extraction-assimilation" was tested against a potassium-availability gradient, with a situation of maximum starvation stress (no potassium availability) and one of maximum availability (potassium provided as a solute in the culture medium). Our study revealed that different phyllosilicate minerals stimulated different patterns of fungal gene expression, which indicated bespoke weathering mechanisms for different phyllosilicates. The potassium uptake capacity of the fungus was highest with K-vermiculite compared to phlogopite and muscovite. Interestingly, the assimilation of phosphorus by the fungus was reduced in K-depleted conditions.Moreover, the potassium deprivation condition prompted the fungus to assimilate sodium instead. Also, in the presence of the minerals, the fungus showed significant differences in gene expression compared with the negative and positive control conditions, suggesting that the mineral environment modulates the starvation stress levels. The nutrients assimilated by the mycelium from both the minerals and the culture medium also varied according to the type of silicate added and the K starvation level to which the fungus was subjected. Based on what has been observed here, many geochemical processes could depend on fungi's genetic and functional plasticity, which would have considerable environmental consequences with a direct link between the evolution of fungi and that of the Earth's crust.

Decoupling the effect of hydraulic oil contamination on the flotation performance of UG2 PGE ore and its interaction with alteration minerals

Oil contamination inadvertently arising from underground mechanised South African platinum mines is known to compromise the subsequent flotation performance. Anecdotal observations suggest that this is further exacerbated in the presence of phyllosilicate alteration minerals. Two ores of varying degrees of alteration from the Bushveld Igneous Complex were utilized in this study to investigate the effects of oil on UG2 platinum group element (PGE) ore flotation and investigate the interaction mechanisms between the oil and phyllosilicate alteration minerals. Mineralogical characterization of the ores indicated a higher percentage of the alteration phyllosilicate minerals in the altered ore (9.2 wt%) in comparison to the normal ore (5.6 wt%); with talc predominating in both ores. Baseline batch flotation test work indicated a reduction of grade with hydraulic oil addition in the normal ore (Pt by 4.5 g/t and Pd by 3.6 g/t), whereas valuable metal grades in the altered ore showed no change. In contrast to the grades, the Pt and Pd recovery dropped by 6 % and 12 %, respectively, in the altered ore floats whereas nearly constant recoveries were obtained for the normal ore as oil concentration increased. The dynamic froth stability and slurry viscosity both increased in the presence of oil and were greater in the altered ore compared to the normal ore. The observed flotation performance of the normal ore was attributed to the increasing froth stability which promoted the recovery of gangue minerals and consequent grade decrease. For the altered ore, the greater increase in the slurry pulp viscosity with oil addition was proposed to lead to poor gas dispersion and reduced interaction between bubbles and particles resulting in the reduction of recovery. The addition of sodium metasilicate successfully mitigated these effects causing a decrease in the viscosity, improvement in particle dispersion and better froth drainage. This study highlighted the potentially harmful effects of oil spillages from mechanised mining and its complex interaction with alteration minerals contained within the ore.

Water Nanochannels in Ultrathin Clinochlore Phyllosilicate Mineral with Ice-like Behavior

Water Nanochannels in Ultrathin Clinochlore Phyllosilicate Mineral with Ice-like Behavior

Lead stabilization and remediation strategy with soil amendment in situ immobilization in contaminated range lands

In situ immobilization is a potential approach that can be used to remediate low-to-medium levels of heavy-metal in contaminated-soil. There is little known about how modifications to soil characteristics may affect Pb’s release from soil. The four different amendments, triple-superphosphate and attapulgite were combined in Ad-1; zeolite and triple-superphosphate were in Ad-2; hydroxyapatite and humus were in Ad-3; and nano-carbon. These amendments are mostly made of phyllosilicate minerals, humus, base minerals, and nano-carbon, respectively. Results revealed that the test amendments’ maximal Pb-adsorption capacity varied from 7.47 to 17.67 mg g−1. Surface precipitation and ion-exchange were found to be the main mechanisms for Pb-adsorption by Ad-1 and Ad-2, while Ad-3 and Ad-4 were promising among the all, according to analysis of the modifications both before and after Pb loading. When the pH dropped (7-1) or the ion-strength rose (0–0.2 M), there was a discernible rise in the Pb-desorption percentages from the amendments. It was determined that Ad-3 and Ad-4 were more effective in situ immobilizing lead in contaminated-soils because of their high adsorption capacities (12.82 and 17.67 mg g−1) and low-desorption percentages (4.46–6.23%) at ion-strengths of 0.01–0.1 mol L−1 and pH levels ranging from 5 to 7.

Geo-mechanical and geo-morphology characterisation of the cap rocks in the Niger Delta for potential carbon capture and storage

The world has been battling climate change which is caused by an excessive amount of carbon dioxide in the atmosphere. Carbon sequestration in geological sinks was identified as one of the major methods to curb and reduce the amount of carbon dioxide in the atmosphere. The carbon dioxide stored in the geological formations must not escape back into the atmosphere. Characterisation of potential reservoirs for geological sequestration is pertinent for injectivity, capacity, and most importantly containment of carbon dioxide. The cap rock is one of the most important factors determining carbon sequestration success. This study focuses on the preliminary characterisation of the caprocks for evaluating potential subsurface storage of carbon dioxide based on their petrophysical characteristics. X-ray Diffraction and X-ray Fluorescence provided the mineralogical composition and geochemical data of the cap rocks while Scanning Electron Microscopy-EDS was used to identify the qualitative information on the micromorphological textural structure of the cap rocks in the Niger Delta. Conventional Triaxial experiments were used to determine the elastic and geo-mechanical strength of the caprocks. It was identified that the grain skeleton of caprocks in the region is predominated by Quartz, Albite, and Muscovite. The ratio of the tectosilicate and phyllosilicate minerals indicates that the cap rocks are silicate shale. The peak strength of the caprocks ranged from 48.85 to 80.50 MPa and are classified as strong rocks. The cap rocks showed a quasi-elastic behaviour after being subjected to compressive axial force. The elastic modulus of the caprocks was also observed. The characteristics exhibited by the shale caprock at the rock matrix level are highly favourable for sealing carbon dioxide and hence indicate capability for use in carbon sequestration.

Shale fault reactivation during hydraulic fracturing in the Sichuan Basin: Evidence from shear experiments and stress perturbation calculations

Induced seismicity triggered during hydraulic fracturing for shale gas exploitation in the Sichuan Basin has aroused wide public concern with these earthquakes closely correlated with the reactivation of faults within the reservoir. The target shale reservoirs in the Sichuan Bain are currently located in the Longmaxi formation. To explore instability on these faults, we conducted shear experiments on simulated fault gouges under hydrothermal conditions to assess frictional stability and also evaluated the stress perturbations resulting from multistage hydraulic fracturing. Experimental results show that the frictional instability on these faults is primarily controlled by both mineral composition and the applied temperatures. With a decrease in the contents of phyllosilicate minerals or an increase in applied temperatures, the shale faults exhibit a transition from velocity-strengthening to velocity-weakening behaviour, indicating the potential for unstable fault slip. The stress perturbations resulting from multistage hydraulic fracturing were calculated from a dislocation model of the fluid-driven fracture. These results show that the stress changes resulting from multistage hydraulic fracturing are sufficient to reactivate adjacent unstable faults in the shale reservoir and trigger the seismicity. Our experimental and modelling results highlight the importance of shale composition, temperature, and stress perturbations on shale fault stability. These results have significant implications for understanding the shale fault instability and the potential triggering of induced seismicity during hydraulic fracturing in the Sichuan Basin.

Near-Infrared Spectroscopic Study of Biotite–Phlogopite (Mg# = 30~99): OH-Stretching Modes and Mg# Content Prediction Equation

Biotite–phlogopite minerals are a complete Mg–Fe isomorphism series of phyllosilicates. A Fourier transform infrared spectroscopy (FTIR) and electron microprobe analysis (EMPA) were conducted on end-member phlogopite, Mg–biotite, and annite samples. In the mid-infrared region, absorption peaks were observed at 460, 1000, 3680, and 3710 cm−1 in the biotite group. Samples with higher Mg content exhibited stronger peaks assigned to OH vibrations and a weak absorption peak at 810 cm−1. In the near-infrared region, combination peaks were observed near 4200, 4300, and 4450 cm−1, with wavenumbers showing a linear inverse relationship with the Mg# [=100 × Mg/(Mg + FeT)] value. For annite, combination peaks occurred at 4173, 4292, and 4439 cm−1, decreasing by 10–15 cm−1 compared to end-member phlogopite. Judging the fundamental peaks of the combination band contributes to identifying suitable near-infrared characteristic peaks for quantitative research. The 4300 cm−1 absorption peak in biotite–phlogopite was assigned to OH-bending and -stretching vibrations, making it suitable for mineral identification and Mg# estimations across all biotite groups. The 4450 cm−1 characteristic peak, assigned to Al–O-stretching vibrations and OH-stretching vibrations, is suitable for accurately predicting Mg# values in high AlVI samples. The first overtones of biotite–phlogopite appeared at 7250 cm−1, with an average factor of 1.955 between the fundamental and corresponding overtones. This study aims to refine the patterns of OH-stretching vibrations and characteristic peak shifts in the near-infrared spectral region of phyllosilicate minerals, providing data references for planetary spectroscopy and ore deposit studies.

Reservoir siltation and sediment characterization for reuse as construction material in a semi-arid area

Anibi S, Ellouze S, Zairi M. 2024. Reservoir siltation and sediment characterization for reuse as construction material in a semi-arid area. Lake Reserv Manage. 40:159–176. In this study, we investigated the siltation rate, evolution, and spatial distribution of sediments within the Siliana Dam reservoir, north-west Tunisia. We analyzed the geotechnical, chemical, mineralogical, and trace metal content properties of sediment samples collected from the reservoir. Additionally, we examined the potential valorization of reservoir sediments in road construction and the effects of hydrated lime treatment on their bearing characteristics. The Siliana dam reservoir is currently 50% silted up, and the sedimentation rate is approximately 1.52% per year. The sediments are mainly fine-grained, low organic with medium to high plasticity and high content of calcium carbonate. The sediments consist of calcite and quartz, with minor amounts of dolomite, hematite, and phyllosilicate minerals. Chromium, zinc, and copper contents in the sediments exceed environmental standards. The lime treatment improved the materials bearing capacity. Adding lime (5% by weight) resulted in an immediate bearing ratio of 26%, a higher ratio compared to the raw sediments. The study of the spatial and temporal evolution of sediment accumulation provides information to develop strategies for mitigating the accumulation of sediments. The sediment characterization evaluated the suitability of sediments to be used as construction materials, offering potential cost savings and contributing to informed decision-making for reservoir management.

Eco-friendly natural mineral biotite as a cesium adsorbent: Utilizing low-concentration acid and hydrogen peroxide

Biotite, a phyllosilicate mineral, possesses significant potential for cesium (Cs) adsorption owing to its negative surface charge, specific surface area (SSA), and frayed edge sites (FES). Notably, FES are known to play an important role in the adsorption of Cs. The objectives of this study were to investigate the Cs adsorption capacity and behavior of artificially weathered biotite and identify mineralogical characteristics for the development of an eco-friendly geologically-based Cs adsorbent. Through various analyses, it was confirmed that the FES of biotite was mainly formed by mineral structural distortion during artificial weathering. The Cs adsorption capacity is improved by approximately 39% (from 20.53 to 28.63 mg g−1) when FES are formed in biotite through artificial weathering using a low-concentration acidic solution mixed with hydrogen peroxide (H2O2). Especially, the Cs selectivity in Cs-containing seawater, including high concentrations of cations and organic matter, was significantly enhanced from 203.2 to 1707.6 mL g−1, an increase in removal efficiency from 49.5 to 89.2%. These results indicate that FES of artificially weathered biotite play an essential role in Cs adsorption. Therefore, this simple and economical weathering method, which uses a low-concentration acidic solution mixed with H2O2, can be applied to natural minerals for use as Cs adsorbents.

Hygroscopic Growth of Adsorbed Water Films on Smectite Clay Particles.

Hygroscopic growth of adsorbed water films on clay particles underlies a number of environmental science questions, from the air quality and climate impacts of mineral dust aerosols to the hydrology and mechanics of unsaturated soils and sedimentary rocks. Here, we use molecular dynamics (MD) simulations to establish the relation between adsorbed water film thickness (h) and relative humidity (RH) or disjoining pressure (Π), which has long been uncertain due to factors including sensitivity to particle shape, surface roughness, and aqueous chemistry. We present a new MD simulation approach that enables precise quantification of Π in films up to six water monolayers thick. We find that the hygroscopicity of phyllosilicate mineral surfaces increases in the order mica < K-smectite < Na-smectite. The relationship between Π and h on clay surfaces follows a double exponential decay with e-folding lengths of 2.3 and 7.5 Å. The two decay length scales are attributed to hydration repulsion and osmotic phenomena in the electrical double layer (EDL) at the clay-water interface.

Variation in the structural order of kaolinite in regolith as an effective indicator of REE mineralization

Abstract Regolith-hosted rare earth element (REE) deposits hosted by the granitic regolith in South China provide &gt;90% of the world’s heavy REEs. Kaolinite is one of the major carriers of REE ions in regolith. The formation and transformation of kaolinite can be affected by chemical weathering and hydrodynamic conditions, but the contribution of each factor has not been evaluated. This study systematically investigated the variation in abundance of phyllosilicate minerals and structural order of kaolinite in the Renju regolith-hosted REE deposit. The total abundance of 1:1 phyllosilicate minerals increased upwards along the profile from Section I to Section III. However, semi-quantitative analyses indicated that Section III-1 (depth at 10–16 m) featured an evident decrease in both abundance and structural order of kaolinite upward along the profile. The morphological feature and abundance of kaolinite revealed intensive kaolinite-to-halloysite transformation and kaolinite dissolution in Section III-1. This suggests that the alternating wetting and drying zone in Section III-1 provided a favorable kinetic environment for the entry of water molecules into the kaolinite interlayer and the kaolinite-to-halloysite transformation, resulting in both lower structural order and abundance of kaolinite in Section III-1. Moreover, REE ions started to be enriched from the alternating wetting and drying zone and formed high-grade ores at the lower part of the water table, due to a significant increase in pore water and decrease in the seepage velocity. Therefore, the abundance and structural order of secondary kaolinite can serve as important indicators of hydrodynamic changes in regolith, as well as the mineralization of regolith-hosted REEs.

Combining sequential extractions with bulk and micro X-ray spectroscopy to elucidate iron and phosphorus speciation in sediments of an iron-treated peat lake.

In shallow lakes, mobilization of legacy phosphorus (P) from the sediments can be the main cause for persisting eutrophication after reduction of external P input. In-lake remediation measures can be applied to reduce internal P loading and to achieve ecosystem recovery. The eutrophic shallow peat lake Terra Nova (The Netherlands) was treated with iron (Fe) to enhance P retention in the sediment. This treatment, however, intensified seasonal internal P loading. An earlier study suggested that Fe addition led to increased P binding by easily-reducible Fe(III) associated with organic matter (OM), which readily releases P when bottom waters turn hypoxic. In this complementary study, bulk and micro Fe K-edge and P K-edge X-ray absorption spectroscopy and micro-focused X-ray fluorescence spectroscopy were applied to characterize the P hosting Fe(III) pool. Combined with sequential extraction data, the synchrotron X-ray analyses revealed that a continuum of co-precipitates of Fe(III) with calcium, phosphate, manganese and organic carbon within the OM matrix constitutes the reducible Fe(III) pool. The complementary analyses also shed new light on the interpretation of sequential extraction results, demonstrating that pyrite was not quantitatively extracted by nitric acid (HNO3) and that most of the Fe(II) extracted by hydrochloric acid (HCl) originated from phyllosilicate minerals. Formation of an amorphous inorganic-organic co-precipitate upon Fe addition constitutes an effective P sink in the studied peaty sediments. However, the high intrinsic reactivity of this nanoscale co-precipitate and its fine distribution in the OM matrix makes it very susceptible to reductive dissolution, leading to P remobilization under reducing conditions.

Effect of lithological and geotechnical characteristics on the generation of debrisflows in Matmata, southeastern Tunisia

The Matmata region, located in the south of Gabès (Tunisia), experienced significant damage during the floods of the Beni zelten wadi on November 11, 2017. These floods, exacerbated by the steep slopes and underlying soil conditions, led to the occurrence of debris flows, posing a threat to road infrastructure. The generation of debris flows is closely linked to intense rainfall events that surpass the soil capacity to retain water. To gain insights into the behaviour of the soil samples, various characteristics were analysed, including texture, clay mineralogy, grain size distribution, and Atterberg limits. The results showed that the mean liquid limit values ranged from 38% to 62%, while the mean plasticity index of the materials in the landslide-prone areas varied from 18% to 27.9%. These findings indicate presence of clay formations and highlight a significance of the increased soil clay content as contributing factors to landslide development. The X-ray Diffraction analysis revealed that gypsum, quartz, phyllosilicate and calcite minerals were the most abundant minerals identified in the soil samples. This work shows the importance of clay mineral and geotechnical parameters of the soils in the occurrence of landslides and predicting debris flows occurrences in the Matmata region.

Periodic Bedrock Ridges at Oxia Planum and Chryse Planitia, Mars: Evidence for widespread aeolian erosion of an ancient surface by regional paleowinds

Periodic Bedrock Ridges (PBRs) are repeating, symmetrical, wind-transverse, bedrock-abraded linear ridges that occur on Mars as parallel sets. Here, we extend our previous survey of PBRs at Oxia Planum – the landing site of ESA's ExoMars Rosalind Franklin rover – to include three additional sites along the margins of the circum-Chryse basin to understand patterns in PBR orientation and occurrence. We analyzed PBR crestline orientation at each study site and found them to be consistent across this large region, but their orientations do not align with global circulation model winds, suggesting contemporary winds are not responsible for PBR development. Furthermore, we used observations of landscape-level stratigraphic relationships at Oxia Planum to constrain the formation age of PBRs to be late Noachian to early Amazonian. Their consistent orientations and age suggest that the Chryse-margin PBRs formed concurrently and represent modification of an ancient palaeosurface. In addition, we find a tendency for PBRs to preferentially occur in regions where Fe/Mg-rich phyllosilicate minerals were detected in hyperspectral remote sensing data. We conclude that regional scale aeolian processes formed the circum-Chryse PBRs, and that exposed bedrock with Fe/Mg-rich phyllosilicate detections were either more susceptible to PBR formation, or better preserve PBRs than other regional lithologies.

Geochemical characteristics and tectonic interpretation of garnet mica schists of Patharkhola area in Kumaun Lesser Himalaya, Uttarakhand Himalaya, India

The Patharkhola area is exposed in the core of the southern limb of the Dudhatoli syncline in the Kumaun Lesser Himalaya. Garnet mica schists of the Patharkhola occur in the folded outcrop pattern being located in between the limbs. They are dominantly composed of garnet, biotite, muscovite, chlorite, plagioclase and a subordinate amount of quartz. Garnet, both xenoblastic as well as idioblastic, is wrapped round by phyllosilicates minerals. These investigated rocks exhibits slightly LREE depleted patterns (LaN/SmN = 0.7, LaN/YbN = 0.64) with flat HREE patterns (SmN/YbN = 0.89). Field evidence along with geochemical characteristics suggests that the Patharkhola schists are peraluminous in nature, showing sedimentary sources having silt to silty clay protolith. They were formed in active continental margins in arc-type setting where the sediments were received both from arc and continental crust.

Decorated Vesicles as Prebiont Systems (a Hypothesis).

Decorated vesicles in deep, seafloor basalts form abiotically, but show at least four life-analogous features, which makes them a candidate for origin of life research. These features are a physical enclosure, carbon-assimilatory catalysts, semi-permeable boundaries, and a source of usable energy. The nanometer-to-micron-sized spherules on the inner walls of decorated vesicles are proposed to function as mineral proto-enzymes. Chemically, these structures resemble synthetic FeS clusters shown to convert CO2, CO and H2 into methane, formate, and acetate. Secondary phyllosilicate minerals line the vesicles' inner walls and can span openings in the vesicles and thus can act as molecular sieves between the vesicles' interior and the surrounding aquifer. Lastly, basalt glass in the vesicle walls takes up protons, which replace cations in the silicate framework. This results in an inward proton flux, reciprocal outward flux of metal cations, more alkaline pH inside the vesicle than outside, and production of more phyllosilicates. Such life-like features could have been exploited to move decorated vesicles toward protolife systems. Decorated vesicles are proposed as study models of prebiotic systems that are expected to have existed on the early Earth and Earth-like exoplanets. Their analysis can lead to better understanding of changes in planetary geocycles during the origin of life.