Petroleum Generation Potential Research Articles

Conditions for Generation, Accumulation, and Preservation of Oil and Gas in Permian Strata, Northwestern Anabar–Khatanga Oil and Gas Region

Abstract ––Integrated seismic, drilling, and generalizing scientific research in the southeastern Anabar–Khatanga oil and gas region (OGR) since the early 1930s led to discoveries of small oil and gas occurrences and one large Central Olgino oil field. However, the petroleum potential of the northwestern part of the region remains poorly investigated and evaluated. To assess the prospects for the oil and gas potential of this territory, all seismic and geological and geochemical information was used, including four new wells drilled in the Sopochnoe uplift and the Zhuravliny swell. The scales of oil and gas formation, accumulation and destruction of hydrocarbon accumulations in the Permian deposits, which are the most promising in terms of the initial potential of the source rocks included in their composition, is given. The source rocks of the Upper Kozhevnikovo, Lower Kozhevnikovo, and Tustakh formations have been characterized in terms of thickness, contents of organic carbon and chloroform bitumen, maturity (catagenesis) of organic matter, and density of oil migration and gas generation. The maximum possible estimates of oil and gas resources that can potentially accumulate in structural traps, without migration losses, are obtained for each of the three reservoir formations by basin modeling. Judging by geological and geochemical criteria, the Upper Kozhevnikovo Formation can preserve only a minor portion of initially accumulated hydrocarbons, while the oil and gas accumulations, as well as the petroleum generation potential of organic matter in the Lower Kozhevnikovo and Tustakh formations, were destroyed by late Permian–Early Triassic trap magmatism and Mesozoic–Cenozoic tectonic activity.

Organic geochemical characteristics of the Late Cretaceous coal and carbonaceous shale succession from the Taranaki Basin, New Zealand: Implications for sedimentary environmental setting and petroleum generation potential

This comprehensive study investigates the organic matter characteristics within the Late Cretaceous Rakopi and Taniwha formations, based on data from four exploration wells situated in New Zealand's Taranaki Basin. It employs a multifaceted approach, integrating bulk geochemical analyses, biomarker measurements and carbon isotopes to unveil the geological history of these formations. Analytical results include total organic carbon content, ranging from 7.27 to 75.78 wt%, and generation potentials spanning from 28.24 to 309.16 mg hydrocarbon/g rock. These observations underscore the source rock potential of these Late Cretaceous strata. These rocks show a mixed organic matter of hydrogen‐rich Type II and Type II/III kerogens, as evidenced by hydrogen index values (HI) between 237 to 428 mg hydrocarbon/g rock. These formations demonstrate promise potential for both oil and gas generation. Biomarker analysis uncovers distinct signatures, featuring a pristane/phytane (Pr/Ph) ratio ranging from 3.27 to 10.91, a Tm/Ts ratio surpassing 7 and elevated concentrations of C29 regular steranes relative to C27 and C28 regular steranes. These biomarker characteristics suggest a composite organic matter composition, influenced by terrigenous organic matter, likely deposited in oxygenated fluvial deltaic environments. Bulk carbon isotopic data corroborate these findings, highlighting the abundance of terrigenous organic matter. Collectively, these insights reveal that the coal and carbonaceous shale intervals in the examined wells are in the early stages of oil generation. Therefore, the Rakopi and Taniwha formations have not yet yielded commercially viable oil and/or gas quantities. In this case, these formations hold substantial promise for future exploration activities in relatively deep wells, with limited oil expulsion from coals.

Organic richness and source rock potential of the La Peña Formation in the Sabinas and Piedras Negras basins, NE of Mexico

This paper investigates the petroleum generation potential of the Lower Cretaceous organic-rich rocks of the La Peña Formation in the Sabinas and Piedras Negras Basin (SB-PNB) of northeastern Mexico. In order to provide insights into the source rock potential of this unit, a total of 25 cutting samples collected from 15 wells at different stratigraphic intervals along the study area were analysed using Rock-Eval Pyrolysis technique. The analytical results revealed that all the analysed samples can be described as hydrogen-poor organic matter with HI <200 mg HC/g TOC. The organic richness indicates a poor to excellent Total Organic Carbon content suggesting that existed different conditions during the deposition and burial of this unit, causing variable organic matter production and preservation. Also, the results revealed a variation in the kerogen types that may be attributed to the relative stratigraphic positions of the selected samples in the wells.
 With respect to the organic matter thermal maturity, given by the geographical distribution of the Tmax values, the mature and overmature zone (435–508 °C) correspond to the Sabinas basin (SB).
 Overall, these results show a variability in the organic richness, thermal maturity and petroleum potential of the La Peña Formation, differentiating the values of the TOC content, petroleum potential and HI content for the samples from the Sabinas Basin and Piedras Negras Basin, respectively.

Investigation of Source and Reservoir Rock Petroleum Generative Potential of Early Eocene and Paleocene Sequences of the Punjab Platform Basin, Pakistan: A Geochemical and Petrophysical Approach

Abstract ––Investigating Early Eocene and Paleocene deposits within the Punjab Platform, Pakistan, involved comprehensive analysis using advanced geochemical and petrophysical techniques. This study evaluates the source potential of three formations: Nammal and Sakesar of Early Eocene age and Dungan and Ranikot of Palaeocene age. The Sakesar Formation, a reservoir rock, was evaluated through interpretation of wireline logs to estimate key petrophysical properties—porosity, water saturation, and hydrocarbon saturation. Geochemical investigations focused on total organic carbon content and Rock-Eval pyrolysis of twenty-one cutting samples from a well. These samples displayed TOC values ranging from 0.21 to 2.04 wt.% and S2 values ranging from 0.09 to 2.14 mg HC/g rock. Analysis positioned all samples within the immature window zone with Type II/III and Type III kerogen, suggesting limited generative potential. Findings suggest limited hydrocarbon generation from these formations. Petrophysical analysis indicated average porosity of 11.2%, water saturation of 32.58%, and hydrocarbon saturation of 67.42% for the Sakesar Formation, categorizing it as average to good reservoir potential. This study highlights complex geochemical and petrophysical characteristics of these formations. While Sakesar shows promising reservoir qualities, significant hydrocarbon generation potential from Nammal, Dungan, and Ranikot formations is constrained. Informed decision-making is crucial when considering these formations as hydrocarbon sources.

Maceral evolution of lacustrine shale and its effects on the development of organic pores during low mature to high mature stage: A case study from the Qingshankou Formation in northern Songliao Basin, northeast China

Organic matter (OM) hosted pores are crucial for the storage and migration of petroleum in shale reservoirs. Thermal maturity and macerals type are important factors controlling the development of pores therein. In this study, six lacustrine shale samples with different thermal maturities from the first member of the Qingshankou Formation in the Songliao Basin, of which vitrinite reflectance (Ro) ranging from 0.58% to 1.43%, were selected for a comparative analysis. Scanning electron microscopy (SEM) and reflected light microscopy were combined to investigate the development of organic pores in different macerals during thermal maturation. The results show that alginite and liptodetrinite are the dominant primary macerals, followed by bituminite. Only a few primary organic pores developed in the alginite at the lowest maturity (Ro = 0.58%). As a result of petroleum generation, oil-prone macerals began to transform to initial-oil solid bitumen at the early oil window (Ro = 0.73%) and shrinkage cracks were observed. Initial-oil solid bitumen cracked to oil, gas and post-oil bitumen by primary cracking (Ro = 0.98%). Moreover, solid bitumen (SB) was found to be the dominant OM when Ro > 0.98%, which indicates that SB is the product of oil-prone macerals transformation. Many secondary bubble pores were observed on SB, which formed by gas release, while devolatilization cracks developed on migrated SB. Additionally, at the late oil window (Ro = 1.16%), migrated SB filled the interparticle pore spaces. With further increase in temperature, the liquid oil underwent secondary cracking into pyrobitumen and gas, and spongy pores developed on the pyrobitumen at higher levels of maturity (Ro = 1.43%), which formed when pyrobitumen cracked into gas. Vitrinite and inertinite are stable without any visible pores over the range of maturities, verifying their low petroleum generation potential. In addition, it was concluded that clay minerals could have a catalytic effect on the petroleum generation, which may explain why organic-clay mixtures had more abundant pores than single OM particles. However, after Ro > 0.98%, authigenic minerals occupied the organic pore spaces on the organic-clay mixtures, resulting in fewer pores compared to those observed in samples at the early to peak oil window.

Integrated Interpretation of Eocene-Palaeocene Rocks in Potwar Basin, Pakistan: Implications for Petroleum Generation

This study demonstrates how an integrated geochemical and petrophysical analysis can be used to evaluate the petroleum generation potential of source and reservoir rocks. The Eocene and Palaeocene sequences of the Potwar Basin, located in the upper Indus Basin of Pakistan, were analyzed. Well logs and Schlumberger log interpretation charts were used for the petrophysical analysis of the Chorgali Formation's reservoir potential. Geochemical methods were applied to 34 well-cutting Sakesar and Patala formations samples. Results from Vitrinite Reflectance (VR) (%Ro) and Tmax data suggest that both formations have reached the peak of their oil generation window. The Sakesar Formation has a mean TOC of 1.88 wt. % and HI values of 375 mg HC/g TOC. The Patala Formation has a mean TOC of 3.33 wt.% in well A and HI values ranging from 2.4 to 369 mg HC/g TOC in well B, with a mean TOC of 3.52 wt%. Both formations have mixed Type II/III kerogen. The findings indicate that both the Sakesar and Patala formations possess good oil/gas-generation potential and may act as source rocks in the Potwar Basin. Petrophysical analysis of the Chorgali Formation shows an average porosity of 10.32%, water saturation of 36.14%, and hydrocarbon saturation of 63.85%. This indicates that the Chorgali Formation has an average to good reservoir potential. The research findings will aid exploration and production companies in the Fimkassar Oilfield.

Properties and Model of a Lacustrine Shale Oil Reservoir: A Case Study of the Upper Fourth Member and Lower Third Member of the Shahejie Formation in Dongying Sag and Zhanhua Sag, Jiyang Depression

By combining thermal simulation experiments with core data, thin sections, scanning electron microscopy (SEM), source rock, and high-pressure mercury and gas adsorption analysis, this paper evaluates the properties and models of shale reservoirs in the upper fourth member and the lower third member of the Shahejie Formation in Dongying Sag and Zhanhua Sag. The results show that the oil shale is a high-quality source rock with petroleum generation potential. Inorganic mineral pores, organic pores, and fractures have developed with petroleum storage capacity. Clay and organic-rich soft shale lithofacies are interbedded with carbonate-rich hard shale lithofacies to form sandwich-type source–reservoir–caprock assemblages with internal sealing properties. Bitumen occurs mostly in the free state, and to a lesser extent is adsorbed, and shows flow characteristics. The migration resistance of the bitumen is displacement pressure, including capillary force and adsorption resistance, and the main force is pore fluid pressure. The migration modes of the bitumen include both subcritical flow and instantaneous flow, which are controlled by pore fluid pressure, displacement pressure, and the rock’s fracture strength. Owing to the multi-scale characteristics of the shale reservoir space, a vein-type model of a multi-scale progressive transport network is developed that obeys Murray’s law with a dominant migration pathway in the shale reservoir. The shale oil reservoir is a special lithologic reservoir controlled by the sedimentary environment and has self-generation, self-storage, and self-sealing characteristics with developed pore fluid overpressure and a multi-scale transport network.

Differential hydrocarbon generation and evolution of typical terrestrial gas-prone source rocks: An example from the Kuqa foreland basin, NW China

Terrestrial gas-prone source rocks are significant for hydrocarbon gas accumulations especially in central and western basins in China. The Kuqa foreland basin in the northern margin of the Tarim Basin, NW China is rich in natural gas with recent discoveries of several large to giant gas-producing fields (e.g., the Kela-2, Dibei, Dabei-1, and Zhongqiu-1 gas fields, etc.) and a proven 3 P gas reserve of over one trillion cubic meters (TCM). This proliferous petroleum province is powered by an effective and diverse gas-prone source rock series in the basin comprising mudstone, carbonaceous mudstone, and coal seams. To date, little systematic research work has been done on the petroleum generation potential of the source rocks. This has seriously restricted the assessment of petroleum resources and further exploration in the frontier areas of the basin. A sealed gold tube pyrolysis approach was employed to simulate the oil and gas generation and cracking yields for the aforementioned three types of source rock. Compared with typical Type I and II1 kerogens, the three types of source rocks in the Kuqa foreland basin are characterized by (1) far less hydrocarbon yield (150 mg/g TOC) with comparatively larger amounts of CO2 (310 mg/g TOC), (2) a limited capacity and narrower window (0.5%–1.08% Ro) for oil generation, and (3) a much earlier secondary cracking for bulk oil to light oil and gases (>0.86% Ro for mudstone and >1.08% Ro for both carbonaceous mudstone and coal). All the source rocks are gas-prone, and significant amount of gas can still be generated during an over-mature stage. The kinetic parameters obtained allow us to model hydrocarbon generation in the Kuqa foreland basin more realistically. It is concluded that (1) two episodes of hydrocarbon generation occurred with hydrocarbon gases being mainly generated during the later stage (12–3 Ma); and (2) the depocenter of the basin is capable of supplying massive high-mature gases as late as in the Quaternary, which is crucial for the formation of giant gas fields. The findings provide new insight on the reconstruction of oil and gas accumulation processes and further hydrocarbon exploration in the basin.

The effects of Jurassic igneous intrusions on the generation and retention of gas shale in the Lower Permian source-reservoir shales of Karoo Basin, South Africa

Shale gas potential of the Whitehill Formation (Permian), Karoo Basin, South Africa is strongly influenced by widespread Jurassic igneous intrusions. A high-resolution organic petrographic and geochemical study is reported here on two stratigraphic sections, the objective being to gain insights into the chemical structure and alteration of oil-prone sedimentary organic matter during contact metamorphism. One section unaffected by intrusion served as background, while the other section was intruded by two laterally continuous dolerite sills with an average thickness of 10.7 and 9.3 m, preferentially emplaced at the upper and lower contacts of the formation, respectively. Heat flow from the sills caused TOC and S2 values from programmed pyrolysis to decline over a distance of 8.7 m from 3.2 to 0.15% and 4.65 to 0.11 mg HC/g TOC, respectively, and cause the reflectance of vitrinite and solid bitumen to increase from 2.03 to 5.82% and 1.58 to 7.87%.Organic matter in the background samples is dominated by solid bitumen, a secondary thermal conversion product of oil-generative Type II kerogen. In the sill-hosting section, the thermal aureoles can be recognized by systematic changes to the optical texture and chemical structure and composition of solid bitumen. Solid bitumen particles develop anisotropy approaching the sills and become transformed into coke and pyrolytic carbon. δ13Corg values become less negative by up to 3.13‰ VPDB. These data suggest significant devolatilization of organic matter to methane and destruction of petroleum generation and retention potential in the contact aureole of the sills. The trend of these datasets, coupled with the presence of several sills and their laterally extensive nature throughout much of the study area suggests that the intrusions have been significant in increasing methane generation on a basinal scale. Together, this study indicates that the complementary application of combined light and electron microscopy (CLEM), programmed pyrolysis, and isotope ratio mass spectrometry (IRMS) is suitable for a comprehensive characterization of organic matter alteration through the maturation continuum. Results also show that contact metamorphic alteration of organic matter by intrusions produced structural and compositional changes that are distinctive from those expected from geological burial maturation where graphite is the end-product.

Linking biomarkers with elemental geochemistry to reveal controls on organic richness in Devonian-Mississippian mudrocks of Oklahoma

Paleoproductivity and depositional redox conditions play critical roles in the development of organic-rich mudrocks. Devonian and Mississippian mudrocks within the central region of Oklahoma, USA were assessed for their depositional redox conditions, paleoproductivity and the effects of these factors on organic matter enrichment using a combination of elemental and organic geochemical proxies.A number of lithofacies with a shallowing upward trend have been defined within Devonian and Mississippian formations. Kerogens in the examined samples are dominantly type II, with organic richness in Mississippian samples exhibiting cyclic fluctuations, whereas organic richness in Woodford samples exhibits a downward-increasing trend. Mississippian sections contained at least three beds of organic-rich mudrocks, with total organic carbon (TOC) ranging from 2 to 6% by weight, indicating good petroleum generation potential. Elemental redox proxies, along with biomarker proxies of photic-zone euxinia, show a strong anoxic signature within the middle Woodford member, while the Mississippian section exhibits signatures consistent with suboxic depositional conditions. Paleoproductivity in the Mississippian section suggests a cyclic trend, with a higher paleoproductivity signature than that preserved in the Woodford Shale. Examined geochemical parameters highlight the different processes that are critical for organic matter enrichment and preservation. Mississippian mudrock organics appear to be enriched because of variations in paleoproductivity, while Woodford Shale organics are likely preserved due to changes in environmental redox conditions. Our findings reflect the variability observed within unconventional tight reservoirs of liquid hydrocarbons and the utility of combining organic and inorganic geochemical approaches in identifying productive sweet spots.

Geochemical Characteristics of the Chang 7 Source Rocks of the Triassic Yanchang Formation in Ordos Basin, China: Implications for Organic Matter Accumulation and Shale Oil Potential

The Chang 7 member of the Upper Triassic Yanchang Formation in the Ordos Basin is considered to hold the main source rocks for conventional and unconventional oil and gas. The lamination or lithology alteration in vertical and lateral directions, even over a short distance, is a common feature in lacustrine source rocks. The differences in the geochemical characteristics of black shales, dark mudstones and interbedded sandstones have been scarcely reported, and their influences on the petroleum generation potential and shale oil potential are not clear. To this end, 22 core samples were collected from the Lower and Middle Chang 7 (C7-3 and C7-2) members of the Triassic from well CYX in the Qingcheng area. By conducting a series of geochemical analyses including TOC, Rock-Eval pyrolysis yields, bitumen extraction and quantification, and the separation and quantification of saturates, aromatics, resins and asphaltenes, along with biomarker analyses, several results were found. Firstly, the C7-3 and C7-2 source rocks are thermally mature and have entered into the stage of hydrocarbon generation. The C7-3 and C7-2 source rocks have a good to very good hydrocarbon generation potential especially the C7-3 black shales. Secondly, terrigenous source input is more abundant in C7-2, whereas the source input of phytoplankton, algae or microbial lipids is more abundant in C7-3. Moreover, a high TOC content basically corresponds to low wax indexes, terrigenous/aquatic ratios (TARs), and Pr/nC17 and Ph/nC18 ratios and high C27/C29 regular sterane ratios, which suggests that the source input of phytoplankton, algae or microbial lipids is favorable for OM accumulation. Third, analyses of the molecular composition of saturated fractions in shales and interbedded sandstones and the production index demonstrate the migration of petroleum from organic-rich source rocks to their organic-lean counterparts. The C7-2 dark mudstones could be considered as a potential “sweet spot” since their oil saturation index (OSI) was the highest among all the studied samples and they are more enriched in light aliphatic fractions.

The Birkhead and Murta formations—organic geochemistry and organic petrography of Mesozoic fluvio-lacustrine source rocks in the Eromanga Basin, central Australia

Due to a historic focus on the underlying Cooper Basin and a growing demand for energy in Australia, a reassessment of the Eromanga Basin in central and eastern Australia is necessary, including a more detailed characterization of its Jurassic-Cretaceous petroleum system elements. The Jurassic Birkhead Formation and the Cretaceous Murta Formation are considered the most important source rocks of the Eromanga Basin. To study the petroleum generation potential of these two formations, a set of 55 rock cores from eight petroleum exploration wells was analysed. The sample set was subject to multiple-organic geochemical and petrographical analyses to evaluate organic richness, hydrocarbon potential (Rock–Eval S1 and S2), maceral composition, thermal maturity (e.g. vitrinite reflectance), and saturated and aromatic biomarker composition. The investigated fluvio-lacustrine siltstones and carbonaceous shales exhibit low to excellent total organic carbon (TOC) content, very low sulphur and low inorganic carbon content. Thermal maturity of both formations is at the onset of the oil window (immature to early mature). The Cretaceous Murta Formation shows good hydrocarbon generation potential and, in part, high production indices, while the Jurassic Birkhead Formation generally shows low kerogen to bitumen conversion and a good to very good hydrocarbon generation potential. Dispersed, rather coarse organic matter of terrigenous origin in fine-grained siliciclastic matrix with well-preserved plant remnants including “cutinite flames” is typical. Liptinite (mainly lamalginite) content is generally higher in the Murta Formation (including the occurrence of Botryococcus green algae), while vitrinite is clearly dominant in the Birkhead Formation. The Birkhead solvent extracts exhibit a more heterogeneous distribution of n-alkanes with distinct maxima in the long-chain range, whereas shorter-chain n-alkanes dominate the Murta extracts. Based on their quality and quantity of incorporated organic matter as well as thermal maturity, the petroleum generation potential of the Murta and Birkhead formations is discussed in detail.

Organic geochemistry and petrology of source rocks from the Banqiao Sag, Bohai Bay Basin, China: Implications for petroleum exploration

The organic geochemistry and petrology of source rocks determine the hydrocarbon generation potential of the Banqiao Sag. In this study, organic geochemistry and petrology were used to determine the abundance of organic matter (OM), OM type, OM maturity, and sedimentary environments of the source rocks, collected from Cenozoic Shahejie Formation, Banqiao Sag, Bohai Bay Basin, China. Vitrinite and liptinite are the main maceral composition of the source rocks, and range from 18% to 81% and from 2% to 82% on a mineral matter free (MMF) basis, respectively. The values of vitrinite reflectance ( R o ) (0.36%–1.20%) and the T max values (397–486 °C) show that the thermal maturity range from low mature to peak-maturity. The abundance of OM varies between 0.22% and 4.37%, suggesting that the source rocks of the Shahejie (Es) Formation are mainly fair to good source rocks. The Rock-Eval pyrolysis results show that the source rocks have good petroleum generation potential. The amount of free hydrocarbons ( S 1 ) and hydrocarbons generated from pyrolysis ( S 2 ) range within 0.01–3.70 mg/g, and 0.04–29.17 mg/g. The hydrogen index (HI) varies between 18.18 and 741.13 mg HC/g TOC, with most of the samples appearing to be mainly Type II kerogen, and thereby exhibiting the ability to generate both oil and gas. The ratios of Pr/Ph, the cross plot of Pr/nC 17 –Ph/nC 18 , the cross plot of C 29 /C 27 –Pr/Ph, and ternary of dibenzothiophene, dibenzofuran, and fluorene, indicate that the Shahejie Formation deposited in suboxic and weak reducing environments. The main biological source is from advanced plants. The maceral composition and rock pyrolysis data indicate the kerogen type is a humic type or mixed sapropelic-humic type. The source rocks of the Shahejie (Es) Formation occur in the oil window, and the abundant organic richness, humic kerogen demonstrate that these rocks are effective oil and gas source rocks. The mudstone rocks in the Shahejie Formation are the main source of oil and gas and represent the main exploration target for the Banqiao Sag. This study enhances the great prospect of oil and gas production in the Banqiao Sag.

Non-overmature equivalents confirmed a high initial hydrocarbon generation potential of the Permian Longtan Shale in southern China

This study presents the first organic and inorganic geochemical characterization of a non-over mature section of the Permian Longtan Shale as it can be found in the southwestern Guizhou Province, China. Compared to previous studies, the here analyzed interval lies in the oil window, which allows a more detailed and precise interpretation of the original kerogen quality, the depositional conditions as well as its initial petroleum generation potential. The chemical and mineralogical index of alteration consistently reveal a warm to hot and humid climate with moderate to strong weathering during the Late Permian. Terrigenous input contributes the main components of the Longtan Shale. The overall organic matter contents are high with an average total organic carbon (TOC) content of 5.9 wt%, and maximum values reaching up to 36.4 wt%. Organic matter is mainly comprised of type III with a small contribution of type II kerogen bearing an intense petroleum generation and expulsion potential based on petrographic and open-system pyrolytic analysis. Organic matter pores are clearly visible (20 to 200 nm) in these samples although they are less developed than in the gas window. Our results suggest that the Longtan Shale had a high initial hydrocarbon generation potential. High mud gas content in a vertical profile correlates with occurrence of organic-rich black shales, which suggests that shale gas exploration in the Longtan Formation should focus on sweet spots in or close to organic matter rich intervals.

Organic matter characteristics and conventional oil potentials of shales from the Early Jurassic Datta Formation in the Upper Indus Basin, Northern Pakistan

This study deals with organic matter in the Early Jurassic Datta shale in the Upper Indus Basin, Pakistan. Organic geochemical and microscopic techniques were used to investigate organic matter input, environmental conditions of deposition as well as petroleum generation potential. The geochemical results suggest that the shales display mainly fair to good source rock generation potential, with poor petroleum generation potential in some samples. The HI varies between 32 and 519 mg HC/g TOC, with many of the samples appearing to be mainly Type II and mixed Type II-III kerogen, and thereby exhibiting the ability to generate both oil and gas. The dominance of such Type II kerogen in some samples is consistent with the high HI values (>300 mg HC/ g TOC) and high fluorescence alginite macerals. A section of the shale within the Datta Formation appears to be gas-prone, with HI values of less than 200 mg HC/g TOC. Biomarkers also indicate the presence of mixed organic matter of planktonic/bacterial and land plant input, which were deposited in a marine environment under relatively oxic conditions. The biomarker characteristics of the extracted shales correlate well with those of the oil from the Chanda Oilfield, indicating that the Datta shales are likely to be the effective source rock. This is supported by the thermal maturity, which ranges from moderate to peak-maturity, as indicated by vitrinite reflectance values of 0.69–0.82%, and the biomarker maturity indicators.

Organic geochemistry, oil-source rock, and oil-oil correlation study in a major oilfield in the Middle East

In this study several major source rocks: Kazhdumi, Pabdeh, and Gurpi formations, along with crude oils from the Asmari and Bangestan reservoirs in the Gachsaran oilfield, southwestern Iran, were investigated from the organic geochemistry point of view. Results indicate that the Kazhdumi and Pabdeh formations have excellent generation potential and are mature and immature source rocks, respectively. In contrast, the Gurpi Formation has lower petroleum generation potential. The organic matter in the Kazhdumi and Pabdeh formations in the neighboring synclines within the Gachsaran oilfield is in the late and peak oil generation stages, respectively. SARA composition by Liquid Chromatography performed on four crude oils produced from these source rocks suggest a paraffinic-naphthenic composition. The source rocks had carbonate and shale lithology. Distinct biomarkers point to an open marine environment characterized by marine kerogen Type II and mixed Types II/III deposited under anoxic-suboxic depositional conditions, although. The presence of relatively high amounts of oleanane in the oils points to contribution from a terrigenous source. Based on biomarkers, the four oils exhibit similar thermal maturity, which is equivalent to the primary stage of oil generation. The star diagrams of various normal alkanes and biomarker ratios show that the four crude oil have high similarities, which suggests a single source origin. Nonetheless, utilizing different ML methods of K-means Clustering, Fuzzy C-means clustering (FCM), Comptlayar Neural Network, Construction of agglomerative clusters, and the obtained dendrogram all suggest that there are two oil families in the Gachsaran oil field. Furthermore, geochemical parameters including specific biomarkers denote the contribution of the Kazhdumi and Pabdeh formations in the Gachsaran oil field whereby charges of mixed origins at different reservoir horizons of Asmari and Bangestan can be identified. Ultimately, two scenarios for the presence of oleanane in Bangestan reservoir are envisaged: 1) connectivity of the Asmari and Bangestan reservoirs as a result of natural fracturing, and 2) emplacement of the Pabdeh Formation near the vicinity of the Bangestan reservoir as a result of thrust faulting. Overall, this study demonstrated that integration of data analytics (ML) methods with conventional geochemical techniques can precisely delineate the correlation between the generated oil and the source rocks. • Geochemical analysis performed on two rarely studied major source rocks in Middle East: kazhdumi and Pabdeh Formations. • Several machine learning (ML) algorithms were implemented to identify existing oil families from these two source rocks. • These two oil families were also confirmed by detection of the Oleanane biomarker in separated oil groups.

Upper Jurassic to Lower Cretaceous source rocks in the Norwegian Barents Sea, part II: Insights from open- and closed-system pyrolysis experiments

The petroleum generation potential of Upper Jurassic to Lower Cretaceous organic rich shales from the southwestern Barents Sea was evaluated using bulk and quantitative pyrolysis analysis. Fifteen thermally-immature samples from the Hekkingen Formation with differing organic facies, as defined by maceral composition, were subjected to total organic carbon, Rock-Eval pyrolysis, pyrolysis gas chromatography, bulk kinetics, and micro-scale sealed vessel pyrolysis analyses. The results were employed to characterize differences in source rock kerogens, gross petroleum type, and the compositional evolution of the generated fluids as well as their physical properties (i.e. gas to oil ratio, saturation pressure, and formation volume factor) as a function of increasing maturity.The investigated samples contain varying proportions of kerogen type II and III. Heterogeneities in the kerogen composition result in different orders of thermal stability, with the onset of petroleum generation predicted to occur over a high and broad temperature range from 123 °C to 144 °C (at 3.3C⁰/Ma). Reduced kerogen stability associated with elevated sulfur contents is only documented in a few samples. Most of the analyzed samples have the potential to generate low GOR oils of an intermediate to aromatic, low wax paraffinic-naphthenic-aromatic (P–N-A) composition and variable amounts of wet gas. Petroleums of similar compositional and physical properties are predicted to have been generated from the natural maturation sequence of various organic facies in thermally mature areas of the Hammerfest Basin and the Ringvassøy-Loppa High and Bjørnøyrenna fault complexes. Vitrinite-rich sources in the Fingerdjupet Sub-basin and the Troms-Finnmark Fault Complex have potential for gas and condensate generation.

PETROLEUM GEOCHEMISTRY OF OILS FROM MYANMAR – A PRELIMINARY ASSESSMENT

Myanmar has a long history of petroleum production, but little information has so far been published pertaining to the detailed composition of the country's oils. The present paper reports the results of the analysis of a total of 28 Cenozoic oil samples collected from producing fields/wells or natural seepages in the onshore Salin and Chindwin Basins of the Central Myanmar Depression and from Ramree Island in the Rakhine Coastal Belt. In addition, a set of 68 mudstones and coals from four Oligocene – Paleocene formations were collected along the western margin of the Central Myanmar Depression and were analysed for petroleum generation potential. Data on five oil samples from the Assam Province of India, situated to the north of the Central Myanmar Depression, were also included in the study for comparison purposes.Previous studies have suggested that the Eocene succession in the Central Myanmar Depression includes organic‐rich source rocks. However, none of the analysed rock samples show any potential for the generation of appreciable amounts of liquid petroleum components. The samples were collected at the basin margin and only cover a small fraction of the succession, and they are probably not therefore representative of the actual source rocks present in deeply buried kitchen areas in the Central Myanmar Depression.The oils from the Central Myanmar Depression appear to have been generated from the same overall source type, which is dominated by terrigenous, higher land‐plant –derived kerogen. Several different parameters consistently show clear north–south trends in the Salin Basin with respect to both thermal maturity and source facies. Oils from the Chindwin Basin in the north of the depression can be distinguished from those of the Salin Basin further south using subtle variations in biomarkers. The oils collected from Ramree Island represent a different basin and are easily distinguished in that they are generated from a predominantly marine source rock, albeit one with a significant terrigenous input. However, one sample from Ramree Island was generated from a predominantly terrigenous source, which may suggest the existence of two viable petroleum systems in the Rakhine Coastal Belt or of marked facies variations within the source succession.Oils from the Central Myanmar Depression and the Assam Province of India are remarkably similar, thus suggesting generation from highly similar source rock types, presumably of Eocene age. This could be a result of these two areas being physically connected during the Eocene as suggested by modern plate reconstructions.

Kerogen composition and origin, oil and gas generation potential of the Berriasian Wealden Shales of the Lower Saxony Basin

This study evaluates the organofacies and petroleum generation potential of kerogen of Early Cretaceous Wealden Shales in the Lower Saxony Basin, Germany. Methods applied include open-system-and Curie-point-pyrolysis, attenuated total reflectance infrared spectroscopy, x-ray diffraction and x-ray fluorescence spectroscopy. The geochemical results give a comprehensive elemental characterization of the Wealden source rocks and indicate an anoxic to oxygen-depleted lacustrine depositional setting in a rather warm climate. The kerogen composition is characterized by high abundance of aliphatic compounds with many alkylated low molecular weight oxygen-bearing compounds, but only a minor aromatic contribution. Differences between organic matter-rich lamalginite facies A and Botryococcus-bearing, less organic matter-rich facies B occur. For both facies, the total hydrocarbon generation potential (Rock-Eval HI) of facies A is higher than that of facies B. TOC-normalized cumulative hydrocarbon gas yields generated during pyrolysis-GC are similar for both facies and account for only 8–16% of the total hydrocarbon generation potential. In contrast, the cumulative yield of molecular hydrogen generated during open-system pyrolysis of facies B is twice as high than for facies A. Overall Wealden Shales generate 55 mg HC per g rock on average, they generate roughly 6 mg H2 per g TOC. Although these H2 yields are rather low compared to other organic-rich rocks or coals with aromatic kerogen structures, this study shows that detecting H2 during open-system-pyrolysis is important for the understanding of kerogen transformation processes during pyrolysis in both natural and laboratory settings.

Upper Jurassic–Lower Cretaceous Source Rocks in the North of Western Siberia: Comprehensive Geochemical Characterization and Reconstruction of Paleo-Sedimentation Conditions

The present work is devoted to geochemical studies of the Bazhenov Formation in the north of the West Siberian Petroleum Basin. The object is the Upper Jurassic–Lower Cretaceous section, characterized by significant variations in total organic carbon content and petroleum generation potential of organic matter at the beginning of the oil window. The manuscript presents the integration of isotopic and geochemical analyses aimed at the evaluation of the genesis of the rocks in the peripheral part of the Bazhenov Sea and reconstruction of paleoenvironments that controlled the accumulation of organic matter in sediments, its composition and diagenetic alterations. According to the obtained data, the sediments were accumulated under marine conditions with a generally moderate and periodically increasing terrigenous influx. The variations in organic matter composition are determined by redox conditions and terrigenous input which correlate with the eustatic sea level changes during transgressive/regressive cycles and activation of currents. Transgression is associated with an intensive accumulation of organic matter under anoxic to euxinic conditions and insignificant influence of terrigenous sources, resulting in the formation of rocks with oil-generating properties. During the regression periods, the terrigenous sedimentation increased along with the dissolved oxygen concentration, and deposits with low organic matter content and gas-generating properties were formed.