Selection Of Phase Change Materials Research Articles

Numerical Investigation of Solar Collector Performance with Encapsulated PCM: A Transient, 3D Approach

This study presents a comprehensive numerical investigation into the thermal performance of solar collectors integrated with encapsulated phase change materials (PCMs) using a transient three-dimensional (3D) approach. The performance of two distinct PCMs—paraffin wax and RT60—was evaluated under varying operational conditions, including seasonal variations, inlet pipe velocities, and inlet temperatures. The results indicate that paraffin wax exhibits a higher peak temperature, reaching approximately 360 K, compared to RT60’s peak of 345 K, making paraffin wax more effective for consistent thermal energy storage. Paraffin wax also maintained higher fluid fractions, with a maximum of 0.9 in summer, indicating superior heat absorption and retention capabilities. In contrast, RT60 demonstrated a quicker phase transition, fully liquefying at a lower fluid fraction, which is advantageous for rapid heat release. Seasonal variations significantly impacted system efficiency, with the highest efficiency observed in June at 365 K and the lowest in December at 340 K. The study also found that lower inlet velocities (e.g., 0.25 L/s) significantly improved heat retention, resulting in higher outlet temperatures, while increasing the inlet temperature from 290 K to 310 K led to a marked increase in outlet temperatures throughout the day. These findings underscore the importance of optimizing PCM selection, inlet velocity, and temperature in enhancing the performance of solar thermal systems, offering quantitative insights that contribute to the development of more efficient and reliable renewable energy solutions.

The innovative application of phase change materials in heat storage products: warmer pads

As the issue of energy shortage becomes increasingly severe, energy storage technology has gradually attracted global attention, with the application of phase change materials (PCMs) being particularly widespread. This paper focuses on a common daily product: the warmer pad, and investigates the selection and ratio of suitable PCMs to achieve a recyclable heat storage solution. The study first outlines the research background, significance, and methods, then summarizes the basic principles of phase change and the role of differential scanning calorimetry (DSC) in the study of phase change heat storage. Finally, the properties of PCMs with different proportions were tested, and the DSC curves were analyzed. The results showed that the phase change material mixture with a ratio of paraffin: OBC: expanded graphite = 77:20:3 exhibits excellent performance in heat storage, with a thermal conductivity of 0.547 W/mK, a phase change latent heat of 150 J/g, and a phase change temperature of 41.9C. The warmer pad achieved a surface temperature close to 40C and a heat release duration of nearly one hour. This study aims to promote the industry's transformation towards sustainable development and provide a reference for research in the field of daily-use products with phase change heat storage.

Electrochemistry of Phase-Change Materials in Thermal Energy Storage Systems: A Critical Review of Green Transitions in Built Environments

This article reviews recent research on phase-change materials (PCMs) used in thermal energy storage systems with the aim of enhancing their performance. The study explores various methods to improve heat transfer in PCMs, such as microencapsulation, infill materials, fins and nanofluids. Additionally, it evaluates techniques to boost heat transfer in latent heat thermal energy storage (LHTES) systems and investigates ways to increase thermal conductivity using porous and low-density materials. PCMs store thermal energy, making them suitable for use in solar energy systems when solar energy is not available. The need for eco-friendly alternatives to conventional heating and cooling in global construction and the significant energy consumption of buildings has driven research on this topic. As such, this study additionally examines current advancements in free cooling systems with latent heat storage to identify the key factors affecting their effectiveness. The findings show that using PCMs for overnight cooling maintains the room temperature within the comfort zone and reduces the cooling loads in various climates. Using machine learning methods, this study also compares recent advancements in the use of PCMs in various solar energy systems, including solar thermal power plants, solar air purifiers, solar water heaters and solar appliances. Results derived feature key factors crucial for the optimal selection of PCMs and the challenges associated with sustainable green transitions in built environments. HIGHLIGHTS This review provides an in-depth examination of PCM thermal energy storage systems. This study investigates the use of fillers, nanofluids, and nanoparticles for enhanced heat transfer. Analytical methods for boosting the PCM thermal conductivity are briefly outlined. Geometric design and thermal conductivity enhancement affect the Latent Heat Thermal Energy Storage (LHTES). The assessment also evaluates advanced free-cooling systems using the LHTES. PCMs help to store heat energy in solar systems and bridge supply gaps. GRAPHICAL ABSTRACT

Enhancing Thermal Performance and Cooling Solutions of Phase Change Material in Battery Thermal Management System: A Computational Analysis

ABSTRACTBatteries, particularly lithium‐ion batteries, are sensitive to temperature changes. Battery thermal management systems (BTMS) are essential in various battery‐powered applications, especially electric vehicles (EVs) and portable electronic devices. This study examines the importance of phase change material (PCM) in battery packs using numerical analysis. An examination is conducted on a battery pack consisting of 18 650 battery cells arranged in a 5 × 5 configuration. A comparative analysis is performed to evaluate the thermal efficiency of the battery pack with and without PCM. The study examines the influence of ambient conditions and charging rates on the selection of PCM for battery packs. A hybrid cooling solution utilizing PCM and a water tube has also been investigated against conventional passive PCM‐based BTMS. Additionally, two types of fins, namely circular and spiral fins, are introduced to improve the heat transfer rate. PCM‐based cooling systems are most effective when the ambient temperature is below the melting temperature of the PCM. However, when the ambient temperature exceeds the melting temperature of the PCM, this cooling system outperforms conventional PCM‐based cooling. The maximum temperature is found as 319, 316.9, and 315.3 K using without fin, circular fin and spriral fina, respectively. The spiral fins are found more effective than circular fins under high ambient temperature. In conclusion, The PCM‐with spiral‐fin system demonstrates notable benefits in high‐temperature environments.

A study on a battery pack in a hybrid battery thermal management system integrating with thermoelectric cooling

An inherent limitation of lithium-ion batteries is their restricted use within a specific thermal working range. To address this problem, efficient battery thermal management systems (BTMS) are required to dissipate the heat created by the cells in the battery pack. In order to control the maximum temperature and minimise the temperature difference through the battery pack during a 5C discharging process, this study investigates a phase change material (PCM)-porous battery thermal management system, cooled by thermoelectric coolers (TEC) on its walls. To calculate the heat generation of Li-ion batteries, the equivalent circuit model (ECM) is employed. In this model, a battery is made up of a set of electric elements, including R–C pairs. Different PCM and porous materials are studied to determine the most suitable material for controlling the thermal behaviour of the battery pack. The study reveals that the solidus temperature and latent heat of PCM are the two most crucial factors in PCM selection. A thermoelectric cooler is an instrument that uses electrical energy to transfer heat from one side of the device to the other, depending on the current direction. The study examines the use of a TEC (thermoelectric cooler) under various ambient temperatures and applied voltage differences. The results demonstrate that adjusting the voltage difference between the two TEC heads from 900 to 1500 mV, while the ambient temperature ranges from 303 K to 323 K, allows for achieving a cold plate temperature between 288 K and 308 K. The designed BTMS is tested in various TEC positions, and it is shown that when TECs are used on side walls, the maximum temperature of the battery back can decrease up to 1 K, and better temperature uniformity is observed.

Cold energy storage enhancement and phase transition temperature regulation

The objective of this study is to prepare a highly adjustable ester phase change material (PCM) and further optimize its cold storage properties using a simple and controllable physical method. Initially, lauric acid (LA) and polyethylene glycol 200 (PEG 200) are selected as raw materials, and a non-toxic and environmentally friendly polyethylene glycol laurate (PLE) with a tiny supercooling is prepared under the condition of acid-alcohol molar ratio of 1:3. To further regulate the cold storage property of PLE, a series of PCMs with different melting temperatures are successfully prepared using PLE blended with ethanol (EA). Among them, the lowest melting temperature in the study reaches −15.2 °C, which is about 94.6 % lower compared to −7.81 °C for PLE, and the highest latent heat of melting is 81.56 J/g. It is also observed that the supercooling of a range of samples is also optimized compared to the PLE, with a maximum reduction of 27.1 %. Additionally, the prepared samples not only exhibit excellent stability but also demonstrate outstanding application potential in temperature control and preservation experiments. This innovative achievement provides a richer selection of PCMs for the cold storage field. More crucially, this is the first report utilizing EA to regulate the temperature range of ester-based PCMs. This method is simple, easy to operate, and highly reproducible. It paves the way for the refinement, diversification, and customization of refrigeration technology.

Phase change material selection for energy storage units using a simple and effective decision-making method

Phase change material selection for energy storage units using a simple and effective decision-making method

Design and Implement a BTMS using Phase Change Material - A Review

Abstract: This paper presents a comprehensive review of the design and implementation of Battery Thermal Management Systems (BTMS) utilizing Phase Change Materials (PCM). The thermal management of batteries is crucial for ensuring optimal performance, safety, and longevity, particularly in electric vehicles and renewable energy storage applications. Phase change materials offer unique advantages for thermal management, including high latent heat storage capacity, thermal conductivity, and temperature regulation capabilities. This review discusses the fundamentals of PCM-based BTMS design, including PCM selection, integration methods, and system optimization techniques. Additionally, recent advancements, challenges, and future directions in PCM-based BTMS are explored, providing valuable insights for researchers, engineers, and industry practitioners in the field of energy storage systems.

Thermal energy storage performance of biaxial voided RCC roof slab integrated with macroencapsulated PCM for passive cooling of buildings

Building space heating and cooling power consumption is growing due to population and economic growth. Integrating phase change materials (PCMs) into various building envelope components is being explored to enhance thermal energy storage capacities. Specifically, roofs exposed to direct sunlight significantly promote thermal energy transfer to the interior, increasing the space heating and cooling requirements. In this study, thermal energy storage performance of a biaxial voided roof slab integrated with PCM is experimentally investigated under ambient conditions and compared with a normal reinforced concrete (RCC) without PCM. PCM selection, characterization, and metal void former development are performed, followed by macroencapsulation and integration into the roof slab. Thermal performance measures are evaluated, including temperature profile, heat flux, thermal load, time lag, and decrement factor. Financial viability indicators such as electricity cost savings, payback period, and CO2 emissions savings are also assessed. The results show PCM integrated biaxial voided roof slab reduces interior temperature by upto 7.2 °C during sunny hours, heat transfer to the interior by upto 60.6 %, and thermal load by upto 54 %. In addition, considering heating and cooling, it offers an average daily saving of 0.06 USD/kWh/m2 and a payback period of about 5.7 years. Further, it gives CO2 emissions savings of upto 13.7, 12.3, and 4.3 kgCO2/kWh for lignite-, coal-, and natural gas-fired power plants. Furthermore, its mean time lag is 4.2 h, with a decrement factor of 0.75 compared to 3.9 h and 0.85 for the normal RCC unit. The study makes significant contribution to knowledge by providing a unique, simple yet highly effective PCM macroencapsulation integration technique for roof slabs and insights into its thermal performance under the hot weather conditions.

Investigation on the effect of physical parameters of PCMs on the exothermic properties of energy storage units of bilayer tubes

Based on the structure of bilayer tube energy storage unit (ESU), the study investigates the effects of physical parameters and arrangement combinations of phase change materials (PCMs) on the heat storage and exothermic performance of the ESU. The control variable method is used to focus on a single physical parameter of the phase change material to analyze its influence on the heat storage and exothermic performance. Use of experimental and numerical modelling, we firstly analyze the influence of the thermal conductivity of PCMs on the thermal storage and discharge performance, and then study the influence of the latent heat value of PCMs on the thermal storage and discharge performance, and compare and analyze its thermal performance parameters with those of traditional ESUs. Studies have shown that the thermal conductivity of the bilayer ESU can be minimized by up to 26.9% and the heat release time can be increased by up to 23.8% compared with the conventional ESU. The latent heat value of the bilayer ESU can be minimized by up to 28.1% and the heat release time can be increased by up to 35.3% as opposed to the conventional ESU. Obviously, the selection of PCMs must be considered for each parameter, and the selection of PCMs with appropriate parameters plays a crucial role for different energy storage conditions.

Optimization of temperature distribution in building envelopes of Ahmedabad region using nano-encapsulated phase change material

The incorporation of Phase Change Materials (PCM) into the building envelopes helps to increase indoor thermal comfort while lowering energy usage. The selection of PCM is directly related to its performance and might be viewed as an optimization challenge. The manuscript highlights the optimization of temperature distribution in building envelopes (walls and roofs) of Ahmedabad by choosing the suitable PCM and Nano-particle. Three different PCMs (RT31, RT 35, and RT42) and Nano-particles (Al2O3, CuO, and ZnO) with different concentrations (12 %, 16 %, and 20 %) are considered for the optimization. The PCMs are encapsulated into the building layer thickness to examine their characteristics like effective thermal conductivity, concentration, melting point, etc. These parameters are evaluated in a room that measures 5 m x 4 m x 3.5 m (L x W x H). The design-builder software (Version 7.0.2.006) is used to carry out the steady-state numerical simulations for this building envelope. The results suggest that the integration of PCM reduces the building's overall energy consumption by 7.92 kWh/m2 per year. The optimal design is proposed by establishing a temperature difference (ΔT) in building envelopes and utilizing a hybrid optimization technique (a combination of Artificial neural network (ANN) and Genetic algorithm (GA)). This temperature difference of the building envelope is confirmed to be dependent on their PCM melting point, effective thermal conductivity, concentration (in%), and PCM layer thickness. Hybrid optimization is found to be the most stable strategy for predicting temperature dilation and energy storage in building envelopes. Thus this paper gives a systematic understanding of the selection of PCM and Nano-particles and identifies the suitable PCM layer thickness for encapsulation.

Revolutionizing solar water distillation: maximizing efficiency with pyramid solar stills enhanced by fins, evacuated tubes, nanomaterial, and phase change materials—a comprehensive review

Abstract The availability of water and energy is crucial for human survival, yet rising industrialization and population growth have escalated demand, particularly in developing economies. Despite efforts to address water scarcity, contamination persists, leading to widespread diseases. Conventional purification methods like reverse osmosis are effective but expensive and energy-intensive while boiling exacerbates air pollution. In this context, solar still systems present a promising solution, harnessing abundant sunlight to distill seawater into drinkable water. By integrating phase change material (PCM) and sensible heat storage, these systems can enhance efficiency and reduce energy consumption. This article explores the optimization of solar still systems through the selection of suitable PCM and sensible heat storage materials. The primary objectives are to improve distillation efficiency and heat recovery, making the process more eco-friendly and cost-effective. By addressing water scarcity and energy consumption simultaneously, these optimized systems offer a sustainable approach to water production, particularly in regions with ample sunlight. Through a comprehensive review, this research aims to advance the understanding of solar still technology and facilitate its widespread adoption, ultimately contributing to global efforts toward water security and environmental sustainability.

Evaluation of PCM thermophysical properties on a compressed air energy storage system integrated with packed-bed latent thermal energy storage

Compressed air energy storage (CAES) is a promising large-scale energy storage technology to mitigate the fluctuations and intermittence of renewable energies. The application of latent thermal energy storage (LTES) using phase change materials (PCM) to recover compressed waste heat can further improve the energy storage density and round-trip efficiency of CAES. However, there are very few guidelines of PCM selection for a CAES system. In view of the challenge, this study first conducts orthogonal experiments to analyze the effects of the thermophysical properties of PCMs on the performance of the packed-bed LTES and CAES system. Then a PCM selection procedure for CAES is developed based on the orthogonal experiment design and TOPSIS method. The results of range analysis indicate that each thermophysical property of PCM has quite different relative importance to the performance indicators of the CAES system. From the aspect of packed-bed LTES, the density (40.8 %) and latent heat (32.8 %) of PCMs are the top two impact factors for the heat storage rate, while the melting temperature (45.7 %) and thermal conductivity (22.4 %) are the top two impact factors for the residual heat. From the aspect of the CAES system, the density (31.9 %) and melting temperature (24.4 %) are the top two impact factors for the round-trip efficiency, while the density (42.2 %) and latent heat (35.2 %) rank the top two impact factors for the air storage capacity.

Hybrid (Optimal) Selection Model for Phase Change Materials Used in the Cold Energy Storage of Air Conditioning Systems

The latent heat storage of phase change materials (PCMs) can be used in refrigeration and air conditioning systems. Storing cool energy during the nighttime (off-peak hours) and releasing the cool energy during the daytime (on-peak hours) to reduce the number of starts of the chiller and pumps is a practical approach for achieving energy saving and carbon reduction. Therefore, selecting PCMs is vital for improving energy efficiency and preventing future energy shortages. However, selecting PCMs is complicated by their unique characteristics and types. The purpose of this study was to establish a PCM selection model by combining the Delphi, analytic hierarchy process (AHP), and VIseKriterijumska Optimizacija I Kompromisno Resenje (VIKOR) methods to select the optimal PCM type applied in cold storage. A numerical example was used to verify the model’s usability, confirming that A9 is the optimal PCM for the cold storage of an air conditioning system. This three-stage PCM selection model combining the Delphi, AHP, and VIKOR approaches provides a more suitable selection model and considers the selection method of material criteria. Moreover, it can solve the problem of difficult PCM selection. Simultaneously, it considers mechanisms to incorporate a company’s primary considerations into material selection for real-world applications. These results can facilitate material evaluation and selection during system design and material qualification, helping companies achieve the goals of energy saving, carbon reduction, and sustainable management in the future.

Selection and thermophysical assessment of phase change materials (PCMs) for space cooling applications in buildings

Phase change materials are gaining more attention in building comfort applications because of their latent heat thermal energy storage (TES) capacity. Identifying the best PCM candidate is a pivotal factor that significantly impacts the thermal performance of a building. This study delves into assessing prospective PCM candidates for potential utilization in cooling systems within buildings in hot subtropical climates. Extending the application of multicriteria decision-making (MCDM) methodologies, this research scrutinizes various commercial PCMs by conducting an exhaustive analysis of pertinent literature in the context of this specific application objective. Thermophysical properties are integrated into the MCDM framework to identify the most fitting candidates with optimal properties and attributes. The properties and attributes of PCMs are subjected to scoring and weighting through the AHP based on their significance in the given application context. TOPSIS and VIKOR techniques select the suitable PCM from the identified PCMs. The results showed that latent heat receives the highest weightage, amounting to 50.2%, due to its paramount importance. Furthermore, OM37 emerged as a promising choice for building space cooling, considering the prescreened temperature range of 30 °C–40 °C and for the specific location under consideration. Following PCM selection, thorough characterization was performed to evaluate the suitability of the chosen PCM for integration within building envelopes. The thermal conductivity of OM37 was determined to be 0.20 W/mK, while the morphology by a Field Emission Scanning Electron Microscope (Fe-SEM) intricate porous structure. Furthermore, a differential scanning calorimeter (DSC) suggests melting and solidification temperatures of 40 °C and 34 °C with a total enthalpy of 197.04 j/g, and a Thermogravimetry Differential Thermal Analysis (TG/DTA) showed a substantial weight loss of approximately 98.9% at around 247.3 °C. The presented experimental test results agree with the literature data and other researchers’ results.

Enhanced performance of photovoltaic thermal module and solar thermal flat plate collector connected in series through integration with phase change materials: A comparative study

The decline in photovoltaic cell efficiency due to temperature elevation, coupled with solar energy's inherent intermittency, presents challenges for solar systems, including photovoltaic panels and solar thermal (ST) collectors. The integration of phase change materials (PCMs) emerges as a promising solution to enhance thermal energy storage and regulation, thereby improving system performance and sustainability. This study investigates the performance of series-connected photovoltaic thermal (PVT) and ST systems with integrated PCMs from energy and exergy viewpoints, utilizing a 3D transient numerical simulation. The proposed system's performance is compared with that lacking a PCM across various heat transfer fluid mass flow rates. Suitable PCM selection based on melting temperature is explored, along with PCM layer thickness and nanoparticle augmentation. The research highlights that PCM integration effectively regulates PV cell temperature, enhancing electrical power and exergy rate. While increasing the mass flow rate improves thermal and electrical power, it reduces the thermal exergy rate. Comparing different PCMs (RT28 HC, RT35 HC, and RT44 HC), the RT28 HC PCM provides the lowest temperature of PV cells and the best electrical performance during the day. Moreover, increasing PCM layer thickness results in lowering PV cell and outlet temperatures and storing more heat. Nanoparticles added to PCMs lead to a marginal improvement in energy and exergy, especially for the system with RT28 HC. This analysis emphasizes PCM integration's role in enhancing solar thermal system performance, highlighting the importance of considering the PCM's melting temperature for effective thermal energy management.

Thermo Physical Properties Based Parametric Analysis To Help PCM Selection

Thermo Physical Properties Based Parametric Analysis To Help PCM Selection

Efficient energy generation and thermal storage in a photovoltaic thermal system partially covered by solar cells and integrated with organic phase change materials

To address the limitations of conventional photovoltaic thermal systems (i.e., low thermal power, thermal exergy, and heat transfer fluid outlet temperature), this study proposes a photovoltaic thermal system with a solar thermal collector enhancer (PVT-STE), incorporating phase change materials for simultaneous electricity and thermal power generation and thermal energy storage. The system consists of a water based solar collector with a partially covered absorber plate utilizing photovoltaic cells, while each component is equipped with a thermal storage enclosure filled with phase change materials. The primary objectives of this research encompass the evaluation of the proposed system's performance and the identification of appropriate phase change materials for each component. To gain comprehensive insight into the effects of employing and selecting appropriate phase change materials, the study investigates various configurations under both hot and cold weather conditions of Shanghai, China. Water serves as the heat transfer fluid under real-world operational conditions. The numerical results indicate that, for the given conditions, optimal phase change material selection entails using higher melting temperatures (e.g., RT42) in the STE component and lower melting temperatures (e.g., RT31) in the PVT component. Employing the optimal phase change materials for each component, the system can store 3234 and 1802 kJ/m2 of thermal energy during the charging process in July and November, respectively. Moreover, the proposed system generates almost 1.8 and 2 times more thermal energy per square meter in July and November, respectively, compared to a standalone photovoltaic thermal system coupled with a phase change material.

Performance analysis of a medium concentrated photovoltaic system thermally regulated by phase change material: Phase change material selection and comparative analysis for different climates

Thermal management of photovoltaic systems is important since their electrical output decreases with the increase in temperature. Thermal regulation of a photovoltaic system using a phase change material is an effective technique, but a careful selection of PCM in terms of its thermophysical properties is essential for its better performance. In this work, performance analysis of a novel medium concentrated photovoltaic system employing two mono-facial polycrystalline cells is carried out. The system is thermally regulated with a phase change material. An experimentally validated finite element-based coupled optical, thermal, and electrical model is used to analyze the system’s performance. The impact of the thermophysical properties of a PCM such as melting temperature, thermal conductivity, and heat of fusion on the thermal regulation of the system is studied using artificial neural networking methods. The optimum thermophysical properties of the PCM are determined using parametric analysis for the ambient temperatures ranging between 25 and 50 °C and a concentration ratio of 20×. Moreover, the performance of the system is analyzed using the optimum PCM for the semi-arid weather conditions of Lahore, Pakistan and the optimum PCM for oceanic weather conditions of Waterford, Ireland. It is found that the melting temperature, thermal conductivity, and heat of fusion of the PCM have a linearly indirect relationship with the temperature of the photovoltaic system while the ambient temperature has a linearly direct relationship with the photovoltaic system’s temperature. The melting temperature of a PCM should be 10–15 °C higher than the ambient temperatures up to the ambient temperature of 40 °C. The melting temperature of a PCM was found to be 5 – 10 °C higher than the ambient temperatures for ambient temperatures greater than 40 °C. The required thermal conductivity of a PCM increases with the increase in ambient temperature ranging from 10 to 12 Wm-1K−1 for the ambient temperature of 25 °C while 18–20 Wm-1K−1 for the ambient temperature of 50 °C. The suitable heat of fusion is found in the range of 210–220 kJkg−1. It is found that the optimum PCM for Lahore has melting temperature, thermal conductivity, and heat of fusion of 53–56 °C, 19 Wm-1K−1 and 220 kJkg−1 respectively. The optimum PCM for Waterford has melting temperature, thermal conductivity, and heat of fusion of 35–37 °C, 11 Wm-1K−1 and 220kJkg−1 respectively. The maximum temperature of concentrated photovoltaic cell for Lahore, Pakistan remains below 83 °C, while for Waterford, Ireland, it is below 59 °C for all the months in a year. From April to August, the output power is higher for Waterford with an average difference of 12%, while from September to March, Lahore has the higher power output with an average difference of 47%. The maximum power obtained for Lahore is 0.185kWh/day/m2, while for Ireland it is 0.213kWh/day/m2. A maximum deviation of 6% is found for electrical output and less than 3% for thermal output between simulated and experimental results during validation.

Novel indicators to evaluate PCM performance under different ventilation strategies by considering the impact of climate change

Due to climate change, the cooling energy demand in the building sector is projected to increase significantly. According to International Energy Agency, for a sustainable future, energy-efficient technology should be implemented in buildings. The potential of Phase change materials (PCM) for reducing building energy consumption has been widely acknowledged by researchers. However, the selection of appropriate PCM and its latent heat exploitation is crucial when PCM is integrated into the building envelope. This research evaluates the implementation of PCM for building cooling energy savings (CES) with climate change in thirty-nine cities located in 13 different zones of the future Koppen-Geiger climate map. Novel performance indicators, energy charging, and discharging coefficients are presented, to evaluate the PCM performance based on the exact latent heat exploitation. A range of PCMs (PCM 18–32) were assessed by coupling PCM with free night ventilation and changeover ventilation using the hybrid downscaled weather files for 2095. The results showed that the optimum PCM varied from PCM27 to PCM30 resulting in substantial CES (1214 kWh-7240 kWh) in all zones except Cfb, Dfa, and Dfb under the indoor HVAC controlled conditions. In natural ventilation conditions, combining PCM with free night ventilation increased CES up to 2490 kWh compared to night ventilation alone, while combining PCM with changeover ventilation, reduced energy consumption by up to 2772 kWh compared to changeover ventilation alone. Overall, free night ventilation with PCM improved the CES by up to a maximum of 35% while changeover ventilation in combination with PCM further increased the CES by up to 96% and appeared to be the best strategy for maximizing the CES in all climate zones.