Phase Manipulation Research Articles

Controlling Metal-Support Interactions to Engineer Highly Active and Stable Catalysts for COx Hydrogenation.

This perspective focuses on the modulation of metal-support interaction (MSI) in catalysts for COx hydrogenation, highlighting their profound impact on catalytic performance. Firstly, it outlines different strategies, including the use of highly reducible oxides and moderate reduction treatments, which induce the classical strong metal-support interaction (SMSI) effect and the electronic metal-support interaction (EMSI) effect. Morphology engineering and crystalline phase manipulation of oxides presented as effective methods to control EMSI are also discussed. The discrimination of SMSI and EMSI can be achieved using oxides with low encapsulation tendencies, such as ZrO2, which supports electronic modifications without or minimizing the overgrowth issues, optimizing the catalytic performance for methanation. Then, the synergy between Cu and ZnO in methanol synthesis, enhanced by SMSI, is emphasized inside. Optimizing support oxides to control oxygen vacancies enhances the catalytic performance of CO2 hydrogenation to methanol. Perspectives for the future research on the fundamental understanding of structure-MSI-performance relationship for catalyst design is discussed.

Exact Equations for the Back and Effective Focal Lengths of a Plano-Concave Thick Lens

In this work, we present the exact equations for the back and effective focal lengths of a plano-concave thick lens. These equations are derived through a detailed ray-tracing approach, calculating the meridional ray’s path parallel to the optical axis while taking into account lens thickness, refractive index, and surface curvature. Our analysis bridges the gap between paraxial approximations and exact ray behavior, highlighting how traditional models (e.g., thin-lens equations) can be extended to thick lenses. Additionally, we review recent advancements in negative refraction and surface phase manipulation techniques to demonstrate how our equations compare to modern numerical methods and metacoating-enhanced designs. This work provides a comprehensive and exact framework for understanding the optical properties of plano-concave thick lenses, offering new insights into their application in precision optics.

P‐Hologen: An End‐to‐End Generative Framework for Phase‐Only Holograms

AbstractHolography stands at the forefront of visual technology, offering immersive, three‐dimensional visualizations through the manipulation of light wave amplitude and phase. Although generative models have been extensively explored in the image domain, their application to holograms remains relatively underexplored due to the inherent complexity of phase learning. Exploiting generative models for holograms offers exciting opportunities for advancing innovation and creativity, such as semantic‐aware hologram generation and editing. Currently, the most viable approach for utilizing generative models in the hologram domain involves integrating an image‐based generative model with an image‐to‐hologram conversion model, which comes at the cost of increased computational complexity and inefficiency. To tackle this problem, we introduce P‐Hologen, the first end‐to‐end generative framework designed for phase‐only holograms (POHs). P‐Hologen employs vector quantized variational autoencoders to capture the complex distributions of POHs. It also integrates the angular spectrum method into the training process, constructing latent spaces for complex phase data using strategies from the image processing domain. Extensive experiments demonstrate that P‐Hologen achieves superior quality and computational efficiency compared to the existing methods. Furthermore, our model generates high‐quality unseen, diverse holographic content from its learned latent space without requiring pre‐existing images. Our work paves the way for new applications and methodologies in holographic content creation, opening a new era in the exploration of generative holographic content. The code for our paper is publicly available on https://github.com/james0223/P-Hologen.

Integrated photonic modular arithmetic processor

Integrated photonic computing has emerged as a promising approach to overcome the limitations of electronic processors in the post-Moore era. However, present integrated photonic computing systems face challenges in achieving high-precision calculations, consequently limiting their potential applications, and their heavy reliance on analog-to-digital (AD) and digital-to-analog (DA) conversion interfaces undermines their performance. Here we propose an innovative photonic computing architecture featuring scalable calculation precision and, to our knowledge, a novel photonic conversion interface. By leveraging the residue number system (RNS) theory, the high-precision calculation is decomposed into multiple low-precision modular arithmetic operations executed through optical phase manipulation. Those operations directly interact with the digital system via our proposed optical digital-to-phase converter (ODPC) and phase-to-digital converter (OPDC). Through experimental demonstrations, we showcase a calculation precision of 9 bits and verify the feasibility of the ODPC/OPDC photonic interface. This approach paves the path towards liberating photonic computing from the constraints imposed by limited precision and AD/DA converters.

Optimizing the surface quality of electrochemical machined Ni-based single crystal superalloy via manipulation of phase and dendrite dissolution

The transpassive dissolution behaviors of Ni-based single crystal superalloy in 10 %NaCl, 10 %NaNO3, and mixed solution are investigated by using potentiodynamic polarization, scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. The alloy exhibits opposite yet complementary dissolution characteristics in NaCl and NaNO3 solutions. The different responses of γ/γ′ phases to Cl− and NO3− contribute to the opposite dissolution behaviors of dendrites and interdendritic regions. The surface flatness is noticeably enhanced in mixed solution due to the synchronous dissolution of the γ/γ′ phases. Our work paves the way for obtaining high-quality surface in electrochemical machining of single crystal superalloys.

Broadband 3-bit coding metasurface antenna with integrated radiation and scattering performance

This paper presents the design of an integrated metasurface antenna, which combines a central radiating patch with a quadru-arc (QAS) structure. The metasurface antenna simultaneously achieves high-gain radiation and complex scattering functionality. The modulation of the radiation function is primarily achieved through phase manipulation of the power division feed network, while modulation of the X-polarization scattering function is mainly accomplished by adjusting the arc of the QAS. The effectiveness of this design is verified by designing two metasurface antennas with distinct functionalities. The feed network phases are arranged in a checkerboard pattern in the first approach, resulting in four-beam radiation with a gain of 16 dBi per beam. Additionally, the scattering component utilizes eight scattering structures with a phase difference of 45 degrees to form a 3-bit coding, enabling vortex beam scattering. The second configuration arranges the feed network in phase with the deflected beam, resulting in a deflected beam radiation pattern characterized by a gain of 22.3 dBi. The scattering function is optimized using a simulated annealing-genetic algorithm for phase alignment, resulting in the achievement of RCS reduction across a wide bandwidth range of 8-24 GHz. The proposed metasurface antenna is ultimately fabricated and subjected to rigorous measurements.

Mozart: A Mobile ToF System for Sensing in the Dark Through Phase Manipulation

Sensing in low-light and dark environments has a wide range of applications. However, existing sensing technologies suffer several major challenges, such as excessive noise and low resolution. In this work, we propose Mozart - a new mobile sensing system that leverages off-the-shelf Time-of-Flight (ToF) depth cameras to generate high-resolution and rich-in-texture maps for applications in dark scenarios. The design of Mozart is based on our key observation that the phase components of ToF measurements can be manipulated to expose texture information. Through in-depth analysis of the physical reflection model, we show that the textures can be exposed and enhanced using highly compute-efficient phase manipulation functions. Moreover, by exploiting the physics texture models, we propose an autoencoderbased unsupervised learning approach that can automatically learn efficient representations from phase components to generate high-resolution maps. We implemented Mozart on several Android smartphone models and an edge testbed with standalone ToF camera platforms for various applications in the dark. The results show that Mozart can work in real time and delivers significant improvement over existing sensing technologies. The demo video at https:// www.youtube.com/watch?v=L_sxyTZxIdU shows that Mozart offers a low-cost, highperformance sensing technology for nextgeneration applications in the dark.

Terahertz beam shaping using space-time phase-only coded metasurfaces

Digital metasurfaces as space-coded surfaces composed of a set of sub-wavelength meta-atoms enable extraordinary capabilities to manipulate electromagnetic waves. Recently, amplitude-phase-joint-coding metasurfaces have been proposed to achieve enhanced beam shaping. However, design of a unit cell structure with a full manipulation of amplitude and phase of the reflected beam is challenging and this kind of unit cell structures are complicated. This paper proposes a space-time phase-only metasurface based on simple graphene-based unit cell that is digitally coded and arranged with a specific time sequence, allowing the effective simultaneous manipulation of both phase and amplitude. In this way, it is demonstrated that the terahertz beam can be shaped using the proposed metasurface.

Room-temperature non-volatile optical manipulation of polar order in a charge density wave

Utilizing ultrafast light-matter interaction to manipulate electronic states of quantum materials is an emerging area of research in condensed matter physics. It has significant implications for the development of future ultrafast electronic devices. However, the ability to induce long-lasting metastable electronic states in a fully reversible manner is a long-standing challenge. Here, by using ultrafast laser excitations, we demonstrate the capability to manipulate the electronic polar states in the charge-density-wave material EuTe4 in a non-volatile manner. The process is completely reversible and is achieved at room temperature with an all-optical approach. Each induced non-volatile state brings about modifications to the electrical resistance and second harmonic generation intensity. The results point to layer-specific phase inversion dynamics by which photoexcitation mediates the stacking polar order of the system. Our findings extend the scope of non-volatile all-optical control of electronic states to ambient conditions, and highlight a distinct role of layer-dependent phase manipulation in quasi-two-dimensional systems with inherent sublayer stacking orders.

Phase Distribution Dictates Charge Transfer and Transport Dynamics in Layered Quasi-2D Perovskite.

Strategic manipulation of spatiotemporal evolution of charge carriers is critical for optimizing performance of quasi-two-dimensional (2D) perovskite-based optoelectronic devices. Nonetheless, the inhomogeneous phase distribution and band alignment engender intricate energy landscapes, complicating internal charge and energy funneling processes. Herein, we integrate high spatiotemporal resolution transient absorption microscopy with multiple time-resolved spectroscopy and find that asynchronous electron and hole transfers rather than direct energy transfer govern the funneling mechanisms. Notably, the charge funneling pathways and transport behaviors can be modifiable by phase manipulation. The accumulation of small-n phases suppresses the electron funneling toward large-n phases and doubles the carrier diffusion rate from 0.085 to 0.20 cm2/s, yielding a 1.5-fold enhancement in diffusion length. Phase order engineering is further corroborated for facilitating charge separation. Our investigation underscores the prospects of manipulating the phase distribution to control internal charge funneling and transport, thereby substantiating the theoretical foundations for optimizing optoelectronic devices.

Directional Phase and Polarization Manipulation Using Janus Metasurfaces.

Janus metasurfaces, exemplifying two-faced 2D metamaterials, have shown unprecedented capabilities in asymmetrically manipulating the wavefront of electromagnetic waves in both forward and backward propagating directions, enabling novel applications in asymmetric information processing, security, and signal multiplexing. However, current Janus metasurfaces only allow for directional phase manipulation, hindering their broader application potential. Here, the study proposes a versatile Janus metasurface platform that can directionally control the phase and polarization of terahertz waves by integrating functionalities of half-wave plates, quarter-wave plates, and metallic gratings within a cascaded metasurface structure. As a proof-of-principle, the study experimentally demonstrates Janus metasurfaces capable of independent and simultaneous control over phase and polarization, showcasing propagation direction-encoded focusing and polarization conversion. Moreover, the directionally focused points are utilized with distinct polarization states for advanced applications in direction- and polarization-sensitive detection and imaging. This unique strategy for simultaneous phase and polarization control with direction-dependent versatility opens new avenues for designing ultra-compact devices with significant implications in imaging, encryption, and data storage.

Effects of nonlinearity on the crest shape of extreme irregular sea waves: Nonlinear harmonic separation and analysis

This work highlights the effects of nonlinearity on the crest shape of extreme directional water wave events in infinite and finite water depths. HOS-ocean, a High-Order Spectral code developed for solving the deterministic propagation of nonlinear wavefields in open ocean [Ducrozet et al., “HOS-ocean: Open-source solver for nonlinear waves in open ocean based on High-Order Spectral method,” Comput. Phys. Commun. 203, 245–254 (2016)], is used for comparisons with linear simulations. Nonlinear wave harmonics were extracted combining and extending previous methods [Fitzgerald et al., “Phase manipulation and the harmonic components of ringing forces on a surface-piercing column,” Proc. R. Soc. A 470, 20130847 (2014) and Hann et al., “A new set of focused wave linear combinations to extract non-linear wave harmonics,” in Proceedings of 29th International Workshop on Water Waves and Floating Bodies, 2014], showing the contribution of various orders of nonlinearity. The work shows that “walls of water,” [Adcock et al., “Nonlinear dynamics of wave-groups in random seas: Unexpected walls of water in the open ocean,” Proc. R. Soc. A 471, 20150660 (2015) and Adcock et al., “On the shape of large wave-groups on deep water—The influence of bandwidth and spreading,” Phys. Fluids 28, 106601 (2016)], a significant increase in the crest width, are also formulated in finite water depths. Mainly responsible for this is the first order harmonic, with significant energy transfers away from components propagating at an angle, which are more pronounced in finite water depths. As nonlinearity increases, higher order harmonics (>second) become, as expected, more significant. In deep water, rapid energy transfers lead to a broadening of the spectrum which is reflected in the increase in the first order amplitude sum and hence increased crest elevations at the point of the large event. However, in finite water depths, energy transfers are gradually leading to a narrowing of the spectrum around the spectral peak and to a general broadening of the spectrum at the higher harmonics; reflected in the significant decrease in the first order amplitude sum and hence a decrease in crest elevations at the point of the large event, also aided by the larger increase in the out-of-phase difference terms (zeroth harmonic).

Spatiotemporal hologram

Spatiotemporal structured light has opened up new avenues for optics and photonics. Current spatiotemporal manipulation of light mostly relies on phase-only devices such as liquid crystal spatial light modulators to generate spatiotemporal optical fields with unique photonic properties. However, simultaneous manipulation of both amplitude and phase of the complex field for the spatiotemporal light is still lacking, limiting the diversity and richness of achievable photonic properties. In this work, a simple and versatile spatiotemporal holographic method that can arbitrarily sculpt the spatiotemporal light is presented. The capabilities of this simple yet powerful method are demonstrated through the generation of fundamental and higher-order spatiotemporal Bessel wavepackets, spatiotemporal crystal-like and quasi-crystal-like structures, and spatiotemporal flat-top wavepackets. Fully customizable spatiotemporal wavepackets will find broader application in investigating the dynamics of spatiotemporal fields and interactions between ultrafast spatiotemporal pulses and matters, unveiling previously hidden light-matter interactions and unlocking breakthroughs in photonics and beyond.

Discrimination of double-click synthetic echoes by bottlenose dolphins: Effects of inter-highlight interval and phasea).

Two bottlenose dolphins (Tursiops truncatus) were trained to discriminate double-click synthetic "echoes" differing in inter-highlight interval (IHI). In the first experimental task, dolphins passively listened to background (S-) stimuli with constant IHI and responded on discriminating a change to target (S+) stimuli with a slightly increased IHI. The second task was similar, but the highlights were assigned random, frequency-independent phase angles. This phase randomization was designed to interfere with potential auditory cues from characteristic spectral interference patterns linked to IHI changes. Discrimination thresholds were higher with randomized phase when the S- stimuli had IHIs of 50-250 μs. Thresholds were highest and comparable at the longest S- IHIs of 375 and 500 μs and were independent of phase condition. Although dolphin detection of changes in highlight envelope timing can explain threshold patterns at 375 and 500 μs, this cue did not explain performance at IHIs less than the dolphin auditory temporal window of ∼250 μs. Modeling results suggested that phase manipulations eliminated the availability of a simple difference in spectral magnitudes at the shortest IHIs, but the perception of a time separation pitch cue may still explain the dolphins' observed threshold patterns.

Directionally Asymmetric in Orbital Angular Momentum Generation Using Single‐Layer Dielectric Janus Metasurfaces

AbstractJanus metasurfaces, offering versatile light manipulation contingent on incident direction, are explored across microwave to mid‐infrared spectra. Nonetheless, prior designs often resort to spatial multiplexing or vertical stacking, entailing complex fabrication. Metallic Janus metasurfaces, owing to material properties, suffer notable Ohmic losses in the visible spectrum. In this study, Single‐layer TiO2‐based Janus metasurfaces with arbitrary polarization control is experimentally demonstrated, exhibiting directionally asymmetric functionalities in spin and orbital angular momentum (OAM). A novel Jones matrix formulation tailored for Janus metasurfaces is presented, enabling efficient generation of two asymmetric, high‐purity OAM states of vortex beams at wavelength of 532 nm, contingent on incidence direction. This innovation facilitates compact and versatile phase manipulation, encompassing applications such as lasers and optical combiners, thereby expanding its utility across diverse domains.

Full-space metasurfaces for independent manipulation of transmission and reflection.

In recent years, beam manipulation using metasurfaces has evolved from being limited to either a transmission or reflection space to encompassing a full space. However, existing methods still inevitably require complex systems and are unable to achieve continuous and arbitrary phase manipulation. Here, one type of a bilayer metasurface is proposed to simultaneously manipulate reflection and transmission phases continuously and independently, which also makes the optical system more compact without requiring any analyzers and enhances the degree of freedom for full-space beam manipulation. As a proof-of-concept demonstration, one device is designed to show different holograms in transmission and reflection spaces. Additionally, the Dammann grating designed in the reflection hologram increases the information capacity. The proposed method may pave the way toward achieving a variety of applications such as multi-channel beam manipulation and multifunctional optical devices.

Moth-wing-inspired metasurface for modulating sound amplitude and phase

Moth wings are multifunctional bio-composite structures serve varied purposes, including sound absorption and flight. Inspired by this, we propose a metasurface for reflective acoustic wave modulation. The metasurface features periodically arranged resonant elements, consisting of perforated plates and resonant cavities, mimicking moth wing scales. The hinged connection between the resonant elements and the background structure allows for precise and wide-range tuning of sound amplitude and phase, and enables deployment on irregular surfaces. We present three detailed metasurface designs, showcasing various structural parameters to demonstrate their quantitative manipulation of sound amplitude and phase, both individually and simultaneously. In addition to conventional energy absorption and path manipulation functions, the metasurface also highlights several striking features, including wavefront tailoring and reflection shunting, as demonstrated through numerical simulations. This study offers novel insights into the precise control of wave amplitude and phase over diverse scales and terrains, whilst also presenting a practical implementation in the field of acoustics.

Optical mode enabled manipulation of topological phase in waveguide-based scattering networks

Optical mode enabled manipulation of topological phase in waveguide-based scattering networks

Nonlocal meta-lens with Huygens’ bound states in the continuum

Meta-lenses composed of artificial meta-atoms have stimulated substantial interest due to their compact and flexible wavefront shaping capabilities, outperforming bulk optical devices. The operating bandwidth is a critical factor determining the meta-lens’ performance across various wavelengths. Meta-lenses that operate in a narrowband manner relying on nonlocal effects can effectively reduce disturbance and crosstalk from non-resonant wavelengths, making them well-suitable for specialized applications such as nonlinear generation and augmented reality/virtual reality display. However, nonlocal meta-lenses require striking a balance between local phase manipulation and nonlocal resonance excitation, which involves trade-offs among factors like quality-factor, efficiency, manipulation dimensions, and footprint. In this work, we experimentally demonstrate the nonlocal meta-lens featuring Huygens’ bound states in the continuum (BICs) and its near-infrared imaging application. All-dielectric integrated-resonant unit is particularly optimized to efficiently induce both the quasi-BIC and generalized Kerker effect, while ensuring the rotation-angle robustness for generating geometric phase. The experimental results show that the single-layer nonlocal Huygens’ meta-lens possesses a high quality-factor of 104 and achieves a transmission polarization conversion efficiency of 55%, exceeding the theoretical limit of 25%. The wavelength-selective two-dimensional focusing and imaging are demonstrated as well. This work will pave the way for efficient nonlocal wavefront shaping and meta-devices.

Harmonic Engineering in Sub-Wavelength Cavities & Design of Ultrabroadband Microwave Absorbers by Reflection Phase Manipulation

Harmonic Engineering in Sub-Wavelength Cavities & Design of Ultrabroadband Microwave Absorbers by Reflection Phase Manipulation