Electrochemical energy storage (EES) plays a crucial role in reducing the curtailed power from wind and solar PV power (WSP) generation and enhancing the decarbonization effects of power systems. However, research on quantifying the carbon emission reduction effects of EES methods in the engineering field is still insufficient, which constrains decision-makers from making intuitive assessments of the decarbonization effects of energy storage. Therefore, drawing on the principles of the clean development mechanism (CDM), this paper proposes a method for quantifying the carbon emission reductions of a standalone EES station. Firstly, based on the design principles of building marginal emission factor in the CDM, a method for calculating the BM weight of WSP is proposed. Secondly, three quantification methods for the carbon emission reductions of EES are presented based on the complexity of the calculations. Lastly, to analyze the impacts of different operational conditions and calculation methods on the carbon emission reduction of energy storage systems, a dispatch model is constructed for various operational scenarios. The results of the case study indicate that different calculation methods yield varying results in terms of the carbon emission reductions of energy storage systems, with the sharply value method yielding the smallest reduction and the output curve method yielding the largest reduction. Additionally, when considering the losses in the state of charge (SOC) of an energy storage system and reducing the overall output fluctuations of WSP-EES, the carbon emission reduction potential of the energy storage will decrease. This study establishes a theoretical basis for quantifying the carbon emission reductions of standalone electrochemical energy storage systems, aiding decision-makers in gaining a deeper understanding of the role of electrochemical energy storage in carbon reduction and operational value.