Ozone (O3) poses serious health risks, prompting numerous countries to implement regulations that establish exposure limits and emission controls, for example, the air quality index (AQI) for O3 ranging from 50 to 150 parts per billion (ppb), with natural levels at around 30 ppb. Electrochemical sensors are favored for detecting pollutant gases due to their high sensitivity, low cost, portability, energy efficiency, and capability for selective detection. In this study, we developed an O3 sensor employing carbon-supported Pt-based binary and ternary nanorods (NRs) combined with room-temperature ionic liquids (RTILs) as electrolytes, aiming at highly sensitive and selective detection of O3 at ppb levels. Initial screening of the O3 sensing performance across different electrolytes identified H2SO4 and [C4mpyrr][NTf2] (BMP) as the most sensitive options. BMP outperformed H2SO4 in terms of linearity, selectivity, reproducibility, and response/recovery times, despite a relatively lower sensitivity. Electrochemical testing of Pt, PtAu, PtAg, and PtAuAg NR electrodes in BMP revealed that the addition of Au enhanced the linear response, while Ag improved sensitivity. Consequently, the ternary PtAuAg NR electrode exhibited the highest sensitivity (10.5 nA/ppm (parts per million)) and a broad detection range, fulfilling the AQI requirements for O3. The current response from the PtAuAg NR electrode closely aligned with results from an ultraviolet (UV) photometric analyzer, confirming its accuracy. Notably, this electrode contains only 20 wt % noble metals, which reduces the overall cost to just 11% of that of a traditional pure Au electrode.
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