Fluid Phase Separation Research Articles

Response of chemically active dimer motor in phase-separating binary fluid mixture: Motility regulation and self-aggregation

Response of chemically active dimer motor in phase-separating binary fluid mixture: Motility regulation and self-aggregation

Statistical properties of microphase and bubbly phase-separated active fluids.

In phase-separated active fluids, the Ostwald process can go into reverse, leading to either microphase separation or bubbly phase separation. We show that the latter is formed of two macroscopic regions that are occupied by the homogeneous fluid and by the microphase separated one. Within the microphase-separated fluid, the relative rate of the Ostwald process, coalescence, and nucleation determines whether the size distribution of mesoscopic domains is narrowly peaked or displays a broad range of sizes before attaining a cutoff independent of system size. Our results are obtained via large-scale simulations of a minimal field theory for active phase separation and reproduced by an effective model in which the degrees of freedom are the locations and sizes of the microphase-separated domains.

A synproportionation-controlled hybrid hydrothermal mineralization system in the Okinawa Trough

Hybrid hydrothermal systems, in which both water-rock reactions and magmatic fluids contribute to sulfide mineralization, have recently been reported in some submarine arcs and mature back-arc basins. Owing to their high mineralization efficiency, hybrid hydrothermal systems have attracted significant attention from geologists. This study provides first clues for the identification of a novel hybrid hydrothermal system (synproportionation-controlled instead of the more common disproportionation-controlled) in the Tangyin field, Southern Okinawa Trough. The studied samples are native sulfur-type precipitates, primarily composed of elemental sulfur with minor sulfide disseminations. The distinct crystallization conditions and S isotope compositions of elemental sulfur and sulfide disseminations indicate their different genesis. The S in sulfide disseminations (δ34S = −2.7 to 1.6 ‰) is derived from water-rock reaction and subsequently influenced by fluid phase separation, which is further demonstrated by the trace element contents of pyrite (low Tl/Pb, Sb/Pb, Te/As, Te/Sb ratios). In contrast, the elemental sulfur (δ34S = 3.9 to 4.3 ‰) is formed by the synproportionation of magmatic SO2 and hydrothermal H2S from the boiled liquid. A simple two-component mixing calculation indicated that the contributions of the water-rock reactions and magmatic fluids to the Tangyin hydrothermal system were approximately equal. The higher temperature (> 350 °C) and oxygen fugacity conditions may be the key factors for the development of a synproportionation-controlled hybrid hydrothermal system in the Tangyin field. Hydrothermal systems in back-arc basins exhibit higher sulfide accumulation rates than those in mid-ocean ridges; this may be attributed to the prevalence of hybrid hydrothermal vents in back-arc settings.

Influence of Water Concentration on the Water/Vapor/ Oil Separation Process in a Vacuum Oil Filter: Modelling and Simulation

The vacuum oil filter (VOF) is widely applied in the oil-water emulsion demulsification separation due to the phase separation by using vacuum evaporation; however, the micro-dynamic characteristics of oil, water and vapor three phases and the influencing factors of separation efficiency are rarely studied. Therefore, the fluid flow and phase separation characteristics of water-in-oil emulsions were numerically analysed by ANSYS software. The demulsification conditions of water/oil emulsion were simulated by using the two-fluid model and the water evaporation model, and the turbulence effect was considered by using the Reynolds stress model. The results show that the established model could provide a convenient way to study the effects of the different water concentrations in oil; the turbulence intensity in VOF increases with the increase of water concentration in oil; The separation efficiency has been influenced by the inlet water concentration reaching values between 20.65-22.62% in the center axis, while 33.18-42.24% in the plate column; the vapor concentration ranged from 0 - 23.64% in the center axis, while 0 - 41.02% in the plate column. The relative volume fraction of water concentration decay tending with the water concentration increases, and the water concentration has a great influence on the separation efficiency.

Hyperuniformity in phase ordering: the roles of activity, noise, and non-constant mobility

Hyperuniformity emerges generically in the coarsening regime of phase-separating fluids. Numerical studies of active and passive systems have shown that the structure factor S(q) behaves as q ς for q → 0, with hyperuniformity exponent ς = 4. For passive systems, this result was explained in 1991 by a qualitative scaling analysis of Tomita, exploiting isotropy at scales much larger than the coarsening length. Here we reconsider and extend Tomita’s argument to address cases of active phase separation and of non-constant mobility, again finding ς = 4. We further show that dynamical noise of variance D creates a transient ς = 2 regime for q^≪q^∗∼Dt[1−(d+2)ν]/2 , crossing over to ς = 4 at larger q^ . Here, ν is the coarsening exponent for the domain size ℓ , such that ℓ(t)∼tν , and q^∝qℓ is the rescaled wavenumber. In diffusive coarsening ν=1/3 , so the rescaled crossover wavevector q^∗ vanishes at large times when d⩾2 . The slowness of this decay suggests a natural explanation for experiments that observe a long-lived ς = 2 scaling in phase-separating active fluids (where noise is typically large). Conversely, in d = 1, we demonstrate that with noise the ς = 2 regime survives as t→∞ , with q^∗∼D5/6 . (The structure factor is not then determined by the zero-temperature fixed point.) We confirm our analytical predictions by numerical simulations of continuum theories for active and passive phase separation in the deterministic case and of Model B for the stochastic case. We also compare them with related findings for a system near an absorbing-state transition rather than undergoing phase separation. A central role is played throughout by the presence or absence of a conservation law for the centre of mass position R of the order parameter field.

Two Film Approach to Continuum Scale Mixing and Dispersion with Equilibrium Bimolecular Reaction

Reliable reactive transport models require careful separation of mixing and dispersion processes. Here we treat displacing and displaced fluids as two separate fluid phases and invoke Whitman’s classical two-film theory to model mass transfer between the two phases. We use experimental data from Gramling’s bimolecular reaction experiment to assess model performance. Gramling’s original model involved just three coupled PDEs. In this context, our new formulation leads to a set of seven coupled PDEs but only requires the specification of two extra parameters, associated with the mass transfer coefficient and its dependence on time. The two film mass transfer model provides a simple and theoretically based method for separating mixing from dispersion in Eulerian continuum-scale methods. The advantage of this approach over existing methods is that it enables the simulation of equilibrium chemical reactions without having to invoke unrealistically small reaction rate coefficients. The comparison with Gramling’s experimental data confirms that our proposed method is suitable for simulating realistic and complicated bimolecular reaction behaviour. However, further work is needed to explore alternative methods for avoiding the need of a time-dependent mass transfer rate coefficient.

Colloid phase separation dynamics driven by chiral turbulent flows

Hydrodynamic interactions significantly influence phase-ordering kinetics in complex fluids. While passive fluid phase separation is well studied, the impact of active components remains relatively unexplored. We examine pure- and quasi-two-dimensional mixtures of attractive colloids and self-rotating particles in a solvent. Varying rotor rotational speed and area fraction yield diverse dynamic patterns such as percolated networks and round droplets composed of passive colloids alone. At intermediate rotation speeds, inertial chiral flows, accompanied by the inverse energy cascade, lead to self-similar power-law coarsening with a growth exponent of 1/2. The flows spontaneously organize within fluid domains, exhibiting turbulent and chiral characteristics. Surprisingly, these turbulent flows can sustain hexatic order hydrodynamically stabilized by the Magnus force under certain conditions. Conversely, at higher speeds, nonlinear hydrodynamic interactions impede phase separation. Our findings illuminate the intriguing dynamic interplay between phase separation and chiral turbulence, effectively bridging the realms of phase ordering and turbulent physics. Published by the American Physical Society 2024

Decoding degassing modes of magma chamber of arc volcanoes: Insights from CO2/Cl and Cl/H2O ratios of magmatic fluids in groundwater

The H2O-CO2-Cl composition of the fluids released from the magma chambers for arc volcanoes was calculated based on the solubilities of H2O and CO2 in the silicate melt and the partition coefficient of Cl between the aqueous fluid and melt for the stages defined by a simple evolution model of the magma chamber. The degassing modes consisted of mafic bubbling (MB: first boiling) and felsic bubbling (FB: second boiling) releasing fluids as separate bubbles due to the mafic magma supply and felsic magma formation by differentiation, respectively, and felsic solidification (FS) releasing fluid due to felsic pluton formation. The variations in the CO2/Cl and Cl/H2O ratios of the fluids were examined for each degassing mode at pressures ranging from 150 to 400 MPa and were found to have very large variations at 0.00024–845 for CO2/Cl and 0.00043–0.041 for Cl/H2O. The CO2/Cl is concluded to be a good indicator of magma chamber conditions because each mode has a specific ratio distinguished from that of the other modes; i.e., CO2/Cl > 43 for MB, 0.027–23 for FB, and < 0.62 for FS.The alteration of magmatic composition of fluid during ascent was discussed considering the phase separation of fluid, CO2 bubbling in groundwater, dissolution, and deposition of minerals; furthermore, the limitation of the method when applied to natural groundwater systems were outlined. This method was tested for a natural volcanic system, the Kuju volcano in central Kyusyu, Japan, which is an active volcano complex composed of various magma types from rhyolitic to basaltic, replacing the eruption centers from west to east. Groundwater samples from springs and boreholes were collected and analyzed for chemical and isotopic compositions to determine the magmatic H2O, dissolved inorganic carbon (DIC), and Cl concentrations. The new approach to determine the magmatic CO2 concentration in groundwater using 3He concentration proposed herein cancelled the effect of carbonate deposition/dissolution, addition of DIC from organic matter, and bubbling of CO2. The estimated magmatic CO2/Cl ratios were 0.0009–14, which overlapped consistently with the modeled variation in the CO2/Cl ratio. The spatial variation of magmatic CO2/Cl in groundwater showed that higher-CO2/Cl are found near the central part of the volcanic complex which composed of felsic to mafic volcanoes, and low-CO2/Cl are only found around old felsic volcanoes. The CO2 bubbling springs were found to be associated with younger mafic volcanoes. The condition of the magma chambers, as shown by the spatial variation in CO2/Cl, were consistent with the record of the eruptive activities of the Kuju volcano. The CO2/Cl method proposed in this study using groundwater is useful for estimating magmatic conditions in chambers.

Unravelling the effects of magmatic fractionation, fluid phase separation and dilution on the composition of magmatic-hydrothermal fluids of the Cornubian Batholith (SW England)

The compositional evolution of magmatic-hydrothermal fluids from the SnW mineralized Cornubian batholith was investigated via in situ fluid inclusion LA-ICP-MS microanalysis and reveals a large degree of variation between intrusive stages and at the sample scale, with complexities due to superposition of several mechanisms affecting fluids chemistry during the protracted evolution of the batholith. Despite large ranges of salinities (from <1 wt% to 48 wt% NaCleq.), the effects of individual processes such as magmatic differentiation, fluid saturation and boiling, fluid mixing and dilution can all be discerned on the basis of fluid inclusion trace element geochemistry combined with detailed petrography and microthermometry.In all samples, different fluid types (aqueous liquid-rich, vapor-rich and brine inclusions) were identified in variable proportions and microthermometry revealed complex temporal trends. Granite-related samples from the G5 intrusive stage are characterized by intermediate density fluids undergoing magmatic fractionation under pressure conditions above 1.5 kbar, indicated by successively decreasing fluid salinities with concomitant increases in Li, B, Rb and Cs concentrations. The latter two elements later strongly partitioned in the brine phase upon boiling, together with most of the other Cl-complexing elements (e.g., Fe, Mn, Pb, Zn). Those brines subsequently underwent progressive dilution with meteoric waters that caused a decrease in the concentration of all elements (besides B) and homogenization temperatures. In G3 granite from Dartmoor, on the other hand, brine inclusions represent the earliest fluid type while intermediate density fluids are absent, and a large salinity range in the fluid inclusion record associated with a decrease in homogenization temperatures represents their progressive dilution with meteoric fluid. The lack of intermediate density fluids at Dartmoor indicates fluid exsolution at relatively low pressures resulting in immediate phase separation into brine and vapor.All studied samples associated with ore mineralization display only the trend of dilution of high-salinity magmatic fluids. Their transition metal contents (e.g. Fe, Mn, Pb and Zn) show the expected positive correlation with salinity of the fluids. Conversely, the compositional trends observed for Sn and particularly W are more enigmatic, as they do not appear to significantly fractionate during most of the physicochemical processes outlined above and appear to be unrelated to fluid salinity, opposite of what would be expected for Sn as it is dominantly transported in Cl-complexes.This study highlights the key advantages of high-resolution geochemical fluid inclusion studies in discerning a variety of magmatic and post-magmatic processes in fluids in comparison to bulk fluid inclusion techniques or more simplistic fluid inclusions studies which might overlook important aspects of the typically complex history of fluids evolution in magmatic-hydrothermal systems.

Multistage evolution of gold mineralization in the Kibali gold district: Insights from pyrite analyses

The Kibali gold district, located on the Congo Craton, comprises a Neoarchean gold resource exceeding 28.7 Moz. The district is located within a westerly-verging stacked fold-and-thrust belt associated with a compressional tectonic regime active from ca. 2.64–2.60 Ga. Deposits are hosted by a major fault zone that consists of a complex series of smaller thrust faults, shear zones, and folds, which extend over 60 km. Gold deposits are primarily hosted in BIF and clastic sedimentary rocks. The gold and associated sulfides are in veins and disseminated in NE-to NNE-trending ore shoots within the deformed and metamorphosed volcanosedimentary rocks. Pyrite is the dominant sulfide mineral and hosts both solid solution gold and free gold. Because of its strong association with the gold mineralization, our study focusses on unravelling the metallogeny of the area by considering pyrite textural analyses, in situ trace element analyses using Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS), and S isotopic composition (δ34S) analyses using Secondary Ion Mass Spectrometry (SIMS).Eight distinct pyrite types were identified, including microcrystalline sooty (py-0a), small grains (<40 μm) (py-0b), aggregate recrystallized (py-1), core-rich inclusion (py-2), vein-like (py-3), non-zoned (py-4a), oscillatory As-bands zoned (py-4b), and cubic euhedral (py-5) pyrite. The ore-forming processes occurred over a polyphase evolution. Syn-diagenetic pyrite py-0a in volcaniclastic layers of older basin sediments served as the primary repository of Au (15.6 ppm median) with a near-zero δ34S value. Late diagenetic or early metamorphic pyrite (py-0b) was found in younger basin sediments. Py-1 resulted from solid-state recrystallization of py-0a and py-0b. During the early ore stage, porous py-2 with high Au concentrations (3.1 ppm) and various trace element enrichments precipitated due to fluid-rock interaction. Metal precipitation occurred through sulfidation and carbonation of wall rock with a relatively reduced fluid undergoing 34S-depletion. However, py-3 displayed notable trace element depletion and a complex mineral association. In a second ore stage, py-4a and zoned py-4b deposition occurred, dominated by an over-pressured fluid fracturing brittle rock. Py-4b, rich in Au (5.5 ppm) concentrated in oscillatory zoned As-rich bands, resulted from interactions during pulsed fluid flow. This process involved fluid phase separation, non-equilibrium conditions, 32S-depletion, and precipitation of py-4b with a high δ34S value (6.4 ‰ mean). Subsequently, pyrite (0–4) generations underwent deformation during a later ductile deformation event, leading to the remobilization and concentration of invisible gold into adjacent gold grains within the high-grade shoot plunging NE. This process involved shearing, boudinaging, and folding ore minerals in tightly folded structures. Late-stage py-5 formed under gold-poor fluid conditions or inefficient gold depositional conditions. Brittle fracturing of these grains later provided local sites for remobilized gold. The study contributes insights into the origin and evolution of gold mineralization in the Kibali gold district, supporting a multistage ore-forming fluid system.

A multidimensional examination of phase separation in single-component fluids

A thermodynamic instability in a homogeneous fluid can lead to spontaneous formation of distinct domains within the fluid. This process involves not only the spatial redistribution of fluid density but also transient exchanges of pressure, temperature, and energy. However, classical theoretical frameworks, such as the Ginzburg–Landau and Cahn–Hilliard models, lack incorporation of these essential thermodynamic aspects. To investigate the dynamics of multiple physical fields during phase separation, we numerically solve a two-dimensional van der Waals fluid model. Thermodynamic consistency is demonstrated by verifying the coexistence curve. While the equilibrium pressure remains similar across the unstable region of the isotherm, we demonstrate that the energy in the system depends on the initial density. Although the majority of energy is stored as heat at typical values of the heat capacity, high-density domains contain less specific energy compared to their low-density counterparts due to interparticle attraction. Consequently, the transition of low-density domains into high-density through the process of coalescence releases excess energy, which redistributes in the form of longitudinal waves and heat. We also highlight the role of parameters, such as heat capacity and thermal conductivity, in less intuitive phenomena, including elevated temperature fluctuations and memory preservation.

Mineralogical and geochemical facets of the massive deposition of stibnite-metastibnite at a seafloor hydrothermal field (Wakamiko Crater, Kagoshima Bay, Ryukyu Volcanic Arc)

Abstract Stibnite precipitates in the form of massive boulders at two active hydrothermal mounds in the submarine Wakamiko Crater (Ryukyu Volcanic Arc) as opposed to commonly observed accessory stibnite in the seafloor hydrothermal deposits. The stibnite dimorph, metastibnite, found here for the first time on the seafloor, appears to always form whenever stibnite is precipitated under submarine hydrothermal conditions. Our study shows that hydrothermal conditions of low temperatures (&amp;lt;50 °C) and low values of pH (&amp;lt;6) are favorable for the precipitation of stibnite on the seafloor. The stibnite probably does not precipitate at the measured vent fluid temperatures (i.e., 177.6 – 187.0 °C) along the chimney conduits, but rather at temperatures &amp;lt;50 °C and at slightly reduced to slightly oxic conditions (Eh = -0.5 to +0.5 V) within the chimney walls and hydrothermal mounds. Metastibnite deposition appears to be the result of rapid quenching of hot hydrothermal fluid when mixed with cold seawater and rapid precipitation at the interface between stibnite and vent fluid. The low concentrations (usually below detection limits) of the trace elements (Cd, Co, Cr, Cu, Li, Mn, Mo, Ni, P, Pb, Sr, V, Zn) in the stibnite deposits from Wakamiko Crater are likely a result of decreased metal-transporting capacity of the precipitating vent fluid due to its low chlorinity. Low-chlorinity venting implies sub-seafloor boiling and phase separation of the hydrothermal fluid. Sluggish hydrothermal fluid/seawater mixing within the walls of the chimneys and mounds favors the reduction of sulfate dissolved in the hydrothermal fluids and results in a heavy S isotope composition of the sulfate in the vent fluids. Sulfate reduction and disproportionation of magmatic SO2, both leading to heavy S isotope composition of sulfate in the vent fluids, seem to be common processes in volcanic arc/back-arc submarine hydrothermal settings.

Peraluminous Rare Metal Granites in Iberia: Geochemical, Mineralogical, Geothermobarometric, and Petrogenetic Constraints

The intensive variables, geochemical, mineralogical, and petrogenetic constraints of the Iberian peraluminous rare metal granites (RMGs), many of them unknown, are presented. The mineral chemistry of ore and gangue minerals, whole rock analyses, geothermobarometry, melt water and phosphorus contents, mass balance, and Rayleigh modeling were performed to achieve these objectives. These procedures allow us to distinguish two main contrasting granitic types: Nb-Ta-rich and Nb-Ta-poor granites. The former have lower crystallization temperatures, higher water contents, and lower emplacement pressures than Nb-Ta-poor granites. Nb-Ta-rich granites also have higher fluoride contents, strong fractionation into geochemical twins, higher Na contents, and different evolutionary trends. At the deposit scale, the fractional crystallization of micas properly explains the variation in the Ta/Nb ratio in both Nb-Ta-poor and Nb-Ta-rich RMGs, although in higher-grade granites, the variation is not as clear due to the action of fluids. Fluid phase separation processes especially occurred in the Nb-Ta rich granites, thus transporting halogens and metals that increased the grades in the top and sometimes in the core of granites. Gas-driven filter pressing processes facilitated the migration of fluid and melt near solidus melt in Nb-Ta-rich granites. The geochemical signature of the Iberian rare metal granites mainly follows the trends of two-mica granites and P-rich cordierite granites, but also of granodiorites.

Tuning properties of phase-separated magnetic fluid with temperature

Phase-separated magnetic fluids provide a very strong magnetic response (μ>25) in a liquid state material. Even small fields can cause a notable material response, but this depends on its properties, which are often difficult to control. Here, we investigate how temperature affects the properties of the system, where phase separation is induced by an increase in ionic strength. Following the deformations of individual microscopic droplets, we can extract surface tension, magnetic permeability, and viscosity. We find that the temperature increase does not affect the surface tension, while the magnetic permeability and viscosity increase. Applying this knowledge to induce a shape instability for a drop only using temperature shows the potential of applicability of our findings.

Vesicle condensation induced by synapsin: condensate size, geometry, and vesicle shape deformations

We study the formation of vesicle condensates induced by the protein synapsin, as a cell-free model system mimicking vesicle pool formation in the synapse. The system can be considered as an example of liquid–liquid phase separation (LLPS) in biomolecular fluids, where one phase is a complex fluid itself consisting of vesicles and a protein network. We address the pertinent question why the LLPS is self-limiting and stops at a certain size, i.e., why macroscopic phase separation is prevented. Using fluorescence light microscopy, we observe different morphologies of the condensates (aggregates) depending on the protein-to-lipid ratio. Cryogenic electron microscopy then allows us to resolve individual vesicle positions and shapes in a condensate and notably the size and geometry of adhesion zones between vesicles. We hypothesize that the membrane tension induced by already formed adhesion zones then in turn limits the capability of vesicles to bind additional vesicles, resulting in a finite condensate size. In a simple numerical toy model we show that this effect can be accounted for by redistribution of effective binding particles on the vesicle surface, accounting for the synapsin-induced adhesion zone.Graphic abstract

Phase separation of a magnetic fluid: Asymptotic states and nonequilibrium kinetics.

We study self-assembly in a colloidal suspension of magnetic particles by performing comprehensive molecular dynamics simulations of the Stockmayer (SM) model, which comprises spherical particles decorated by a magnetic moment. The SM potential incorporates dipole-dipole interactions along with the usual Lennard-Jones interaction and exhibits a gas-liquid phase coexistence observed experimentally in magnetic fluids. When this system is quenched from the high-temperature homogeneous phase to the coexistence region, the nonequilibrium evolution to the condensed phase proceeds with the development of spatial as well as magnetic order. We observe density-dependent coarsening mechanisms-a diffusive growth law ℓ(t)∼t^{1/3} in the nucleation regime and hydrodynamics-driven inertial growth law ℓ(t)∼t^{2/3} in the spinodal regimes. [ℓ(t) is the average size of the condensate at time t after the quench.] While the spatial growth is governed by the expected conserved order parameter dynamics, the growth of magnetic order in the spinodal regime exhibits unexpected nonconserved dynamics. The asymptotic morphologies have density-dependent shapes which typically include the isotropic sphere and spherical bubble morphologies in the nucleation region, and the anisotropic cylinder, planar slab, cylindrical bubble morphologies in the spinodal region. The structures are robust and nonvolatile, and exhibit characteristic magnetic properties. For example, the oppositely magnetized hemispheres in the spherical morphology impart the characteristics of a Janus particle to it. The observed structures have versatile applications in catalysis, drug delivery systems, memory devices, and magnetic photonic crystals, to name a few.

Textural, trace element, and sulfur isotope analyses of pyrite from the Yindongpo deposit, East Qinling Orogen: Implications for gold mineralization

The Yindongpo deposit is a large-scale gold deposit with complicate mineralization types in East Qinling Orogen, triggering the debate on its ore genesis. Here we conduct textural, in situ trace elements and sulfur isotope analyses of pyrite to elucidate the genesis of gold mineralization in the Yindongpo deposit. Three types of pyrite were identified according to their occurrences in different hydrothermal veins. Py-Ⅰ mainly formed in the host rock, parallel to the foliation of the schist, occurring as crystal nodules with blurred boundary. Py-Ⅱ principally occur in the quartz-pyrite veins crosscutting the stratum. It is characterized by the pervasive occurrence of sulfide and silicate inclusions, which suggest phase separation (fluid boiling) took place during its formation. Py-Ⅲ commonly precipitate within quartz-dolomite-pyrite veins crosscutting or overprinting former quartz-pyrite veins, commonly associated with coarse-grained sulfides and native gold/electrum. All pyrite types exhibit a superimposed history. The Co, Ni, As characteristics and δ34S data show that from Py-Ⅰ, through Py-Ⅱ, to Py-Ⅲ, the portion of magmatic-hydrothermal fluid is increasing. Gold is tightly associated with base metal sulfides (galena, sphalerite, chalcopyrite), filling the voids, cracks, or margins of Py-Ⅰ, Py-Ⅱ, and Py-Ⅲ. The trace element bounded in the lattice of base metal sulfides include: (1) Cd for sphalerite, (2) Ag, Sb for galena, (3) Ag for tetrahedrite. Combined with previous studies, we conclude that the magmatic-hydrothermal activities at Early Cretaceous formed the major gold mineralization in the Yindongpo deposit.

Simulating glacier lake outburst floods (GLOFs) with a two-phase/layer debris flow model considering fluid-solid flow transitions

AbstractGlacier lake outburst floods (GLOFs) initiate with the rapid outburst of a glacier lake, endangering downstream populations, land, and infrastructure. The flow initiates as a mud flow; however, with the entrainment of additional solid material, the flood will often transform into a debris flow. As the run-out slope flattens, the coarse solid material deposits and the flow de-waters. The flow transforms back into a muddy, hyperconcentrated flow of fine sediments in suspension. These flow transitions change the flow composition dramatically and influence both the overall mass balance and flow rheology of the event. In this paper, we apply a two-phase/layer model to simulate flow transitions, solid–fluid phase separations, entrainment, and run-out distances of glacier lake outburst floods. A key feature of the model is the calculation of dilatant actions in the solid–fluid mixture which control flow transitions and phase separations. Given their high initial amount of fluid within the flow, GLOFs are sensitive to slope changes inducing flow transitions, which also implies changes in the flow rheology. The changes in the rheology are computed as a function of the flow composition and do not need any adaptation by ad-hoc selection of friction coefficients. This procedure allows the application of constant rheological input parameters from initiation to run-out. Our goal is to increase the prediction reliability of debris flow modeling. We highlight the problems associated with initial and boundary (entrainment) conditions. We test the new model against the well-known Lake 513 (Peru, 2010), Lake Palcacocha (Peru, 1941), and Lake Uchitel in the Aksay Valley (Kyrgyzstan) GLOF events. We show that flow transition modeling is essential when studying areas that have significant variations in slope.

Genesis of the Daliuhang Gold Deposit, Jiaodong Peninsula, Eastern China: Constraints from H-O-S-Pb-He-Ar Isotopes, and Geochronology

The Daliuhang gold deposit in the Qipengfu (Qixia–Penglai–Fushan) ore concentration area is a typical gold deposit of medium-low temperature hydrothermal veins. Uncertainties regarding the primary sources of ore-forming fluids, as well as whether host rocks contribute materials to the mineralization of the gold deposits in the Jiaodong Peninsula, are still subject to intense debate. Hydrogen–oxygen isotope results show that atmospheric water is involved in ore-forming fluids. According to the results of the helium–argon isotopes of pyrite, it is hypothesized that the initial fluid source was located in the oceanic crust or upper mantle lithosphere above the Early Cretaceous Paleo-Pacific Plate, as it was subducted into the eastern part of the eastern North China Craton. In situ sulfur isotope results show that high δ34S values characterize the pyrite in the main mineralization period. It is inferred that during the thinning and melting process of the lithospheric mantle, the volatile components enriched in pyrite contributed to the release of δ34S. At the same time, when the fluids ascended to the weak zones, such as fissures of ore-endowed peripheral rocks, the δ34S in the peripheral rocks were extracted, and the two processes acted together to cause high δ34S values to occur. Similarly, the lead and strontium isotopic compositions indicate a crust–mantle mixing attribute of the mineralized material source. The zircon U–Pb age of the ore-hosting granodiorite was 130.35 ± 0.55 Ma, and the Rb–Sr isochron age of the pyrite from the main mineralization period was 117.60 ± 0.10 Ma, which represents the timing of felsic magmatism and gold mineralization, respectively, with at least 10 Ma between the magmatism and mineralization. The magma gradually cooled over time after its formation, and when the granodiorite cooled down to 300 ± 50 °C, the temperature and pressure conditions were most conducive to the precipitation of gold. It is inferred that gold-rich initial mantle fluids with volatile components, rising along tectonically weak zones, such as fractures, underwent fluid phase separation in the fractured position of the granite and extracted the gold from the granodiorite, forming gold deposits.

Effects of hydrogeochemistry on the microbial ecology of terrestrial hot springs.

Temperature, pH, and hydrochemistry of terrestrial hot springs play a critical role in shaping thermal microbial communities. However, the interactions of biotic and abiotic factors at this terrestrial-aquatic interface are still not well understood on a global scale, and the question of how underground events influence microbial communities remains open. To answer this, 11 new samples obtained from the El Tatio geothermal field were analyzed by 16S rRNA amplicon sequencing (V4 region), along with 191 samples from previous publications obtained from the Taupo Volcanic Zone, the Yellowstone Plateau Volcanic Field, and the Eastern Tibetan Plateau, with their temperature, pH, and major ion concentration. Microbial alpha diversity was lower in acid-sulfate waters, and no significant correlations were found with temperature. However, moderate correlations were observed between chemical parameters such as pH (mostly constrained to temperatures below 70°C), SO4 2- and abundances of members of the phyla Armatimonadota, Deinococcota, Chloroflexota, Campilobacterota, and Thermoplasmatota. pH and SO4 2- gradients were explained by phase separation of sulfur-rich hydrothermal fluids and oxidation of reduced sulfur in the steam phase, which were identified as key processes shaping these communities. Ordination and permutational analysis of variance showed that temperature, pH, and major element hydrochemistry explain only 24% of the microbial community structure. Therefore, most of the variance remained unexplained, suggesting that other environmental or biotic factors are also involved and highlighting the environmental complexity of the ecosystem and its great potential to test niche theory ecological associated questions. IMPORTANCE This is the first approach to investigate whether geothermal processes could have an influence on the ecology of thermal microbial communities on a global scale. In addition to temperature and pH, microbial communities are structured by sulfate concentrations, which depends on the tectono-magmatic settings (such as the depth of magmatic chambers) and the local settings (such as the availability of a confining layer separating NaCl waters from steam after phase separation) and the possibility of mixing with more diluted fluids. Comparison of microbial communities from different geothermal areas by homogeneous sequence processing showed that no significant geographic distance decay was detected on the microbial communities according to Bray-Curtis, Jaccard, unweighted, and weighted Unifrac similarity/dissimilarity indices. Instead, an ancient potential divergence in the same taxonomic groups is suggested between globally distant thermal zones.